Linear Tail Research Articles

Ballooning instability‐induced plasmoid formation in near‐Earth plasma sheet

The formation of plasmoids in the near‐Earth magnetotail is believed to be a key element of the substorm onset process. Previous work has identified a new scenario in MHD simulations where the nonlinear evolution of a ballooning instability is able to induce the formation of plasmoids in a generalized Harris sheet with finite normal magnetic component. In present work, we further examine this novel mechanism for plasmoid formation and explore its implications in the context of substorm onset trigger problem. For that purpose, we adopt the generalized Harris sheet as a model proxy to the near‐Earth region of magnetotail during the substorm growth phase. In this region the magnetic component normal to the neutral sheet Bn is weak but nonzero. The magnetic field lines are closed, and there are no Xlines. Simulation results indicate that in the higher Lundquist number regime , the linear axial tail mode, which is also known as “two‐dimensional resistive tearing mode,” is stabilized by the finite Bn, hence cannot give rise to the formation of X lines or plasmoids by itself. On the other hand, the linear ballooning mode is unstable in the same region and regime, and its nonlinear development leads to the formation of a series of plasmoid structures in the near‐Earth and middle magnetotail regions of plasma sheet. This new scenario of plasmoid formation suggests a critical role of ballooning instability in the near‐Earth plasma sheet in triggering the onset of a substorm expansion.

Tails of plane wave spacetimes: Wave-wave scattering in general relativity

One of the most important characteristics of light in flat spacetime is that it satisfies Huygens' principle: Initial data for the vacuum Maxwell equations evolves sharply along null (and not timelike) geodesics. In flat spacetime, there are no tails which linger behind expanding wavefronts. Tails generically do exist, however, if the background spacetime is curved. The only non-flat vacuum geometries where electromagnetic fields satisfy Huygens' principle are known to be those associated with gravitational plane waves. This paper investigates whether perturbations to the plane wave geometry itself also propagate without tails. First-order perturbations to all locally-constructed curvature scalars are indeed found to satisfy Huygens' principles. Despite this, gravitational tails do exist. Locally, they can only perturb one plane wave spacetime into another plane wave spacetime. A weak localized beam of gravitational radiation passing through an arbitrarily-strong plane wave therefore leaves behind only a slight perturbation to the waveform of the background plane wave. The planar symmetry of that wave cannot be disturbed by any linear tail. These results are obtained by first deriving the retarded Green function for Lorenz-gauge metric perturbations and then analyzing its consequences for generic initial-value problems.

RADIO DETECTION OF A CANDIDATE NEUTRON STAR ASSOCIATED WITH GALACTIC CENTER SUPERNOVA REMNANT SAGITTARIUS A EAST

We report the VLA detection of the radio counterpart of the X-ray object referred to as the "Cannonball", which has been proposed to be the remnant neutron star resulting from the creation of the Galactic Center supernova remnant, Sagittarius A East. The radio object was detected both in our new VLA image from observations in 2012 at 5.5 GHz and in archival VLA images from observations in 1987 at 4.75 GHz and in the period from 1990 to 2002 at 8.31 GHz. The radio morphology of this object is characterized as a compact, partially resolved point source located at the northern tip of a radio "tongue" similar to the X-ray structure observed by Chandra. Behind the Cannonball, a radio counterpart to the X-ray plume is observed. This object consists of a broad radio plume with a size of 30\arcsec$\times$15\arcsec, followed by a linear tail having a length of 30\arcsec. The compact head and broad plume sources appear to have relatively flat spectra ($\propto\nu^\alpha$) with mean values of $\alpha=-0.44\pm0.08$ and $-0.10\pm0.02$, respectively; and the linear tail shows a steep spectrum with the mean value of $-1.94\pm0.05$. The total radio luminosity integrated from these components is $\sim8\times10^{33}$ erg s$^{-1}$, while the emission from the head and tongue amounts for only $\sim1.5\times10^{31}$ erg s$^{-1}$. Based on the images obtained from the two epochs' observations at 5 GHz, we infer the proper motion of the object: $\mu_\alpha = 0.001 \pm0.003$ arcsec yr$^{-1}$ and $\mu_\delta = 0.013 \pm0.003$ arcsec yr$^{-1}$. With an implied velocity of 500 km s$^{-1}$, a plausible model can be constructed in which a runaway neutron star surrounded by a pulsar wind nebula was created in the event that produced Sgr A East. The inferred age of this object, assuming that its origin coincides with the center of Sgr A East, is approximately 9000 years.

