Large Coercivity Research Articles

A comparative study on the lamella effect and properties of atomized iron powder and reduced iron powder in Fe-based soft magnetic composites

We prepared Fe soft magnetic composites (SMCs) with lamellar structure by using the flaky Iron powder, and studied the effects of types of iron powder on the microstructure and properties of Fe SMCs. The results show that the atomized iron powder and the reduced iron powder are deformed into flaky structure after ball milling, and these flaky iron powder have greater magnetic susceptibility and eddy current diameter perpendicular to the magnetic flux direction. In addition, compared with flaky gas atomized iron powder, the flaky reduced iron powder has large aspect ratio and lower coercivity. Therefore, the Fe SMCs with flaky reduced iron powder exhibit relatively high permeability (82) and low eddy current loss (0.033 W/kg at 50 kHz, 0.05 T), which shows the potential possibility of application at high frequency.

Large coercivity and enhanced magnetization in La-substituted Sm6Mn23 alloys

The magnetic properties of Sm6Mn23-based alloys are still not fully understood for their high complexity in magnetic and crystallographic structures. This work presents studies of the structure and magnetic properties of Sm6Mn23 and Sm5LaMn23 alloys. The results show that both the binary and La-substituted ternary alloys crystallize in a cubic Th6Mn23 type structure (Fm-3m) with trace amount of Mn impurities. The lattice parameter of Sm5LaMn23 is slightly larger than that of Sm6Mn23. The Curie temperature of Sm5LaMn23 is ∼403 K, which is lower than that of Sm6Mn23. A field-dependent magnetic transition was observed in Sm5LaMn23, which shows a decreasing temperature at which Sm5LaMn23 exhibiting maximal magnetization with increasing field, indicating a suppression of the antiferromagnetic coupling of the rare earth and Mn moments under applied field. Large coercivities up to 0.74 T and 1.2 T are observed in Sm5LaMn23 bulk alloys and powders, respectively. The saturate magnetization, the remanent magnetization, and the coercivity of Sm5LaMn23 at 5 K are much higher than that of Sm6Mn23. The ball-milled Sm5LaMn23 powders exhibit significantly enhanced coercivity and magnetization. The refinement of the grain size during ball-milling results in the enhanced coercivity. The magnetic purification of the powders and possible local ferromagnetic configuration of the surface Mn atoms may result in the enhanced magnetization.

Engineering hard ferrite composites by combining nanostructuring and Al3+ Substitution: From nano to dense bulk magnets

We have investigated the bottom-up sol-gel synthesis of nanocomposite powders comprising two magnetic phases (hexagonal Sr ferrite and spinel Co ferrite) in order to outline a strategy to obtain permanent magnets with large coercivities via low-cost and scalable syntheses. The correlation between morphological, structural and macroscopic magnetic properties of Al-substituted SrFe12O19 and SrFe12O19/CoFe2O4 nanocomposites was analyzed in detail. The hysteretic behavior can be tuned by cation substitution and/or modulation of the super-exchange coupling at the interface of the constituting phases. The magnetic data, supported by Monte Carlo simulations, indicates enhanced magnetic coupling within the composite: this observation underscores the significance of soft crystallite size and epitaxial growth quality at the interface as key factors influencing super-exchange coupling strength, ranging from fully coupled to essentially decoupled composites. Bulk magnets with high density were manufactured by compacting these nanostructured phases using spark plasma sintering, without an applied magnetic field. Consolidation of powders significantly impacted magnetic properties, by increasing remanent magnetization and decreasing coercivity due to enhanced super-exchange coupling. The presence of two phases hindered reciprocal growth, influencing coercivity differently in various compositions. Overall, the compaction enhanced magnet performance through improved particle alignment and super-exchange coupling, offering the potential for optimized magnet design.

Synthesis of Low-Symmetric α-Cobalt(II) Hydroxide-Incorporated Cyanuric Acid Layers with High Néel Temperature and Large Coercivity: Structure and Magnetism.

α-Cobalt(II) (CoII) hydroxide (compound 1) incorporating cyanuric acid layers was synthesized via the solvothermal method. 1 exhibited two distinct characteristics, which were different from reported α-CoII hydroxides. (i) The presence of abundant consecutive hydrogen bonds between the adjacent hydroxide layers enhanced the driving force of crystallization along the direction of the c axis. Thus, 1 revealed high crystallinity without the disorder phenomenon. (ii) 1 showed low symmetry. The configuration of CoTd sites did not follow the regular triangular net. The low symmetry favored the magnetic anisotropy. Thus, 1 revealed ferrimagnetic behavior with a high Néel temperature (TN = 56.8 K) and coercivity (Hc = 36 kOe at 2 K). The ferrimagnetic behavior of 1 was validated via the Hubbard U correction density functional theory.

