Key Source Areas Research Articles

Simulation and attribution analysis of agricultural nitrogen non-point source pollution in Huang-Huai-Hai Plain based on the InVEST model

The study of agricultural non-point source pollution (ANNSP) patterns and driving mechanisms is crucial for regional ecological management. This paper evaluates the sources of ANNSP in the Huang-Huai-Hai Plain for the years 2000, 2010, and 2020 using the source list method. Additionally, nitrogen source data for the InVEST model were supplemented and adjusted, and the nitrogen output load and proportions derived in farmland from both methods were compared. The temporal and spatial distribution of nitrogen emission intensity was analyzed based on InVEST model outputs. Key source areas were identified through hotspot analysis, and spatial driving factors were examined using geodetector. Key findings reveal: 1) While the source list method estimated a higher nitrogen output load, both methods concurred on the proportion of agricultural nitrogen. The main sources of nitrogen input were overuse of fertilizer and livestock breeding. 2) Over this period, nitrogen emission intensity declined, exhibiting a distinct spatial pattern of “northwest low, southeast high.” 3) The extent of critical source areas underwent a dynamic shift, initially contracting before expanding. 4) Rainfall emerged as the primary driver of spatial variability in agricultural TN emission intensity. These insights offer critical reference points for achieving efficient ANNSP management in the Huang-Huai-Hai Plain.

Analysis of total nitrogen pollution load and identification of key pollution sources in Futuan River basin based on SWAT model

In order to identify the key source area of the Futuan River basin, the Futuan River basin is taken as the target area, establishes the Soil Water Assessment Tool (SWAT) model, simules the runoff and total nitrogen pollution process in the basin, and analyzes the spatiotemporal characteristics of total nitrogen pollution. The key source areas of total nitrogen pollution in the basin were identified by the cumulative load curve method. The results show that the total nitrogen pollution load in the Futuan River basin presents obvious seasonal distribution characteristics. The subbasins with high load intensity of total nitrogen into the river are mainly in the middle and upper reaches of the Futuan River.

Distribution characteristics of non-point source pollution of TP and identification of key source areas in Nanyi Lake (China) Basin: based on InVEST model and source list method.

The Nanyi Lake basin, located in the middle and lower reaches of the Yangtze River, is a crucial component of the Yangtze River ecosystem. Excessive phosphorus levels lead to eutrophication in rivers and lakes. This study aims to enhance the identification efficiency of key source areas for non-point source pollution of total phosphorus (TP) in the Nanyi Lake Basin and improve decision-making regarding the treatment of these areas. The study employs the InVEST model and utilizes GIS spatial hot spot analysis to identify key source areas of agricultural TP non-point source pollution. The accuracy of the InVEST model's simulation results was verified using the source list method. The findings indicate that paddy fields serve as the primary pollution source. TP non-point source pollution in Nanyi Lake is influenced by pollution sources, pollution load filtration rate, and potential TP runoff mass concentration. Different pollution sources correspond to distinct key source areas, and the pollution generated by these sources in different administrative regions, ultimately affecting the lake, varies as well. The InVEST model demonstrates great applicability in regions where agricultural TP is the primary pollution source. For the Nanyi Lake basin, which predominantly experiences agricultural TP non-point source pollution, a combination of the InVEST model and the source list method is recommended. The InVEST model serves as the primary tool, while the source list method supplements it. This approach not only compensates for any limitations of the InVEST model's simulation results but also avoids unnecessary economic waste. The outcomes of this study contribute to a deeper scientific understanding of TP pollution in the Nanyi Lake Basin. They also aid in effectively identifying key source areas and formulating appropriate measures based on the pollution characteristics, thereby providing guidance for non-point source pollution control in the basin.