Comets as solar probes

By rapidly evaporating as they fly through the Sun’s hot outer atmosphere, sungrazing comets reveal an otherwise invisible magnetic field that shapes the very beginnings of the solar wind.

Structure of 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide Ionic Liquids with Linear, Branched, and Cyclic Alkyl Groups

X-ray scattering and molecular dynamics simulations have been carried out to investigate structural differences and similarities in the condensed phase between pyrrolidinium-based ionic liquids paired with the bis(trifluoromethylsulfonyl)amide (NTf2(-)) anion where the cationic tail is linear, branched, or cyclic. This is important in light of the charge and polarity type alternations that have recently been shown to be present in the case of liquids with cations of moderately long linear tails. For this study, we have chosen to use the 1-alkyl-1-methylpyrrolidinium, Pyrr(1,n(+)) with n = 5 or 7, as systems with linear tails, 1-(2-ethylhexyl)-1-methylpyrrolidinium, Pyrr(1,EtHx(+)), as a system with a branched tail, and 1-(cyclohexylmethyl)-1-methylpyrrolidinium, Pyrr(1,ChxMe(+)), as a system with a cyclic tail. We put these results into context by comparing these data with recently published results for the Pyrr(1,n(+))/NTf2(-) ionic liquids with n = 4, 6, 8, and 10.1,2 General methods for interpreting the structure function S(q) in terms of q-dependent natural partitionings are described. This allows for an in-depth analysis of the scattering data based on molecular dynamics (MD) trajectories that highlight the effect of modifying the cationic tail.

On the Design of Zinc‐Finger Models with Cyclic Peptides Bearing a Linear Tail

Cyclic peptides with a linear tail (CPLT) have been successfully used to model two zinc fingers (ZFs) adopting the treble-clef- and loosened zinc-ribbon folds. In this article, we examine the factors that may influence the design of such ZF models: mutations in the sequence, size of the cycle, and size of the tail. For this purpose, several peptides derived from the CPLT-based models of the treble-clef- and loosened zinc-ribbon ZF were synthesized and studied. CPLT-based models appear to be robust toward mutations, accommodate various cycle sizes, and are sensible to the size of the linking region of the tail located between the cycle and the coordinating amino acids. Based on these criteria, we describe the design of a new CPLT-based model for the zinc-ribbon ZFs, LZR , and compare it to a linear analogue, LZR(lin) . The model complex Zn⋅LZR is able to fold correctly around the metal ion contrary to Zn⋅LZR(lin) , suggesting that CPLT-based models are more likely to yield structurally meaningful models of ZF sites than linear peptide models. Finally, we draw some rules that could allow the design of new CPLT-based metallopeptides with a controlled fold.

Nature of axial tail instability and bubble‐blob formation in near‐Earth plasma sheet

ABSTRACTPrevious global magnetohydrodynamic (MHD) simulations of substorm events have identified the dynamic presence of an axial tail instability that is uniform in the dawn‐dusk direction in the near‐Earth plasma sheet. The axial tail instability is found to be a major cause of the initial growing MHD force imbalance on closed field lines prior to the subsequent magnetic reconnection and substorm expansion onset processes. In this work, energy principle analysis indicates that a two‐dimensional thin current sheet configuration in the magnetotail is typically stable to the axial mode within the framework of ideal MHD model. However, linear resistive MHD calculations find axial tail instabilities on closed field lines in the generalized Harris sheet configurations. The properties of these instabilities are similar to the axial tail modes observed in the global MHD simulations. The axial tail mode is unstable in regimes of low Lundquist number and regions with small normal component of magnetic field. Such resistive axial tail instability would by many researchers be considered as tearing instability in a two‐dimensional tail configuration. Unlike the conventional tearing mode of Harris sheet, the linear axial tail instability does not involve any reconnection process. Instead, the nature of the mode is dominantly a slippage process among neighboring flux tubes as facilitated by resistive dissipation. A natural consequence of the axial tail instability is shown to be the formation of bubble‐blob pairs in the pressure and entropy profiles in the near‐Earth plasma sheet.

