Leakage Pathways Research Articles

Shale gas leakage and fault activation: Insight from the 2021 Luxian MS 6.0 earthquake, China

In the region of large gas fields, extensive research has been conducted on earthquakes induced by industrial production in shale gas fields. However, limited attention has been given to the impact of post-earthquake events on shale gas reservoir leakage and fault activation. The Luxian MS 6.0 earthquake, which occurred on 16 September 2021 in the Luzhou shale gas field, has raised concerns about post-earthquake shale gas leakage. Post-earthquake measurements of soil gases (Rn, CO2, CH4, and H2) and isotopic analyses (δ13CCO2, δ13CCH4 and δDCH4) in the Luzhou shale gas field area reveal that the Huayingshan fault zone, a natural pathway for shale gas leakage, was not activated by the Luxian earthquake and did not exhibit any further shale gas leakage after the 2021 earthquake. Furthermore, the seismogenic fault, which was impacted by the earthquake, did not damage the shale gas reservoir, causing shale gas leakage. This study provides an important foundation for future research on shale gas extraction and seismic activity in the region.

Study on the Influence of Casing Surface Morphology on the Plugging Performance of Downhole CO2 Plugging with Sn58Bi

Aimed at the problem of gas flurries in carbon dioxide (CO2) geologic sequestration in the wellbore, this paper proposes a sealing method in which the downhole casing is processed with threaded grooves and then plugged with a low-melting-point alloy plug. Based on this method, a small-scale experimental setup was developed for alloy plug molding and gas sealing in this study. Molding and gas sealing experiments with Sn58Bi alloy plugs inside casings with different surface morphologies were carried out. The gas leakage pathway was determined. The microstructure of the interface between the alloy plug and casing was analyzed using an optical microscope. The influence of the inner surface roughness, threaded groove, length-to-diameter ratio, and ambient temperature on the gas sealing performance of the alloy plugs was analyzed. The experimental results show that, with an increase in ambient temperature, the gas sealing performance of the casing increases significantly; when the inner surface of the casing is processed through threaded grooves, the gas sealing performance is better than with smooth hole casing; the gas sealing performance of the alloy plug presents an obvious linear positive correlation with their length-to-diameter ratio. This research provides theoretical support for downhole CO2 plugging using Sn58Bi in the casing.

Simulation study of the influence of the outer target geometry on tungsten contamination: Horizontal vs. vertical target

The core tungsten (W) concentration must be limited to an extremely low level for future fusion reactors. It was found that the effects of E × B drift can lead to a dramatic increase in the core W concentration in our recent work [J. Guo et al., Nucl. Fusion 63 (2023) 126033], in which the simulation study is performed for the divertor geometry with both inner and outer vertical targets. In this work, the influence of the outer target geometry is further investigated by numerical simulations under the direction of toroidal field BT favorable for H-mode access based on a typical EAST upper single-null configuration with two different outer target geometries, i.e. horizontal target (HT) and vertical target (VT). The background plasmas are simulated using SOLPS-ITER, and the W transport is simulated separately using DIVIMP. For the HT case, it is found that detachment in the outer divertor is promoted relative to the VT case, which leads to the suppression of W sputtering flux from the outer target. In contrast, the W sputtering flux from the outer target dominates for the VT case. The plasma profiles are similar for both cases at the inner vertical target, where detachment is achieved due to the drift effects under favorable BT except for the region near the inner strike point. Because the plasma detaches across most of the inner and outer target, the upstream W flux is significantly reduced for the HT case, and the core W concentration is about 2 orders of magnitude lower compared to the VT case. According to the analysis of the W transport for the HT case, two leakage pathways through the inner and outer scrap-off layer near the separatrix are indicated for the W impurities sputtered near the inner strike point.

