Intensity Of Light Source Research Articles

Photoisomerization Dynamics of 2-[(E)-(4-fluorophenyl)diazenyl]-1H-imidazole: A Theoretical and Experimental Insight

This study investigates the photoresponsive behavior of substituted azobenzenes with a specific focus on their nonlinear optical response. This study suggests that azoimidazole substitution is a better alternative to azobenzene derivatives for nonlinear optical responses. The synthesis, characterization, photophysical property and isomerization pathway of 2-[(E)-(4-fluorophenyl)diazenyl]-1H-imidazole (E-2g) are presented as an optical limiter through a comprehensive blend of experimental and theoretical approaches. Notably, E-2g exhibited a lower energy barrier than reported azobenzenes. The trans-to-cis photostationary state was reached in 75 min, while the cis-to-trans state was achieved in 60 min at 354 nm. The study further explores the photoisomerization pathway of E-2g, highlighting its nonlinear absorption, which has a nonlinear absorption coefficient ([Formula: see text]) of 8.8 × 10–11 m/W at 20 [Formula: see text]J, as determined by Z-scan measurements. The results suggest that E-2g exhibits significant nonlinear absorption characteristics, which helps in applications requiring protection from intense light sources.

Field experimental mode-pairing quantum key distribution with intensity fluctuations.

The mode-pairing quantum key distribution (MP-QKD) protocol, which can achieve high key rates over long distances without phase locking, is a potential candidate for implementing intercity QKD. However, achieving precise control of the light source intensity in a field MP-QKD experiment is an exceedingly challenging task. In this Letter, we study the decoy-state MP-QKD protocol with light source intensity fluctuations. Furthermore, we propose a statistical analysis method based on the T-distribution to calculate confidence intervals of intensity fluctuations. Finally, in the field MP-QKD experiments, considering intensity fluctuations and the finite size effect, we obtain secure key rates of 1.03 × 10-6 bit/pair and 3.64 × 10-6 bit/pair for the symmetric (195.8 km) and asymmetric (127.7 km) cases, respectively.

Molecular Imprinting Strategy Enables Circularly Polarized Luminescence Enhancement of Recyclable Chiral Polymer Films

AbstractCircularly polarized luminescence (CPL) plays a crucial role in the fields of optical display and information technology. The pursuit of high dissymmetry factors (glum) and fluorescence quantum yields in CPL materials remains challenging due to inherent trade‐offs. In this work, molecular imprinting technology is employed to develop novel CPL‐active polymer films based entirely on achiral fluorene‐based polymers, achieving an enhanced glum value exceeding 4.2 × 10−2 alongside high quantum yields. These chiral molecularly imprinted polymer films (MIPF) are synthesized via a systematic three‐step process: co‐assembly with limonene and a porphyrin derivative (TBPP), interchain crosslinking, and subsequent removal of small molecules. During this process, limonene acts as the chiral inducer, while TBPP serves dual roles as both the chiral enhancer and imprinted molecule. The elimination of TBPP creates chiral sites for various fluorescent molecules, facilitating full‐color CPL emission. The chiral MIPF exhibits stable CPL performance even after multiple cycles of post‐assembly and removal. Furthermore, these films can function as interfacial microreactors, enabling in situ chemical reactions that dynamically regulate CPL signals. Additionally, chiral self‐organization within achiral azobenzene polymer films can also be achieved using MIPF, serving as intense chiral light sources.

Estimation of nighttime PM2.5 concentrations over Seoul using Suomi NPP/VIIRS Day/Night Band

