Kg Of Volatile Solids Research Articles

Optimization of ultrasonication and alkalinization as pretreatment methods for leachate co-digested with food waste toward maximum synergistic effects

Anaerobic co-digestion (AcoD) of food waste (FW) and landfill leachate has shown promising results in enhancing the methane yield. However, leachate includes toxic and refractory compounds that may impact the decomposition process. In this research, co-digested leachate was pretreated using ultrasonication and alkalinization to manipulate its characteristics toward improved synergism with FW. Experimental optimization was conducted through biochemical methane potential (BMP) assays to identify the optimum operating conditions of the pretreatment methods. The study evaluated the synergistic effects of co-digestion with raw and pretreated leachate on enhancing the performance in terms of feedstock solubilization and methane production. The BMP test demonstrated that alkalinization and ultrasonication improved the total methane generation by 35% and 27%, respectively, yielding around 397 and 375 mL CH4 per g of volatile solids. Moreover, ultrasonication and alkalinization enhanced the synergistic effects by 28% and 36%, respectively, compared to co-digestion with untreated leachate. Optimization by response surface methodology revealed that maximum performance could be achieved with leachate sonication at 212 W for 37.5 min or augmenting 788 g NaOH per kg of volatile solids. Kinetic and statistical models were derived to simulate and assess the impacts of the pretreatment parameters on the AcoD process. The results indicated that the ultrasonication energy had a higher influence on total solubility and methane production than alkaline dosage. Additionally, energy efficiency analyses were performed to examine the overall viability of the examined management approach and found that alkalinization increased the net energy efficiency by 23%, whereas ultrasonication was inefficient within the examined laboratory conditions despite the improved performance. The findings support an integrated organic waste management system where separated FW is co-treated with landfill leachate.

Process and quality evaluation of different improved composts made with a smart laboratory pilot plant

This study monitored the process and investigated the quality of compost obtained from different biomasses. Five blends of agri-food waste were composted by a laboratory pilot plant named COMPOSTER, that is designed to optimize biodegradation, and produce compost efficiently. The COMPOSTER consists of two 35-liter nearly adiabatic, aerated bioreactors that simulate an industrial process involving the typical sequence of mesophilic-thermophilic-mesophilic phases. It continuously monitors and records temperature, internal pressure, and biomass weight, while controlling and quantifying oxygen consumption and carbon dioxide emissions resulting from aerobic biodegradation. All composts were characterized for their main chemical, physical, and molecular features, as well as their suppressiveness against Fusarium oxysporum f.sp. lycopersici (FOL), tested on tomato seedlings. Optimized biodegradation yielded 50–60 % mature compost with a cumulative oxygen consumption ranging from 282 to 456 gO2 per kg of dry matter, with peaks of 2.55 gO2 per kg of volatile solids per hour, and carbon dioxide emissions of 22–36 % of the initial carbon content, with peaks of 5.89 g CO2 per kg of volatile solids per hour. Blends containing more ligno-cellulosic ingredients showed higher yields and lower CO2 emissions. Most of the nitrogen present initially was retained in the final compost; indeed, all mixtures exhibited an apparent nitrogen concentration increase due to carbon loss. Composting determined deep modifications in the molecular structure of the organic matter. 13C CPMAS-NMR and off-line thermochemolysis GC-MS analyses highlighted decomposition degree of polysaccharides and peptidic moieties, selective preservation of aliphatic and aromatic recalcitrant compounds, and optimal ongoing humification. All composts were non-phytotoxic, except for that including pepper crop residues, and all resulted rich in macro- and micro-elements for plant nutrition and proved to be active in controlling FOL disease. Compost comprising 81.2 % tomato crop waste exhibited the best growth performance and pathogen control on tomato. Mature, non-phytotoxic, nutrient-rich, and suppressive composts represent promising by-products that can be successfully recycled in agriculture, including high-value applications, leading to lower use of fertilizers and pesticides.

