Decommissioning the the 250MW Prototype Fast Breeder Reactor (PFR) at Dounreay is the heart of the site restoration programme, but the reactor presents particular problems. In liquid-metal cooled fast breeder reactors (LMFBRs) the primary and secondary coolants are highly reactive alkali metals (sodium and potassium, NaK). The alkali metals react very strongly with water and in the presence of air liquid sodium can ignite, so it must first be converted to a stable chemical product that is then safely converted into effluent streams for final treatment. In 1995 UKAEA awarded NNC the contract to design, build, and commission a sodium disposal plant. The £17m process removes the sodium from the reactor vessel and other vessels at a rate of 2.5t per day and reacts in a special vessel with sodium hydroxide. The resulting solution is neutralised with hydrochloric acid to produce a saline solution, which is processed to remove the caesium content. The next problem is to deal with the residues, which is discussed in this paper.
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