Ferric Oxide Research Articles

A novel chitosan and polyferric sulfate composite coagulant for biogas slurry pretreatment by simultaneous flocculation and floatation: Performance and underlying mechanisms

Biogas slurry from anaerobic digestion is rich in nutrients but has not been fully utilized due to a high content of suspended solids (SS) causing clogging during agricultural irrigation. This study aimed to evaluate the performance of a novel chitosan and polyferric sulfate (CTS-PFS) composite coagulant for simultaneous flocculation and floatation to enhance SS removal while preserving nutrients in biogas slurry. Orthogonal method was used for experimental design to determine the optimal synthesis and operational conditions of CTS-PFS. Results show that CTS-PFS outperformed individual CTS and PFS coagulant in terms of SS removal and nutrient (nitrogen, phosphorus, and potassium) preservation. Compared to individual CTS and PFS coagulation, the combination of CTS and PFS at the mass ratio of 1:6 showed significantly higher performance by 41.5 % increase in SS removal and 5.2 % reduction in nutrient loss. The improved performance of CTS-PFS was attributed to its formation of polynuclear hydroxyl complexes with ferric oxide groups (e.g. Fe-OH, Fe-O-Fe, Fe-OH-Fe and COO-Fe) to strengthen charge neutralization and adsorption bridging. Data from this study further confirm that CTS-PFS enhanced the removal of small suspended particles and dissolved organic matter in the molecular weight range of 0.4–2.0 kDa and preserved ammonia and potassium better in biogas slurry. Bubbles were generated as hydrogen ions from coagulant hydrolysis interacted with bicarbonate and carbonate in biogas slurry for removing the produced flocs by floatation. Floc flotation was more effective in CTS-PFS coagulation due to the significant production of uniform bubbles, evidenced by the reduction in the viscosity of biogas slurry.

Adsorption of fast green dye onto Fe3O4 MNPs and GO/Fe3O4 MNPs synthesized by photo-irradiation method: Isotherms, thermodynamics, kinetics, and reuse studies

In this study, the adsorption of Fast Green dye (FGD) on the surface of ferrous ferric oxide Fe3O4 MNPs and Graphene oxide Nano-Sheets/ferrous ferric oxide GO/Fe3O4 MNPs as adsorbents was examined. The photo-irradiation method was successfully used to synthesize Fe3O4 MNPs and GO/Fe3O4 MNPs using UV lamp. Raman spectroscopy was used to characterize the GO and GO/ Fe3O4 MNPs. XRD, FESEM, and EDX were used to characterize the Fe3O4 MNPs and GO/ Fe3O4 MNPs. Optimal adsorption conditions were studied, including a contact time of 60 min, MNPs amount of 0.05 g, pH 2, FGD concentration of 10 mg/L, and temperature of 308 K. Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich (D-R) isotherm models were used to fit the experimental equilibrium data at five different temperatures (288, 298, 308, 318, and 328 K). It was noticed that FGD adsorption on Fe3O4 MNPs and GO/ Fe3O4 MNPs is consistent with the Freundlich model at 308 K. The PSO rate kinetics suggests that both MNPs are promising materials for the removal of FGD from aqueous solutions. Thermodynamic studies showed that the adsorption processes are non-spontaneous on both MNPs surfaces, endothermic for Fe3O4 MNPs, and exothermic for GO/ Fe3O4 MNPs. All the results confirm that Fe3O4 MNPs and GO/ Fe3O4 MNPs have the potential to be efficient, low-cost, reusable, and stable adsorbents for the removal of FGD from aqueous solutions.

