Late Cements Research Articles

Chronology and geofluids characteristics of calcite cement in the Upper Triassic Xujiahe Formation tight sandstone reservoir, Western Sichuan Basin, SW China

Geological fluid activities significantly influence diagenesis and hydrocarbon accumulations in reservoir rocks. However, it remains challenging to precisely determine the timing of these activities. This study aims to investigate the chronology and geofluids characteristics of calcite cement that leads to reservoir tightness in the Upper Triassic Xujiahe Formation in the Western Sichuan Foreland Basin, which is a critical exploration target for hydrocarbon resources. We examine calcite cement as a marker of fluid activities, employing petrological analyses, U-Pb dating, and in-situ carbon-oxygen isotope analysis. These methods are integrated with simulations of regional burial and thermal histories to assess pore evolution and hydrocarbon accumulation mechanisms in these tight sandstone reservoirs. Results reveal two main calcite cementation stages within the second member of the Xujiahe Formation (Xu-2 Member): early cements from the Middle Jurassic around 175 ± 11 Ma and late cements from the Late Jurassic between 161 and 156 Ma. Initially, basin-derived alkaline fluids and near-surface atmospheric freshwater supplied the calcium and carbon for early cements during ongoing basin subsidence. Calcium and carbon for the late calcite cements came from the dissolution of carbonate rock fragments by organic acids. The heavier δ13C is primarily associated with in-situ generation and consumption of carbon within the system, while the δ18Ofluid, which is close to modern seawater values, is mainly related to active water-rock reactions induced by processes such as the dissolution of carbonate rock fragments by organic acids. The closed diagenetic system due to calcite cementation in the Late Jurassic led to reservoir tightening. Therefore, basin-scale chronological constraints on calcite cement are of great significance for quantitatively studying sandstone reservoir densification and exploring the mechanism and control factors of hydrocarbon accumulation.

Characteristics and Control Factors of a High-Quality Deeply Buried Calcareous Sandstone Reservoir, the Fourth Member of the Upper Xujiahe Formation in the Western Sichuan Basin, China

A special type of sandstone in which carbonate rock fragments (CRFs) dominate the composition developed in the Upper Triassic Xujiahe Formation’s fourth member (Xu4) in the western Sichuan Basin, known as calcareous sandstone. Calcareous sandstones are widely distributed in the western Sichuan and is the main production target of tight sandstone gas in the Sichuan Basin. In this study, thin sections, porosity–permeability testing, scanning electron microscopy, and X-ray diffraction are applied to examine the characteristics and control factors for high-quality reservoirs in the calcareous sandstones, with a view to providing guidance for natural gas exploration and development in calcareous sandstones. The results show that the calcareous sandstone belongs to litharenite, with an average framework grain composition of 30% quartz, 1% feldspar, and 69% rock fragments, while the Xu4 sandstone has a high quartz content (average content of 71%). Primary intergranular pores are the main storage space, and the reservoir quality is quite poor. Under the influence of different parent rock properties of sandstones, there are obvious differences in the composition of framework grains between the calcareous sandstone and the ordinary Xu4 sandstone, which in turn affects the reservoir storage space, diagenesis, and reservoir quality. High-energy depositional conditions, low content of late cements, and the development of fractures are the main controlling factors for the formation of high-quality reservoirs in Xu 4 calcareous sandstones.

Early cement augmentation may be a good treatment option for pain relief for osteoporotic compression fractures: a systematic review and meta-analysis.

The incidence of osteoporotic compression fractures (VCFs) have been rising over the past decades. Presently, vertebral cement augmentation procedures such as balloon kyphoplasty and vertebroplasty are common treatments allowing pain relief and functional recovery. However, there is controversy on whether different timeframes for cement augmentation affects clinical outcomes. Hence, this study aimed to compare pain relief and complication rates between early versus late cement augmentation. A comprehensive systematic review of PubMed, EMBASE, Scopus and Cochrane Library was conducted, identifying studies that compared early versus late cement augmentation for VCFs. As the definitions of "early" and "late" phases across studies are heterogenous, we established the cut-off between early and late phase as intervals to accommodate as many studies as possible for analysis. We conducted two separate analyses with different cut-off intervals and included studies that reported interventions within these respective time intervals. In analysis 1, we included studies which grouped patients into "early" and "late" group based on a cut-off time frame of 2-4weeks. On the other hand, in analysis 2, we included studies which grouped patients into "early" and "late" groups based on a cut-off time frame of 6-8weeks. Meta-analysis was conducted via random-effect models, comparing outcomes of interest between early and late groups. Eleven studies were included. The total cohort size was 712 and 775 patients in analysis 1 and 2 respectively. Mean follow-up was 12.9 ± 3.7months and 11 ± 0.6months respectively. VAS change at final follow-up was significantly greater in the early group for both analyses. (MD = - 0.66, p = 0.01; and MD = - 1.18, p < 0.005 respectively). There was no significant difference in post-operative absolute VAS score, number of cement leakage, number of adjacent compression fractures and local kyphotic angle, for both analyses. Patients in both groups experienced reductions in VAS score that exceeded the minimum clinically important difference. Both early and late timeframes for cement augmentation offered significant improvement in pain relief, with similar post-operative absolute pain score, kyphotic angle, cement leakage and adjacent vertebral fractures. Early surgery may offer substantial pain relief in patients presenting with pain as early as < 2-4weeks of VCFs.

