Lake Sediment Cores Research Articles

Impact of precipitation and temperature changes on limnology and sediment characteristics in NW Himalaya

In recent decades, the ecologically sensitive region of NW Himalaya, a transition zone between the westerlies and the Indian summer monsoon (ISM), has witnessed extreme precipitation events as well as an increase in seasonal temperatures, the impact of which on the lacustrine systems is unknown. In this study, we use a two-pronged approach involving (1) reconstruction of precipitation pathways and moisture sources using the HYSPLIT model during years with extreme (seasonal) precipitation in NW Himalaya; and (2) documentation of the impact of climate extremes on limnology and sediment characteristics by comparing μ-XRF and mineralogical data from a Manasbal Lake sediment core (Kashmir) with the lake monitoring data. Our results show that (a) the most significant change in precipitation pathways is observed during summer when the Bay of Bengal branch of the ISM, in addition to the Arabian Sea branch, also contributes to the regional precipitation; (b) moisture pathways from the Bay of Bengal and the Arabian Sea at different levels also indicate that moisture availability at mid tropospheric level plays an important role in creating extreme wet conditions over Kashmir during the summer monsoon season. In the years with above normal spring precipitation, back trajectories from the Arabian Sea and the Middle East carry more moisture at 1.5 km and 5 km levels; (c) the sub-decadal extremes in seasonal temperature and precipitation can be linked to drier events preserved in the core demonstrating the high sensitivity of the lake systems to short term climate variability; (d) changes in hydrochemistry resulting from inflow of groundwater can provide insights into prolonged anoxia and hypolimnion ventilation; (e) the lake level appears to be insensitive to isolated extreme rainfall events, and anomalous winter and spring warming observed in recent decades. The results of this study have wider implications for understanding changes in moisture pathways and sources during prolonged extreme events, and their impact on lacustrine systems.

Concentrations and Source Identification of Priority Polycyclic Aromatic Hydrocarbons in Six Lake Sediment Cores From South and Northeast Thailand

Concentrations and Source Identification of Priority Polycyclic Aromatic Hydrocarbons in Six Lake Sediment Cores From South and Northeast Thailand

Tracing the sources and depositional history of mercury to coastal northeastern U.S. lakes.

Mercury (Hg) deposition was reconstructed in sediment cores from lakes in two coastal U.S. National Parks: Acadia National Park (ANP) and Cape Cod National Seashore (CCNS), to fill an important spatial gap in Hg deposition records and to explore changing sources of Hg and processes affecting Hg accumulation in these coastal sites. Recent Hg deposition chronology was assessed using (1) a newly developed lead-210 (210Pb) based sediment age model which employs 7Be to constrain deposition and sediment mixing of 210Pb-excess, (2) coinciding Pb flux and isotope ratios (206Pb/207Pb), and (3) Hg isotope ratios and their response to changes in Hg flux. At both sites, Hg flux increased substantially from pre-1850 levels, with accumulation in ANP peaking in the 1970s, whereas in CCNS, Hg levels were highest in recent sediments. Negative values of δ202Hg and Δ199Hg indicated terrestrially-derived Hg was a major constituent of Hg flux to Sargent Mountain Pond, ANP, although recent decreases in Hg flux were in agreement with precipitation Hg records, indicating a rapid watershed response. By contrast, δ202Hg and Δ199Hg profiles in Long Pond, CNNS reflect direct Hg deposition, but disturbances in the sedimentary record were indicated by bomb fallout radionuclide inventories and by peaks in both Pb and Hg isotope depth profiles. These cores provided poor reconstructions of atmospheric deposition and reveal responses that are decoupled from emissions reduction due to complex post-depositional redistribution of atmospheric metals including Hg. The application of multiple tracers of Hg deposition provide insight into the sources and pathways governing Hg accumulation in these lakes.

Study of Holocene aeolian morpholithogenesis of the Eastern coast of the White Sea using georadiolocation and palaeolimnological methods

Abstract. Holocene aeolian topography and sediments were investigated at two key sites on the Zimny Coast and one key site on the Kaninsky Coast of the White Sea. Field work included ground penetration radar profiling, paleolimnological and geomorphological study, as well as aerial imagery and topography surveys. Analytical studies including grain-size, geochemical and diatom analyses and radiocarbon dating of lake sediment cores were performed. Accumulative aeolian relief was formed in areas with a positive coastal-marine sediment balance. The sands are brought in by a longshore drift or river discharge. The aeolian topography and the number of stages of aeolian activation vary across the key areas. The present-time coastal dunes have been forming since the late or middle Holocene, when relative sea level became close to contemporary levels.