Sewage sludge as carbon source for polyhydroxyalkanoates: a holistic approach at pilot scale level

In the present study, polyhydroxyalkanoates (PHA) production by mixed microbial cultures (MMC) has been carried out using thermally pre-treated excess thickened waste activated sludge (WAS), applying the feast-famine approach at pilot scale. The preliminary results of WAS fermentation conducted both in mesophilic and thermophilic conditions, in combination with a thermal pre-treatment at 70 °C for 48 h, highlighted how the thermal hydrolysis has a crucial role for the solubilization of the chemical oxygen demand (COD), which allows a significant increase of the final volatile fatty acid (VFA) concentration (roughly 8.5 g CODVFA/L). Since thermophilic fermentation after thermal pre-treatment was the best performing condition, it has been applied at pilot scale in order to routinely produce VFA as precursors for the following PHA synthesis. The selection and enrichment of PHA-producing biomass was successfully established and maintained in a Sequencing Batch Reactor (SBR) during the whole experimentation period, under short hydraulic retention time (HRT; 2 days) and medium-low organic loading rate (OLR; 2.0–2.2 g COD/L d). At the end of the production process an average PHA content of 53 ± 3 %w/w was achieved. The polymer was finally extracted and recovered from the biomass using traditional chloroform and sodium hypochlorite extraction and then characterized for the quantification of thermal properties (Tm = 156.8–160.9 °C) and molecular weight (Mv = 396–405 kDa). A final overall mass balance, usually poorly reported in the literature, has been also assessed, resulting in an overall yield of 56 g PHA per kg of volatile solids (VS).

Alkaline pre-treatment (NAOH) as a strategy to increase the performance and feasibility of the anaerobic digestion of cattle slurry

ABSTRACT Dairy cattle manure with bedding (CB), including manure, urine, water, and shavings, is lignocellulosic biomass and needs to be pre-treated in anaerobic reactors to enhance biomass digestibility. This study analyzed the technical and economic feasibility of physical treatment (milling) and alkaline treatment of CB for biogas production. Pre-treatment included drying, milling, and alkaline hydrolysis at room temperature for 24 h. Maximum biogas production was determined using the biochemical methane potential (BMP) test. Physicochemical analyses were performed to characterise CB before and after pre-treatment and the BMP test. The characteristics of the lignocellulosic material were examined by scanning electron microscopy. The economic feasibility (return on investment) of each treatment (USD per ton of CB) was determined. Treatment with 3% NaOH achieved the highest biogas production (771 mL per kg of volatile solids) and was 104.5% higher than that of milling and 124.7% higher than that of chemical pre-treatment with 4% NaOH. The analysis of economic feasibility showed that the payback period of treatment with 3% NaOH was 1.4 years for scenario 1 (continuous stirred tank reactor - CSTR) and 3 years for scenario 2 (covered lagoon digester). These results demonstrate the feasibility of producing biogas as a renewable energy source via the anaerobic digestion of CB.

Possibilities of Obtaining Biogas from Manure and Amaranth

Introduction. The use of biomass allows increasing the rate of biogas formation and its specific yield. This work aims to study the kinetics of methanogenesis and determine the optimal duration of digestion and organic load, which are the main indicators of the technological process of biogas formation. Materials and Methods. The substrate (dairy manure, biomass of amaranth) was the study object. Experimental studies were carried out using a laboratory biogas plant. The computer program (certificate No. 2018662045) was used to obtain modified Gompertz models describing the kinetics of biogas formation. Based on the obtained data, the hydraulic retention time and organic loading rate (the key parameters in the design of biogas plants were determined). Results. The paper presents the experimental studies results of the biogas formation kinetics when using dry amaranth biomass. The Gompertz mathematical models were obtained. Methane-tank control parameters (hydraulic retention time and organic loading rate) were obtained for anaerobic digestion of a new substrate. Discussion and Conclusion. The use of new co-substrate Amaranthus retroflexus L. allowed increasing the specific biogas yield from dairy manure by 52.2 % and the ultrasonic pre-treatment in combination with the herbal supplement by 89.1 %. The optimal hydraulic retention time value was 10 days and organic loading rate was 4.1 kg of volatile solids per m3 of digester per day.

