Linewidth Variation Research Articles

Ca2+/Mg2+ co-substituted strontium nanohexaferrites: magnetic investigation and Mossbauer analysis

We report a comprehensive evaluation of the microstructures, magnetic, and hyperfine traits of Ca2+/Mg2+ co-substituted strontium nanohexaferrites (SHFs) of chemical compositions Sr1–2xCaxMgxFe12O19 (x ≤ 0.1). These SHFs were prepared using sol–gel unified auto-combustion strategy and characterized by diverse analytical measurements to determine the effects of Ca2+/Mg2+ co-substitution on the aforesaid properties. XRD and high resolution transmission electron microscpe (HRTEM) analyses confirmed the nucleation of HF nanocrystallites. UV-visible diffuse reflectance (DR–UV–Vis) spectra were used to evaluate the optical band gap of the proposed SHFs, which was reduced with the increase in co-substitution contents. The 57Fe Mossbauer spectra was exploited to assess the quadrupole splitting, spectral line-width variation, isomer shift, distribution of cations (Ca2+ and Mg2+), and hyperfine magnetic fields. Measured magnetic parameters such as saturation magnetization, remanence, squareness ratio (SQR), coercivity, and magnetic moment were significantly improved due to the Ca2+/Mg2+ co-substitution. All the prepared SHFs revealed ferrimagnetic nature both at 10 and 300 K. Achieved SQR values ≈0.5 of the studied SHFs clearly disclosed their single domain character possessing uniaxial anisotropy.

Use of beam-shaping optics for wafer-scaled nanopatterning in laser interference lithography

Laser interference lithography is a widely used technology for large-area patterning of surfaces on the micro- and nanoscale. It is mostly used for research purposes due to the limited area that can be uniformly patterned due to the Gaussian intensity profile of the laser. In the scope of this work, the lithography system was extended by a freeform refractive glass which provided a spatially uniform energy distribution for a homogenous structuring process. The energy variation of the introduced light was reduced to 2.6% for the exposed area (4 × 9 cm), which is one magnitude lower than the energy variation of a Gaussian beam. With the refractive beam shaper, it was possible to produce a uniform nanopattern with an absolute linewidth variation of 7 nm over an area of 4 × 9 cm2. The structurable area is limited by the mirror size of the Lloyd’s mirror device. The demonstrated LIL system was also able to generate variable light fields from Gaussian to flat-top as well as inverse Gaussian profiles. This paper demonstrates nanopatterning of negative resist with a square homogenous output profile of the beam shaper. The square shape of the beam profile gives the opportunity to efficiently structure substrates with a square shape. Apart from standard silicon-based photolithographic processes, this technique is also attractive for nanopatterning of organic light-emitting diodes on glass or graduated grid structures like polarizers. Consequently, the advantages of the LIL fabrication (high-throughput and low-cost fabrication) are extended by the opportunity to scale the single-exposure process to large areas with only small variations in the detail.

Anomalous variations of spectral linewidth in internal excitonic quantum transitions of ultrafast resonantly excited single-walled carbon nanotubes

How the exciton fine structure and spectral linewidth in single-walled carbon nanotubes (SWNTs) evolve after ultrafast photoexcitation is critical for both understanding the fundamental optoelectronic properties and the development of nanophotonic functional devices. Yet, studies so far have mostly detected a subset of excitons near the Brillouin-zone center due to symmetry and momentum restrictions of the interband optical probes used, such as photoluminescence and absorption. Here we use ultrafast terahertz spectroscopy to probe the excitonic spectral linewidth associated with internal quantum transition across the entire momentum $K$ space in resonantly excited semiconducting SWNTs. The lowest-lying intraexcitonic transition surprisingly sharpens at both high pump fluence and initial times immediately following the photoexcitation. We attribute these anomalous variations in the spectral linewidth to the role of the dark state $1s(g)$ that influences the lifetime broadening of the bright state $1s(u)$, consistent with the temperature-dependent dephasing time with a crossover temperature set by the internal quantum level spacing of excitons.