Facile fabrication of 3D-α-Fe2O3@2D-g-C3N4 heterojunction composite materials: Effect of iron oxide loading on the electrochemical performance

Designing heterojunction nanocomposites is crucial for optimizing supercapacitor electrodes. This study addresses the challenge by introducing a facile synthesis method for creating 3D-α-Fe2O3@2D-g-C3N4 heterojunctions through a bulk carbon nitride-assisted hydrothermal process. During this process, the growth of ferric oxide particles coincides with the exfoliation and deposition of carbon nitride, leading to simultaneous structural changes in both iron oxide and carbon nitride phases. The resulting composite's properties strongly correlate with the iron oxide loading. Comprehensive characterization using XRD, FTIR, SEM-EDAX, XPS and TEM identified three distinct structures for α-Fe2O3/g-C3N4 composites based on iron oxide loading: low, medium, and high. The medium-loaded sample demonstrated superior electrochemical performance, attributed to better interfacial contact and the formation of 3D-Fe2O3@2D-g-C3N4 heterojunctions. This composite, with an optimized 22 wt% iron oxide loading, exhibited a maximum specific capacitance of 925.1 Fg−1 at 5 mVs−1 and 498.6 Fg−1 at 6 Ag−1 in charge-discharge analysis, with stable performance over 2000 cycles. Overall, this research presents an enhanced hydrothermal method for facile preparation of effective α-Fe2O3/g-C3N4 heterojunction materials.

Dissipative heat transfer on MHD micropolar hybrid nanofluid flow through infinite parallel squeezing plates

The hybrid nanoparticles suspended in an ethylene glycol water mixture are modeled as micropolar nanofluids. Studying the properties of such a mixture through a squeezing channel is vital in heat exchangers and as a cooling agent in producing sheets out of molten solids. The study aims to regulate the heat transfer rate through a hybrid nanofluid of carbon nanotubes and ferrous oxide nanoparticles immersed in ethylene glycol water. The motion of the fluid and the heat transfer with the plates are studied through the Navier-Stokes equation and the first law of thermodynamics by assuming that the base fluid has micropolar fluid properties. Apart from the usual viscous dissipation, heat dissipation due to the fluid’s micropolar nature is vigorously studied by solving the governing equations through a shooting technique with Runge-Kutta 4th-order algorithm. The results of the current study are compared against the ones with earlier studies as exceptional cases, and are very close. It is noticed that an increase in the micropolar viscosity naturally lowers the momentum in the radial direction and, at the same time, it enhances the axial momentum due to squeezing phenomena. Further, an escalating behavior is noticed in both temperature and microrotation, with an increase in micropolar parameters due to the squeezing force.

A Phosphorylated Dendrimer-Supported Biomass-Derived Magnetic Nanoparticle Adsorbent for Efficient Uranium Removal.

A novel biomass-based magnetic nanoparticle (Fe3O4-P-CMC/PAMAM) was synthesized by crosslinking carboxymethyl chitosan (CMC) and poly(amidoamine) (PAMAM), followed by phosphorylation with the incorporation of magnetic ferric oxide nanoparticles. The characterization results verified the successful functionalization and structural integrity of the adsorbents with a surface area of ca. 43 m2/g. Batch adsorption experiments revealed that the adsorbent exhibited a maximum adsorption capacity of 1513.47 mg·g-1 for U(VI) at pH 5.5 and 298.15 K, with Fe3O4-P-CMC/G1.5-2 showing the highest affinity among the series. The adsorption kinetics adhered to a pseudo-second-order model (R2 = 0.99, qe,exp = 463.81 mg·g-1, k2 = 2.15×10-2 g·mg-1·min-1), indicating a chemically driven process. Thermodynamic analysis suggested that the adsorption was endothermic and spontaneous (ΔH° = 14.71 kJ·mol-1, ΔG° = -50.63 kJ·mol-1, 298. 15 K), with increasing adsorption capacity at higher temperatures. The adsorbent demonstrated significant selectivity for U(VI) in the presence of competing cations, with Fe3O4-P-CMC/G1.5-2 showing a high selectivity coefficient. The performed desorption and reusability tests indicated that the adsorbent could be effectively regenerated using 1M HCl, maintaining its adsorption capacity after five cycles. XPS analysis highlighted the role of phosphonate and amino groups in the complexation with uranyl ions, and validated the existence of bimodal U4f peaks at 380.1 eV and 390.1 eV belonging to U 4f7/2 and U 4f5/2. The results of this study underscore the promise of the developed adsorbent as an effective and selective material for the treatment of uranium-contaminated wastewater.