Unraveling spatial patterns and source attribution of nutrient transport: Towards optimal best management practices in complex river basin

A comprehensive understanding of nutrient transport patterns and clarification of pollutant sources' load contributions are critical prerequisites for developing scientific pollution control strategies in complex river basins. Here, we focused on the Minjiang River Basin (MRB) and employed the Soil and Water Assessment Tool (SWAT) model to systematically investigate the nitrogen (N) and phosphorus (P) loads from both point and non-point sources. Results revealed that the key source areas of N and P pollution in the MRB were predominantly located along the riverbanks, influenced by a combination of sediment, precipitation, agricultural activities such as fertilization. Our analysis indicated that soil nutrient loss, fertilization, and livestock farming were the major contributors to N and P inputs, accounting for over 70 % of the total input, followed by rural residential and urban point sources. Based on the identification of non-point source pollution as the primary load source, a multi-objective optimization was conducted using response surface methodology (RSM) coupled with the non-dominated sorting genetic algorithm-II (NSGA-II), resulting in the identification of optimal best management practices (BMPs) that achieve a reduction of 40.04 % in N load, 39.22 % in P load, and a net economic benefit of −1.13 billion yuan per year. Compared to the RSM and automated optimization results, the proposed management measures exhibited significant improvements in N and P load reduction and net benefits. Overall, the findings provide important insights for formulating agricultural management policies in the MRB and offering valuable implications for pollution management in other complex river basins.

TP Concentration Inversion and Pollution Sources in Nanyi Lake Based on Landsat 8 Data and InVEST Model

Phosphorus is a limiting nutrient in freshwater ecosystems. Therefore, it is of great significance to use remote sensing technology to estimate the Total phosphorus (TP) concentration in the lake body and identify the contribution of TP inflow load in the surrounding area of the lake body. In this study, two main frameworks (empirical method and machine learning algorithm) for TP estimation are proposed and applied to the development of the Nanyi Lake algorithm. Based on the remote sensing data and ground monitoring data, the results obtained by the two main algorithms are compared to explore whether the machine learning algorithm has better performance than the empirical method in the TP inversion prediction of Nanyi Lake. The Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) model was used to simulate the TP inflow load in the Nanyi Lake Basin and determine the key pollution source areas. The results show that the accuracy of the machine learning algorithm is higher than that of the empirical method and has better performance. Among the four machine learning algorithms—support vector machines (SVR), artificial neural network (BP), extreme gradient boosting algorithm (XGBoost) and random forest regression (RF)—the TP concentration inversion model established by the XGBoost algorithm is more accurate and has strong spatiotemporal heterogeneity. The simulation results in the southern and northeastern parts of the Nanyi Lake Basin contribute the most to the pollution load of the lake area, and the simulation results can provide direction for the effective prevention and control of Nanyi Lake, help to further effectively identify the key source areas of TP pollution in the water body of Nanyi Lake, and provide a meaningful scientific reference for water quality monitoring and management, to comprehensively improve the water quality of Nanyi Lake.

Hydrological and water quality simulation and future runoff prediction under CMIP6 scenario in the upstream basin of Miyun Reservoir

AbstractWater resources are a key factor restricting human survival and social and economic development. The Miyun Reservoir, which is the only surface drinking water source in Beijing and the water storage reservoir of the South-to-North Water Diversion Project, plays a decisive role in ensuring water-use sustainability of the capital. This study focused on the Baihe River Basin, which is one of the important inflows of the Miyun Reservoir. The mathematical data on the climate and hydrological changes of the Baihe River Basin over the past 30 years were obtained, and the evolution law of the Baihe River runoff and its influencing factors was analyzed. Our analysis used the data obtained via multi-source meteorology to establish the Soil and Water Assessment Tool (SWAT) model of the Baihe River Basin. Sequential Uncertainty Fitting version 2 (SUFI-2) and Generalized Likelihood Uncertainty Estimation (GLUE) were used to simulate runoff from 1990 to 2017 on a monthly scale, along with sediment, total nitrogen (TN), and total phosphorus (TP) contents from 1990 to 2010. Then, the parameter uncertainty of the SWAT model and the applicability of the SWAT model in the Baihe River Basin were determined. The land-use transfer matrix showed that land-use changes are complex and the transformation forms are diverse. The simulation results showed that the transformation of land-use patterns in 1990 and 2010 had slight impacts on the hydrologic and water quality of the basin. By identifying the key source areas of non-point source pollution in the basin, the impacts of three management measures on the hydrological and water quality of the basin were simulated. The results showed that the reductions in flow rates, sediment content, TN, and TP (4.37, 31.93, 23.13, and 35.30%, respectively) obtained through terrace engineering were significantly better than those acquired via stubble mulch and contour planting. Additionally, this study uses the Sixth International Coupling Mode Comparison Program (CMIP6) climate change scenario and the BCC-CSM2-MR climate model coupled with the corrected SWAT model to predict future runoff, thereby providing references and suggestions for managing the Baihe River Basin and the Miyun Reservoir.