Relationship between the line width of the atomic and molecular ISM in M33

ABSTRACT We investigate how the spectral properties of atomic (H i) and molecular (H2) gas, traced by CO(2−1) , are related in M33 on 80 pc scales. We find the H i and CO(2−1) velocity at peak intensity to be highly correlated, consistent with previous studies. By stacking spectra aligned to the velocity of H i peak intensity, we find that the CO line width (σHWHM = 4.6 ± 0.9 ${\rm km\, s^{-1}}$ ; σHWHM is the effective Gaussian width) is consistently smaller than the H i line width (σHWHM = 6.6 ± 0.1 ${\rm km\, s^{-1}}$), with a ratio of ∼0.7, in agreement with Druard et al. The ratio of the line widths remains less than unity when the data are smoothed to a coarser spatial resolution. In other nearby galaxies, this line width ratio is close to unity which has been used as evidence for a thick, diffuse molecular disc that is distinct from the thin molecular disc dominated by molecular clouds. The smaller line width ratio found here suggests that M33 has a marginal thick molecular disc. From modelling individual lines of sight, we recover a strong correlation between H i and CO line widths when only the H i located closest to the CO component is considered. The median line width ratio of the line-of-sight line widths is 0.56 ± 0.01. There is substantial scatter in the H i –CO(2−1) line width relation, larger than the uncertainties, that results from regional variations on <500 pc scales, and there is no significant trend in the line widths, or their ratios, with galactocentric radius. These regional line width variations may be a useful probe of changes in the local cloud environment or the evolutionary state of molecular clouds.

AC susceptibility and hyperfine interactions of Mg-Ca ions co-substituted BaFe12O19 nanohexaferrites

Magnesium and calcium co-substituted Ba M-type nanohexaferrite (NHFs) is fabricated via sol-gel auto-combustion technique. The phase formation was proved by XRD powder pattern, FESEM and HR-TEM. Magnetic properties of Ba1-2xCaxMgxFe12O19 (x ≤ 0.1) NHFs investigated by Mossbauer Spectroscopy. The variations in line width, quadrupole splitting, isomer shift, the cation distribution of Ca2+ and Mg2+ ions and hyperfine magnetic field values were estimated. The AC magnetic susceptibility and ZFC-FC measurements were also performed for the Ba1-2xCaxMgxFe12O19(x = 0.02 and 0.08) NHFs. The MFC-MZFC results do not show blocking temperature peak, indicating the ferrimagnetic (FM) behavior of prepared products. Different models including Neel-Arhenius (N-A), Vogel-Fulcher (V-F) and critical slowing down (CSD) were tested to evaluate the AC-magnetic susceptibility behaviors. It is demonstrated that the magnetic interactions are important for x = 0.02 NHFs.

XRD, EDX, FTIR and ESR spectroscopic studies of co-precipitated Mn–substituted Zn–ferrite nanoparticles

Co-precipitation synthesizing technique was adopted to prepare manganese doped zinc ferrite nanoparticles with varying concentrations 0.5, 0.6, 0.7. EDX proved the consistency of stoichiometry of compositions in the ferrite samples considered under preparation. XRD patterns authenticated the ferrite phase in the investigating samples. The experimental lattice parameter (8.412–8.438 Å) is increasing and crystallite size (7.6–6.4 nm) appears to be decreasing with substitution of Mn2+. The grain size (1.1 µm) in the sample (x = 0.7) with smaller crystallites (6.4 nm) is found to be bigger than that of remaining compositions (x = 0.5, 0.6). The vibrational frequencies detected in the FTIR spectra also authorized the obtained spinel phase in the current ferrite systems. The elastic moduli illustrate the mechanical strength of ferrite systems which are dependent on interatomic distances. The variation of line width and Lande's g–factor in ESR studies revealed the possibility of core-shell morphology of present ferrite nanoparticles.

Comparing the main oscillation characteristics in the solar chromosphere and magnetosphere based on studies made in ISTP SB RAS

The aim of this paper is to structure and extend the knowledge of solar chromospheric sources of oscillations in the solar wind and their relationships with pulsations registered in the magnetosphere. We compare the oscillation spectra that we observe using instruments of the Institute of Solar-Terrestrial Physics in different chromospheric structures with those observed in the solar wind and magnetosphere. We explore the possibility that the observed periodic variations of the chromospheric line widths can be interpreted as torsional Alfvén wave manifestation—this mode can propagate long distances without dissipating in the interplanetary space; it can penetrate into Earth’s magnetosphere directly or due to processes occurring at the plasmapause. We emphasize the similarities in the oscillation characteristics observed in different media, the similarities in the parameters of the media themselves and the processes developing in them. We believe that similar approaches can be applied to studying these media.