Control of phosphorus release from sediment by the combined use of Elodea nuttallii, hydrous ferric oxide, zeolite and calcite: Efficiency, mechanism and response of bacterial communities

The effectiveness of Elodea nuttallii combined with a mixture of hydrous ferric oxide, zeolite and calcite (HZC) to reduce the internal loading of phosphorus (P) from sediment and its mechanism were studied, and the effect of Elodea nuttallii combined with HZC on the composition and function of the microbial communities in the surface sediment was also investigated. The results showed that the combination utilization of Elodea nuttallii and HZC can decrease the risk of phosphorus liberation from sediment to the overlying water, and the controlling efficiency of Elodea nuttallii combined with HZC was higher than that of Elodea nuttallii or HZC alone. The passivation of labile P measured by diffusive gradient in thin film device and mobile P played a crucial role in the control of internal P loading from sediment by the combined Elodea nuttallii + HZC treatment. HZC capping had a promoting effect on the growth of Elodea nuttallii. This was beneficial to the absorption of phosphorus from sediment by Elodea nuttallii. The combined application of Elodea nuttallii and HZC not only had a certain negative effect on the diversity of bacteria in the surface sediment, but also changed the microbial compositions of the surface sediment at the levels of phylum and genus. However, the microbial communities in the surface sediment still can perform good ecological function. The above results suggest that the combined application of Elodea nuttallii and HZC has a high potential in the management of internal P loading from sediment.

Transformative Dynamics: Self-Assembly of Iron Oxide Hydroxide Nanorods into Iron Oxide Microcubes for Enhanced Perfluoroalkyl Substance Remediation.

We report the controlled synthesis of iron oxide microcubes (IOMCs) through the self-assembly arrays of ferric oxide hydroxide nanorods (NRs). The formation of IOMCs involves a complex interplay of nucleation, self-assembly, and growth mechanisms influenced by time, thermal treatment, and surfactant dynamics. The self-assembly of vertically aligned NRs into IOMCs is controlled by dynamic magnetism properties and capping agents like cetyltrimethylammonium bromide (CTAB), whose concentration and temperature modulation dictate growth kinetics and structural uniformity. These controlled structural growths were obtained via a hydrothermal process at 120 °C at various intervals of 8, 16, 24, and 32 h in the presence of CTAB as the capping agent. In this hydrothermal method, the formation of vertically oriented NR arrays was observed without the presence of ligands, binders, harsh drying techniques, and solvent evaporation. The formation of the self-assembly of NRs to IOMCs is obtained with an increase in saturated magnetization to attain the most stable state. The synthesized IOMCs have a uniform size, quasi-shape, and excellent dispersion. Due to its excellent magnetic and catalytic properties, IOMCs were employed to remove the various emerging pollutants known as per- and polyfluorinated substances (PFAS). Various microscopic and spectroscopic techniques were employed for the characterization and interaction studies of IOMCs with various PFAS. The interaction between IOMCs and perfluoroalkyl substances (PFAS) was investigated, revealing strong adsorption tendencies facilitated by electrostatic interactions, as evidenced by UV-vis and FT-IR spectroscopic studies. Furthermore, the higher magnetic and positive surface charge of IOMCs is responsible for an effective remediation eliminating any secondary pollution with ease of recovery after the sorption interaction studies, thereby making it practically worthwhile.