Pre-deformation assisted fabrication of bulk Nd2Fe14B/α-Fe nanocomposites with high energy density

For Nd2Fe14B/α-Fe nanocomposite magnets, which exhibit great superiority in theoretical energy products, it is a great challenge to obtain controlled nano-scale microstructural features while eliminating the harmful metastable phases due to the general metastable fabrication methods. Here, we report a strategy to control the nano-scale features and simultaneously eliminate metastable phases for Nd2Fe14B/α-Fe nanocomposites through low-temperature pre-deformation of amorphous alloys combined with subsequent thermal annealing. The resultant bulk Nd2Fe14B/α-Fe nanostructure exhibits desired ultrafine grain sizes, ∼20 nm for soft-magnetic α-Fe phase with a high fraction of Vα-Fe ≈ 30 wt% and ∼33 nm for hard-magnetic Nd2Fe14B phase. The desired microstructure results in a larger coercivity (Hci = 4.1 kOe) and higher saturation magnetization (Ms = 1.51 T) compared to those (Hci = 3.3 kOe and Ms = 1.35 T) of the counterpart without pre-deformation, contributing to a high energy density of 26.3 MGOe. This energy density is 200% larger than that of the counterpart without pre-deformation and far beyond that (around 20 MGOe) of previously reported bulk Nd2Fe14B/α-Fe nanocomposites with Vα-Fe ≥ 20 wt%. The superior property stems from the purposely introduced low-temperature pre-deformation that changed the structure and local chemistry of the amorphous alloy, facilitating the decomposition of harmful metastable phases and the formation of Nd2Fe14B phase during annealing processes, which lowers the temperature, from 750 to 700 °C for producing the Nd2Fe14B/α-Fe nanostructure and thus yields ultrafine nanograins. These results demonstrate an effective means to prepare high-performance bulk Nd2Fe14B/α-Fe nanocomposite magnets.

FePd2Te2: An Anisotropic Two-Dimensional Ferromagnet with One-Dimensional Fe Chains.

Two-dimensional (2D) magnets have attracted significant attention in recent years due to their importance in the research on both fundamental physics and spintronic applications. Here, we report the discovery of a new ternary compound FePd2Te2. It features a layered quasi-2D crystal structure with 1D Fe zigzag chains extending along the b-axis in the cleavage plane. Single crystals of FePd2Te2 with centimeter size could be grown. Density functional theory calculations, mechanical exfoliation, and atomic force microscopy on these crystals reveal that they are 2D materials that can be thinned down to ∼5 nm. Magnetic characterization shows that FePd2Te2 is an easy-plane ferromagnet with TC ∼ 183 K and strong in-plane uniaxial magnetic anisotropy. Magnetoresistance and the anomalous Hall effect demonstrate that ferromagnetism could be maintained in FePd2Te2 flakes with large coercivity. A crystal twinning effect is observed by scanning tunneling microscopy which makes the Fe chains right angle bent in the cleavage plane and creates an intriguing spin texture. Besides, a large electronic specific heat coefficient of up to γ ∼ 32.4 mJ mol-1 K-2 suggests FePd2Te2 is a strongly correlated metal. Our results show that FePd2Te2 is a correlated anisotropic 2D magnet that may attract multidisciplinary research interests.

Coercive Fields Exceeding 30 T in the Mixed-Valence Single-Molecule Magnet (CpiPr5)2Ho2I3.