The effect of meteoric water on the very fine crystalline dolomite reservoir in the shallow burial zone: A case study of the Ma55 submember of Majiagou Formation in Ordos Basin

The meteoric water has obviously changed the physical properties of dolostone reservoirs in the vertical vadose zone and the horizontal phreatic zone, but its influence on the dolostone reservoirs in the shallow burial zone beneath the phreatic surface is still unclear. This study aims to reveal the effect of meteoric water on the dolostone reservoirs in the shallow burial zone through X-ray diffraction, cathodoluminescence, C, O, and Sr isotope using the sample from Majiagou Formation in the Daniudi gas field, Ordos Basin. The diagenesis and paragenesis of the Ma 55 submember were identified and interpreted through petrological study, combined with data from electron probe, X-ray diffraction analysis, and geochemical parameters of diagenetic minerals. The color of the very fine crystalline dolomite under the cathodeluminescence is dark red and red. The order degree of dolomite ranges from 0.54 to 0.91, showing the origin of early seepage-reflux dolomitization. There are a large number of different calcite cements as fills within the pores and fractures. The color of the calcite cement under the cathodoluminescence is orange-yellow, with a zonal structure. Hydrothermal fluid during late diagenesis could be identified by the authigenic fluorite filling in the fractures. According to the assembly of diagenetic minerals, the very fine crystalline dolostones have experienced the seepage-reflux dolomitization, meteoric water dissolution, shallow burial cementation and late cementation. The void spaces of the very fine crystalline dolostones are intercrystalline pores and microfractures. Although a large number of dissolved pores and caves developed in the period of meteoric water dissolution, these caves and dissolved pores has been mostly filled by multi-stages of cementation. Therefore, the effect of meteoric water on dolostone reservoirs in the shallow burial zone beneath the phreatic surface is not obvious. The main controlling factor for the quality of dolostone reservoir was dolomitization. This study provides a new understanding of the influence of meteoric water on reservoir quality in the shallow burial zone during the paleokarst period.

Літогенез верхньоюрських відкладів Зовнішньої зони Передкарпатського прогину

Geological- and biological-paleogeographical conditions of sedimentogenesis within the Carpathian segment of Tethys ocean during Tithonian were considered. The rock-forming organisms with calcic function (flora and fauna), which compose main lithological types of carbonate rocks were identified. On the base of biological-paleoceanographical and lithological investigation of different genetic types of Upper Jurassic carbonate rocks of the Outer zone of the Carpathian Foredeep and analysis of literature data on modern carbonate sediments, the structural classification of Late Jurassis epipelagic sediments of the Carpathian segment of the Meso-Tethys was made. In that classification pelitic, aleuritic, psammitic and ruditic fractions of sediments were distingnished. Geological-paleogeographical model of occurrence of the Tithonian sediments within the Carpathian segment of the Meso-Tethys (the Outer zone of the Carpathian Foredeep) was built by the author. That model presents areals of biogenic and abiogenic epipelagic sediments and depicts their facial variations. Geological-paleogeographical study of Upper Jurassic sediment complexes of epipelagic part of the Meso-Tethys has shown that they were formed within widespread interior shelf, probably, with small inclination of the sea bottom. In Upper Jurassic there was abundant growth of the benthos with calcic function and avalanchecal sedimentation of their skeletal remains took place with forming of biogenic carbonate sediments. The coral-algae biocoenosis there were biological indicators of considered parts of Tethys region. In modern basins of the World ocean analogous processes take place at the depths of about 50 m, in temperature conditions about 23–25 °C and the salinity of the sea waters about 2.7–3.8 ‰. The manifestations of diagenetic and katagenetic processes in the Upper Jurassic carbonate rocks of Outer zone of the Carpathian Foredeep have been investigated and their influence of the formation of the reservoir properties of rocks has been found out. During the diagenesis, the rocks were recrystallized, micritizated and cemented. From the mineralogical point of view, the changes consisted in the transformation of primary aragonite and magnesium-calcite skeletal remains of organisms into calcite, as well as processes of dolomitization, ferruginization and silicification. At the stage of diagenesis, Fe-containing minerals ̶ glauconite and pyrite ̶ has been formed. The dolomitization of Jurassic organogenic limestones of Outer zone of the Carpathian Foredeep has been caused by the mixing of the fresh meteoric waters with buried marine pore waters in the underground phreatic zone adjacent to the ancient coastline. Silicification is a consequence of the metasomatic substitution of the carbonate substance by silicate, which has been caused by decrease of the pH occurred after dolomitization. Katagenetic transformation of the rocks are manifested in the dissolution of the remains of organisms, grains of carbonate cement and the late cementation of pores and microfractures. Changes of carbonate rocks are associated with the bringing of certain substances in the sediment (sulphatization, celestinization) or their removal (dedolomitization, decementation). Neoplasm minerals of the katagenesis stages are represented by anhydrite and celestine. The proceses of recrystallization of carbonate rocks at different stages of katagenesis contributed to the selective leaching of limestones and dolomites and led to formation of secondary cavities and caverns, different in shape and size. The predominance of cavities of certain types determines the type of reservoir, among which are distinguished pores, pore-caverns and joint caverns. The processes of diagenesis and katagenesis are associated with the dissolution of carbonate material, which differently affects the reservoir properties of sediments. Authigenous mineral formation, with the exception of dolomitization, impairs the reservoir properties of the Upper Jurassic carbonate rocks, and recrystallization improves. Burial of carbonate rocks at depth contributes to the preservation and even improvement of their reservoir properties both due to dissolution and textural heterogeneity (jointing develops at the boundary of the elements of textural heterogeneity). Observations show that the most favourable in this respect are organogenic and detrital varieties of carbonate rocks. The presence of clay minerals in the composition of their cement increases the textural heterogeneity and, as a consequence, the ability to formation of joints.