Exploring the nature of new main-belt comets with the 10.4 m GTC telescope: (300163) 2006 VW139

We aim to study the dust ejected by main-belt comet (MBC) (300163) 2006 VW139 to obtain information on the ejection mechanism and the spectral properties of the object, to see if they are compatible with those of "normal" comets. Images in the g and r band and a low-resolution spectrum in the 0.35-0.9 micron region were obtained with the GTC telescope (La Palma, Spain). Images were analyzed to produce a color map and derive a lower limit of the absolute magnitude. A Monte Carlo (MC) scattering model was used to derive dust properties such as mass loss rates and ejection velocities as a function of time. The spectrum was compared to that of MBC 133P/Elst-Pizarro and used to search for CN emission. The spectrum of 2006 VW139 is typical of a C-class asteroid, with a spectral slope S=0.5+/-1.0%/1000A. It is similar to the spectrum of 133P and other MBCs. No CN emission is detected. A CN production rate upper limit of 3.76e23 1/s is derived. The MBC present a narrow almost linear tail that extends up to 40.000 km in the anti-solar direction and more than 80.000 km in the direction of the object's orbital plane. The color of the tail is slightly redder than the Sun (S=3 to 6%/1000A). The MC dust tail model derived the mass loss rates and ejection velocity as a function of time, and the results show that the activity onset occurs shortly after perihelion, and lasts about 100 days; the total ejected mass is about 2e6 kg. The spectrum of VW139 suggests that it is not a "normal" comet. It is typical of the other observed MBCs. Even if no CN emission is detected, the more likely activation mechanism is water-ice sublimation. Like other well studied MBCs, VW139 is likely a primitive C-class asteroid that has a water-ice subsurface depth reservoir that has recently been exposed to sunlight or to temperatures that produce enough heat to sublime the ice.

Precise Synthesis and Characterization of Tadpole-Shaped Polystyrenes with High Purity

Tadpole-shaped polystyrenes (PS) were successfully synthesized anionically by coupling reaction between ring polystyrene with two functional groups and living linear polystyrenes. Crude coupling product was confirmed to include unreacted linear tail polymer and tadpole polymer having one tail (single-tail tadpole polymer) and two tails (twin-tail tadpole polymer) by SEC analysis. In order to isolate the tadpole polymers, interaction chromatography (IC) was conducted to remove the linear polymer from the crude product; subsequently, two kinds of tadpole polymers were carefully separated by SEC fractionation. It has been found by SEC-MALS that the absolute molecular weights of the two fractionated products agree well with the sums of the component ring and linear chains, which prove two tadpole polymers, i.e., single-tail and twin-tail, were obtained as designed. It was confirmed that the two tadpole polymers have high molecular weight (58k for ring and 67k for a tail), narrow molecular weight distribution (Mw/Mn = 1.01), and high purity over 99% by rigorous HPLC analyses.