The role of fault pathways for modern and deep recharge to a semi-confined aquifer: revised analysis of modern water leakage pathways in the Davis wellfield, Memphis, Tennessee, USA

Hydrologic tracer, borehole log and geophysical data provide new insight into recharge sources and pathways to the semi-confined Memphis aquifer in the Davis wellfield, Memphis, Tennessee, U.S.A. New data and recent studies highlight the importance of faults as potential pathways for the migration of modern water into the Memphis aquifer, an important regional public, industrial, and agricultural water supply. Geochemical and environmental tracer data collected over the past 28 years, combined with hydrologic, stratigraphic, and structural data, were used to evaluate changes in water quality and different recharge pathways to the Memphis aquifer. Assessment of stratigraphic and structural relationships argue for the wellfield being bound by a fault along the bluff line (west) and another fault or faults along the eastern and southeastern margins. Modern water recharge (< 60 years old) occurs through the fault along the western boundary of the wellfield, whereas modern water and, seasonally, deep-seated (helium-bearing) fluids recharge along the fault on the southeastern margin. Each recharge source and pathway present different vulnerabilities, suggesting that the role of faults in wellfields within active tectonic regions needs to be assessed.

Ultra-broadband Photodetectors Based on Formamidinium Lead Iodide Quantum Dots

Near-infrared photodetectors were fabricated by incorporating formamidinium lead iodide (FAPbI3) quantum dots (QDs) as the light-harvesting layer. Through systematic optimization of the device architecture, high device performance was achieved by utilizing PCBM as the electron transport material and a 50 nm-thick TAPC film as the hole transport layer. The energy level alignment between PCBM and the FAPbI3 QDs enabled efficient exciton dissociation and hole blocking, while the optimized TAPC thickness decrease current leakage pathways. The resulting photodetectors exhibited an impressive external quantum efficiency of 59.56 % at 750 nm, along with a high specific detectivity of 2.63 x 1011 Jones. A broadband photoresponse from 300–900 nm was observed, as well as a fast temporal response with 30.58/31.26 μs rise/fall times. A substantial linear dynamic range of 61.5 dB was achieved under 780 nm illumination. Furthermore, the low dark current densities facilitated by the judiciously selected materials and thicknesses contributed to the excellent overall device performance. The device performance of the PCBM/FAPbI3 QDs/TAPC system demonstrate its promising potential for near-infrared optoelectronic applications requiring high sensitivity, speed, and broad spectral response, opening up opportunities for further advances in photodetection as well as other relevant device technologies.

Quantitative assessment of well leakage, part I: Cement stress evolution

A damaged cement sheath in wells can open a leakage pathway to shallow freshwater aquifers and atmosphere. Quantitative assessment of leakage along wells has become an area of interest for both the industry and the regulatory bodies. The well leakage can be of importance in both active and legacy wells. In order to estimate leakage through cement sheaths, the size of the leakage pathway and the damage in the cement sheath must be estimated. In this work, we have developed a hydro-thermo-mechanically coupled near-well model that aims to calculate the evolution of cement’s stress as it cures. This process takes into account the cement’s gradual increase in stiffness, chemical shrinkage, and the heat of hydration. The results are verified using lab measured cement stress and pore pressure data from the literature. A case study was developed based on a low-enthalpy geothermal doublet in the Netherlands. The results show that during the cold water injection, an outer microannulus may open to 60 µm. The presence of an external source of water and formation stiffness are of significant importance in determining the damage to the cement sheath. The heat of hydration in cement increases the temperature of cement during curing. The subsequent drop in temperature due to drilling or completion reduces the cement stress and exacerbates the damage to the cement sheath. The producer well may not form a microannuli, however shear and cyclical failure may be of higher likelihood. The modelling framework presented here allows for estimation of annular cement stress in the well. The analysis provides quantitative estimates of the size of the leakage pathway along a well that can be used to estimate well leakge. Quantitative estimate of well leakage provides crucial information for quantitative risk analysis and provides a framework to optimize well operations to minimize leakage risk.