Comparative Water Environment Simulation Study of Two Typical Models with BMPs in a Karst Basin

Carbonate rocks are widely distributed in southwest China, forming a unique karst landscape. The Lijiang River Basin provides a typical example of an area with concentrated karst. Research on the laws of hydrology and water quality migration in the Lijiang River Basin is important for the management of the water resources of Guilin City and similar areas. In this study, we combined three meteorological data with the soil and water assessment tool (SWAT) model and the hydrological simulation program-Fortran (HSPF) model to simulate the hydrological and water quality processes in the Lijiang River Basin separately. We chose the Nash–Sutcliffe efficiency (NSE) coefficient, coefficient of determination (R2), root mean square error-observations standard deviation ratio (RSR), and mean absolute error (MAE) as the metrics used to evaluate the models. The results, combined with the time-series process lines, indicated that the SWAT model provides a more accurate performance than the HSPF model in streamflow, ammonia nitrogen (NH3-N), and dissolved oxygen (DO) simulations. In addition, we divided the karst and non-karst areas, and we analyzed the differences between them in water balance, sediment transport, and pollution load. We further identified the key source areas of pollution load in the Lijiang River Basin, evaluated the pollution reduction effect of best management practices (BMPs) on surface source pollution, and proposed some pollution control countermeasures. Each scenario, especially returning farmland to forest and creating vegetation buffer zones, reduces the NH3-N and DO pollution load.

Output Characteristics of Nitrogen and Phosphorus from Non-Point Source Pollution of Typical Land Use in A Micro-Watershed in Hilly Red Soil Region

Scientific identification of runoff output characteristics of different land use patterns is the premise of controlling non-point source pollution in watersheds. The hydrology and output process of non-point source pollutants of forest, planting, and construction land with different rainfall characteristics were observed using a micro-watershed in a low mountain and hilly region of Southern China. The results showed that land use affected the hydrological characteristics and water quality processes of runoff. The characteristics of runoff generation time and cumulative rainfall under typical rainfall conditions were as follows:construction land(9 min, 2.0 mm), planting land(35 min, 11.4 mm), and forest land(108 min, 24 mm). There were significant differences in the three land use types in the pollution output process characteristics, such as pollutant concentration of total suspended matter(TSS), total nitrogen(TN) and phosphorus(TP), their components, N/P ratio change, and output intensity. Under typical rainfall, different land use types had similar pollution output stages, the mass concentrations of TSS, TN, and TP in the initial runoff were high, and then gradually stabilized. In addition, the first 30 min of the flow generation process contributed to the TSS, TN, and TP loads within the 23%-43% range. At the annual scale, there were significant differences between the contribution rate of each land use type to TN and TP load and ratio per unit area; the highest contribution to total pollution load was planting land(57% and 45%), while the highest in pollution load per unit area was construction land(9.50-12.50). The results also showed that the distribution of key non-point source areas had different spatial and temporal dynamics, which was comprehensively determined by the land use types in catchment units, the characteristics of annual rainfall, among other factors. With the increase in rainfall, the main contribution non-point source pollution in the micro-watershed changed from construction land to planting land. Targeted ecological interception strategies should be implemented based on the distribution characteristics of key source areas and characteristics of underlying surface runoff production process.