Depositional and diagenetic controls on sandstone compactional fabrics in an Andean broken foreland basin, the Miocene Vinchina formation, northwestern Argentina

The very thick (up to 6000 m thick) Miocene Vinchina Formation was deposited between 16 and 8 Ma ago and later covered by more than 2500 m of Pliocene-Pleistocene sediments in a broken foreland basin. The very thick sedimentary pile accumulated in a medium to low-gradient basin must have suffered intense mechanical compaction during burial.Seventy thin sections of unaltered sandstones collected in three sections along the depositional strike of the Vinchina Formation at the Sierra de Los Colorados, La Rioja Province, northwestern Argentina, were analyzed under the microscope for determining compactional paths and controls.The role of compaction in sandstone diagenesis was firstly assessed using the change in intergranular volume (IGV), which is the sum of all cement and remaining primary porosity. It is clear from the IGV analysis that most of the studied sandstones lose more porosity by compaction (COPL) than by cementation (CEPL). In general compaction increased from the upper to the lower member of the Vinchina Formation (i.e with depth) and there is a clear trend of the compaction index ICOMPACT increase from the northern, shorter Los Pozuelos to the central, thicker La Troya sections. Surprisingly, the thickest southern El Yeso section shows anomalous results possibly due to the extensive development of cements as indicated by the highest CEPL values. Cements are related to the depositional environment (gypsum, calcite) and clast composition (zeolites). Early cements may have prevented further compaction while late cements may have produced open fabrics by dissolution of matrix and framework clasts. Both cases show that diagenetic processes are not homogeneous basin-wide and that the diagenetic pathways are not only controlled by the increase in burial depth but also by characteristics associated with depositional environments and framework clast composition.We also attempted to relate compaction to burial depth based on the nature (point, long, concave-convex and sutured contacts) and the number (contact and packing indexes) of grain-to-grain contacts in the studied sandstones. The sandstones present predominance of concave-convex grain-to-grain contacts and IC indexes mostly between 3 and 4. Sutured contacts are uncommon, and stylolites were not observed at all. Persistence of open fabrics, floating textures and point grain-to-grain contacts at different depths are the result of dissolution-cementation processes. A clear trend of increasing mechanical compaction with depth is only seen along the northern coarser-grained but thinner Los Pozuelos section. Although compaction seems to have increased with depth and also from north to south, the thickest but overall finer-grained El Yeso (southern) section do not show a clear pattern of change with depth. This behavior seems to be the result of at least four main factors: 1) mean sandstone grain-size, 2) thickness of muddy intervals, 3) development of early diagenetic cements, and 4) depth of burial.Comparison with comparable examples suggests that similar compactional characteristics are achieved between 3.5 and 6 km of maximum burial depths. However, cumulative thickness of the Vinchina basin-fill indicate that the base of the Vinchina Formation may have been buried at 8.5 km deep but preliminary backstripping models suggest that by 5 Ma this surface may have reached up to 10 km depth. Alternatively, recorded repetitive episodes of deformation, uplift, and erosion (progressive unconformities) in the Vinchina basin may have prevented the sedimentary pile to be deeply buried and therefore allow to reconcile the observed compactional textures with depth of burial.The results obtained in this work show that the analysis of mechanical compaction in sandstones constitutes a complex task and in occasions there is not a linear relationship between the contact indexes and depth of burial. Sandstone compaction is controlled not only by the depth of burial but also by other factors such as, time, geothermal flow, matrix content, the development of early cements, the ratio between ductile and rigid lithic fragments and, in tectonically active basins the development of progressive unconformities. Therefore, in most cases, it is very speculative to extend diagenetic conditions to basin-wide scales. In particular, the porosity-depth relationship must be based on primary porosity only.