Сравнение основных характеристик колебаний хромосферы Солнца и магнитосферы по исследованиям, выполненным в ИСЗФ СО РАН

The aim of this paper is to structure and extend the knowledge of solar chromospheric sources of oscillations in the solar wind and their relationships with pulsations registered in the magnetosphere. We compare the oscillation spectra that we observe using instruments of the Institute of Solar-Terrestrial Physics in different chromospheric structures with those observed in the solar wind and magnetosphere. We explore the possibility that the observed periodic variations of the chromospheric line widths can be interpreted as torsional Alfvén wave manifestation—this mode can propagate long distances without dissipating in the interplanetary space; it can penetrate into Earth’s magnetosphere directly or due to processes occurring at the plasmapause. We emphasize the similarities in the oscillation characteristics observed in different media, the similarities in the parameters of the media themselves and the processes developing in them. We believe that similar approaches can be applied to studying these media.

Control of magnetization dynamics by spin-Nernst torque

Control of magnetization dynamics is one of the primary goals in spintronics. It has been demonstrated using spin Hall effect i.e charge current to spin current conversion in non-magnetic metal which has large spin-orbit coupling such as Pt, W etc. Recently different groups have shown generation of spin current in Pt, W while thermal gradient is created by virtue of spin Nernst effect. In this work we show the evidence of magnetization control by spin Nernst torque in Pt/Py bi-layer. We compared relative strength of spin Nernst Torque and spin Hall torque by measuring the systematic variation of magnetic linewidth on application of constant heat or charge current. Spin-torque ferromagnetic resonance (ST-FMR) technique is adopted to excite the magnet and to measure line-width precisely from the symmetric and anti-symmetric voltage component. Control of magnetization dynamics by spin Nernst torque will emerge as an alternative way to manipulate nano-magnets.

Spatially resolved spectroscopy across stellar surfaces

Context. Spectroscopy across spatially resolved stellar surfaces reveals spectral line profiles free from rotational broadening, whose gradual changes from disk center toward the stellar limb reflect an atmospheric fine structure that is possible to model by 3D hydrodynamics. Aims. Previous studies of photospheric spectral lines across stellar disks exist for the Sun and HD 209458 (G0 V) and are now extended to the planet-hosting HD 189733A to sample a cooler K-type star and explore the future potential of the method. Methods. During exoplanet transit, stellar surface portions successively become hidden and differential spectroscopy between various transit phases uncovers spectra of small surface segments temporarily hidden behind the planet. The method was elaborated in Paper I, in which observable signatures were predicted quantitatively from hydrodynamic simulations. Results. From observations of HD 189733A with the ESO HARPS spectrometer at λ/Δλ~ 115 000, profiles for stronger and weaker Fe I lines are retrieved at several center-to-limb positions, reaching adequate S/N after averaging over numerous similar lines. Conclusions. Retrieved line profile widths and depths are compared to synthetic ones from models with parameters bracketing those of the target star and are found to be consistent with 3D simulations. Center-to-limb changes strongly depend on the surface granulation structure and much greater line-width variation is predicted in hotter F-type stars with vigorous granulation than in cooler K-types. Such parameters, obtained from fits to full line profiles, are realistic to retrieve for brighter planet-hosting stars, while their hydrodynamic modeling offers previously unexplored diagnostics for stellar atmospheric fine structure and 3D line formation. Precise modeling may be required in searches for Earth-analog exoplanets around K-type stars, whose more tranquil surface granulation and lower ensuing microvariability may enable such detections.