Biomethanation Potential (BMP) Study of Mesophilic Anaerobic Co-Digestion of Abundant Bio-Wastes in Southern Regions of Tunisia

Tunisia is a country that suffers from energy demand problems and environmental matters. Thus, Tunisian authorities desire to encourage the development of renewable energy sources, especially from biological processes, like anaerobic digestion. Therefore, this study is focused on the evaluation of biogas and bio-methane yield from the co-digestion of three available and abundant bio-wastes in the southern regions of Tunisia. The three different raw materials are an organic fraction of municipal solid waste, chicken manure, and olive mill wastewater. In this context, experimental work to evaluate the potential of biogas and bio-methane production was carried out at mesophilic temperature 35 °C and batch mode. The present work highlights the possibility of generating biogas from these organic wastes and reducing the amounts of the wastes to dispose of in landfills. The experimental study of the co-digestion process under specific conditions of carbon to nitrogen ratio (C/N), T, pH, and inoculums to substrate ratio ISR provided a high yield of net methane and net biogas, in comparison with other research works. Results showed a higher specific net methane production per kg of volatile solids, which is equal to 0.338 Nm3 methane/kg VS and 0.430 Nm3 methane/kg VS for two studied cases. The obtained volatile solids reduction was found to be 91% of the initial content, for a hydraulic retention time (HRT) of 40 days.

Study on interchangeability of seed based feedstocks for biogas production in multi-feeding mode

Biogas is an excellent renewable fuel providing gas for clean energy applications and fertilizers for organic farming. In the present study, seeds from four tree species of Acacia nilotica , Albizia lebbeck , Prosopis juliflora , and Leucaena leucocephala have been utilized for biogas production as alternative feedstocks. They have been investigated in a mixed-feeding mode in a single digester to tackle the feedstock availability and seasonality challenges. The investigations were conducted in a 300 ​L anaerobic digester for 120 days under daily feeding mode. The average specific biogas yield and specific methane yield was found to be 0.425 ​m 3 /kg of volatile solids and 0.228 ​m 3 /kg of volatile solids, respectively. The average volumetric methane content in biogas was 54.7%. This paper presents a unique study on anaerobic digestion of selected seeds in a mixed-feeding mode to provide broad opportunities for their efficient and sustainable utilization. • Interchangeability of tree species seeds explored for 120 days in the mixed-feeding mode for biogas production. • Anaerobic digestion parameters for the utilization of these seeds are investigated in detail. • An amount of 3.0–3.5 ​kg of seeds is required to produce one cubic metre of biogas. • Specific biogas yield of 0.425 ​m 3 /kg VS with methane of 54.7% and TVSMRE as 46.0% were found.

Biogas and combustion potential of fresh reed canary grass grown on cutover peatland

(1) In Finland, in recent years, the combustion of dry reed canary grass (RCG, Phalaris arundinacea) grown intensively on cutover peatlands, has decreased markedly. We therefore made experiments in two areas to assess the alternative of using freshly harvested RCG grown for biogas production on cutover peatland. We measured both biogas production and combustion energy release. (2) The experiments show that the RCG biomass yields in total solids (TS) in both areas, with two cuts a year, were surprisingly small (yields of 2.7 and 4.2 Mg ha-1 [1 Mg ha-1 = 100 g m-2 ]); having biogas and combustion potentials, on the two areas, of 277–348 dm3 kg-1 VS (volatile solids) and 14.8–16.3 MJ kg-1 TS, and 11.8–21.9 MWh ha-1 in combustion. (3) Fresh RCG may produce larger biomass yields if cut several times a year, together with lower lignin proportion, and better suitability for biogas production compared with spring harvested dry RCG. (4) For cutover peatlands there are several after-use possibilities, however, with different benefits and challenges. For example, peat soil emissions may be affected during the after-use period, and this should be considered when planning the use of cutover peatlands.