The Effect of Working Time and Application Technique on Cement Penetration into a Tibial Model

BackgroundAseptic loosening of the cemented tibial component is a source of failure in total knee arthroplasty. This study examined common techniques for cement application by quantifying depth and volume of penetration into tibia models. Material and methodsThirty-six composite tibia models were cemented with a tibial component using 3 application techniques (gun, osteotome, and layered) with either early or late cement working time. Computed tomography and 3D-modeling were used to quantify volume and depth of penetration. Statistical analysis was conducted with analysis of variance with Bonferroni correction and Student’s t-test. ResultsNo difference was found in overall volume of penetration between early and late cement application (P = .16). Beneath the baseplate, the layered technique had significantly less penetration and averaged less than 3 mm with early and late cement. The gun technique had the greatest depth of penetration with early cement and averaged greater than 3 mm in all zones regardless of cement working time. The osteotome technique achieved significantly greater depth of penetration around the keel with early and late cement, P < .01. ConclusionsUsing a cement gun ensures adequate penetration beneath the baseplate regardless of cement working time while the osteotome technique is effective to increase penetration around the implant keel. According to our study, applying cement early in its working time may not increase volume of penetration. This study raises concern regarding adequate cement penetration using the layered technique for cementing the tibial component in total knee arthroplasty, and future research is warranted.

Research on Diagenetic Evolution and Hydrocarbon Accumulation Periods of Chang 8 Reservoir in Zhenjing Area of Ordos Basin

The Mesozoic Chang 8 Section in the Zhenjing area is a typical low permeability-tight sand reservoir and is regarded as the most important set of paybeds in the study area. Guided by the principles of basic geological theory, the diagenetic evolution process and hydrocarbon accumulation periods of the Chang 8 reservoir in the study area were determined through various techniques. More specifically, core observation, scanning electron microscopy (SEM), X-ray diffraction (XRD), and vitrinite reflectance experiments were performed in combination with systematic studies on rock pyrolysis and the thermal evolutionary history of basins, the illite-dating method, and so on. The Chang 8 reservoir is dominated by feldspar lithic and lithic feldspar sandstones. Quartz, feldspar, and lithic fragments are the major clastic constituents. In clay minerals, the chlorite content is the highest, followed by illite/smectite formation and kaolinite, while the illite content is the lowest. The major diagenesis effect of the Chang 8 reservoir includes compaction, cementation, dissolution, metasomatism, and rupturing. The assumed diagenetic sequence is the following: mechanical composition → early sedimentation of chlorite clay mineral membrane → early cementation of sparry calcite → authigenic kaolinite precipitation → secondary production and amplification of quartz → dissolution of carbonate cement → dissolution of feldspar → late cementation of minerals such as ferrocalcite. Now, the study area is in Stage A in the middle diagenetic period. Through the inclusion of temperature measurements, in conjunction with illite dating and thermal evolutionary history analysis technology in basins, the Chang 8 reservoir of this study was determined as the phase-I continuous accumulation process and the reservoir formation epoch was 105~125 Ma, which was assigned to the Middle Early Cretaceous Epoch.

Diagenetic facies and reservoir porosity evaluation of deep high-quality clastic reservoirs: A case study of the Paleogene Shahejie Formation, Nanpu Sag, Bohai Bay Basin, China

Petrological analysis, thin-section observation and laboratory analysis data were selected to systematically study the physical and diagenetic features of the first member of the Paleogene Shahejie Formation (Es1) in the No. 3 structural belt of the Nanpu Sag, Bohai Bay Basin. The intensities of different diagenetic processes were determined, the diagenetic evolution sequence was reconstructed, the typical diagenetic facies were identified and the effects of different diageneses on the reservoir were quantitatively analyzed. The results show that the main intergranular fillings include authigenic-quartz, quartz secondary enlargement, clay minerals, carbonate cement and matrix. The pore types include intergranular porosity, dissolution porosity and microfractures. The reservoir has experienced compaction, early cementation, dissolution and late cementation, among which compaction is the most important porosity reducer. Compaction was the main diagenetic process involved in porosity reduction, accounting for about 24.4% of the loss of thin-section porosity. The dissolution process clearly improved the porosity, increasing thin-section porosity by 2.7%. Five diagenetic facies were identified on the basis of petrographic analyses, namely, (a) strongly compacted-weakly cemented-weakly dissolved facies; (b) weakly compacted-strongly cemented-weakly dissolved facies; (c) moderately compacted-moderately cemented-weakly dissolved facies; (d) strongly compacted-weakly cemented-moderately dissolved facies; and (e) strongly compacted-weakly cemented-strongly dissolved facies. According to the analysis of diagenesis intensity, the porosity evolution model of various diagenetic facies was reconstructed, and the reservoir quality of various diagenetic facies was quantitatively predicted. The reservoir quality of different diagenetic facies clearly changed with depth. The best reservoir quality was in strongly compacted–weakly cemented–strongly dissolution facies, which have good sorting, contain a large amount of feldspar and soluble debris, and are mainly developed in the main part of the river channel. Our study can provide a reference for the subsequent exploration and development of deep petroleum systems.