Mixed-valence dilanthanide complexes of the type (CpiPr5)2Ln2I3 (CpiPr5 = pentaisopropylcyclopentadienyl; Ln = Gd, Tb, Dy) featuring a direct Ln-Ln σ-bonding interaction have been shown to exhibit well-isolated high-spin ground states and, in the case of the Tb and Dy variants, a strong axial magnetic anisotropy that gives rise to a large magnetic coercivity. Here, we report the synthesis and characterization of two new mixed-valence dilanthanide compounds in this series, (CpiPr5)2Ln2I3 (1-Ln; Ln = Ho, Er). Both compounds feature a Ln-Ln bonding interaction, the first such interaction in any molecular compounds of Ho or Er. Like the Tb and Dy congeners, both complexes exhibit high-spin ground states arising from strong spin-spin coupling between the lanthanide 4f electrons and a single σ-type lanthanide-lanthanide bonding electron. Beyond these similarities, however, the magnetic properties of the two compounds diverge. In particular, 1-Er does not exhibit observable magnetic blocking or slow magnetic relaxation, while 1-Ho exhibits magnetic blocking below 28 K, which is the highest temperature among Ho-based single-molecule magnets, and a spin reversal barrier of 556(4) cm-1. Additionally, variable-field magnetization data collected for 1-Ho reveal a coercive field of greater than 32 T below 8 K, more than 6-fold higher than observed for the bulk magnets SmCo5 and Nd2Fe14B, and the highest coercive field reported to date for any single-molecule magnet or molecule-based magnetic material. Multiconfigurational calculations, supported by far-infrared magnetospectroscopy data, reveal that the stark differences in magnetic properties of 1-Ho and 1-Er arise from differences in the local magnetic anisotropy of the lanthanide centers.

Giant enhancement of coercivity in β-Ni(OH)2 decorated Ti3C2T x MXene nanosheets

Ti3C2T x MXenes are of great interest due to their high conductivity, easy synthesis and unique functional properties. Functionalisation and structural engineering are essential for various applications because of their dramatic influences on different chemical and physical properties. Therefore, understanding the mechanism of the etching reaction of Ti3C2T x from its parent MAX phase is crucial. The structural details also need to be understood for application in different practical devices. In this study, 2D Ti3C2T x sheets with an average thickness of 3.48 nm and lateral dimension of 5.5 µm were synthesised by removing Al layers from the Ti3AlC2 MAX phase. The step-by-step etching mechanism was analysed with the help of Rietveld refinement of the powder x-ray diffraction data. The structural details and influence of different functional groups on the surface were also studied using transmission electron microscopy, x-ray photoelectron spectroscopy, and Raman spectroscopy. The magnetic behaviour and magnetic interaction of bare 2D Ti3C2T x decorated with β-Ni(OH)2 nanosheets on its surface was studied. For the bare 2D Ti3C2T x MXene sheets, a weak ferrimagnetic ordering with negligible coercivity was found. However, the β-Ni(OH)2-decorated Ti3C2T x MXene sheets exhibit strong ferrimagnetic ordering with a sufficiently large coercivity of 0.2 T at 2 K and a transition temperature of 246 K. The generation of this interfacial ferrimagnetism is discussed in light of the interfacial charge transfer originating from d-p mixing. These 2D magnets generated at the interface could be useful for application in different spintronic devices.

Low temperature garnet phase formation in Mn-substituted Y3Fe5-xMnxO12 nanoparticles via citrate combustion synthesis

In this article, we report on the formation of a low-temperature garnet phase in Mn-substituted Y3Fe5-xMnxO12 (x = 0, 0.05, 0.15, and 0.25) nanopowders. We studied the structural, microstructural, static, and dynamic magnetic properties of Mn-substituted Y3Fe5-xMnxO12 (YIG) nanopowders calcined at two different temperatures. The Mn-substituted garnet powders were synthesized using the citrate combustion method followed by calcination at 800 and 1200 °C for 3 h. An increase in Mn substitution (x = 0.15, 0.25) favored the growth of a single garnet phase at low temperatures, even at 800 °C. The lattice constant of these samples ranged from 12.3815 to 12.3679 Å. Microstructural and morphological studies revealed the growth of homogeneous and dense particles, with an average particle size in the range of ∼35–58 nm, close to the single-domain particle size in YIG. Microwave resonance spectra and magnetic hysteresis curves revealed the formation of a ferromagnetic phase in undoped and Mn-doped garnet ferrites at room temperature. The maximum saturation magnetization (26 emu/g) was observed for the sample with Mn content x = 0.05 at 1200 °C, while the largest coercivity (33 Oe) was found for the sample with Mn content x = 0.15 at 1200 °C, among all the samples. The increase in Mn content led to a decrease in peak-to-peak linewidth of FMR spectra from 698.8 to 569.4 G at 800 °C and from 916 to 614.7 G at 1200 °C. This study suggests that Mn substitution in YIG garnet improves structural properties and enhances magnetic anisotropy.