HSA, free Radicals, and antibacterial interaction with ferrous oxide nanoparticles synthesized from Amorphophallus paeoniifolius

This work provides a sustainable method for producing iron oxide nanoparticles (FeONPs) using an extract from Amorphophallus paeoniifolius (AP) tubers. The nanoparticles were then thoroughly characterized by TGA/DSC, UV, FTIR, and SEM examination. They demonstrated their strong antibacterial properties against Gram-positive and Gram-negative microbes. The sizes of the ZOI were found to be 19, 25, 16 and 14 at 100 mg/mL as compared to cefoxitin as 18, 23, 8 and 12 mm for Pseudomonas aeruginosa (P. aeruginosa), Escherichia coli (E. coli), Bacillus subtilis (B. subtils) and Staphylococcus aureus (S. aureus) respectively. Their interaction with 2,2-diphenylpicrylhydrazyl (DPPH) revealed their free radical scavenging up to 70 %. NPs at 260 nm (λmax) have shown a hypo-chromic effect in the spectrophotometric approach, suggesting that FeONPs are intercalating in nature. The fluorescence quenching tests indicated the development of a non-fluorescent complex, implying FeONPs interaction with human serum albumin (HSA). As per Scatchard parameters, five binding sites observed in HSA during the interaction with FeONPs, where the Kb value indicated the NPs strong binding strength. The HSA and DPPH interaction nature of FeONPs suggests that they might be helpful in medical applications.

Ferric Oxide Nanoparticles Enhance Cytotoxicity and Reduce the Occurrence and Development of Cervical Cancer Metastases

Fe3O4 nanoparticles can be used in diagnostic imaging and therapeutic applications. However, poor solubility limits its use in tumors. In this study, we used ferric oxide and nanoparticles to covalently bind ferric oxide nanoparticles as a strategy for treatment of cervical cancer metastases. We aimed to evaluate their biological effects on cervical cancer metastases in vivo. Confocal microscopy was used to detect transfection efficiency, ferric oxide or ferric oxide nanoparticles were used to intervene cervical cancer cell lines, and flow cytometry explored cell apoptosis. The mouse model of cervical cancer metastasis was further treated with ferric oxide or ferric tetroxide nanoparticles through intraperitoneal injection. The tumor volume was counted and size was measured. Cell proliferation and apoptosis were detected by IHC and Western-blot was used to detect protein expression. Nanoparticles significantly enhanced the cellular uptake of Fe3O4, which inhibited cell proliferation and promoted cell apoptosis. In the in vivo transplanted tumor model, the same was observed in mice. In the mice model, ferric oxide nanoparticles significantly inhibited the growth of tumors, slowed down tumor growth rate, and accelerated apoptosis. Our research results showed that nanoparticles contributed to the uptake of oxidized particles, and Fe3O4 nanoparticles regulated studied tumors by enhancing cytotoxicity, thereby inhibiting cell proliferation and promoting cell apoptosis, achieving Fe3O4 nanoparticles. The particles significantly inhibited tumor growth, slowed down multiplication rate, and accelerated apoptosis, suggesting that Fe3O4 nanoparticles have a significant inhibitory effect on cervical cancer transplanted tumors.

Effects of food waste biogas residue composting on soil aggregates and its organic matter content in relocation site

Understanding the effects of food waste biogas residue composting and chemical amendments on soil aggregates composition of different particle sizes, stability, and organic matter distribution in relocation sites could provide primary data for improving soil quality and land utilization of food waste biogas residue composting. We analyzed the characteristics of soil aggregates distribution, stability of aggregates, and organic matter content in different particle sizes under treatments with different application amounts of food waste biogas residue composting, chemical amendments (β-cyclodextrin, calcium sulfate and ferric oxide were mixed at a mass ratio of 1:1:1), and control (100% soil). The results showed that 20% (soil: biogas residue composting=8:2) and 30% (soil: biogas residue composting =7:3) biogas residue composting significantly decreased the micro-aggregates content with the particle size of <0.106 mm and increased the large aggregates content with the particle size of 0.5-1.0 mm. All treatments significantly increased large aggregates content with the particle size of ≥2.0 mm, soil aggregate structure content, and mean weight diameter, but reduced the percentage of aggregate destruction. Among all the treatments, the effect of mixes application of 20% biogas residue composting and chemical amendments was the best. Biogas residue composting treatments significantly affected the distribution of organic matter in soil aggregates, with the strongest effect under 30% biogas residue composting treatment. Biogas residue composting treatments significantly increased soil organic matter content in all aggregates, with the maximal increase of organic matter content in soil micro-aggregates with the particle size of 0.106-0.25 mm. In conclusion, biogas residue composting could increase organic matter content of soil aggregates in different particle sizes, promote the formation of large soil aggregates, and improve the stability of aggregation. Specifically, the mixed application of biogas residue composting and chemical amendments performed better on soil improvement in relocation site.