Relationship between local molecular field theory and density functional theory for non-uniform liquids

The local molecular field theory (LMF) developed by Weeks and co-workers has proved successful for treating the structure and thermodynamics of a variety of non-uniform liquids. By reformulating LMF in terms of one-body direct correlation functions we recast the theory in the framework of classical density functional theory (DFT). We show that the general LMF equation for the effective reference potential φ(R)(r) follows directly from the standard mean-field DFT treatment of attractive interatomic forces. Using an accurate (fundamental measures) DFT for the non-uniform hard-sphere reference fluid we determine φ(R)(r) for a hard-core Yukawa liquid adsorbed at a planar hard wall. In the approach to bulk liquid-gas coexistence we find the effective potentials exhibit rich structure that can include damped oscillations at large distances from the wall as well as the repulsive hump near the wall required to generate the low density "gas" layer characteristic of complete drying. We argue that it would be difficult to obtain the same level of detail from other (non-DFT based) implementations of LMF. LMF emphasizes the importance of making an intelligent division of the interatomic pair potential of the full system into a reference part and a remainder that can be treated in mean-field approximation. We investigate different divisions for an exactly solvable one-dimensional model where the pair potential has a hard-core plus a linear attractive tail. Results for the structure factor and the equation of state of the uniform fluid show that including a significant portion of the attraction in the reference system can be much more accurate than treating the full attractive tail in mean-field approximation. We discuss further aspects of the relationship between LMF and DFT.

A cyclic peptide-based redox-active model of rubredoxin

A model of rubredoxin based on a cyclic peptide with a linear tail is presented. This model reproduces almost perfectly the fold, the spectroscopic characterizations and the redox activity of rubredoxins.

Double Smectic Self-Assembly in Block Copolypeptide Complexes

We show double smectic-like self-assemblies in the solid state involving alternating layers of different polypeptide α-helices. We employed rod-coil poly(γ-benzyl l-glutamate)-block-poly(l-lysine) (PBLG-b-PLL) as the polymeric scaffold, where the PLL amino residues were ionically complexed to di-n-butyl phosphate (diC4P), di(2-ethylhexyl) phosphate (diC2/6P), di(2-octyldodecyl) phosphate (diC8/12P), or di-n-dodecyl phosphate (diC12P), forming PBLG-b-PLL(diC4P), PBLG-b-PLL(diC2/6P), PBLG-b-PLL(diC8/12P), and PBLG-b-PLL(diC12P) complexes, respectively. The complexes contain PBLG α-helices of fixed diameter and PLL-surfactant complexes adopting either α-helices of tunable diameters or β-sheets. For PBLG-b-PLL(diC4P), that is, using a surfactant with short n-butyl tails, both blocks were α-helical, of roughly equal diameter and thus with minor packing frustrations, leading to alternating PBLG and PLL(diC4P) smectic layers of approximately perpendicular alignment of both types of α-helices. Surfactants with longer and branched alkyl tails lead to an increased diameter of the PLL-surfactant α-helices. Smectic alternating PBLG and PLL(diC2/6P) layers involve larger packing frustration, which leads to poor overall order and suggests an arrangement of tilted PBLG α-helices. In PBLG-b-PLL(diC8/12P), the PLL(diC8/12P) α-helices are even larger and the overall structure is poor. Using a surfactant with two linear n-dodecyl tails leads to well-ordered β-sheet domains of PLL(diC12P), consisting of alternating PLL and alkyl chain layers. This dominates the whole assembly, and at the block copolypeptide length scale, the PBLG α-helices do not show internal order and have poor organization. Packing frustration becomes an important aspect to design block copolypeptide assemblies, even if frustration could be relieved by conformational imperfections. The results suggest pathways to control hierarchical liquid-crystalline assemblies by competing interactions and by controlling molecular packing frustrations.

Molecular discriminators using single wall carbon nanotubes

The interaction between single wall carbon nanotubes (SWNTs) and amphiphilic molecules has been studied in a solid phase. SWNTs are allowed to interact with different amphiphilic probes (e.g. lipids) in a narrow capillary interface. Contact between strong hydrophobic and amphiphilic interfaces leads to a molecular restructuring of the lipids at the interface. The geometry of the diffusion front and the rate and the extent of diffusion of the interface are dependent on the structure of the lipid at the interface. Lecithin having a linear tail showed greater mobility of the interface as compared to a branched tail lipid like dipalmitoyl phosphatidylcholine, indicating the hydrophobic interaction between single wall carbon nanotube core and the hydrophobic tail of the lipid. Solid phase interactions between SWNT and lipids can thus become a very simple but efficient means of discriminating amphiphilic molecules in general and lipids in particular.