With rapid economic development and urban growth, Seoul experiences severe air pollution due to fine particulate matter with an aerodynamic diameter of ≤2.5 μm (PM2.5), which is detrimental to human health. Although recent studies have extensively focused on estimating daytime PM2.5 concentrations using various types of satellite data, there remains a significant lack of research on nighttime PM2.5 estimations. This study estimated nighttime PM2.5 in Seoul from December 2018 to November 2019 using multiple linear regression (MLR) and random forest (RF) models. These models, which incorporated data on radiance, moon illumination fraction, and terrain height from the Visible Infrared Imaging Radiometer Suite (VIIRS) Day/Night Band (DNB) on board the Suomi National Polar-orbiting Partnership satellite covering all moon phases, also utilized meteorological data from the ERA5 reanalysis by the European Centre for Medium-Range Weather Forecasts (ECMWF). To address multicollinearity, seasonal models were developed using forward stepwise regression and variance inflation factor analysis. DNB radiance analysis indicates that the high intensity of artificial light sources in Seoul significantly reduces the impact of moonlight, leading to notable changes in the DNB radiation associated with PM2.5 concentrations. Consequently, this study estimated nighttime PM2.5 over Seoul across all moon phases. These estimates were then validated through 10-fold cross-validation. The RF model exhibited superior accuracy, with a coefficient of determination (R2) of 0.65–0.90, compared to MLR, with R2 of 0.15–0.50, reflecting seasonal fluctuations in the model performance. The developed models can be applied to estimate reliable nighttime PM2.5 concentrations in megacities with strong artificial light sources, utilizing a comprehensive dataset from satellite observations for all moon phases. Additionally, our findings can serve as scientific data for establishing environmental policies by providing valuable insights into understanding air pollution primarily caused by PM2.5.

10-[(4-Cyanobenzylidene)]-Anthracen-9(10H)-One: syntheses, characterization and application in UV light detection

In this work, the compound 10-[(4-cyanobenzylidene)]-anthracen-9(10H)-one (1) has been synthesized from the corresponding anthrone and 4-cyanobenzaldehyde. It has been characterized by nuclear magnetic resonance (NMR), infrared spectroscopy (IR), high-resolution mass spectroscopy (HRMS) and single-crystal X-ray diffraction (XRD) analysis. Moreover, square wave voltammetry (SWV) was performed to determine the HOMO and LUMO potential levels of the anthrone derivative 1, which indicates that sensitization of TiO2-based electrodes is thermodynamically feasible. Therefore, this characteristic of compound 1 allowed its incorporation in a Grätzel-type solar cell. Photocurrent density measurements under UV irradiation are proportional to the light source intensity, and the operational parameters of the photoelectrochemical cell are relatively stable over time. In fact, the sensitivity of the generated photocurrent normalized by the supplied irradiance for TiO2-1 (7.73 µA/mW) as a photoanode is higher than that of TiO2 alone (5.14 µA/mW), indicating the improvement that 1 provides to TiO2 with respect to UV light detection. The higher photocurrent and the improved stability due to the implementation of 1 are very promising for possible applications as a sensitizer for UV light intensity sensors in dye-sensitized solar cells (DSSC).

Accelerated measurement technology quantifying packaging light protection performance for soymilk nutrient and chemical stability

An accelerated in situ (AIS) light exposure and measurement technology for prediction of retail light protection performance of soymilk packaging is reported. The ability of a packaging material to protect light sensitive marker solutions, either comprising riboflavin (RF) or chlorophyll-a (CHLA), from an intense light source was determined. The light-induced decay of the marker was tracked with in situ spectroscopy and modeled to quantify the light protection performance of each packaging material. For a set of packages, chemical analyses (RF, thiobarbituric acid reactive substances (TBARS), hexanal) of packaged soymilk under Simulated Retail (SR) storage conditions demonstrated excellent correlation to the light protection performance data of the same package set determined by AIS (R2 > 0.97). The use of AIS enables rapid quantification of soymilk packaging material light protection performance and the associated preservation of soymilk nutrient and sensory properties, thus it may be applied to improve the design of soymilk packaging materials for light protection performance and contribute towards the improvement of packaged soymilk product shelf life.

Characterization of human lightness discrimination thresholds for independent spectral variations.

The lightness of an object is an intrinsic property that depends on its surface reflectance spectrum. The visual system estimates an object's lightness from the light reflected off its surface. However, the reflected light also depends on object extrinsic properties of the scene, such as the light source. For stable perception, the visual system needs to discount the variations due to the object extrinsic properties. We characterize this perceptual stability for variation in two spectral properties of the scene: the reflectance spectra of background objects and the intensity of light sources. We measure human observers' thresholds of discriminating computer-generated images of 3D scenes based on the lightness of a spherical target object in the scene. We measured change in discrimination thresholds as we varied the reflectance spectra of the objects and the intensity of the light sources in the scene, both individually and simultaneously. For small amounts of extrinsic variations, the discrimination thresholds remained nearly constant indicating that the thresholds were dominated by observers' intrinsic representation of lightness. As extrinsic variation increased, it started affecting observers' lightness judgment and the thresholds increased. We estimated that the effects of extrinsic variations were comparable to observers' intrinsic variation in the representation of object lightness. Moreover, for simultaneous variation of these spectral properties, the increase in threshold squared compared to the no-variation condition was a linear sum of the corresponding increase in threshold squared for the individual properties, indicating that the variations from these independent sources combine linearly.