Diagenesis and pore evolution model of tight sandstone gas reservoirs of Benxi Formation in the south-central Ordos Basin, China

ABSTRACT In recent years, gas tests in Benxi Formation in the south-central Ordos Basin have shown good oil and gas displays. In 2009, a gas reservoir was encountered in the Benxi Formation during drilling by the Shanxi Yanchang Petroleum Company, and the open flow potential was estimated at over a million cubic meter per day. Thus, studying the reservoirs in this area is of great exploration and guidance significance. In the paper, reservoirs were studied by casting thin sections, scanning electron microscopy, and high-pressure mercury intrusion experiments, and then, a diagenetic evolution sequence was established. Combined with the recovery model of the initial porosity of the sandstone and a quantitative pore analysis technique, the quantitative porosity evolution model of the Benxi Formation reservoir was established. The results show that i) the Benxi Formation mainly includes quartz sandstone, with less lithic quartz sandstone and lithic sandstone; ii) In general, five types of pores are generally developed in the Benxi Formation, namely, residual intergranular pores, intergranular dissolution pores, intercrystalline pores, micropores and microfractures; iii) Reservoir development was mainly affected by sedimentation and diagenesis; iv) At present, the main reservoir has currently reached the end of the mid-diagenesis of the B stage or late diagenesis stage. The average primary porosity of the sandstone was approximately 38.1%. The reservoir underwent a porosity reduction stage due to strong compaction, a porosity reduction stage due to early cementation, a porosity enhancement stage due to dissolution and a porosity reduction stage due to late cementation. The average porosity of the reservoir is now 4.89%.

Integrated study of water Sr isotopes and carbonate Sr–C–O isotopes reveals long-lived fluid compartments in the Langfjellet oil discovery, Norwegian North Sea

Routine measurements of reservoir pressure variation with depth can detect pressure discontinuities indicative of barriers to vertical fluid movement. This study investigates how pressure data can be augmented by detailed profiles of formation water 87Sr/86Sr ratio to determine the precise location and cause of such barriers, and by C–O–Sr isotope analysis of carbonate cements to determine the duration over which the barrier has persisted. The study focuses on the clastic Hugin Formation reservoir in the Langfjellet Oil Discovery (Norwegian North Sea). Here, pressure data indicated a barrier somewhere within a 25 m depth interval. Formation water 87Sr/86Sr was measured with high spatial resolution by extraction from core samples using the residual salt analysis (RSA) method. This revealed three homogeneous populations of water separated by a small step in 87Sr/86Sr over a 7 m interval containing coal and shale layers, and a very large step in 87Sr/86Sr over a 1.2 m interval corresponding to a thin coal and shale layer situated below a major flooding surface. The latter is the main candidate for the pressure barrier. Modelling confirmed that this inferred pressure barrier also greatly retards Sr diffusion.Carbonate cements occur disseminated throughout the reservoir and in several heavily-cemented zones. Oxygen isotope-derived temperatures indicate that these formed in two episodes: (1) Pre-compactional, precipitated shortly after deposition in the zone of bacterial methanogenesis (~30 °C, ~200 m depth, ~162 Ma); (2) Post-compactional incorporating thermal decarboxylation-derived carbon (~90 °C, ~2500 m depth, ~46 Ma). Carbonate 87Sr/86Sr data reveal the same compositional populations present in the current formation water to be present in both cement generations. The water compositional stratification must thus have been present when the early and late cements precipitated, down till today. The persistence of a compositional step for most of the geological history of the rocks confirms the presence of a major fluid communication barrier. The Sr RSA data show invariant water composition across the heavily carbonate cemented intervals, implying no barrier effect.The combination of pressure data (to identify pressure barriers), Sr RSA (to add spatial resolution) and Sr–C–O isotopes of carbonates of different ages (to add a time dimension) is useful for identifying major long-term fluid communication barriers and differentiating them from smaller, less effective or shorter-term features. The method has applications for identifying seals in exploitation of petroleum and water resources, and underground storage of CO2 and radioactive waste.