Fully coupled hydromechanical study of tunnel excavation considering leachate leakage from a high water-level landfill

The Jigongshan Mountain Tunnel was constructed beneath a high water-level landfill in Shenzhen, China. Previous studies could not fully capture the hydraulic interactions between the tunnel excavation and the landfill leachate seepage. In this study, a fully coupled hydromechanical numerical model, considering the unsaturated properties and the changing permeability of the waste and geological materials, was established to simulate the landfill leakage and the tunnel excavation simultaneously. Parameter analysis was conducted to explore the effects of the configuration and dimensions of the leakage pathway and leakage points on the seepage field. Results indicate the landfill leakage has a minimal effect on tunnel displacement. The leakage width and the leakage path in the clay significantly affect the pore pressure of the tunnel. In scenarios of severe leakage, the pore pressure of the tunnel can reach as high as 0.615 MPa. Three defensive lines and the fully cover waterproofing layer were suggested for the tunnel waterproofing system under the Xiaping landfill. This research contributes valuable insights for the design and construction of subsurface structures in proximity to landfills.

Rutin, a natural flavonoid glycoside, ameliorates zearalenone induced liver inflammation via inhibiting lipopolysaccharide gut leakage and NF-κB signaling pathway in mice

Zearalenone (ZEN) poses a potential threat on human and animal health partly through the nuclear factor (NF)-κB signaling pathway. In silico study suggested that rutin effective against TLR4 and NF-κB. A wetting test was designed to evaluate the effect and underlying mechanism of rutin in alleviating ZEN-induced inflammation in animals. Twenty-four female mice were randomly divided into 4 groups: control (basal diet), ZEN group (basal diet + ZEN), rutin group (basic diet + rutin), Z + R group (basal diet + rutin + ZEN). Results showed that rutin effectively alleviated ZEN-induced inflammation and damage of liver and jejunum in mice. Rutin addition reduced the content of lipopolysaccharide (LPS) in serum and liver mainly by improving the intestinal barrier function resulted from the production increase of short-chain fatty acids (SCFA). In sum, this study showed that rutin alleviated ZEN-induced liver inflammation and injury by modulating the gut microbiota, increasing the production of SCFA and improving intestinal barrier function, leading to the decrease of LPS in liver and the inhibition of MyD88 independent NF-κB signaling pathway in mice. Specifically, these findings may provide useful insights into the screening of functional natural compounds and its action mechanism to alleviate ZEN induced liver inflammation.

Closed wellbore integrity failure induced by casing corrosion based on solid-chemical coupling model in CO2 sequestration

The safety and stability of carbon sequestration are key in CCS technology, and the wellbore is a critical pathway for leakage, which can lead to the failure of sequestration. In this study, the process of casing corrosion-induced closed wellbore integrity failure is investigated based on a solid-chemical coupling model. The influence of temperature and CO2 pressure on the development of cement damage is also investigated. The results show that the corrosion rate increases and then decreases with increasing depth, and the time of damage initiation gradually shifts backward. During the process of casing corrosion-induced cement damage, the corrosion scale that accumulates on the surface of the casing causes stress redistribution within the cement system. The damage initiates at the interface between the bottom of the cement system and the casing, progressing upwards to create a potential leakage pathway. Moreover, the damage in the cement sheath develops more rapidly, while the rate of damage development in the cement plug gradually decreases. This study will be helpful for understanding the initial stage of closed wellbore failure in carbon sequestration and for implementing corresponding preventive measures in engineering practice.

Seismo-stratigraphic and morpho-bathymetric analysis revealing recent fluid-rising phenomena on the Adventure Plateau (northwestern Sicily Channel)

The northwestern region of the Sicily Channel hosts a great number of morphological highs, the widest of which is the Adventure Plateau that is part of the Sicilian Maghrebian Fold and Thrust Belt system, formed since the Neogene. The Adventure Plateau was shaped in the Early Pliocene by an extensional phase that produced high-angle normal faults mostly WNW-ESE to N-S oriented. Through these faults, magmatic fluids ascended and produced widespread volcanic manifestations often associated to fluid flow processes. The interpretation of multibeam echosounder, seismic reflection (sparker, airgun) and well-log data allow us to identify several features related to the presence of fluids in the study area. The morpho-structural analysis showed a NW–SE oriented fault system and a string of pockmarks that follow the same trend. A detailed well-log analysis confirmed the presence of oil traces, at a depth of ~ 250 m, and gas (i.e., CO2) at a depth of ~ 450 m. The seismo-stratigraphic analysis highlighted seismic signals located below the pockmarks, (e.g. seismic chimneys, bright spots) which suggest the presence of fluids that would rise to a few meters’ depth. Based on the observations, two sources and two corresponding rising mechanisms have been identified. Morphometric analysis of pockmarks has been performed to delineate their possible interaction with the bottom currents. A fluids pathway model has been reconstructed, revealing the source of fluids emissions at depth in the Adventure Plateau, and providing new insights into the identification of fluid leakage pathways.