Sedimentary DNA and molecular evidence for early human occupation of the Faroe Islands

The Faroe Islands, a North Atlantic archipelago between Norway and Iceland, were settled by Viking explorers in the mid-9th century CE. However, several indirect lines of evidence suggest earlier occupation of the Faroes by people from the British Isles. Here, we present sedimentary ancient DNA and molecular fecal biomarker evidence from a lake sediment core proximal to a prominent archaeological site in the Faroe Islands to establish the earliest date for the arrival of people in the watershed. Our results reveal an increase in fecal biomarker concentrations and the first appearance of sheep DNA at 500 CE (95% confidence interval 370-610 CE), pre-dating Norse settlements by 300 years. Sedimentary plant DNA indicates an increase in grasses and the disappearance of woody plants, likely due to livestock grazing. This provides unequivocal evidence for human arrival and livestock disturbance in the Faroe Islands centuries before Viking settlement in the 9th century.

Temporal variability of microbial communities during the past 600 years in a Tibetan lake sediment core

Over the past decades, the Tibetan Plateau has been experiencing rapid climate change and increasing anthropogenic disturbance. The existing multi-proxy sediment records highlight the complex interplay of physical and ecological changes as a response to past climate changes on the Tibetan Plateau. Yet, it remains an open question of how sedimentary microbial communities respond to past climate changes and anthropogenic interventions. Using high-throughput Illumina sequencing, this study investigated the temporal changes of prokaryotic and eukaryotic communities in a Tibetan lake sediment core spanning the last 600 years. There were obvious temporal distributions of prokaryotic and eukaryotic indicator taxa, and these temporal patterns were mainly influenced by mean annual temperature (MAT), total phosphorus (TP) and nitrogen:phosphorus ratio (N:P). The alpha diversity of eukaryotic communities significantly increased with time ( P < 0.001), while the alpha diversity of prokaryotic communities did not exhibit obvious temporal turnover. Both prokaryotic and eukaryotic communities exhibited significant temporal-decay relationships. However, the turnover rate of the temporal-decay of eukaryotes (0.119) was significantly higher than that of prokaryotes (0.092). The effect of TP and N:P on the prokaryotic and eukaryotic communities were higher than that of MAT. The insights gained from this study can be helpful to understand the effects of past climate change and anthropogenic activities on the temporal distribution patterns of microbial communities, thus providing insights into predicting the succession of microbial communities and underlying mechanisms that drive them under future climate scenarios. • Microbial indicator taxa displayed obvious temporal distribution patterns. • Eukaryotes showed higher temporal turnover rate than bacteria. • MAT, TP and N:P influenced prokaryotic and eukaryotic communities in past 600 years.

Effect of dissolved oxygen on nitrogen and phosphorus fluxes from lake sediments and their thresholds based on incubation using a simple and stable dissolved oxygen control method

AbstractLaboratory incubation of intact sediments is a popular and useful method for obtaining nutrient fluxes from lake sediments to the overlying water. However, one of the main problems facing this method is that the lake sediment core itself consumes oxygen from the overlying water due to the decomposition of organic matter. In this study, addition of headspace with controlled oxygen concentration and circulation of overlying water to the traditional intact sediment incubation method allows for incubation with a stable dissolved oxygen (DO) concentration in the overlying water. In 24 columns incubated for 179–269 h, the mean DO concentration in the overlying water ranged from 0.35 to 9.95 mgO2 L−1. In most cases, stability was high, with the standard deviation of the fluctuation in DO concentration less than 0.1 mgO2 L−1. The DO concentration of the overlying water could be adjusted by changing the partial pressure of oxygen in the headspace. This method supported a detailed description of the relationship between DO concentration and nutrient fluxes from sediments. The soluble reactive phosphorus fluxes and first‐order reaction constants of NO2− + NO3− fluxes increased rapidly when the DO concentration decreased below the thresholds of 1.5 and 3.0 mgO2 L−1, respectively, in Lake Biwa. The thresholds and precise relationships between DO concentration and nutrient fluxes provide useful information for predicting the effect of DO concentration decreases in the lake bottom on nutrient release from sediments. Our results indicate that this incubation method is a powerful tool for clarifying those relationships.