Investigating the performance of internet of things based anaerobic digestion of food waste

A pilot scale decentralised Continuously Stirred Tank Reactor (CSTR) was designed, developed and installed, with 675 L working volume, to treat food waste generated from the Asian Institute of Technology (AIT) campus community. The reactor was operated in mesophilic, anaerobic and wet condition with feedstock as food waste of 10% Total Solids (TS) content. This study aims for performance evaluation of food waste anaerobic digestion and development of remote monitoring system suitable for centralised monitoring of decentralised anaerobic digestion plants. The performance of the reactor was remotely monitored with the installation of pH, Temperature and Oxidation Reduction Potential (ORP) electrodes connected with the Programmable Logic Controller (PLC). The quality of biogas produced was monitored by online biogas analyzer system. The CSTR was operated with three different Organic Loading Rates (OLR) viz., 1, 2 and 3 kg of volatile solids per cubic meter of digester per day (kg VS/m3.d) to evaluate performance of the food waste digestion and biogas production. The average biogas yield was 0.75, 0.62 and 0.52 cubic meter per kilogram of volatile solids (m3/kg VS), with average methane yield of 0.42, 0.33 and 0.27 m3/kg VS at OLR of 1, 2 and 3 kg VS/m3.d respectively. Furthermore, it was observed that the average reduction in total solids was 70.7, 66.5 and 54.98% and average reduction in volatile solids was 78.3, 72 and 67% at OLR of 1, 2 and 3 kg VS/m3.d respectively. Internet of Things (IoT) enabled remote monitoring on real time basis and aided the centralised operator to improve the process performance resulting in better operation and maintenance of the decentralised anaerobic digestion systems.

Assessment of the effect of drying temperature and composition on the biochemical methane potential of in-house dried household food waste.

Household food waste management and treatment has been recognised as a significant issue worldwide and at a European Union level. Source-separation of household food waste following drying at source presents a viable solution to this problem. The present research aims at investigating the effect of drying of model household food waste at different temperatures (i.e. 63 ±3 °C and 83 ±3 °C) on its biochemical methane potential. The drying process was carried out using a prototype household waste dryer. The model sample consisted of 77%w/w vegetables and fruits (48%w/w and 29%w/w, respectively), 12%w/w pasta/rice, 6%w/w meat and fish, 3%w/w bread and bakery and 2%w/w dairy. Moreover, drying at the same temperatures was applied for two household food wastes samples with different composition, in order to assess the influence of the samples' composition on both the drying process and the methane generation. For all temperatures used, the higher %w/w mass reduction was observed for model waste (MD) (67.39%w/w and 75.79%w/w for 63 °C and 83 °C, respectively), then for rich-in-protein content (PRO) (66.18%w/w and 69.73%w/w for 63 °C and 83 °C, respectively) and finally for rich-in-fat content (FAT) samples (54.35%w/w and 66.31%w/w for 63 °C and 83 °C, respectively), which confirmed the effectiveness of the drying process. The biochemical methane potential experiments have confirmed that the substrate produced the highest methane yields was the FAT, producing 524.25 ±2.86 L CH4 kg-1 volatile solids.

Operational strategy of high rate anaerobic digester with mixed organic wastes: effect of co-digestion on biogas yield at full scale