Implications of microbial mat induced sedimentary structures (MISS) in carbonate rocks: An insight from Proterozoic Rohtas Limestone and Bhander Limestone, India

A variety of microbial mat induced sedimentary structures (MISS) occur in the basal part of the Mesoproterozoic Rohtas Limestone and the Bhander Limestone, India. The combined outcrop and petrographic studies establish unicellular microbial origin of the MISS in the Rohtas Limestone and the Bhander Limestone. Micro-scale deformations associated with MISS imply the late cementation. Paradoxically MISS, once formed, has a better preservation potential in carbonate sediments because of their proneness to get cemented early. The studied basal sections of both the formations built up in a low energy depositional condition. In warm and arid tropical climate, high concentration of dissolved inorganic carbon exacerbated precipitation of aragonite crystals in successive stacks and sulfur concentration led to gypsum precipitation. However, the temperature in the palaeodepositional environment could have been high enough to restrict the sulfur reduction rate severely hampering the growth of sulphur reducing bacteria (SRB) population which was the most powerful post-Archaean calcification engine. The available results indicate Mesoproterozoic palaeotemperature raised up to 32°C at a mid-latitude location. In the Vindhyan sea straddling across the equator, temperature is predicted to have been considerably higher. The ancient marine limestone formations having MISS, irrespective of their age, developed in similar low palaeolatitudinal locations. Thus, it is reasonable to attribute that high temperature at depositional site cards carbonate sediments to acquire MISS by delayed cementation. Early cementation hinders MISS formation in carbonate sediments, till the sea water temperature crosses an optimal value.

Gas trap stability in the Zechstein Limestone from the Rudna Copper Mine (SW Poland)

A gas and crashed rock burst in 2009 in the Rudna Copper Mine was the motivation to re-investigate the dolomite succession of the first Permian cyclothem (Werra), which covers the ceiling section of the excavations. Gas traps were recognized by previous research; however, the stability of gas traps during mining operations has not been studied yet. Mitigation of future gas bursts requires a complex analysis of these gas traps, involving petrological, petrophysical and mechanical analysis of the reservoir dolomite facies. The results indicate the significant influence of dolomite texture, porosity and extent of late diagenetic dolomite cement on the reservoir and geomechanical properties, and the induced failure pattern of the dolomite facies. The mechanism of dolomite failure allowed for interpreting the degree of dolomite degassing during and after mining operations.

Adsorption of Eu(III) onto Gaomiaozi bentonite corroded by cement waters: Effect of cement solutions on the long-term sorption performance of bentonite in the repository conditions

Abstract The adsorption of europium (Eu(III)) onto Gaomiaozi (GMZ) bentonite corroded by cement water at different stages was studied by batch experiments considering the in-situ conditions in a high-level radioactive waste (HLW) repository. Before this, the corrosion tests were carried out on compacted GMZ bentonite specimens with two cement solutions (Young Cement Water -YCW and Evolved Cement Water -ECW) simulating the early and late cement degradation waters during the long-term operation of a repository. X-Ray diffractometry (XRD) tests and scanning electron microscope (SEM) tests were performed to identify the characteristics of corroded GMZ bentonite. The results indicate that the adsorption capability of YCW corroded bentonite is similar to that of ECW corroded bentonite, and both of them are higher than that of raw GMZ bentonite. Cement solutions impact the adsorption performance of bentonite mainly by increasing pH of pore water in bentonite and altering its mineralogy (forming secondary minerals). Increasing pH implies increasing the sorption percentage of nuclide ions. Besides, most of the secondary minerals in bentonite have a good adsorption capacity. As a consequence, the cement solutions have positive effect on the long-term adsorption performance of bentonite, suggesting that GMZ bentonite is a good retention material in a high-level radioactive waste (HLW) disposal system.

The complexity of mudstone diagenesis – some insight from the Tøyen Shale, Lower to Middle Ordovician, southern Sweden

ABSTRACTThe Lower to Middle Ordovician Tøyen Shale in southern Sweden, a biostratigraphically well-dated siliciclastic mudstone unit, shows 18 distinct authigenic cements that include sulfides, carbonates, silicates, clays, and phosphates. Marcasite, sphalerite, galena, and six texturally distinct types of pyrite characterize the sulfides whereas only one type of dolomite and three different generations of calcite are observed in this unit. Quartz, phosphate, and organic matter occur as only one generation each. Authigenic clay minerals are represented by chlorite and kaolinite. The paragenetic sequence of cements is subdivided into the two pre-burial carbonates, succeeded by ten relatively early burial cements, and six late burial cements, the kaolinite being the latest of them all and potentially being of Cretaceous age. Based on textural relationships, the paragenetic sequence of alterations started with dolomite precipitation followed by calcite, and then five different generations of pyrite. All eleven other phases post-date these initial seven cements in the Tøyen Shale.

Efficacy of Fiber Post Bonding To Root Dentin after Different Obturation Techniques and Cementation Timings: In Vitro Study.