Characterization of Lateralite: An Environment Friendly Chemical Additive for Soil Stabilization

The objective of this paper is to determine the chemical composition of Lateralite stabilizer and to characterize Lateralite, stabilizer as a solution for improving the engineering properties of fined grained lateritic and clayey soil for road construction. Oxides and metallic compositions of Lateralite was determined by Atomic Absorption Spectroscopy, AAS, composition of chemical elements of Lateralite stabilizer was determined by X-ray Photoelectron Spectroscopy (XPS) and a quantitative analysis by Scanning Electron Microscopy (SEM) associated with Energy Dispersive X-ray spectroscopy (EDX). The oxide composition of Lateralite as determined by AAS is: Calcium Oxide (63.89%), Silicon Oxide (18.31%), Aluminium Oxide (5.89%), Ferrous oxide (1.67%), Magnesium oxide (1.56%), Sulphur oxide (1.22%), Potassium oxide (0.78%), Sodium oxide (0.41%) and L.O.I 6.27%. The elemental composition analysis by XPS revealed ten (10) elements with Percentage Atomic Concentration, PAC, as: Oxygen (54.33%), Carbon (18.26%), Silicon (9.38%), Calcium (7.56%), Magnesium (4.08%), Aluminium (2.90%), Sodium (2.47%), Ferrous (0.44%), Sulphur (0.31%) and Nitrogen (0.27%) while SEM revealed eleven (11) elements: Oxygen (57.9%), Calcium (21.13%), Silicon (11.08%), Aluminium (4.23%), Ferrous (1.89%), Sulphur (1.07%), Magnesium (1.02%), Sodium (0.99%), Potassium (0.35%), Tin (0.18%) and Barium (0.17%). The three (3) characterization techniques used, (AAS, XPS and SEM) revealed the exchangeable cations in Lateralite are Calcium (7.56%), Magnesium (4.08%), Aluminium (2.90%) and Sodium (2.47%) which are in the ratio 3: 1.65:1.17:1, (Ca2+: Mg2+: Al3+ :Na+). This shows a high concentration and quantity of exchangeable calcium cations over other cations. This will enable the formation of Calcium compounds with very strong and stable inter-particle bonds and a stable Lateralite-stabilized soil mixture.

Ortho-parahydrogen catalyst test facility

With the growing interest in hydrogen as one pillar of the future energy economy, the relevance of hydrogen liquefaction for storage and transportation is increasing rapidly. However, the liquefaction process still offers much potential for improvement in terms of cost and efficiency. One problem faced with achieving more cost- and energy-efficient liquefiers is the uncertainty associated with the dimensioning of the ortho-para converters. Literature data on the existing ortho-para catalysts stem mainly from the 1950s and 1960s and are partly inconsistent. Therefore, a new facility for the comprehensive investigation of catalytic ortho-parahydrogen conversion was set up at the Dresden University of Technology (TU Dresden) as part of the government-funded HyCat (“Improvement of the Ortho-Para-Catalysts for Hydrogen Liquefaction”) project. It enables the testing of catalysts in the whole operational range of ortho-para converters in modern large-scale liquefaction plants by allowing the independent variation of temperature, pressure, flow rate, inlet ortho-para ratio, and sample reactor internal geometry. The setup has been tested and validated preliminarily. It can soon be used to produce new high-quality data sets on the performance of the commercial catalyst Ionex (hydrous ferric oxide), for the qualification of alternative catalysts, and for gaining a deeper understanding of the reaction kinetics involved.