ABSTRACTThe present research work is aimed at providing an economically feasible solution for the farmers to exploit the mixed organic wastes (MOW) as resources for the generation of biogas based electrical power and utilize the same for irrigation purpose to reduce the dependence on electricity board. A full scale biomethanation plant has been installed based on anaerobic gas lift reactor (AGR) technology to analyse, understand the operational parameters of anaerobic digestion and assess the performance of a high rate biomethanation plant by co-digesting the MOW such as poultry litter (PL), cattle manure (CM) and napier grass (NG) at ambient temperature. The biomethanation plant was incorporated with inline pre and post-processing unit assembly. The plant was fed with 1000 kg of MOW per day having 250 kg of total solids, about 178–200 kg of volatile solids and operated continuously for 52 weeks under ambient temperature. Electrical power generated (84.5–104 kWh/day) from biogas (65–80 m3/day) containing methane (40–48 m3/day) was used for operating the water pumps for agricultural purpose and the digestate (115–130 kg/day) was exploited as organic manure for growing crops in the same field. Napier grass was grown in the same land and other feedstocks were procured from the nearby area at the cost of $10–$15 per ton. Around 6 acres of land was being cultivated using the biogas based power generated from the MOW that was being used for growing vegetables and maize.

Energy Recovery Together with Amorphous Nanosilica Production from Rice Straw via Dry Anaerobic Digestion

Rice straw burning is the most widely used industrial process for silica production, resulting in the loss of carbohydrate energy and environmental pollution. In this study, dry anaerobic digestion was applied to convert an organic fraction of rice straw into biogas while generating a solid digestate rich in silica. The methane yield obtained from the dry digestion was 119 L per kg of volatile solids of the straw. The silica content in the ash of the digested straw was 20.7% higher than that of the ash from raw rice straw. The X-ray diffraction pattern revealed the existence of amorphous silica in the ash of the digested straw. The Fourier transform infrared analysis dispelled concerns about the addition of silica impurities by the anaerobic digestion process. The transmission electron microscopy results revealed the formation of nanosilica with particle sizes between 15 nm and 30 nm. It was concluded that high-quality nanosilica can be obtained from anaerobically digested rice straw. The application of this process can decrease the annual global greenhouse gas emissions by 10.5 million tons.

Anaerobic co-digestion of hatchery waste and wastewater to produce energy and biofertilizer - Batch phase

ABSTRACT Aiming to evaluate different wastewaters in the anaerobic co-digestion (ACoD) of hatchery wastes, a batch test was conducted in bench horizontal digesters. At the end of the process, the potential production of biogas and methane was calculated as well as the chemical composition (macro- and micronutrients) of the effluent and the concentrations of methane and carbon dioxide gas at 60 days. The monitoring of the process included observations of the reduction of the organic carbon, chemical oxygen demand, and total (TS) and volatile solids (VS), as well as the variation of pH and electrical conductivity (EC). The results showed that the mixing between the hatchery fresh waste and swine wastewater (T4) and among fresh hatchery waste, water from the first anaerobic pond of the hatchery and swine wastewater (T5) represent significant sources of renewable energy and thereby greater potential for biogas production (192.50 and 205.0 L biogas per kg of VS added to T4 and T5, respectively). The average concentration of methane in the biogas varied from 72 to 77% among the treatments. For all treatments, reductions were observed in TS and VS and increases in pH and EC. It was concluded that the energy recovery from hatchery wastes is favoured by the addition of swine wastewater in the ACoD process.

Effect of Harvest Time and Frequency on Biomass Quality and Biomethane Potential of Common Reed (Phragmites australis) Under Paludiculture Conditions

This study examined the effect of harvest time (from May to September) and dry matter partitioning on biomethane potential and methane yield per unit area of Phragmites australis cultivation under paludiculture conditions. The experimental site is part of a larger experimental platform (San Niccolo, Pisa) located within the Massaciuccoli Lake Basin in Central Italy (Tuscany, IT). The study also took into account the double cut strategy by evaluating the regrowth from June to September. Biomethane potentials ranged from 384 to 315 and from 412 to 283 NL CH4 kg VS−1 (normal liters of methane per kg of volatile solids) for leaves and stems, respectively. About digestion kinetics, maximum daily production rate (R max) was significantly affected by harvest time and not by plant partitioning. Along the harvest season, biomethane yield per unit area was mostly driven by the biomass yield showing an increasing trend from May (1659 Nm3 ha−1) to September (3817 Nm3 ha−1). The highest value was obtained with the double harvest option (4383 Nm3 ha−1), although it was not statistically different from the single harvest carried out in September. Owing to its remarkably lower yields, P. australis cannot be considered along the same lines as crops conventionally used for biogas production, but it may represent an interesting option for paludiculture cropping systems by coupling peatland restoration with bioenergy production. September harvest management seemed the most feasible option, although further investigation on crop lifespan is needed.