The shading isophotes: Model and methods for Lambertian planes and a point light

Structure-from-Motion (SfM) and Shape-from-Shading (SfS) are complementary classical approaches to 3D vision. Broadly speaking, SfM exploits geometric primitives from textured surfaces and SfS exploits pixel intensity from the shading image. We propose an approach that exploits virtual geometric primitives extracted from the shading image, namely the level-sets, which we name shading isophotes. Our approach thus combines the strength of geometric reasoning with the rich shading information. We focus on the case of untextured Lambertian planes of unknown albedo lit by an unknown Point Light Source (PLS) of unknown intensity. We derive a comprehensive geometric model showing that the unknown scene parameters are in general all recoverable from a single image of at least two planes. We propose computational methods to detect the isophotes, to reconstruct the scene parameters in closed-form and to refine the results densely using pixel intensity. Our methods thus estimate light source, plane pose and camera pose parameters for untextured planes, which cannot be achieved by the existing approaches. We evaluate our model and methods on synthetic and real images.

Organic-Inorganic Hybrid Halide X-ray Scintillator with High Antiwater Stability.

In recent years, low-dimensional organic-inorganic hybrid metal halides have garnered significant attention for optoelectronic applications due to their exceptional photophysical properties, despite their persistent challenge of low stability. Addressing this challenge, our study introduces 1-[5-(trifluoromethyl)pyridin-2-yl]piperazinium (TFPP) as a cation, harvesting a novel one-dimensional hybrid cadmium-based halide semiconductor (TFPP)CdCl4, which exhibits intense blue-light emission upon UV excitation. Additionally, (TFPP)CdCl4 demonstrates a high scintillation performance under X-ray excitation, producing 16600 ± 500 photons MeV-1 and achieving a low detection limit of 0.891 μGyair s-1. Notably, (TFPP)CdCl4 showcases remarkable stability against water, intense light sources, heating, and corrosive environments, positioning it as a promising candidate for optoelectronic applications. Through a blend of experimental techniques and theoretical analyses, including density functional theory calculations, we elucidate the unique photophysical properties and structural stability of (TFPP)CdCl4. These findings significantly contribute to the understanding of low-dimensional hybrid halide semiconductors, offering valuable insights into their potential application in advanced optoelectronic devices and paving the way for further research in this field.

Degradation of citrinin by different types of light and hydrogen peroxide.

Citrinin (CIT), a mycotoxin produced by Monascus, Penicillium, and other fungies, can contaminate red yeast rice and other foods, thus constraining their application and development. Exploring efficient degradation methods of citrinin is becoming as one of the hot research topics. In this study, the degradation of citrinin, irradiated by visible (Vis) light, ultraviolet (UV) light, and simulated sunlight alone, as well as in combination with hydrogen peroxide (light/H2O2), was investigated. The research demonstrates UV, Vis, and simulated sunlight all have a degree of degradation on citrinin, and the degradation efficiency correlates with light source and light intensity. Interestingly, when combined with 100W Vis and 0.01M H2O2, the citrinin degradation rate increases to 32%, compared to 1% and 5% achieved by Vis and H2O2 alone. Hydroxyl radicals, arising from the uniform cracking of H2O2 under Vis, were experimentally validated by electron spin resonance measurement and could accelerate the dissociation of citrinin by nucleophilic attacking. Employing the density functional theory, we deduced nucleophilic •OH mainly attack onto C8 and C5 site by comparing the electrophilic Parr functions (Pk+) value of main C atom of citrinin. This research presents a rapid and efficient degradation of citrinin by combining visible light with H2O2. PRACTICAL APPLICATION: This research presents a rapid and efficient method for the degradation of citrnin in red yeast rice and other citrnin containing products by combining visible light with H2O2.