Tracking historical sources of polycyclic aromatic compounds (PACs) in dated lake sediment cores near in-situ bitumen operations of Cold Lake, Alberta

Most bitumen in the Alberta oil sands (Canada) is extracted by thermal in-situ recovery. Despite the widespread use of in-situ bitumen extraction, little information is available on the release of petroleum hydrocarbons by this method to adjacent land and water. Here we analyzed the composition and abundance of parent and alkylated polycyclic aromatic compounds (PACs) in 11 radiometrically-dated lake sediment cores collected near in-situ operations at Cold Lake Alberta to assess potential petroleum contamination sources to surrounding lakes over the past century. Like open-pit mining areas, alkylated PACs in Cold Lake sediments were elevated compared to unsubstituted parent PACs and increased coeval with the onset of bitumen extraction in the area. Diagnostic ratios and pyrogenic indices showed that PAC sources to these lake sediments were dominantly pyrogenic, likely from historic forest fires, however they shifted to more petrogenic sources coeval with expanding oil sands extraction at Cold Lake. PACs in sediment from regional lakes are weakly correlated to their proximity to in-situ oil wells, once corrected for lake area. These results suggest that in-situ operations, via diesel-fueled vehicular emissions and the combustion of natural gas for steam generation, are a source of PACs to nearby lakes, but PACs did not exceed Canadian sediment quality guidelines for the protection of aquatic life.

Harmful algal blooms and cyanotoxins in Lake Amatitlán, Guatemala, coincided with ancient Maya occupation in the watershed

Human-induced deforestation and soil erosion were environmental stressors for the ancient Maya of Mesoamerica. Furthermore, intense, periodic droughts during the Terminal Classic Period, ca. Common Era 830 to 950, have been documented from lake sediment cores and speleothems. Today, lakes worldwide that are surrounded by dense human settlement and intense riparian land use often develop algae/cyanobacteria blooms that can compromise water quality by depleting oxygen and producing toxins. Such environmental impacts have rarely been explored in the context of ancient Maya settlement. We measured nutrients, biomarkers for cyanobacteria, and the cyanotoxin microcystin in a sediment core from Lake Amatitlán, highland Guatemala, which spans the last ∼2,100 y. The lake is currently hypereutrophic and characterized by high cyanotoxin concentrations from persistent blooms of the cyanobacterium Microcystis aeruginosa Our paleolimnological data show that harmful cyanobacteria blooms and cyanotoxin production occurred during periods of ancient Maya occupation. Highest prehistoric concentrations of cyanotoxins in the sediment coincided with alterations of the water system in the Maya city of Kaminaljuyú, and changes in nutrient stoichiometry and maximum cyanobacteria abundance were coeval with times of greatest ancient human populations in the watershed. These prehistoric episodes of cyanobacteria proliferation and cyanotoxin production rivaled modern conditions in the lake, with respect to both bloom magnitude and toxicity. This suggests that pre-Columbian Maya occupation of the Lake Amatitlán watershed negatively impacted water potability. Prehistoric cultural eutrophication indicates that human-driven nutrient enrichment of water bodies is not an exclusively modern phenomenon and may well have been a stressor for the ancient Maya.

Quantification of Spatial and Temporal Trends in Atmospheric Mercury Deposition across Canada over the Past 30 Years.

Mercury (Hg) is a pollutant of concern across Canada and transboundary anthropogenic Hg sources presently account for over 95% of national anthropogenic Hg deposition. This study applies novel statistical analyses of 82 high-resolution dated lake sediment cores collected from 19 regions across Canada, including nearby point sources and in remote regions and spanning a full west-east geographical range of ∼4900 km (south of 60°N and between 132 and 64°W) to quantify the recent (1990-2018) spatial and temporal trends in anthropogenic atmospheric Hg deposition. Temporal trend analysis shows significant synchronous decreasing trends in post-1990 anthropogenic Hg fluxes in western Canada in contrast to increasing trends in the east, with spatial patterns largely driven by longitude and proximity to known point source(s). Recent sediment-derived Hg fluxes agreed well with the available wet deposition monitoring. Sediment-derived atmospheric Hg deposition rates also compared well to the modeled values derived from the Hg model, when lake sites located nearby (<100 km) point sources were omitted due to difficulties in comparison between the sediment-derived and modeled values at deposition "hot spots". This highlights the applicability of multi-core approaches to quantify spatio-temporal changes in Hg deposition over broad geographic ranges and assess the effectiveness of regional and global Hg emission reductions to address global Hg pollution concerns.