Process intensification with inline pre and post processing mechanism for valorization of poultry litter through high rate biomethanation technology: A full scale experience

High rate biomethanation technology based on anaerobic gas lift reactor (AGR) for the treatment of poultry litter (PL) has been demonstrated to generate biogas and digestate. The plant was installed and operated continuously for 95 weeks (September 2012 to June 2014) under ambient temperature conditions (in the range of 24–31 °C) for the treatment of 1000 kg of PL per day containing 254 kg of total solids and 220 kg of volatile solids. Biogas (68 m3/day) produced in the plant was successfully converted to electrical power (89 kWh/day) that was utilized to operate water pumps in the agricultural fields. The digestate (105 kg/day) was effectively employed in the nearby fields as an organic fertilizer. The plant was operated by establishing an intensified process mechanism incorporating inline pre and post processing unit assembly along with ammonia inhibition control mechanism. It is understood from the full scale experience of this plant that, decentralized off grid power generation from PL could be a remunerative option to poultry farmers.

Potential methane emission reductions for two manure treatment technologies

ABSTRACTThe effect of two dairy manure treatments, solid–liquid separation (SLS) and anaerobic digestion (AD), on methane potential and the speed of production was evaluated. Assays were performed in the lab to measure methane (CH4) production over 202 d from dairy manure samples taken before and after each treatment. Compared to raw manure, CH4 emissions on a per-L basis were reduced 81% by SLS and 59% by AD, on average. The mean (SD) ultimate CH4 emission potential (B0) per kg of volatile solids (VS) was 247 (8) L CH4 kg−1 VS for raw manure, 221 (9) L CH4 kg−1 VS for separated liquid, and 160 (4) L CH4 kg−1 VS for anaerobic digestate. Thus, SLS reduced the B0 of the liquid fraction by 11% and AD reduced B0 by up to 35% compared to raw manure. Manure treatment affected the speed of CH4 production: SLS increased the CH4 production rate and thus separated liquid manure was the fastest to produce 90% of the ultimate CH4 production. Therefore, both the speed of degradation and B0 should be considered when assessing these techniques for farm-scale manure storages, because actual emission reductions will depend on storage conditions.

Energy Generation from Horse Husbandry Residues by Anaerobic Digestion, Combustion, and an Integrated Approach

Horse-related activities often occur close to urban areas, where acreage for horse manure disposal is scarce, and subsequently alternative recovery options are necessary. Anaerobic digestion, direct combustion, and the integrated generation of solid fuel and biogas from biomass (IFBB) process are potential techniques focusing on energy provision. In this study, samples of horse faeces were analysed for chemical composition as pure feedstock and in mixture with straw or wood shavings, as well as for energy yield by biogas production or from combustion of solid fuel. It was observed that chemical properties of faeces, in a mixture with wood shavings, were promising for direct combustion, but achieved low methane yields. The methane yield of pure faeces and the straw mixture was 222.33 ± 13.60 and 233.01 ± 31.32 lN·kg-1 volatile solids (VS)added, respectively. The IFBB process divided the biomass into a press cake with reduced mineral concentration and a press fluid. Methane yields of press fluids were low (108.2 lN·kg-1 VSadded, on average). The chemical composition of the press cake allowed for combustion and led to a higher gross energy potential than anaerobic digestion (two-fold higher for pure manure and the mixture with straw, and five-fold higher for the mixture with shavings). Consequently, the gross energy potential of IFBB is higher compared to anaerobic digestion, however it should be noted that local conditions might favour the implementation of anaerobic digestion.