Simulation of nitrogen and phosphorus pollution in typical agricultural and forested basins as well as relevant reduction effect based on SWAT model

Abstract Non-point source nitrogen and phosphorus pollution is a critical threat to aquatic ecosystems and a potential risk to drinking water safety. To precisely control nitrogen and phosphorus pollution in the river basin, in this study, we identified key pollution areas of the river basin, analyzed the main characteristics of pollution sources as well as their contribution to the river basin pollution, and conducted simulation analysis on reduction measures based on the SWAT model. The results showed the following. (1) The simulation effect of the calibrated model was good, and sub-basins 3, 39 and 96 were the key source areas, the main sources of pollution were combined pollution from livestock and poultry breeding and planting industry. (2) Crops had the largest input and output for both nitrogen and phosphorus, the output of which was 6,137.8 t/a and 562.4 t/a respectively. The urban point sources had the highest output rates of nitrogen and phosphorus, 75.7% and 67.5% respectively. (3) With the optimal combination of reduction measures, nitrogen and phosphorus were reduced by 1,438.9 t and 85.3 t respectively, i.e., the reduction rates were the highest. The reduction effect for total nitrogen was better than that for total phosphorus.

Identifying Key Potential Source Areas for Ambient Methyl Mercaptan Pollution Based on Long-Term Environmental Monitoring Data in an Industrial Park

Precise source identification for ambient pollution incidents in industrial parks were often difficult due to limited measurements. Source area analysis method was one of the applicable source identification methods, which could provide potential source areas under these circumstances. However, a source area usually covered several sources and the method was unable to identify the real one. This article introduces a case study on the statistical source identification of methyl mercaptan based on the long-term measurements, in 2014, in an industrial park. A procedure for statistical source area analysis was established, which contains independent pollution episode extraction, source area calculation scenario definition, meteorological data selection, and source area statistical analysis. A total of 414 violation records were detected by five monitors inside the park. Three kinds of calculation scenarios were found and, finally, three key source areas were revealed. The typical scenarios of source area calculations were described in detail. The characteristics of the statistical source areas for all pollution episodes were examined. Finally, the applicability of the method, as well as the source of uncertainties, was discussed. This study shows that more concentrated source areas can be identified through the statistical source area method if several excessive emission sources exist in an industrial park.

Provenance of Tertiary volcanoclastic sediment in NW Thrace (Bulgaria): Evidence from detrital amphibole and pyroxene geochemistry

Detrital heavy mineral and bulk rock geochemistry and a review of sandstone petrographic data have been used to investigate the post-collisional effusive magmatism that followed the closure of the Vardar Ocean and the generation of volcanic sediments in a complex and compositionally variable volcanic region. Available petrographic data gives evidence of contributions from three key source areas corresponding to the three main tectonic units: the structurally lower Gneiss–Migmatite Complex (Byala Reka-Kechros and Kesebir-Kardamos domes) and the upper Variegated (Kimi) Complex, both fringed by the low-to-medium-grade Mesozoic rocks of the Circum-Rhodope Belt. Besides the deposition of siliciclastic material, volcanic contributions from both, intermediate and acid products represent an important source of sediment in the area. Despite dominant intermediate to acid volcanic products, volcanic lithic fragments in sandstones (microlithic, lathwork and brown vitric textures) indicate main inputs from intermediate and basic-intermediate products generating questions on the interpretation of volcanic detritus in reconstruction of provenance. Detrital amphibole and pyroxene chemistry is used to characterise the supply of volcanic material as well as the dispersal mechanisms and understand the role played by each of the volcanic centers present in the area in the infill of the north-western Thrace basin. Amphibole chemistry reveals high compositional heterogeneity according to both compositional variability of the numerous volcanic centres active at the time of deposition and presence of metamorphic amphibole. 4Al and AlT apfu values indicate that most of the amphiboles from the NERZ are not of volcanic origin and their presence can only be attributed to the numerous amphibolite facies metamorphic rocks abundantly documented in the area. Detrital amphibole compositions from the ZKVS indicate major contributions from the Iran Tepe and Zvedzel volcanoes. Analysed detrital clinopyroxenes from the NERZ are mostly diopside–augite, with no hedenbergite or Fe–augite detected. The 4Al/6Al ratio is comparable with compositions of volcanic pyroxenes from the Momchilgrad–Arda (ZKVS) region and products from the pre-caldera phase of the Borovitza.