Thermal and reactive effects in nanofluid flow around a contracting cylinder under magnetic field influence

This study investigates the dynamic behavior of natural ester-based ferrous oxide (Fe3O4) nanofluid flow around an unsteady contracting cylinder under the influence of a magnetic field, heat generation, and homogeneous-heterogeneous reactions. The governing equations for the flow, heat transfer, and chemical reactions are solved numerically using appropriate mathematical models. The bvp4c built-in MATLAB package is applied to address the complexity of the problem. The effects of magnetic field, heat generation, and reactive chemistry on the flow field, temperature distribution, and species concentration profiles are analysed comprehensively. As part of the validation process, we validate the reliability of our findings by comparing them to established benchmarks. Motivated by the increasing interest in environmentally friendly and sustainable fluid mediums, natural esters are chosen as the base fluid due to their biodegradability, low toxicity, and excellent insulating properties. This research aims to provide valuable insights into optimizing processes involving nanofluid flow in magnetohydrodynamic systems with reactive heat generation, utilizing natural esters as a promising alternative to conventional fluids. Insights gained from this study offer potential applications in various engineering and industrial contexts, contributing to the advancement of eco-friendly technologies.

Synthesis and application of multifunctional magnetic mesoporous nanomaterials with redox reaction and NIR response in tumor treatment

In recent years, the novel minimally invasive combination therapy for tumors has garnered widespread attention due to its controllable therapeutic target, effective combination therapy outcome, and minimal toxic side effects. This study integrated inorganic nanospheres of ferric oxide (Fe3O4) with mesoporous silica nanoparticles (MSN), along with polymeric organic polymers—polyaniline (PANI) and hyaluronic acid (HA)—to create a multifunctional tumor treatment platform (Fe3O4@MSN@PANI@HA), aiming to enhance the efficacy of therapies that have monotherapy limitations. The Fe2+ within the Fe3O4@MSN@PANI@HA nanoparticles can react with the unique hydrogen peroxide present in the tumor microenvironment to generate hydroxyl radicals (·OH), which possess cytotoxic properties that can selectively eradicate tumor cells, thereby facilitating chemodynamic therapy (CDT). Moreover, Fe3O4@MSN@PANI@HA nanoparticles, when loaded with the chemotherapy drug doxorubicin hydrochloride (DOX), yield Fe3O4@MSN@PANI@HA-DOX nanoparticles. It has been demonstrated that these nanoparticles exhibit commendable drug-loading efficiency and controlled drug-release capabilities, contributing to the chemotherapy of tumors. The inclusion of PANI in the Fe3O4@MSN@PANI@HA nanoparticles endows them with an exceptional photothermal conversion capability. Upon exposure to an 808-nm near-infrared laser (NIR), the photothermal conversion efficiency of the composite nanomaterials reaches 42.76 %, thereby enabling photothermal therapy (PTT) through the thermal ablation of tumor cells. The HA component of the composite nanoparticles provides excellent biocompatibility and a sustained drug-release effect. Simultaneously, it could target tumor cells by recognizing specific receptors that are overexpressed on the cell surfaces, directing the transport of the composite nanoparticles to the tumor site, and selectively destroying tumor cells. This paper confirms the potent therapeutic impact of composite nanoparticles on tumors and offers a novel perspective for designing multifunctional composite nanomaterials.

Study on the mechanism of second phase formation in high-purity fused silica materials for semiconductor application

Gas bubble is a common defect in high-purity fused silica materials, but the formation of the second phase particles related to gas bubble and its mechanism remain unclear till now. In this work, we have presented a method for characterization of colored gas bubbles in high-purity fused silica crucibles for Czochralski silicon by the means of TEM and EDX. Based on it, the origin of the coloring of the gas bubbles is demonstrated to be induced by the gathering of Fe impurity and then, the formation of high-density second phase—ferric oxide (Fe2O3) crystals around the gas bubbles. Moreover, our results provide insight into the formation mechanism of second phase crystals which can be induced by stress field variations around gas bubbles during the cooling process that probably promoted by volume shrinkage effect and increasing solubility of gas from gas bubbles into fused silica substrate. The understanding of the second phase particle formation mechanism in high-purity fused silica materials is valuable for its further controlling.