Cobalt substituted nickel ferrites via Pechini’s sol–gel citrate route: X-band electromagnetic characterization

Cobalt substituted nickel spinel ferrites were synthesized in the form of Ni1-xCoxFe2O4(x=0-1,Δx=0.15) via Pechini’s sol–gel citrate method with final sintering at 1000 °C for 6 h. Structural purity of the prepared ferrites is examined by using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Thermo-gravimetric and differential thermal analysis (TG-DTA) show that the formation of spinel phase is completed upto 700 °C. Lattice constant, cationic distribution and cationic site parameters are estimated from XRD data. For the first time, lattice parameter (a) is determined using four different methods and quite similar values are obtained in those. Characteristic peaks of nickel ferrites are observed in the Raman spectrum of each ferrite composition. Grain size (80–95 nm) is observed to be higher than crystallite size (26.2–31.8 nm) due to agglomeration of grains. Mössbauer spectra recorded at 300 K temperature show the presence of iron in only +3 valency. Variations of isomer shift, hyperfine field, quadrupole splitting and line width are analyzed with the amount of doped cobalt. This paper also presents the electromagnetic and shielding properties of these Ni–Co ferrites in X-band (8.2–12.4 GHz) frequency range using vector network analyzer (VNA). The analysis of shielding effectiveness shows that increasing the amount of cobalt in nickel ferrites results in increase in shielding efficiency of the ferrites which proves the utility of this specific doping.

Microstructural, Optical, and Magnetic Properties of Vanadium-Substituted Nickel Spinel Nanoferrites

The current study investigates the impact of vanadium substitution on the structural, magnetic, and optical properties of NiFe2−xVxO4 (x ≤ 0.3) nanoparticles (NPs) produced by the cost-effective sol-gel route. The as-prepared spinel ceramic powders were examined by X-ray diffraction (XRD), UV-visible diffuse reflectance spectroscopy (DRS), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM). The functional groups, spinel phase, and crystal structure were confirmed by XRD and FT-IR, respectively. The crystallites size decreased from 45.24 to 36.56 nm as the doping process increases. The plots of Tauc were drawn to determine optical band gap magnitudes of 1.291, 1.302, and 1.312 eV for x = 0.0, 0.2, and 0.3, respectively. The estimated saturation magnetization is maximum for pristine NiFe2O4 NPs and decreases to minimum for NiFe1.7V0.3O4 NPs. The σ-H hysteresis loops have finite coercivity (between 125 and 169 Oe) and retentivity (between 9.36 and 14.04 emu/g) values. The calculated σr/σs ratios are lower than 0.500, assigning the uniaxial anisotropy for NiFe2−xVxO4. The effective anisotropy constants (Keff) are in the range of 0.824 × 105 and 1.303 × 105 Erg/g. The magnetocrystalline anisotropy field (Ha) values are around 5.0 kOe. The characteristics of hysteresis (σ-H) curves and the order of magnetic data reveal the soft ferrimagnetic feature of as-prepared nanoparticle samples. From Mossbauer analysis, the variations in hyperfine magnetic field, quadrupole splitting, line width, and isomer shift have been evaluated. The distribution of cations showed that the octahedral B sites are occupied by all the ions of V3+. Mossbauer spectra are composed of four Zeeman sextets and one doublet.

Structural, magneto-static and magneto-dynamic properties of Fe substituted Ni-Mn-In films

Off-stoichiometric Ni-Mn-In films of 500 nm thickness were deposited on Si (100) substrate by dc magnetron sputtering at ambient temperature. As-deposited films were annealed ex situ at 550 °C and 700 °C for 1 h under high vacuum. As-deposited Ni-Mn-In films which were amorphous, exhibited orthorhombic martensite structure upon annealing. The amorphous film was found to be paramagnetic whereas the annealed (martensite) film exhibited weak ferromagnetic behavior. Fe substituted Ni-Mn-In films of the same thickness annealed at 550 °C exhibited orthorhombic martensite structure, whereas films annealed at 700 °C exhibited dual phase (cubic L21 austenite and orthorhombic martensite) structure. Martensite Ni-Mn-Fe-In films showed large magnetic moment as compared to the ternary alloy film. Interestingly, films with dual phase structure yielded much higher magnetic moment. Ni-Mn-Fe-In films with higher thicknesses annealed at 700 °C showed enhanced magnetic moment due to higher L21 phase content in them. Analysis of polar angle variation of resonance field and linewidth of the dual phase Ni-Mn-Fe-In films revealed very low effective perpendicular magnetic anisotropy (3.0 × 103 J/m3) and low Gilbert damping constant (0.009 ± 0.001) for the first time. The new results obtained are interpreted in terms of the crystalline nature of the films.