Large Coercivity and High Remanence in Iron‐Rich 2:17‐Type SmCo Magnets:Effect of Dislocation on Solid‐Solution Precursors

Large Coercivity and High Remanence in Iron‐Rich 2:17‐Type SmCo Magnets:Effect of Dislocation on Solid‐Solution Precursors

Nanocrystalline Fe(Co)ZrMoBCu soft magnetic alloys: A transmission electron microscopy study of the microstructures

Nanocrystalline Fe81Zr7Mo2B9Cu1 and Fe40.5Co40.5Zr7Mo2B9Cu1 alloy ribbons were prepared by annealing the as-quenched amorphous alloys at their first exothermic peak temperature. The primary crystallization phases of Fe81Zr7Mo2B9Cu1 and Fe40.5Co40.5Zr7Mo2B9Cu1 consisted of nanoscale body-centered cubic α-Fe and α-FeCo grains, respectively. The microstructures and compositions were analyzed via transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), and area maps were obtained through energy-dispersive spectroscopy (EDS). The addition of Co decreased the mean grain size (D) and broadened the grain-size distribution (σ). The effect of the addition of Co on the Cu clusters and element distribution was studied in detail. Scanning transmission electron spectroscopy combined with energy-dispersive spectroscopy revealed that both alloys contained Cu clusters; the Fe40.5Co40.5Zr7Mo2B9Cu1 alloy exhibited a Cu-cluster density similar to that of the Fe81Zr7Mo2B9Cu1 alloy. Both alloys contained relatively less Fe in their residual amorphous phases than in their nanocrystals, with the nanocrystals in Fe40.5Co40.5Zr7Mo2B9Cu1 containing less Co than in the residual amorphous phase. Fe40.5Co40.5Zr7Mo2B9Cu1 exhibited higher specific saturation magnetization (Ms), specific remanent magnetization (Mr) and larger coercivity (Hc) than Fe81Zr7Mo2B9Cu1.

Permanent-magnet-based transverse thermoelectric generator with high fill factor driven by anomalous Nernst effect

A transverse thermoelectric generator for magnetic-field-free and high-density power generation utilizing the anomalous Nernst effect is constructed and its performance is characterized. By alternately stacking two different permanent magnets with the large coercivity and anomalous Nernst coefficients of opposite sign, transverse thermoelectric voltage and power can be generated in the absence of external magnetic fields and enhanced owing to a thermopile structure without useless electrode layers. In the permanent-magnet-based stack, the magnetic attractive force enables easy construction of the thermopile structure with a high fill factor. In this study, we construct a bulk module consisting of 12 pairs of SmCo5- and Nd2Fe14B-type permanent magnets having positive and negative anomalous Nernst coefficients, respectively, whose fill factor reaches ∼80%, whereas that of conventional thermoelectric modules based on the Seebeck effect is typically 30%–60%. We demonstrate magnetic-field-free anomalous Nernst power generation up to 177 µW at a temperature difference of 75 K around room temperature, which corresponds to the largest anomalous Nernst power density of 65 µW/cm2. The presented module structure concept will provide a design guideline for high-performance transverse thermoelectric power generation.

Exceptional magnetic and magnetoelastic behavior of rare-earth non-centrosymmetric Sm7Pd3

Magnetic compounds possessing an intrinsic combination of near-zero magnetization with high magnetic anisotropy are highly desirable for spinronic applications and memory recording. A comprehensive study of Sm7Pd3 binary compound uncovered a unique combination of strong magnetoelastic behavior, very low net magnetization, and exceptionally high magnetic coercivity. The temperature-dependent X-ray synchrotron powder diffraction study indicates the abrupt changes in the compound's lattice parameters at the magnetic ordering temperature of TC=169 K, although the crystal structure remains non-centrosymmetric hexagonal Th7Fe3-type down to 6 K. Density functional theory calculations confirm high intrinsic magnetocrystalline anisotropy of Sm7Pd3, which explains the extremely large coercivity of the polycrystalline sample, up to Hcr = 130 kOe at 2 K. This discovery brings to life a novel class of highly anisotropic materials that are distinctly different from known spintronic materials, making them interesting future systems for magnetic memory research.

Coercivity enhancement with reduced Tb usage for NdFeB sintered magnets by grain boundary diffusion with multicomponent Tb-Ce-Al-Cu-Zn alloy powders