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Nano-computed tomography analysis of downscaled cement sheath samples: Insights into porosity distribution

Mitigating greenhouse gas emissions from hydrocarbon wells is an industrywide challenge, with microstructural variations in the cement sheaths lining the wells recognized as key factors in forming leakage pathways. To better understand the microstructural variations in cement sheaths and the corresponding mechanisms, downscaled samples simulating rock–cement–casing and casing–cement–casing cement sheaths were prepared and then scanned using nano-computed tomography at resolutions of 11.93 μm and 6.80 μm, respectively. Both the radial and axial porosity of regions of interest were quantified and analyzed. The results showed that radial porosity distributions were quite different between the rock–cement–casing and casing–cement–casing samples. In the rock–cement–casing samples, the radial porosity decreased from the cement–rock to the cement–casing interface due to cement migration, while in the casing–cement–casing samples, the highest radial porosities occurred in both the cement–casing interfaces due to the influence of an interfacial transition zone. The axial porosity distribution was similar in all the rock–cement–casing and casing–cement–casing samples because the porosity decreased from the top to the bottom due to the particle settling phenomenon. These findings enhance our understanding of the factors affecting gas leakage pathways from wells, and the proposed methodology can be used to optimize cement blends to produce effective wellbore barriers.

Defining the geomechanical operating limits for subsurface CO2 storage

Carbon capture and storage (CCS) is a critical component of proposed pathways to limit global warming, though considerable upscaling is required to meet emissions reduction targets. Quantifying and managing the risks of fault reactivation is a leading barrier to scaling global CCS projects from current levels of ~40 million tonnes of carbon dioxide(CO2) per year (to target levels of several gigatonnes of CO2 per year), because CO2 injection into reservoirs can result in increased pore-fluid pressure and temperature changes, which can reduce the strength of rocks and faults and induce brittle failure. This can result in induced seismicity, whilst hydraulic fracturing of seals could provide pathways for CO2 leakage. Consequently, identifying favourable geomechanical conditions (typically determined through data on pre-injection rock stress, mechanical and elastic properties, and pore-fluid pressures) to minimise deformation of reservoirs and seals represents a key challenge in the selection of safe and effective sites for CCS projects. Critically, however, such geomechanical data are typically spatially limited (i.e. restricted to wells) and mainly consist of pre-injection crustal stress orientation measurements, rather than a full 3D description of the stress tensor and related geomechanical properties. This paper reviews some key geomechanical issues and knowledge gaps (particularly those associated with data availability and limitations) that need to be understood to enable successful reservoir and seal management for CCS projects. We also highlight recent advances in multi-scale and dimensional geomechanical modelling approaches that can be used to assess sites for the secure storage of CO2 as well as other gases, including hydrogen.

Improvement Performance of p-GaN Gate High-Electron-Mobility Transistors with GaN/AlN/AlGaN Barrier Structure.