OBJECTIVE:The aim of this in vitro study was to assess the effect of obturation technique and cementation timings on the bonding of fibre-reinforced posts to the root canal walls.METHODS:Twenty extracted teeth were randomly allocated to two groups according to the obturation technique and cementation timing. Central incisors with single canals were used after being decoronated. Every extracted tooth of the {vertical compaction group} (VC) group (n = 10) had been obturated using the {E & Q plus obturation system} with posts cemented in the same day; The other (CO) conventional group (n = 10) teeth were obturated using the conventional lateral compaction technique and posts cemented after one week. “SF” Fiber posts were used after bonding and cementation using Rely X ARC resin cement with all the endodontically treated teeth. The push-out test was performed in a universal testing machine. Data were analysed by 2 way analysis of variance with Statistical significance was set to 0.05.RESULTS:Heat softened gutta percha group showed more push out the bond strength of the bonded posts than the conventional obturation group (p < 0.05). In the middle region, there was no statistical significance between the two groups while there was significance in the coronal and apical thirds.CONCLUSION:The vertical compaction technique and early cementation improved the bond strength of the resin posts in comparison to the conventional obturation technique with late cementation.

High-temperature alteration and porosity generation in Upper Ordovician microbial reefs, Hudson Bay intracratonic Basin, Arctic Canada

Upper Ordovician biohermal mounds of the Red Head Rapids River Formation in the Hudson Bay Basin consist of microbial and sponge boundstone and cementstone. The cementstone is made up of isopachous layers and botryoids of former aragonite now calcite. Secondary dissolution porosity and small fractures are cutting through the bioherm. Secondary pore-fillings consist of drusy calcite cement and subsequent bitumen. The δ18OVPDB and δ13CVPDB values of late cements are invariably more negative than those of the marine cements. Fluid inclusion microthermometry documents the presence of two distinct populations of homogenization temperatures, one in secondary pore-filling burial calcite cement (Th average 93 ± 10 °C) and a second one in recrystallized marine calcite cements (Th average 118 ± 25 °C). The combined δ18OVPDB and Th data suggest that burial cements precipitated from a fluid having δ18OSMOW values between +0.5 and −2‰, whereas the marine cement data indicate resetting of the fluid inclusions in the presence of a high temperature, δ18OSMOW heavy brine (+2.5 to +12‰). The lower temperature fluid inclusions of the late pore-filling cement agree with recent Apatite Fission Track data suggesting early oil window temperature at maximum burial. The higher Th values recorded in the marine cement represent resetting of initial or entrapment of new fluid inclusions from fracture-controlled circulation of basement-derived fluids. The petrographic and geochemical data suggest that fracture-controlled high temperature brine circulation occurred after the inception of burial and recrystallization of original marine aragonite to calcite, which resulted in the generation of significant secondary porosity that was later filled by lower temperature burial cements and hydrocarbons.

Diagenetic evolution vis-a-vis reservoir characteristics of Dhosa sandstones, Ler dome, Kachchh, western India

The detrital mineralogy as well as diagenetic characters of the Dhosa Sandstone Member of Chari Formation exposed at the Lerdome, south of Bhuj was studied. In order to assess the potential of the Dhosa Sandstone as a reservoir, it is substantial to understand the diagenetic processes that are controlled largely by post-depositional cementation and compaction in addition to framework composition and original depositional textures. The petrologic analysis of 33 thin sections was carried out to discern primary composition and diagenetic features including primary and secondary porosity patterns. Monocrystalline quartz dominates the detrital mineralogy followed by polycrystalline quartz. Among the polycrystalline variety recrystallized metamorphic quartz surpasses stretched metamorphic quartz in terms of abundance. Feldspars comprise microcline and plagioclase where the former is dominant over the latter. Orthoclase too comprises a very small percentage. Mica, chert, rock fragments, and heavies form the remaining detrital constituent in descending order of their constituent percentage. The diagenetic precipitates are mainly carbonate (8.30%) and iron (7.80%) followed by clay (0.66%) and silica (0.88%) that are minor constituent of the total cementing material. The main paragenetic events identified are early cementation, mechanical compaction, late cementation, dissolution, and authigenesis of clays. The overall reservoir quality seems to be controlled by compaction and authigenic carbonate cementation. The minus cement porosity average 29.4%. The porosity loss due to compaction is 21.92% and by cementation is 29.71%. The loss of original porosity was due to early cementation followed by moderate mechanical compaction during shallow burial. Preservation of available miniscule primary porosity was ascribed to dissolution of carbonates and quartz overgrowth which resisted chemical compaction during deep burial. The studied sandstones may have low reservoir quality owing to existing porosity of less than 9%. More carbonate dissolution and its transformation in dolomite in sub-surface condition and macro-fracture porosity may result in enhanced secondary porosity and good diagenetic traps.