In this work, coercivity enhancement and thermal stability improvement for NdFeB sintered magnets by grain boundary diffusion (GBD) with Tb75Cu25-xZnx (x = 0–25) alloy powders are investigated. The coercivity (iHc) is enhanced from 10.6 kOe to 19.5–22.5 kOe by GBD with Tb75Cu25-xZnx (x = 0–25). Proper Zn addition into diffusion source can further improve the coercivity and its thermal stability for NdFeB sintered magnets. Besides, the costs of the diffusion sources have been significantly reduced by multicomponent Tb75-y-zAlyCez (Cu, Zn)25 alloy powders, and nearly without sacrificing the magnetic properties. Coercivity is significantly increased to 20.3–22.1 kOe by GBD with Tb75-yAlyCu20Zn5 (y = 0–30) alloy powders, and large coercivity increment (ΔiHc) of 11.0–11.5 kOe is found for y = 0–30. To further reduce the Tb usage, Tb45-zCezAl30Cu20Zn5 (z = 0–25) alloy powders are adopted as diffusion sources. Although the ΔiHc is gradually decreased as Ce content increases, the large coercivity of 18.4–21.6 kOe can be attained for z = 0–25. The formation of (Nd, Tb)2Fe14B shells can inhibit the nucleation of reverse domain. While Ce, Al, Cu and Zn prefer to distribute at grain boundary and triple junction, which can strengthen the decoupling effect between adjacent grains. Both effects contribute to the large coercivity enhancement. The optimized magnetic properties of iHc = 20.5 kOe, ΔiHc = 9.9 kOe and (BH)max = 49.1 MGOe can be achieved for the magnet GBD with Tb30Ce15Al30Cu20Zn5 alloy powders.

Reliable Accessibility of Intermediate Polarization States in Textured Ferroelectric Al0.66Sc0.34N Thin Film

AbstractFerroelectric materials are promising candidates for neuromorphic computing synaptic devices due to the nonvolatile multiplicity of spontaneous polarization. To ensure a sufficient memory window, ferroelectric materials with a large coercivity are urgently required for practical applications in highly scaled multi‐bit memory devices. Herein, a remarkable reliability of intermediate ferroelectric polarization states is demonstrated in a textured Al0.66Sc0.34N thin film with a coercive field of 2.4 MV cm−1. Al0.66Sc0.34N thin films are prepared at 300 °C on Pt (111)/Ti/SiO2/Si substrates using a radio frequency reactive sputtering method. Al0.66Sc0.34N thin films exhibit viable ferroelectricity with a large remanent polarization value of >100 µC cm−2. Through the conventional current–voltage characteristics, polarization switching kinetics, and temperature dependence of coercivity, the reproducibility of multiple polarization states with apparent accuracy is attributed to a small critical volume (3.7 × 10−28 m3) and a large activation energy (3.3 × 1027 eV m−3) for nucleation of the ferroelectric domain. This study demonstrates the potential of ferroelectric Al1‐xScxN for synaptic weight elements in neural network hardware.

Magnetic Putty as a Reconfigurable, Recyclable, and Accessible Soft Robotic Material.

Magnetically hard materials are widely used to build soft magnetic robots, providing large magnetic force/torque and macrodomain programmability. However, their high magnetic coercivity often presents practical challenges when attempting to reconfigure magnetization patterns, requiring a large magnetic field or heating. In this study, magnetic putty is introduced as a magnetically hard and soft material with large remanence and low coercivity. It is shown that the magnetization of magnetic putty can be easily reoriented with maximum magnitude using an external field that is only one-tenth of its coercivity. Additionally, magnetic putty is a malleable, autonomous self-healing material that can be recycled and repurposed. The authors anticipate magnetic putty could provide a versatile and accessible tool for various magnetic robotics applications for fast prototyping and explorations for research and educational purposes.

Unveiling the origin of the large coercivity in (Nd, Dy)-Fe-B sintered magnets

Nd-Fe-B-based permanent magnets are widely used for energy conversion applications. However, their usage at elevated temperatures is difficult due to the relatively low coercivity (Hc) with respect to the anisotropy field (HA) of the Nd2Fe14B compound, which is typically 0.2HA. In this work, we found that the coercivity of an (Nd0.8Dy0.2)-Fe-B sintered magnet could reach 0.4HA, which was twice as high as the Hc/HA of its Dy-free counterpart. Detailed microstructural characterizations, density functional theory and micromagnetic simulations showed that the large value of coercivity, Hc = 0.4HA, originated not only from the enhanced HA of the main phase (intrinsic factor) but also from the reduced magnetization of the thin intergranular phase (extrinsic factor). The latter was attributed to the dissolution of 4 at.% Dy in the intergranular phase that anti-ferromagnetically coupled with Fe. The reduction in the magnetization of the intergranular phase resulted in a change in the angular dependence of coercivity from the Kondorsky type for the Dy-free magnet to the Stoner–Wohlfarth-like shape for the Dy-containing magnet, indicating that the typical pinning-controlled coercivity mechanism began to show nucleation features as the magnetization of the intergranular phase was reduced by Dy substitution.