Deglaciation of the Scandinavian Ice Sheet and a Younger Dryas ice cap in the outer Hardangerfjorden area, southwestern Norway

Understanding past responses of ice sheets to climate change provides an important long‐term context for observations of present day, and projected future, ice‐sheet change. In this work, we reconstruct the deglaciation of the marine‐terminating western margin of the Scandinavian Ice Sheet in the outer Hardangerfjorden area of southwestern Norway, following the Last Glacial Maximum (LGM) until the start of the Holocene. We base our interpretations on a combination of geomorphological mapping using high‐resolution (LiDAR) terrain models, 68 new cosmogenic nuclide 10Be exposure ages and radiocarbon‐dated lake sediment cores, supported by the stratigraphic position of the 12.1 ka Vedde Ash. We show that even the highest mountain summits in the area (~1200–1400 m a.s.l.) were ice‐covered during the LGM, thus settling debates concerning the Scandinavian Ice Sheet thickness in this region. These summits emerged as nunataqs through the ice sheet about 22–18 ka, potentially owing to upstream ice thinning caused by the break‐up and retreat of the Norwegian Channel Ice Stream. Following the break‐up of the Norwegian Channel Ice Stream, the ice margin seemingly stabilized at the outermost coast for 3500–5500 years before the mouth of Hardangerfjorden became ice free at c. 14.5 ka. Subsequently, during the Bølling and Allerød periods, the ice sheet retreated rapidly into the inner parts of Hardangerfjorden before a major ice sheet re‐advance during the Younger Dryas. We identify and reconstruct a sizeable, independent ice cap on the Ulvanosa mountain massif during the Younger Dryas (YD), a massif that earlier was mapped as covered by the Scandinavian Ice Sheet during the YD. We also document ice‐free areas that are more extensive than previously thought between Hardangerfjorden and Matersfjorden during the YD.

A multi-proxy record of environmental change through the last 53,000 years recorded in the sediments of Lake Kanono, Northland, New Zealand

ABSTRACTLake sediment archives from Southern Hemisphere mid-latitude regions provide invaluable records of late Quaternary environmental change. Here, changes in depositional environment over the past ca. 53,000 years were reconstructed using a range of physical, sedimentological, geochemical, and μ-XRF elemental proxy datasets analyzed from lake sediment cores obtained from Lake Kanono, Northland, New Zealand. The Lake Kanono stratigraphy displays a terrestrial peat environment (ca. 53,700–6,670 cal yr BP), followed by a trend of increased influx of detrital sediment during the Late Glacial–Interglacial Transition (LGIT) at ca. 14,000 cal yr BP with a peak from ca. 12,000 to 9,000 cal yr BP driven by increasingly dry conditions. The increase in sediment influx continued during the early to mid-Holocene, leading to dune reactivation which altered the catchment dynamics of the region, leading to the inception of a shallow lake basin at ca. 6,670 cal yr BP. The timing of the formation of this lake basin can be associated with changes in intensity of the Southern Westerly Winds (SWW) and the appearance and increase in intensity of the El Niño Southern Oscillation (ENSO) after ca. 7,500–7,000 cal yr BP (Moy et al. 2002; Moreno et al. 2018). Drier conditions peaked from ca. 4,000 to 2,400 cal yr BP, possibly culminating in decreased lake levels that persisted from ca. 2,400 to 2,210 cal yr BP, renewed dune accumulation, and blocked stream outlets, resulting in a deep lake basin with thermal stratification that persisted to the present. Cluster analysis of the μ-XRF data demonstrates that the most prominent change in chemistry is near the onset of the Last Glacial Maximum (LGM) at ca. 26,700 cal yr BP associated with a transition to a drier, windier climate. The second most prominent change in the μ-XRF data is during the Polynesian phase of human settlement at ca. 612–575 cal yr BP (1338– 1375 CE). Hence, we can demonstrate the utility and power of a multi-proxy approach coupled with μ-XRF element data to interpret changing sediment sources to a lake basin. Such an approach allows rapid and reliable evaluation of catchment processes influenced by climate events and land-use changes at a resolution not available using other approaches.