Exploitation of rapid acidification phenomena of food waste in reducing the hydraulic retention time (HRT) of high rate anaerobic digester without conceding on biogas yield

The aim of the present work was to study and infer a full scale experience on co-digestion of 1000kg of FW (400kg cooked food waste and 600kg uncooked food waste) and 2000L of rice gruel (RG) on daily basis based on a high rate biomethanation technology called “Anaerobic gas lift reactor” (AGR). The pH of raw substrate was low (5.2–5.5) that resulted in rapid acidification phenomena with in 12h in the feed preparation tank that facilitated to obtain a lower hydraulic residence time (HRT) of 10days. At full load, AGR was fed with 245kg of total solids, 205kg of volatile solids (167kg of organic matter in terms of chemical oxygen demand) which resulted in the generation of biogas and bio manure of 140m3/day and 110kg/day respectively. The produced biogas replaced 60–70kg of LPG per day.

Estimation of Methane Emissions from Slurry Pits below Pig and Cattle Confinements.

Quantifying in-house emissions of methane (CH4) from liquid manure (slurry) is difficult due to high background emissions from enteric processes, yet of great importance for correct estimation of CH4 emissions from manure management and effects of treatment technologies such as anaerobic digestion. In this study CH4 production rates were determined in 20 pig slurry and 11 cattle slurry samples collected beneath slatted floors on six representative farms; rates were determined within 24 h at temperatures close to the temperature in slurry pits at the time of collection. Methane production rates in pig and cattle slurry differed significantly at 0.030 and 0.011 kg CH4 kg-1 VS (volatile solids). Current estimates of CH4 emissions from pig and cattle manure management correspond to 0.032 and 0.015 kg CH4 kg-1, respectively, indicating that slurry pits under animal confinements are a significant source. Fractions of degradable volatile solids (VSd, kg kg-1 VS) were estimated using an aerobic biodegradability assay and total organic C analyses. The VSd in pig and cattle slurry averaged 0.51 and 0.33 kg kg-1 VS, and it was estimated that on average 43 and 28% of VSd in fresh excreta from pigs and cattle, respectively, had been lost at the time of sampling. An empirical model of CH4 emissions from slurry was reparameterised based on experimental results. A sensitivity analysis indicated that predicted CH4 emissions were highly sensitive to uncertainties in the value of lnA of the Arrhenius equation, but much less sensitive to uncertainties in VSd or slurry temperature. A model application indicated that losses of carbon in VS as CO2 may be much greater than losses as CH4. Implications of these results for the correct estimation of CH4 emissions from manure management, and for the mitigation potential of treatments such as anaerobic digestion, are discussed.

Optimization of solid content, carbon/nitrogen ratio and food/inoculum ratio for biogas production from food waste.

Biogas production from food waste has been used as an efficient waste treatment option for years. The methane yields from decomposition of waste are, however, highly variable under different operating conditions. In this study, a statistical experimental design method (Taguchi OA9) was implemented to investigate the effects of simultaneous variations of three parameters on methane production. The parameters investigated were solid content (SC), carbon/nitrogen ratio (C/N) and food/inoculum ratio (F/I). Two sets of experiments were conducted with nine anaerobic reactors operating under different conditions. Optimum conditions were determined using statistical analysis, such as analysis of variance (ANOVA). A confirmation experiment was carried out at optimum conditions to investigate the validity of the results. Statistical analysis showed that SC was the most important parameter for methane production with a 45% contribution, followed by F/I ratio with a 35% contribution. The optimum methane yield of 151 l kg-1 volatile solids (VS) was achieved after 24 days of digestion when SC was 4%, C/N was 28 and F/I were 0.3. The confirmation experiment provided a methane yield of 167 l kg-1 VS after 24 days. The analysis showed biogas production from food waste may be increased by optimization of operating conditions.