Microstructure and magnetic properties of binary Mn54-Al46 alloy particulates obtained by severe plastic deformation processing via end-milling and annealing

We utilize the plastic deformation process associated with the machining operation of end-milling for the preparation of ε-phase Mn-Al particulates with micron scale external dimensions and self-similar shapes from binary as-cast feedstock with composition 54 at.% Mn and 46 at.% Al. The structural evolution and development of magnetic properties in response to the single-pass plastic deformation processing by the end-milling and subsequent thermal annealing have been studied. Effects of end-milling process parameter combinations, primarily the rotational speed of the cutting tool, have been identified to permit genesis of morphological self-similar particulates of ε-phase characterized by cold-worked and sub-micron to nanometer scale refined microstructures. The end-milling derived particulates were suitable for preparation of τ-phase based MnAl particulates with enhanced permanent magnet properties via isothermal annealing. Discernibly higher rates for the exothermic ε-phase decomposition reactions in the end-milling derived particulates have been observed for isothermal annealing at temperatures in the range of 673 K ≤ T ≤ 723 K. The enhanced decomposition reaction kinetics have been attributed to reduced effective nucleation barriers for the respective product phases stemming primarily from reduced grain size. Large saturation magnetization and coercivity in combination with reasonable squareness ratios of the magnetization curves resulted in a (BH)max = 4.2 MGOe for the end-milling derived binary Mn54Al46 particulates obtained for the highest rotational tool speed of 4200 RPM used here after annealing for 20 min at 673 K. The ε-phase Mn-Al particulates derived by end-milling have potential as precursors for the fabrication of τ-phase Mn-Al based PM materials.

Revealing the effect of rapid annealing on nano-crystallization behavior and soft magnetic properties of Fe–Co–B amorphous alloy

Rapid annealing (RA), or the application of a high temperature for a short duration, is an efficient strategy to promote the nano-crystallization of Fe-based amorphous alloys and improve their soft magnetic properties. Herein, the ternary Fe–Co–B amorphous alloy is investigated as a typical system to reveal the effect of RA on crystallization behavior and soft magnetic properties. It is found that the large superheating generated during RA significantly increases the homogenous nucleation rate of nanocrystals, while the short duration greatly inhibits the growth kinetics, yielding fine and dense nanograins in the amorphous matrix. The Fe–Co–B alloy shows optimized properties of low coercivity (5.6 A/m) and high saturation magnetization (1.87 T) after RA at 813 K for 3 s. In contrast, all superheating and long duration used in conventional annealing produce large and sparse grains with single crystal morphology and large coercivity above 30 A/m. This work reveals the thermodynamic and kinetic effects of RA on the nano-crystallization behavior of Fe-based amorphous alloys, showing that the RA treatment (high annealing temperature and short annealing time) can induce in-situ homogeneous nucleation and growth, which may help guide the design of Cu-free amorphous/nanocrystalline alloys with desirable soft magnetic properties.

Overcoming coercivity-remanence trade-off via tuning the composition of ferromagnetic intergranular phase in Ga-doped Nd-Fe-B ribbons

The high-performance of a Nd-Fe-B magnet needs both large coercivity and remanence. However, the coercivity – remanence trade-off leads to a dilemma that the coercivity and the remanence cannot be simultaneously increased, and subsequently reduces the maximum energy product ((BH)max). Here, we use atom probe tomography (APT) and demonstrate a strategy that can simultaneously improve the coercivity (Hci) and the remanence (Br) by tuning the concentration of rare earths (Nd + Pr) and ferromagnetic elements (Fe + Co) of the ferromagnetic intergranular phase in (Nd0.1023Pr0.0256Fe0.6832Co0.1308B0.0581)99.7Ga0.3 melt-spun ribbons. In comparison to the Ga-free alloy, the Hci and the Br both increase to 1369 kA/m by 7.0% and to 0.85 T by 2.4%. Interestingly, the magnetic field annealing treatment (1 T, 623 K for 15 min) further improves the Br to 0.90 T with a minor decrease of the Hci. The (BH)max of 134 kJ/m3 is obtained, 12.6% higher than that of the 0.3 at% Ga-doped as-spun sample. Our findings provide an idea to overcome the coercivity-remanence trade-off and subsequently to design prospective permanent alloys with excellent magnetic properties by modifying the content of rare earths and ferromagnetic elements in the ferromagnetic intergranular phase.