A Holocene palaeomagnetic secular variation record from Lake Pupuke, New Zealand

ABSTRACT Palaeomagnetic records from three cores of lake sediment have been merged, producing a new Holocene geomagnetic secular variation record for northern New Zealand. The cores are from Lake Pupuke, a maar lake in Auckland Volcanic Field (AVF). They contain tephra from Rangitoto Volcano (530 ± 10 yr BP), Taupō (1718 ± 10 yr BP), Tūhua/Mayor Island (7637 ± 100 yr BP) and Rotomā tephra from Ōkataina Volcanic Centre (9423 ± 120 yr BP). These tephra dates are supplemented by selected radiocarbon age estimates. The cores were correlated using tephra and fine-scale variations in magnetic susceptibility. The natural remanent magnetisation is strong, stable and carried by fine-grained titanomagnetite from AVF’s basaltic volcanoes. The resulting palaeosecular variation (PSV) record spans from 10,000 to 1500 yr BP. It shows well-defined, millennial-scale swings in direction between 10,000 and 8000 yr BP and between 4000 and 1500 yr BP, while between 8000 and 4000 yr BP variations are of higher frequency and lower amplitude and centre on the geocentric axial dipole field direction. This is in excellent agreement with published PSV records from Mavora Lakes, 1000 km further south, indicating the regional nature of PSV – resulting from broad-scale changes in the circulation of conducting iron-rich fluid of Earth’s outer core.

Paleotoxicity of petrogenic and pyrogenic hydrocarbon mixtures in sediment cores from the Athabasca oil sands region, Alberta (Canada)

Despite the economic benefits of the oil and gas industry in Northern Alberta, significant concerns exist regarding the impacts of increased oil production on the environment and human health. Several studies have highlighted increases in the concentrations of polycyclic aromatic compounds (PACs) and other hydrocarbons in the atmosphere, water, soil and sediments, plants, wildlife and fish in the Athabasca Oil Sands Region (AOSR) as a result of oil sands industrial activity. Sediment cores can provide information on the temporal trends of contaminants to the environment and provide important baseline information when monitoring data are absent. Here we combined analytical chemistry and a mammalian cell-based bioassay in dated lake sediment cores to assess paleotoxicity in freshwater systems in the AOSR. Sediment intervals were radiometrically dated and subsequently analysed for PACs. PAC extracts from select dated intervals were used in cell-based bioassays to evaluate their endocrine disrupting properties. We demonstrated spatial and temporal variability in the PAC composition of sediment cores around the AOSR with some of the highest concentrations of PACs detected near oil sands industrial activity north of Fort McMurray (AB) in La Saline Natural Area. Recent sediment had positive enrichment factors across most PAC analytes at this site with heavier pyrogenic compounds such as benz(a)anthracene/chrysene and benzofluoranthene/benzopyrene dominating. Our study is the first to link chemical analysis of sediment cores with biological effect assessments of endocrine activity showing feasibility of extending the usefulness of sediment cores in monitoring programs interested in complex mixture assessments. While we observed no spatial or temporal differences in ERα mediated signaling, AhR CALUX results mirrored those of the chemical analysis, demonstrating the utility of coupling biological effects assessments to historical reconstructions of contaminant inputs to the natural environment.

Spatiotemporal Characterization of Mercury Isotope Baselines and Anthropogenic Influences in Lake Sediment Cores

AbstractIncreasing mercury isotope ratios from pre‐industrial (1510–1850) to present‐day (1990–2014) in lake sediment cores have been suggested to be a global phenomenon. To assess factors leading to spatiotemporal changes, we compiled mercury concentration (THg) and mercury isotope ratios in 22 lake sediment cores located at various regions of the world. We find that the positive δ202Hg shifts together with THg increases from pre‐industrial to present‐day are a widespread phenomenon. This is caused by increased contribution of mercury from local to regional anthropogenic mercury emission sources, which lead to higher sediment δ202Hg (−1.07 ± 0.69‰, 1 SD) than pre‐industrial sediments (−1.55 ± 0.96‰, 1 SD). The positive Δ199Hg shifts were observed in 15 lake sediment cores, which have low pre‐industrial Δ199Hg (−0.20 ± 0.32‰) compared to the sediment cores with near‐zero to positive pre‐industrial Δ199Hg (0.08 ± 0.07‰). The magnitudes of δ202Hg (r2 = 0.09) and Δ199Hg (r2 = 0.20, both p &gt; 0.05) changes from pre‐industrial to present‐day did not correlate with the magnitude of THg changes. Instead, the magnitudes of δ202Hg and Δ199Hg changes decreased with increasing pre‐industrial δ202Hg and Δ199Hg values, suggesting that the baseline mercury isotope ratios play a more important role in determining the magnitude of mercury isotope changes compared to the degree of THg input. We suggest that the spatiotemporal assessments of δ202Hg in lake sediment cores can be used as an important proxy for monitoring changes in anthropogenic mercury sources for the Minamata Convention on Mercury.