Dependence of magnetic and microwave loss on evolving microstructure in yttrium iron garnet

The parallel magnetic and microwave loss dependence on microstructural evolutions in several polycrystalline yttrium iron garnet samples were studied in detail, focusing on the attendant occurrence of their relationships. In this study, polycrystalline YIG samples were synthesized by employing the mechanical alloying technique and sintering toroidal compacts at temperatures from 600 to 1400 °C. The samples were characterized for their evolution in crystalline phases, structure, microstructure, magnetic hysteresis parameters, microwave losses and electrical resistivity. The results showed an increasing tendency of the saturation magnetization with grain size, which is attributed to crystallinity increase in the grains. The M–H hysteresis loop results showed a transition from disordered-to-ordered magnetism which belongs to different magnetically dominant stages of formation. The starting appearance of room temperature ferromagnetic order suggested by the sigmoid-shaped loops seems to be dependent on crystallinity, phase purity and a sufficient number of large enough magnetic domain-containing grains having been formed in the microstructure. An increasing trend of transmission loss with grain size may be attributed to increment of loss contribution from hysteresis and domain wall resonance of the samples. The changes in crystallinity and microstructure, and the associated processes of microwave resonance and relaxation due to domain wall movements and damping of spin rotation contributes to the variations in transmission loss and ferromagnetic linewidth of the samples. The increased electrical resistivity while the microstructure was evolving is believed to strongly indicates improved phase purity and compositional stoichiometry.

AC susceptibility and Mossbauer study of Ce3+ ion substituted SrFe12O19 nanohexaferrites

Ce3+ ion substituted SrFe12O19, SrFe12-xCexO19 (0.0 ≤ x ≤ 0.5), nanohexaferrites were fabricated by citrate sol-gel combustion approach. X–ray diffractometry (XRD), Scanning electron microscopy (SEM), Energy dispersive spectroscope (EDX), EDX Elemental mapping, Fourier transform infrared spectroscopy (FT-IR) were used to study the structure and morphology of the samples. AC magnetic susceptibility and 57Fe Mossbauer spectroscopy have been operated to examine the hyperfine structure, static and dynamic magnetic properties. The values of variations in line width, quadrupole splitting, hyperfine magnetic field, and isomer shift have been estimated. The impact of Ce-ion substitution on AC magnetic susceptibility properties of Sr-hexaferrite were explored. The AC-susceptibility measurements reveal the frequency dependence of the magnetic responses, indicating strong magnetic interactions among the nanoparticles of the various products. In addition, it is determined that the magnetic interaction between the nanoparticles is weakened in the substituted products, due to the substitution of Fe3+ ions by Ce3+ ions.

Coexistence of spin-lattice and spin-spin relaxation mechanism in perovskite manganite (La0.5Pr0.5)0.67Ca0.33MnO3

Electron paramagnetic resonance (EPR) was applied extensively to probe the phase separation and spin relaxation mechanism in the perovskite manganites. In this study, we conducted the measurement of EPR for the perovskite manganites (La0.5Pr0.5)0.67Ca0.33MnO3. We found that both paramagnetic and ferromagnetic resonance peaks simultaneously emerged on resonance spectrum near below TC, exhibiting a typical characteristic of phase separation. The linewidth of EPR spectrum progressively enlarged upon the rising of temperature in the temperature range of T>TC and a quasilinear variation of peak-peak width was observed at TC<T<500 K. In contrast to the usual beliefs that the variation of peak-peak linewidth can be understood either by spin-lattice relaxation or by spin-spin relaxation, however, the linewidth behavior observed here shows a coexistence of two spin relaxation mechanisms. We proposed that the inhomogeneous electronic phases due to the intrinsic self-organizing growth were responsible for the appearance of multiple spin exchange interactions and variational relaxation mechanism. This finding would be possible to pave a new way for further investigating magnetic correlations and spin dynamics in the paramagnetic hole-doped manganites.

Monitoring local redox processes in LiNi0.5Mn1.5O4 battery cathode material by in operando EPR spectroscopy.