Synthesis of amphiphilic tadpole‐shaped copolymers by combination of glaser coupling with living anionic polymerization and ring‐opening polymerization

AbstractThe tadpole‐shaped copolymers polystyrene (PS)‐b‐[cyclic poly(ethylene oxide) (PEO)] [PS‐b‐(c‐PEO)] contained linear tail chains of PS and cyclic head chains of PEO were synthesized by combination of Glaser coupling with living anionic polymerization (LAP) and ring‐opening polymerization (ROP). First, the functionalized polystyrene‐glycerol (PS‐Gly) with two active hydroxyl groups at ω end was synthesized by LAP of St and the subsequent capping with 1‐ethoxyethyl glycidyl ether and then deprotection of protected hydroxyl group in acid condition. Then, using PS‐Gly as macroinitiator, the ROP of EO was performed using diphenylmethylpotassium as cocatalyst for AB2 star‐shaped copolymers PS‐b‐(PEO‐OH)2, and the alkyne group was introduced onto PEO arm end for PS‐b‐(PEO‐Alkyne)2. Finally, the intramolecular cyclization was performed by Glaser coupling reaction in pyridine/Cu(I)Br/N,N,N′,N″,N″‐pentamethyldiethylenetriamine system under room temperature, and tadpole‐shaped PS‐b‐(c‐PEO) was formed. The target copolymers and their intermediates were well characterized by size‐exclusion chromatography, proton nuclear magnetic resonance spectroscopy, and fourier transform infrared spectroscopy in details. The thermal properties was also determined and compared to investigate the influence of architecture on properties. The results showed that tadpole‐shaped copolymers had lower Tm, Tc, and Xc than that of their precursors of AB2 star‐shaped copolymers. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012

Imaging Features of Superficial and Deep Fibromatoses in the Adult Population

The fibromatoses are a group of benign fibroblastic proliferations that vary from benign to intermediate in biological behavior. This article will discuss imaging characteristics and patient demographics of the adult type superficial (fascial) and deep (musculoaponeurotic) fibromatoses. The imaging appearance of these lesions can be characteristic (particularly when using magnetic resonance imaging). Palmar fibromatosis demonstrates multiple nodular or band-like soft tissue masses arising from the proximal palmar aponeurosis and extending along the subcutaneous tissues of the finger in parallel to the flexor tendons. T1 and T2-weighted signal intensity can vary from low (higher collagen) to intermediate (higher cellularity), similar to the other fibromatoses. Plantar fibromatosis manifests as superficial lesions along the deep plantar aponeurosis, which typically blend with the adjacent plantar musculature. Linear tails of extension (“fascial tail sign”) along the aponeurosis are frequent. Extraabdominal and abdominal wall fibromatosis often appear as a heterogeneous lesion with low signal intensity bands on all pulse sequences and linear fascial extensions (“fascial tail” sign) with MR imaging. Mesenteric fibromatosis usually demonstrates a soft tissue density on CT with radiating strands projecting into the adjacent mesenteric fat. When imaging is combined with patient demographics, a diagnosis can frequently be obtained.

Polyglycerol‐Derived Amphiphiles for the Solubilization of Single‐Walled Carbon Nanotubes in Water: A Structure–Property Study

A series of nonionic amphiphiles derived from polyglycerol dendrons were studied for their ability to solubilize and isolate single-walled carbon nanotubes. The amphiphiles possessed differently sized polar head groups, hydrophobic tail units, and various aromatic and non-aromatic groups between the head and tail groups. Absorbance analysis revealed that amphiphiles with anchor groups derived from pyrene were far inferior to those that possessed simple linear aliphatic tail groups. Absorbance and near-infrared fluorescence analyses revealed a weak dependence on the dendron size of the head group, but a strong positive trend in suspended nanotube density and fluorescence intensity for amphiphiles with longer tail units. Variations in the moieties linking the head and tail groups led to a range of effects on the suspensions, with linkers imparting flexibility and a bent shape that gave improved performance overall. This was illustrated most dramatically by a pair of benzamide-containing amphiphiles, the para isomer of which showed evidence in the fluorescence data of increased nanotube aggregate formation when compared with the meta isomer. In addition, statistical AFM was used to illustrate more directly the microscopic differences between amphiphiles that were effective at nanotube bundle disruption and those that were not.