Petrological, Geochemical, and Statistical Analysis of Eocene-Oligocene Sandstones of the Western Thrace Basin, Greece and Bulgaria

Abstract The Rhodopian Orogen developed since the Late Cretaceous–early Eocene during accretionary processes following the closure of the Vardar ocean basin, a branch of Neotethys. Through a multidisciplinary approach, including sandstone petrology and geochemistry of the clastic and volcanoclastic sediments, we reconstruct the unroofing history of the Rhodopian orogen and characterize the formation and the evolution of the western portions of the Thrace basin, in Greece and Bulgaria, between the late Eocene and Oligocene. Detrital modes of 127 sandstone samples provide evidence of three distinctive petrofacies: quartzolithic, quartzofeldspathic, and volcanoclastic. The petrographic composition gives evidence of contributions from three key source areas corresponding to the three main tectonic units: the Circum-Rhodope Belt, the Variegated Complex (ultramafic complex), and the Gneiss–Migmatite Complex. The three petrofacies reflect multiple provenance from different tectonic settings as they evolve from quartzolithic to quartzofeldspathic to volcanoclastic, corresponding to collisional orogen, crustal block uplift, and volcanic arc settings, respectively. Geochemical data on major elements and trace elements are used to discuss the efficacy of tectonic-setting discrimination diagrams and compare them to the Dickinson model as well as to distinguish and characterize (i) petrographically homogeneous gneiss-supplied subbasins and (ii) volcanic contributions to sandstone composition. Multivariate statistical techniques are used to unravel the complex web of factors controlling sediment composition. Biplot analysis highlights the influence of two independent processes: (1) mixing between carbonate and silicate phases, and (2) evolution from mafic to felsic source rocks. The latter indicates progressively increasing supply rates from deeper crustal levels. The compositional evolution of the sandstone suites of Thrace basin in NE Greece and SE Bulgaria is strictly related to various geodynamic stages of the Rhodope region. Provenance analysis of Thrace sandstones provide an example of the changing nature of orogenic belt sand associate basins through time, and may contribute to the general understanding of similar geodynamic settings.

Unravelling provenance from Eocene–Oligocene sandstones of the Thrace Basin, North‐east Greece