This study demonstrates a particular composited barrier structure of high-electron-mobility transistors (HEMTs) with an enhancement mode composed of p-GaN/GaN/AlN/AlGaN/GaN. The purpose of the composite barrier structure device is to increase the maximum drain current, reduce gate leakage, and achieve lower on-resistance (Ron) performance. A comparison was made between the conventional device without the composited barrier and the device with the composited barrier structure. The maximum drain current is significantly increased by 37%, and Ron is significantly reduced by 23%, highlighting the synergistic impact of the composite barrier structure on device performance improvement. This reason can be attributed to the undoped GaN (u-GaN) barrier layer beneath p-GaN, which was introduced to mitigate Mg diffusion in the capping layer, thus addressing its negative effects. Furthermore, the AlN barrier layer exhibits enhanced electrical properties, which can be attributed to the critical role of high-energy-gap properties that increase the 2DEG carrier density and block leakage pathways. These traps impact the device behavior mechanism, and the simulation for a more in-depth analysis of how the composited barrier structure brings improvement is introduced using Synopsys Sentaurus TCAD.

Strategic Qualitative Risk Assessment of Thousands of Legacy Wells within the Area of Review (AoR) of a Potential CO2 Storage Site

The subsurface confinement of anthropogenic carbon dioxide (CO2) demands robust risk assessment methodologies to identify potential leakage pathways. Legacy wells within the Area of Review (AoR) represent one potential leakage pathway. Robust methodologies require enormous amounts of data, which are not available for many old legacy wells. This study strategically categorizes 4386 legacy wells within the AoR of a potential CO2 storage site in the Illinois basin and identifies the high-risk wells by leveraging publicly available data—reports and well logs submitted to state regulatory agencies. Wells were categorized based on their proximity to the injection well location, depth, the mechanical integrity of well barriers, and the accessibility to these wells throughout the project lifecycle. Wells posing immediate risks were identified, guiding prioritized corrective actions and monitoring plans. Out of 4386 wells, 54 have high priority for corrective action, 10 have medium priority, and the remainder are of low priority. Case study results from the Illinois basin demonstrate the effectiveness and applicability of this approach, to assess the risk associated with legacy wells within the AoR of potential CO2 storage site, strategically categorizing over 4000 such wells despite data limitations.

Transient H2O–CO2 wellbore leakage under evolving recharge conditions considering CO2 phase change

Abandoned wells are one of the dominant pathways of deep CO2 leakage, threatening the safety and effectiveness of CO2 geological storage. Although CO2 wellbore flow has been discussed in several studies, the analysis of the CO2 wellbore leakage under evolving recharge conditions based on the transient wellbore-reservoir fully coupled model, which can describe the CO2 gas-liquid phase change, has yet to be reported. Thus, a transient wellbore-reservoir fully coupled model is established in this study to investigate the interaction between CO2 injection and wellbore leakage. The results show that the fluid wellbore leakage may cause significant disturbance to the reservoir and injection well, and the fluid leakage process can be divided into different stages according to the leakage and recharge characteristics. Besides, the wellhead temperature of the abandoned well shows a different variation trend compared with previous studies, which is attributed to the evolving reservoir recharge. The parameter analysis indicates that the gap aperture in the plugs of the abandoned well, plug locations, CO2 injection rate, and reservoir permeability have apparent effects on the fluid leakage rates but have little impact on the leakage pattern. Finally, a dimensionless parameter, the ratio of leakage to injection mass, is proposed to generalize the leakage degree, and the empirical relationship of the ratio of leakage to injection mass with time is established to facilitate quick estimation. This study broadens the understanding of CO2 wellbore leakage and provides a simple method to predict similar leakage scenarios approximately.

Intrinsic endothelial hyperresponsiveness to inflammatory mediators drives acute episodes in models of Clarkson disease.

Clarkson disease, or monoclonal gammopathy-associated idiopathic systemic capillary leak syndrome (ISCLS), is a rare, relapsing-remitting disorder featuring the abrupt extravasation of fluids and proteins into peripheral tissues, which in turn leads to hypotensive shock, severe hemoconcentration, and hypoalbuminemia. The specific leakage factor(s) and pathways in ISCLS are unknown, and there is no effective treatment for acute flares. Here, we characterize an autonomous vascular endothelial defect in ISCLS that was recapitulated in patient-derived endothelial cells (ECs) in culture and in a mouse model of disease. ISCLS-derived ECs were functionally hyperresponsive to permeability-inducing factors like VEGF and histamine, in part due to increased endothelial nitric oxide synthase (eNOS) activity. eNOS blockade by administration of N(γ)-nitro-l-arginine methyl ester (l-NAME) ameliorated vascular leakage in an SJL/J mouse model of ISCLS induced by histamine or VEGF challenge. eNOS mislocalization and decreased protein phosphatase 2A (PP2A) expression may contribute to eNOS hyperactivation in ISCLS-derived ECs. Our findings provide mechanistic insights into microvascular barrier dysfunction in ISCLS and highlight a potential therapeutic approach.