Modern lake sedimentary record of PAHs and OCPs in a typical karst wetland, south China: Response to human activities and environmental changes

The sedimentary history of polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) over the past 140 years in a lake sediment core from Huixian karst wetland was reconstructed. The total PAHs and OCPs concentrations ranged from 40.0 to 210 ng g−1 and 0.98 to 31.4 ng g−1, respectively. The vertical distribution of PAHs and OCPs in different stages was great consistent with the history of regional socio-economic development and the usage of OCPs. As the indicators of socio-economic development, gross domestic product (GDP), population, energy consumption, highway mileage, and private vehicles correlated with the PAHs concentrations, indicating the impact of human activities on PAHs levels. The PAHs and OCPs concentrations were also affected by environmental changes in the wetland, as reconstructed by total organic carbon (TOC), sand, silt, clay, quartz, and calcite in sediments. Redundancy analysis (RDA) results showed TOC was the dominant factor to explain the concentrations of PAHs and OCPs with the explanation of 86.7% and 43.5%, respectively. In addition, TOC content had significantly positive correlation with PAHs (0.96, p < 0.01) and OCPs (0.78, p < 0.01). In particular, the significantly positive correlation (p < 0.05) between calcite and PAHs and OCPs inferred that karstification might play an important role in the migration of PAHs and OCPs in the karst area. Therefore, the lake in Huixian wetland tended to be a sink more than a source of PAHs and OCPs influenced by the increasing TOC content and karstification under climate warming.

Application of XRF Scanning to Different Geological Archives

AbstractHigh‐resolution XRF scanning is widely used on marine and lake sediment cores as a means of rapidly acquiring elemental concentrations from closely spaced intervals with no damage to the samples. Therefore, guidance on how to obtain reliable datasets and select suitable step sizes for different geological media are of great importance. Here we apply this efficient analytical method to loess, stalagmite, and tridacna samples. The results show that 11 elements (Al, Si, K, Ca, Ti, Mn, Fe, Rb, Sr, Zr, and Ba), eight elements (Ca, Si, K, Fe, Cu, Ni, Sc, and Sr) and seven elements (Ca, Sr, Cu, Fe, Sc, Ni, and Si) can be robustly detected by this method for loess, stalagmite and tridacna archives respectively, demonstrating the capacity to reconstruct high‐resolution paleoclimate changes. For loess cores, efficiency emission decay of the X‐ray tube, water content, matrix, and grain size effects are the main factors influencing elemental intensities. The efficiency emission decay of the X‐ray tube, scanning path, scanning interval, and radiation area have a significant effect on element intensities of stalagmite and tridacna samples. Based on our investigations, we suggest optimal resolutions for scanning these three archives for millennial to seasonal‐scale paleoclimatic reconstructions. We compare our analyses with existing results from traditional (discrete) analyses, demonstrating similar scales of variability. Our results suggest that geochemical proxies measured by XRF scanning, such as Rb/Sr, Zr/Rb, and Ca/Ti ratios of loess and the Sr/Ca ratio of speleothem and tridacna, can be effectively used to reconstruct high‐resolution paleoclimate changes.

Early presence of Bythotrephes cederstr\xf6mii (Cladocera: Cercopagidae) in lake sediments in North America: evidence or artifact?