AbstractNew sandstone petrology and petrostratigraphy provide insights on Palaeogene (Middle Eocene to Oligocene) clastics of the Thrace Basin in Greece, which developed synchronously with post‐Cretaceous collision and subsequent Tertiary extension. Sandstone petrofacies are used as a tool to unravel complex geodynamic changes that occurred at the southern continental margin of the European plate, identifying detrital signals of the accretionary processes of the Rhodope orogen, as well as subsequent partitioning related to extension of the Rhodope area, followed by Oligocene to present Aegean extension and wide magmatic activity starting during the Early Oligocene. Sandstone detrital modes include three distinctive petrofacies: quartzolithic, quartzofeldspathic and feldspatholithic. Major contributions are from metamorphic basement units, represented mostly by low to medium‐grade lithic fragments for the quartzolithic petrofacies and high‐grade metamorphic rock fragments for the quartzofeldspathic petrofacies. Volcaniclastic sandstones were derived from different volcanic areas, with a composition varying from dominantly silicic to subordinate intermediate products (mainly rhyolitic glass, spherulites and felsitic lithics). Evolution of detrital modes documents contributions from three key source areas corresponding to the two main crystalline tectonic units: (i) the Variegated Complex (ultramafic complex), in the initial stage of accretion (quartzolithic petrofacies); (ii) the Gneiss–Migmatite Complex (quartzofeldspathic petrofacies); and (iii) the Circum‐Rhodope Belt. The volcaniclastic petrofacies is interbedded with quartzofeldspathic petrofacies, reflecting superposition of active volcanic activity on regional erosion. The three key petrofacies reflect complex provenance from different tectonic settings, from collisional orogenic terranes to local basement uplift and volcanic activity. The composition and stratigraphic relations of sandstones derived from erosion of the Rhodope orogenic belt and superposed magmatism after the extensional phase in northern Greece provide constraints for palaeogeographic and palaeotectonic models of the Eocene to Oligocene western portions of the Thrace Basin. Clastic detritus in the following sedimentary assemblages was derived mainly from provenance terranes of the Palaeozoic section within the strongly deformed Rhodope Massif of northern Greece and south‐east Bulgaria, from the epimetamorphic units of the Circum‐Rhodope Belt and from superposed Late Eocene to Early Oligocene magmatism related to orogenic collapse of the Rhodope orogen. The sedimentary provenance of the Rhodope Palaeogene sandstones documents the changing nature of this orogenic belt through time, and may contribute to a general understanding of similar geodynamic settings.

Context-dependent pattern and process: the distribution and competitive dynamics of an invasive grass, Brachypodium sylvaticum

Brachypodium sylvaticum, or false brome, a recent invader of North America, has spread rapidly following establishment in Oregon in 1939 and is now colonizing at least five US states. To understand how ecological processes and environmental context interact to facilitate invasion, we combined a GIS analysis of spatial patterns of invasion with a greenhouse competition experiment under two light and two nutrient levels, and a field competition-removal experiment. Brachypodium sylvaticum was concentrated along human-use corridors and in forests, where our experiments indicate it is a better competitor than co-occurring grasses. Forested areas near trails require the greatest focus for detection and control because the species’ dual propensities to establish and thrive in these locations may make them key source areas for further invasion. Our methodology demonstrates how understanding both the patterns and processes of invasion enables the prescription of context-specific remedial actions.

Role of eolian dust deposits in landscape development and soil degradation in southeastern Australia

Eolian dust plays a significant role in landscape development and landscape processes in Australia. Thin dust mantles, rarely exceeding 3 m in thickness, have been identified across many parts of the Australian landscape, particularly in southeastern Australia. The nature and properties of these dust materials can have a major influence on environmental degradation processes such as salinisation and soil erosion. Despite the existing body of research regarding this topic, there are still conflicting views about the likely sources, transport modes and properties of eolian dust in the Australian landscape. The aim of this review is to synthesise much of the available information and put forward a working hypothesis for the distribution and fundamental properties of dust deposits in southeastern Australia. A conceptual model describing the various dust sources and sinks, and the modes of transport of dust materials both into and out of these source areas, is introduced. The model identifies key source areas, such as the alluvial and lacustrine environments of the Lake Eyre and Murray–Darling Basins, and sinks, such as the Eastern Highlands. Transport rates and paths for eolian-dust materials across the Australian continent are also outlined. The model places particular emphasis on the recycling of dust, whereby sediments sourced from the Eastern Highlands are transported westward via the major alluvial networks, and deposited on floodplains or in terminal drainage systems. These sediments are then available to be reworked into local eolian landforms prior to re-entrainment of the finer materials in the easterly dust pathway. The characteristics of deposited eolian sediments are then outlined in detail, focusing particularly on their particle-size distribution, mineralogical composition, and geophysical and geochemical properties. The review also presents data and images of dust materials sampled from source areas, sink areas, as well as materials that have been deposited by modern dust events. Finally, the role of dust materials in land-degradation processes, particularly soil erosion, is discussed. The degree of reworking of the eolian sediments, the extent of leaching and the level of sodicity are all important in determining soil structural stability and hence erosion potential of these materials.