Highly Sensitive and Wide-Range Detection of Thiabendazole via Surface-Enhanced Raman Scattering Using Bimetallic Nanoparticle-Functionalized Nanopillars.

Thiabendazole (TBZ) is a benzimidazole; owing to its potent antimicrobial properties, TBZ is extensively employed in agriculture as a fungicide and pesticide. However, TBZ poses environmental risks, and excessive exposure to TBZ through various leakage pathways can cause adverse effects in humans. Therefore, a method must be developed for early and sensitive detection of TBZ over a range of concentrations, considering both human and environmental perspectives. In this study, we used silver nanopillar structures (SNPis) and Au@Ag bimetallic nanoparticles (BNPs) to fabricate a BNP@SNPi substrate. This substrate exhibited a broad reaction surface with significantly enhanced surface-enhanced Raman scattering hotspots, demonstrating excellent Raman performance, along with high reproducibility, sensitivity, and selectivity for TBZ detection. Ultimately, the BNP@SNPi substrate successfully detected TBZ across a wide concentration range in samples of tap water, drinking water, juice, and human serum, with respective limits of detection of 146.5, 245.5, 195.6, and 219.4 pM. This study highlights BNP@SNPi as a promising sensor platform for TBZ detection in diverse environments and contributes to environmental monitoring and bioanalytical studies.

Qualitative risk assessment of legacy wells based on publicly available data for class VI well permit applications—Illinois basin case study

Carbon Capture & Storage (CCS) refers to capturing the anthropogenic carbon dioxide (CO2) at a source followed by injecting and storing it safely in the subsurface. The success of the CCS projects therefore heavily relies on how efficiently the confining zones (containment seals) prevent migration of the CO2 to the surface and/or to the underground sources of drinking water (USDW) through leakage pathways. CCS projects requires drilling of Underground Injection Control (UIC) Class VI wells for permanent storage of CO2 in subsurface. Detailed information of all the wells within the Area of Review (AoR) is needed to develop the map and tabulation components of the Class VI well permit application. This paper discusses the generic process that can be used by permit applicants to develop the dataset necessary for preparing the map and tabulation components of the Class VI permit application and perform qualitative risk assessment of all the wells within the AoR. This methodology directs the corrective action plans as well as monitoring plans to some extent. Results of the application of the newly developed methodology for wells in Illinois basin is discussed in detail. This methodology can be applied to all wells including orphaned wells, abandoned wells, active oil and gas wells, stratigraphic wells, disposal wells, etc. This methodology generalized categorization of legacy wells that will help in easier comparison of different CCS projects across the globe. The qualitative risk assessment methodology discussed in this paper is a good starting point for developing crossflow modeling.

Thermal Conductivity of Bottle-Brush Polymers.

Using molecular dynamics (MD) simulations of a generic model, we investigated heat propagation in bottle-brush polymers (BBP). An architecture is referred to as a BBP when a linear (backbone) polymer is grafted with the side chains of different length Ns and grafting density ρg, which control the bending stiffness of a backbone. Investigating κ-behavior in BBP is of particular interest due to two competing mechanics: increased backbone stiffness, via Ns and ρg, increases the thermal transport coefficient κ, while the presence of side chains provides additional pathways for heat leakage. We show how a delicate competition between these two effects controls κ. These results reveal that going from a weakly grafting (ρg < 1) to a highly grafting (ρg ≥ 1) regime, κ changes non-monotonically that is independent of Ns. The effect of side chain mass on κ and heat flow in the BBP melts is also discussed.