In this study, we review changes in Archean granitoid chemistry using stacked probability density estimation and statistical change-point analyses. A significant change in Archean sodic granitoid composition occurs in the 3.9–3.75 Ga period, marked by a shift of SiO2, Al2O3, Na2O, V, Cr, Sr, Sr/Y to higher, and TiO2, FeOT, MnO, P2O5, A/NK, A/CNK, Sc, Ba, Ta, Nb, Hf, Y, and rare earth elements to lower values, which reflects different formation P-T regime and petrogenetic processes. Using phase equilibria and trace element modelling, we demonstrate that the pre-3.9 Ga Acasta Tonalite Gneiss (ATG)-like granitoids formed at shallow depths (∼3 km) but are chemically distinct from impactites of all known large impact craters with basaltic/mixed target rocks. Impact melting produces MgO-rich melts at relatively greater “apparent” depths, reflecting target rock chemistry and contribution from the upwelling mantle, and is unlikely to have produced the shallow-seated ATG rocks. The ATG trace element chemistry is similar to many modern-day non-arc settings felsic rocks, which suggests that the melting regime in these extensional settings also existed before 3.9 Ga and ATG formed in a mantle plume-driven extensional tectonic regime involving melting of long-lived mafic proto-crust at shallow crustal depths above mantle upwelling. In contrast, the 3.9–3.75 Ga transitional and post-3.75 Ga TTGs formed by deep-seated (25–50 km) melting in equilibrium with garnet-bearing amphibolite. When considered together with Ti isotopic evidence of shift from tholeiitic to calc-alkaline magmatism in the 4.0–3.75 Ga period, the evidence for a transition from a regime dominated by crustal reworking to one of significant juvenile input at 3.60–3.85 Ga, noted in trace element/Hf-isotope composition of detrital zircon from several cratons and the reported ultra-high pressure metamorphism/interleaving arc-plume sequence, require a greater depth of melting. We interpret this transition to mark a gradual shift from stagnant-lid to intermittent mobile-lid-type plate tectonics involving deeper subduction of oceanic lithosphere. However, from the single occurrence of pre-3.9 Ga ATG rocks and their similarity with some Archean Fe-rich silica-saturated rocks chemistry, it is unknown whether plume magmatism was the only active mechanism or operated in conjunction with mobile-lid tectonics on early Earth, like in Archean.
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