Experimental study of light transmitting concrete with ultra-high content of polymethyl methacrylate

Light Transmitting Concrete (LTC) is an innovative material for crafting unique and sustainable architectural and civil structures. Previous studies primarily utilized optical fibers with diameters below 1.5 mm, which did not exceed 10 % of the volumetric content in concrete. This study aims to develop LTC with ultra-high light transmission capabilities while preserving its mechanical strength. An important innovation is the use of polymethyl methacrylate (PMMA) with larger diameters than normal optical fibers. Specifically, PMMA fibers of 2.0 mm diameter and PMMA tubes of 10–20 mm diameter were employed to increase the spacing between these materials when arranged in an ultra-high volumetric content within the concrete, facilitating easier compaction of the fresh concrete. Experiments of the material's mechanical properties, microstructure, and optical performance were conducted. The findings suggest that although the increased PMMA content might reduce the concrete’s mechanical strength due to a smaller effective cross-sectional area, the LTC still achieves compressive strength exceeding 40 MPa. This underscores the viability of LTC with a substantially higher content of light transmitting functional materials compared to previous studies, while still maintaining a mechanical strength greater than normal concrete. The light transmission efficiency of LTC is nearly directly proportional to its PMMA content, and able to reach up to 30 % of the light source's intensity. Additionally, LTC with PMMA fibers provides uniform light distribution across its surface because of scattering, while LTC with larger-diameter PMMA tubes focuses light around the core areas due to direct lighting.

Ultrabright attosecond gamma ray from irradiating solid foil with tailored vortex laser pulse

Intense attosecond light sources are required for investigating ultrafast electron dynamics, such as that in molecules and atoms, etc. However, so far the achievable photon energy remains at the keV level, thereby limiting their range of applications. For instance, probing intranuclear dynamics requires photon energies in the gamma-ray regime. We propose here a scheme for generating intense attosecond gamma-ray pulses by irradiating a thin solid-density foil with intense vortex laser. In the interaction, the laser driven-foil electrons are differentially accelerated within a quarter-wave field and become highly bunched. Three-dimensional particle-in-cell simulations show that they can efficiently (with ∼30% energy conversion efficiency) radiate ultrashort ( ∼400 as), high-flux ( >1010 photons per pulse), and ultrabrilliant (up to 1027 photons s−1 mm−2 mrad−2 per 0.1% BW at 1 MeV photon energy) gamma rays. With an x-ray driving laser, the scheme can even produce isolated bright sub-attosecond gamma-ray pulses that are useful for time-resolved nuclear spectroscopy and many other areas.

The Cultivation of Spirulina maxima in a Medium Supplemented with Leachate for the Production of Biocompounds: Phycocyanin, Carbohydrates, and Biochar

Cyanobacteria are microorganisms that grow rapidly in an aquatic medium, showing the capacity of accumulations of biocompounds subsequently converted into value-added biocompounds. The cyanobacterium Spirulina maxima can produce pigments besides accumulating significant amounts of carbohydrates and proteins. An alternative to reducing biomass production costs at an industrial scale is the use of landfill leachate in the growing medium, as well as the mitigation of this pollutant. The objective of this work was to cultivate Spirulina maxima in a medium supplemented with leachate, using the design of experiments to evaluate the effects of leachate concentration (% v/v), light source, and light intensity in an airlift photobioreactor, analyzing them as a response to the productivity of biomass, phycocyanin, carbohydrates, and biochar. The highest values of productivity (mg L−1d−1) were 97.44 ± 3.20, 12.82 ± 0.38, 6.19 ± 1.54, and 34.79 ± 3.62 for biomass, carbohydrates, phycocyanin, and biochar, respectively, adjusted for experiment 2 with the factors of leachate concentration (5.0% v/v), light source (tubular LED), and luminosity (54 µmol m−2 s−1), respectively. The use of leachate as a substitute for macronutrients in Zarrouk’s medium for the cultivation of Spirulina maxima is a viable alternative in the production of biocompounds as long as it is used at an appropriate level.