Despite the multitude of analytical methods available to characterize battery cathode materials, identifying the factors responsible for material aging is still challenging. We present the first investigation of transient redox processes in a spinel cathode during electrochemical cycling of a lithium ion battery by in operando electron paramagnetic resonance (EPR). The battery contains a LiNi0.5Mn1.5O4 (LNMO) spinel cathode, which is a material whose magnetic interactions are well understood. The evolution of the EPR signal in combination with electrochemical measurements shows the impact of Mn3+ on the Li+ motion inside the spinel. Moreover, state of charge dependent linewidth variations confirm the formation of a solid solution for slow cycling, which is taken over by mixed models of solid solution and two-phase formation for fast cycling due to kinetic restrictions and overpotentials. Long-term measurements for 480 h showed the stability of the investigated LNMO, but also small amounts of cathode degradation products became visible. The results point out how local, exchange mediated magnetic interactions in cathode materials are linked with battery performance and can be used for material characterization.

Spectrum radial velocity analyser (SERVAL)

Context.The CARMENES survey is a high-precision radial velocity (RV) programme that aims to detect Earth-like planets orbiting low-mass stars.Aims.We develop least-squares fitting algorithms to derive the RVs and additional spectral diagnostics implemented in the SpEctrum Radial Velocity AnaLyser (SERVAL), a publicly available python code.Methods.We measured the RVs using high signal-to-noise templates created by coadding all available spectra of each star. We define the chromatic index as the RV gradient as a function of wavelength with the RVs measured in the echelle orders. Additionally, we computed the differential line width by correlating the fit residuals with the second derivative of the template to track variations in the stellar line width.Results.Using HARPS data, our SERVAL code achieves a RV precision at the level of 1 m/s. Applying the chromatic index to CARMENES data of the active star YZ CMi, we identify apparent RV variations induced by stellar activity. The differential line width is found to be an alternative indicator to the commonly used full width half maximum.Conclusions.We find that at the red optical wavelengths (700–900 nm) obtained by the visual channel of CARMENES, the chromatic index is an excellent tool to investigate stellar active regions and to identify and perhaps even correct for activity-induced RV variations.

Accretion-driven turbulence in filaments – I. Non-gravitational accretion

We study accretion driven turbulence for different inflow velocities in star forming filaments using the code ramses. Filaments are rarely isolated objects and their gravitational potential will lead to radially dominated accretion. In the non-gravitational case, accretion by itself can already provoke non-isotropic, radially dominated turbulent motions responsible for the complex structure and non-thermal line widths observed in filaments. We find that there is a direct linear relation between the absolute value of the total density weighted velocity dispersion and the infall velocity. The turbulent velocity dispersion in the filaments is independent of sound speed or any net flow along the filament. We show that the density weighted velocity dispersion acts as an additional pressure term supporting the filament in hydrostatic equilibrium. Comparing to observations, we find that the projected non-thermal line width variation is generally subsonic independent of inflow velocity.

Magneto-optical properties of BaCryFe12−yO19 (0.0 ≤ y ≤ 1.0) hexaferrites

In this study, nanocrystalline BaCryFe12−yO19 (0.0 ≤ y ≤ 1.0) hexaferrite powders were prepared by sol–gel auto combustion method and the effect of Cr3+ ion substitution on morphology, structure, optic and magnetic properties of Barium hexaferrite were investigated. X-ray powder diffraction (XRD) analyses confirmed the purity of all samples. The XRD data shows that the average crystallite size lies between 60.95 nm and 50.10 nm and same was confirmed by Transmission electron microscopy. Transmission electron and scanning electron microscopy analyses presented the hexagonal morphology of all products. The characteristic hysteresis (σ-H) curves proved the ferromagnetic feature of as grown nanoparticle samples. Specific saturation magnetization (σs) drops from 46.59 to 34.89 emu/g with increasing Cr content while the coercive field values lie between 770 and 1652 Oe. The large magnitude of the magnetocrystalline (intrinsic) anisotropy field, (Ha) between 11.0 and 12.6 kOe proves that all products are magnetically hard. The energy band gap values decrease from 2.0 eV to 1.84 eV with increasing Cr content. From 57Fe Mössbauer spectroscopy, the variation in line width, isomer shift, quadrupole splitting and hyperfine magnetic field values were determined and discussed.