The spiny water flea (Bythotrephes cederströmii), a freshwater crustacean considered to be the world’s best-studied invasive zooplankter, was first recorded in North America in the Laurentian Great Lakes during the 1980s. Its arrival is widely considered to be the result of ocean-going cargo ships that translocated contaminated ballast water from Eurasia to the Great Lakes during the 1970–1980s. The subsequent first discovery of the species in inland lakes is consistent with the hypothesis that propagules dispersed initially from established Great Lakes populations. Here we present evidence of exoskeletal remains, including mandibles, tail spines, and resting eggs, in 210Pb-dated lake sediment cores, which suggests that B. cederströmii was already resident in four inland North American lakes (two in Minnesota, USA; two in Ontario, Canada) by at least the early 1900s. Densities of exoskeletal remains were low and relatively steady from first appearance until about 1990, after which time they increased in all cores. The earliest evidence that we found was a mandible at 33-cm depth (pre-1650) in the sediments of Three Mile Lake, Ontario, Canada. These unexpected findings challenge the current paradigm of B. cederströmii invasion, renew uncertainty about the timing and sequence of its colonization of North American lakes, and potentially question our ability to detect invasive species with traditional sampling methods. We attempted to eliminate errors in the dated stratigraphies of the exoskeletal remains that might have been introduced either methodologically (e.g., core-wall smearing) or naturally (e.g., bioturbation). Nonetheless, given the very low numbers of subfossils encountered, questions remain about the possible artifactual nature of our observations and therefore we regard our results as ‘preliminary findings’ at this time.

Source analysis and influencing factors of historical changes in PAHs in the sediment core of Fuxian Lake, China

In this study, the influencing factors and sources of historical changes in polycyclic aromatic hydrocarbons (PAHs) in the sediment core of Fuxian Lake were analyzed. Before 1970, the Σ16PAH concentration fluctuated widely, with one or more maximum values. During 1971–2004, the Σ16PAH concentration showed a slow growth trend, while during 2005–2017, the concentration increased sharply, reaching a peak value of 821 ng g−1. dw in 2017. The results of a positive matrix factorization (PMF) model demonstrated that before 1970, PAHs were mainly derived from biomass burning in the Fuxian Lake sediment core, with an overall contribution of 40 %. During 1971–2004, the source of PAHs was mainly coal combustion, with an overall contribution of 34 %. During 2005–2017, PAHs primarily originated from traffic, with an overall contribution of 33 %. Population, coal, GDP, motor, and petroleum had a significant influence on low molecular weight (LMW) PAHs in 1980–2004 and 2005–2017. Motor, coal, population, and GDP had a greater impact on high molecular weight (HMW) PAHs. Before 1970 and in 1971–2004, meteorological factors had little effect on PAHs in the sediment core in Fuxian Lake. During 2005–2017, day and rainfall were significantly negatively correlated with HMW PAHs, while temperature and wind were not correlated with PAH concentrations. During 2005–2017, total organic carbon (TOC) and total nitrogen (TN) had greater adsorption effects on HMW PAHs than on LMW PAHs. Before 1970 and in 1971–2004, the adsorption effects of TOC and TN on 3–4-ring PAHs were greater than those of 2-ring and 5–6-ring PAHs. Total phosphorus (TP) had no adsorption effect on PAHs in the entire sedimentary column.

High‐Resolution Elemental Record From the Holocene Sediments of an Alpine Lake in the Central Altai Mountains: Implications for Arctic Sea‐Ice Variations

AbstractIt is well known that Arctic sea ice and Arctic amplification have played an important role in recent climate change in middle to high latitudes of the Northern Hemisphere. We present a high‐resolution elemental data set, spanning the past 9,000 years, obtained using in‐situ synchrotron radiation X‐ray fluorescence measurements of a lake sediment core from Lake Shuang in the Altai Mountains. Based on calibration against the local instrumental climatic record, the Rb/Sr ratio of the sediments is interpreted as an indicator of weathering intensity, which is related to precipitation and temperature variations. There is very little bromine in the granites and moyites in the catchment of Lake Shuang, and the sedimentary Br is derived primarily from wet deposition originating from precipitation and enriched by biogenic processes in this open lake system. The Br variation is positively correlated with local precipitation. The Rb/Sr and Br time series show distinct decadal‐scale to millennial‐scale cycles that are similar to those of Arctic sea‐ice variations, which implies the important role of Artic sea ice in modulating environmental change at Lake Shuang. Our results support a previous suggestion that sea ice loss would cause an increase in atmospheric water vapor content in the Arctic, resulting in the frequent incursion of cold air masses from the Arctic into middle latitudes, and leading to increased snow cover and precipitation, and vice versa.