High-speed and high-precision measurement of biaxial in-plane displacements: tens of nanometers principle error suppression in microprobe sensors

When the microprobe sensor is faced with the demand of high-speed biaxial displacement measurement, due to the characteristics of phase generated carrier (PGC) technology, accompanying optical intensity modulation (AOIM) and unfavorable phase modulation depth (PMD) will bring about the tens of nanometer cyclic nonlinear errors, further hindering high-speed and high-precision measurement. Herein, a light source intensity stabilization system based on semiconductor optical amplifier (SOA) feedback control is achieved to eliminate the error caused by AOIM in the presence of high-frequency and large-amplitude laser modulation. Based on this, the reasons for large nonlinear errors in biaxial measurements and the inability to ensure the stability of the accuracy of multiple measurement axes are methodically examined, and an effective nonlinear error elimination methodology based on the normalized amplitude correction of active temperature scanning is proposed. The continuity and linearity of the temperature scanning are also discussed. The performed experiments show that the above approach is capable of reducing the displacement demodulation error from the nanometer scale to the sub-nanometer scale. Further, the nonlinear error is reduced to within 0.1 nm for both measurement axes and the performance becomes consistent. The dual-axis measurement resolution of the microprobe sensor reaches 0.4 nm and the measurement speed is better than 1.2 m/s with the standard deviation of lower than 0.5 nm.

Classical and quantum light-induced non-adiabaticity in molecular systems

The exchange of energy between electronic and nuclear motion is the origin of non-adiabaticity and plays an important role in many molecular phenomena and processes. Conical intersections (CIs) of different electronic potential energy surfaces lead to the most singular non-adiabaticity and have been intensely investigated. The coupling of light and matter induces conical intersections, which are termed light-induced conical intersections (LICIs). There are two kinds of LICIs, those induced by classical (laser) light and those by quantum light like that provided by a cavity. The present work reviews the subject of LICIs, discussing the achievements made so far. Particular attention is paid to comparing classical and quantum LICIs, their similarities and differences and their relationship to naturally occurring CIs. In contrast to natural CIs, the properties of which are dictated by nature, the properties of their light-induced counterparts are controllable by choosing the frequency and intensity (or coupling to the cavity) of the external light source. This opens the door to inducing and manipulating various kinds of non-adiabatic effects. Several examples of diatomic and polyatomic molecules are presented covering both dynamics and spectroscopy. The computational methods employed are discussed as well. To our opinion, the young field of LICIs and their impact shows much future potential.

Optimized coupling of photocatalysis and cavitation for phenol degradation: Use of an extended-kinetic approach

The coupling of hydrodynamic cavitation (HC) and photocatalysis (PC) predominantly exhibits a complementary nature, which is highlighted through a synergistic index. However, this calculation, based on pseudo-first order kinetics, fails to accurately represent the concentration data, often skewed by the formation of reaction intermediates. To address this, an ‘extended’ kinetic approach previously developed with two parameters, which accounts for the formation of intermediates, was adopted. The PC process was optimized for a simulated wastewater containing phenol of concentration (C0) of 100 ppm by applying a UV-A light source of intensity 175 ± 8 W/cm2 on an operating volume (VL) of 200 mL. Catalyst loading, solution pH and initial concentration (C0) were optimized. These optimal parameters were used to operate HC-PC (VL = 3500 mL) at a comparable illumination intensity across the 2 techniques’ reactors. It was observed that phenol conversion was observable only with halved C0 (= 50 ppm) for the HC-PC system, increasing catalyst loading from 0.5 to 1.0 g/L exhibited no increase in phenol conversion. The obtained results from experiments were interpreted with the help of the two-parameter model. For the PC system, the initial rate constant (k0) exhibits a similar trend to the final oxidation extent, however, it did not compare quantitatively. The second parameter – ‘y’ showed a high finite value, denoting the need for dosing external oxidants. The trends of the two-parameters with respect to different relevant parameters presented will help leverage this kinetic approach for AOPs, while optimizing and translating processes to larger scales of operation.

ANALISYS OF TEMPERATURE CHANGES DURING LIGHT POLYMERIZATION OF RESIN MODIFIED CALCIUM SILICATE CEMENTS

Resin-modified calcium silicate cements belong to the fourth generation. This type of material is a combination of calcium silicates and resin. They are hardened by two types of reactions: light polymerization and hydration. Ð arameters related to temperature increases during light polymerization were analyzed. The main factors affecting the amount of generated heat are the type of light sources (LS), the light intensity of LS, the position of LS, the distance between the material surface and LS, the composition and transmission properties of hybrid material, curing time, remaining dentin thickness and the thickness of the layer of hybrid CSCs. Different methods of measuring temperature changes are criticall discussed.