OBSERVATIONAL EVIDENCE FOR AN IMPACT ON THE MAIN-BELT ASTEROID (596) SCHEILA

An unexpected outburst was observed around (596) Scheila in 2010 December. We observed (596) Scheila soon after the impact using ground-based telescopes. We succeeded in the detection of a faint linear tail after 2011 February, which provides a clue to determine the dust ejection date. It is found that the dust particles ranging from 0.1-1 ?m to 100 ?m were ejected into the interplanetary space impulsively on December 3.5 ?1.0 day. The ejecta mass was estimated to be (1.5-4.9)?108?kg, suggesting that an equivalent mass of a 500-800?m diameter crater was excavated by the event. We also found that the shape of the light curve changed after the impact event probably because fresh material was excavated around the impact site. We conclude that a decameter-sized asteroid collided with (596) Scheila only eight days before the discovery.

Bicephalic amphiphile architecture affects antibacterial activity

A series of cationic amphiphiles, each with an aromatic core, was prepared and investigated for antimicrobial properties. The synthesized amphiphiles in this study are bicephalic (double-headed) in that they each possess two trimethylammonium head groups and a single linear alkoxy tail. Minimum inhibitory and minimum bactericidal concentrations of these amphiphiles were in the low micromolar range. Antimicrobial activities are highly sensitive to the chain length of the hydrophobic region, and modestly reliant on the relative positioning of the head groups on the aromatic core. These trends were more pronounced in time kill assays, wherein longer chain compounds required significantly shorter times to completely kill bacteria. Microscopy suggested that the mode of cell death was lysis. Strong inhibition was observed with both biscationic compounds and monocationic comparisons against Gram-positive bacteria; only biscationic amphiphiles maintained good activity versus the Gram-negative bacteria tested. These observations provide direction for future antimicrobial structural investigations.

An investigation of phenylthiazole antiflaviviral agents

Flaviviruses are one of the most clinically important pathogens and their infection rates are increasing steadily. The phenylthiazole ring system has provided a template for the design and synthesis of antiviral agents that inhibit the flaviviruses by targeting their E-protein. Unfortunately, there is a correlation between phenylthiazole antiflaviviral activity and the presence of the reactive and therefore potentially toxic mono- or dibromomethyl moieties at thiazole-C4. Adding a linear hydrophobic tail para to the phenyl ring led to a new class of phenylthiazole antiflaviviral compounds that lack the toxic dibromomethyl moiety. This led to development of a drug-like phenylthiazole 12 that had high antiflaviviral selectivity (TI = 147).

Investigation of optical and compositional properties of thin SiN x:H films with an enhanced growth rate by high frequency PECVD method

Hydrogenated thin silicon nitride (SiN x:H) films were deposited by high frequency plasma enhanced chemical vapor deposition techniques at various NH 3 and SiH 4 gas flow ratios [R = NH 3/(SiH 4 + NH 3)], where the flow rate of NH 3 was varied by keeping the constant flow (150 sccm) of SiH 4. The deposition rate of the films was found to be 7.1, 7.3, 9 and 11 Å/s for the variation of R as 0.5, 0.67, 0.75 and 0.83, respectively. The films were optically and compositionally characterized by reflectance, photoluminescence, infrared absorption and X-ray photoelectron spectroscopy. The films were amorphous in nature and the refractive indices of the films were varied between 2.46 and 1.90 by changing the gas flow ratio during the deposition. The PL peak energy was increased and the linear band tails become broad with the increase in R. The incorporation of nitrogen takes place with the increase in R.