Origin of the megabreccias in the Katanga Copperbelt (D.R.Congo)

The megabreccias in the Katanga part of the Neoproterozoic Central African Copperbelt contain up to several km-long blocks and fragments of the Mines Subgroup which host most of the stratiform Cu-Co deposits. New observations, particularly on cores from boreholes drilled at Luiswishi indicate three types of fracturing: 1) brittle post-folding in the Mines Subgroup; 2) hydraulic; and 3) ductile in soft incompetent siltstones of the R.A.T. and Dipeta subgroups. These fracturing phases dislocated the Roan succession into blocks and fragments and, in particular, clearly showed that there is an evolution from an in situ hydraulic fracturing, to a heterometric brecciation implying some movement and abrasion of the fragments. The process points to significant compression, and was accompanied by fluid expulsion and precipitation of dolomite after decompression. Fluid inclusion microthermometry in dolomite grains shows that the fluids were of high salinity and high temperature, suggesting dissolution of evaporites most likely contained in the Roan sedimentary pile. These saline fluids allowed the fluidization of the breccias, facilitating the displacement of the nappes, pinching out (extrusion-like) megabreccias along thrust-faults, and resulting in intrusion of breccias between the blocks or into large fractures. Breccias between the blocks are clearly identified as friction breccias. They contain a fine material, as part of the matrix, resulting from abrasion of the fragments during transportation. Abrasion and attrition explain the rounding of the fragments. A late cementation phase from less saline and lower temperature fluids suggests the addition of meteoric water in the system, and the mixing with the ambient fluids. The minimum burial depth of the meteoric water incursion is estimated at 2.8 km. Such under-saturated fluids may have contributed to the dissolution of residual evaporites and of the evaporitic material from the Kiubo rocks at the base of the nappes, and led to further brecciation, possibly explaining the multi-phase features of the breccia. The megabreccias occur at the base of the thrusts sheets and are marked by thrust-fault zones. Results of the study support a process of formation of the megabreccias related to a fold-and-trust event, and invalidate a syn-orogenic sedimentary origin as an olistostrome formed by subaqueous conglomeratic debris flows and clastic syn-orogenic sediments. They also contradict a pure salt tectonic hypothesis that propose the extrusions and enlargements of allochthonous evaporites-gigabreccia before the Lufilian deformation. However, the model is compatible with a “fluid behaviour” of pressured saline fluids trapped in folds and/or thrust sheets, and resulting from evaporites dissolution at variable depth.

Fluid-chemical evidence for one billion years of fluid flow through Mesoproterozoic deep-water carbonate mounds (Nanisivik zinc district, Nunavut)

Ancient carbonate rocks commonly contain numerous post-depositional phases (carbonate minerals; quartz) recording successive diagenetic events that can be deciphered and tied to known or inferred geological events using a multi-pronged in situ analytical protocol. The framework voids of large, deep-water microbial carbonate seep-mounds in Arctic Canada (Mesoproterozoic Ikpiarjuk Formation) contain multiple generations of synsedimentary and late cement. An in situ analytical study of the post-seafloor cements used optical and cathodoluminescence petrography, SEM-EDS analysis, fluid inclusion (FI) microthermometry and evaporate mound analysis, LA-ICP-MS analysis, and SIMS δ18O to decipher the mounds’ long-term diagenetic history. The six void-filling late cements include, in paragenetic order: inclusion-rich euhedral dolomite (ED), finely crystalline clear dolomite (FCD), hematite-bearing dolomite (HD), coarsely crystalline clear dolomite (CCD), quartz (Q), replacive calcite (RC) and late calcite (LC). Based on the combined analytical results, the following fluid-flow history is defined: (1) ED precipitation by autocementation during shallow burial (fluid 1; Mesoproterozoic); (2) progressive mixing of Ca-rich hydrothermal fluid with the connate fluid, resulting in precipitation of FCD followed by HD (fluid 2; also Mesoproterozoic); (3) precipitation of hydrothermal dolomite (CCD) from high-Ca and K-rich fluids (fluid 3; possibly Mesoproterozoic, but timing unclear); (4) hydrothermal Q precipitation (fluid 4; timing unclear), and (5) RC and LC precipitation from a meteoric-derived water (fluid 5) in or since the Mesozoic. Fluids associated with FCD, HD, and CCD may have been mobilised during deposition of the upper Bylot Supergroup; this time interval was the most tectonically active episode in the region’s Mesoproterozoic to Recent history. The entire history of intermittent fluid migration and cement precipitation recorded in seemingly unimportant void-filling mineral phases spans over 1 billion years, and was decipherable only because of the in situ protocol used. The multiple-method in situ analytical protocol employed in this study substantially augments the knowledge of an area’s geological history, parts of which cannot be discerned by means other than meticulous study of diagenetic phases, and should become routine in similar studies.