A method and optical references for compensating signal drift in a fluorescent microarray reader

A point-of-need fluorescent microarray assay is a promising tool for on-site high-throughput and multiplex detection. However, its low-cost and portable read-out system, based on an image sensor, suffers from temporal and spatial signal variations caused by measurement drifts. This work presents a method to compensate for these variations without the need for an additional sensor. The method utilizes two inexpensive fluorescent references specifically designed to mitigate the variations while offering cost-saving benefits and broad portable applicability. This method relies on employing a representative signal instead of raw signals. Relevant systems with both variations were conducted to validate and demonstrate the method's effectiveness by varying light-source temperatures and analysis areas. Under investigation of different International Organization for Standardization (ISO) settings, shutter speeds, and light-source intensities, the method significantly reduced the influence of the variations, enhancing detection repeatability by up to a factor of 26-fold.

Endoscopic 5-Aminolevulinic Acid–Induced Fluorescence-Guided Intraparenchymal Brain Tumor Resection—Can the Endoscope Detect More Fluorescence Than the Microscope?

ObjectivesUsing a laboratory-based optical setup we show that 5ALA fluorescence is better detected using the endoscope than the microscope. Furthermore, we present our case series of fully-endoscopic 5ALA guided resection of intraparenchymal tumors. MethodsA Zeiss Pentero® microscope was compared to the Karl Storz Hopkins® endoscope. The spectra and intensity of each blue light source were measured. Quantitative fluorescence detection thresholds were measured using a spectrometer. Subjective fluorescence detection thresholds were measured by 6 blinded neuro-oncology surgeons. Clinical data were prospectively collected for all consecutive cases of fully-endoscopic 5ALA guided resection of intraparenchymal tumors between 2012-2023. ResultsThe intensity of blue light on the sample was greater for the endoscope than the microscope at working distances below 20mm. The quantitative fluorescence detection thresholds were lower for the endoscope than the microscope at both 30/10mm working distances. Fluorescence detection threshold was 0.65-0.80% relative DCM concentration (3.20x10-7 to 3.94x10-7mol/dm-3) for the microscope, 0.40-0.55 % relative concentrations (1.97x10-7 to 2.71x10-7mol/dm-3) for the endoscope at 30mm and 0.15-0.30% relative concentrations (7.40x10-8 to 1.48x10-7mol/dm-3) for the endoscope at 10mm.49 5ALA endoscope-assisted brain tumor resections were carried out on 45 patients (mean age=41, male=28). Greater than 95% resection was achieved in 80% of cases and gross total resection (GTR) in 42%. GTR was achieved in 100% of tumors in non-eloquent locations. There was 1 new neurological deficit. ConclusionThe endoscope provides enhanced visualization/detection of 5ALA-induced fluorescence compared to the microscope. 5ALA endoscopic-assisted resection of intraparenchymal tumors is safe and feasible.

Online detection of eggshell cracks using adaptive light‐source intensity

AbstractUnder the fixed light source intensity (LSI), eggshell thickness difference results in excessive exposure or darkening in imaging, which affects the accuracy of crack identification. To optimize it, a solution involves the utilization of an innovative adaptive light source for optical imaging is proposed. A multi function station is adopted. Among them, one station serves as a reference workstation is utilized to obtain the average grayscale value of the eggs image. The other sub stations serve as detection workstations to acquire and detect the panoramic images of the eggshell. By using the red component average grayscale as a reference to adjust the LSI in the remaining sub stations, imaging consistency is effectively. Moreover, a dual threshold segmentation algorithm was developed to attenuate the dark spot, thereby improving crack detection. Experiments results demonstrating the proposed method significantly improving the detection accuracy of non microcracked eggs while achieving approximately 90% and 92% detection accuracy for intact and cracked eggs, respectively.Practical ApplicationsThere are a few studies on the consistency of light for eggs, and in actual online detection, the light source is often set to a fixed light intensity value, which can lead to overexposure or over‐darkening of the egg image due to variations in the eggshell thickness, and both overexposed and over‐darkened images will result in decreased accuracy of crack recognition. This study designed and built an online detection system for eggshell cracks based on variable light intensity. Therefore, the system not only can help to improve the crack recognition rate of poultry eggs and improve their quality but also would help to promote the development of the commercialization of poultry eggs, which has a broad application prospect.