Isolation and Electrochemical Analysis of a Facultative Anaerobic Electrogenic Strain Klebsiella sp. SQ-1.

Electricigens decompose organic matter and convert stored chemical energy into electrical energy through extracellular electron transfer. They are significant biocatalysts for microbial fuel cells with practical applications in green energy generation, effluent treatment, and bioremediation. A facultative anaerobic electrogenic strain SQ-1 is isolated from sludge in a biotechnology factory. The strain SQ-1 is a close relative of Klebsiella variicola. Multilayered biofilms form on the surface of a carbon electrode after the isolated bacteria are inoculated into a microbial fuel cell device. This strain produces high current densities of 625 μA cm-2 by using acetate as the carbon source in a three-electrode configuration. The electricity generation performance is also analyzed in a dual-chamber microbial fuel cell. It reaches a maximum power density of 560 mW m-2 when the corresponding output voltage is 0.59 V. The facultative strain SQ-1 utilizes hydrous ferric oxide as an electron acceptor to perform extracellular electricigenic respiration in anaerobic conditions. Since facultative strains possess better properties than anaerobic strains, Klebsiella sp. SQ-1 may be a promising exoelectrogenic strain for applications in microbial electrochemistry.

Geochemical Specifications for Raw Materials Used in Gasin Cement Factory in Kurdistan Region Ne-Iraq

This paper intends to provide background information on the chemically investigated raw materials used in the cement industry at the Gasin Cement Factory. Since it was found that the average carbonate ratio of CaCO3 is 89.84 percent by weight ratio, the sulfide is less than 1 percent by weight ratio, and the magnesium carbonate is less than 3 percent, the raw materials entering the factory, including limestone, clay, iron, sand, and gypsum, were examined. Magnesium carbonate was less than or equal to 3 percent, in the iron with sand mixture, and the overall mixture carbonates were less than or equal to 76.24 percent. The findings of the analysis for silica oxides in the sand were greater than 82 percent. For sulfide oxide less than 1%, as well as for iron, the average value of ferric oxide that was examined in a laboratory was 35.51percent, from local iron ore, and an average reached 50.66% from Iranian iron ore, the percentage of alumina oxide that was tested in a laboratory was 9.37 percent and 3.40 percent from Local iron and Iranian iron respectively, silica oxide is more than 8.3 percent. As well as gypsum analysis, it was discovered that the average percentage of sulfur dioxide is higher than 40.97%. We identified the locations of the models that were evaluated and analyzed, as well as their storage locations.

Application of Magnetic Separation Technology in Resource Utilization and Environmental Treatment

Magnetic separation technology is a physical separation method that uses the differences in magnetism between matter to separate them from each other by different motion behaviors in a non-uniform magnetic field. It is highly efficient, green, and environmentally friendly, with little change in the physical and chemical properties of raw materials. Magnetic separation technology is commonly used in the field of mineral processing engineering for magnetite, hematite, titanite, and other magnetic ferrous metal oxide minerals. This paper summarizes the application of magnetic separation technology for resource utilization and environmental treatment in different fields, such as non-metal decomposition, valuable metal recovery, use of magnetic carrier chemical separation, biomedical targeted magnetic separation, and use of magnetic species separation in water and wastewater treatment. We seek to review the application and potential of magnetic separation technology in various fields, emphasize their key role, and explore possible directions for their future development.

Diethyldithiocarbamate-ferrous oxide nanoparticles inhibit human and mouse glioblastoma stemness: aldehyde dehydrogenase 1A1 suppression and ferroptosis induction.

The development of effective therapy for eradicating glioblastoma stem cells remains a major challenge due to their aggressive growth, chemoresistance and radioresistance which are mainly conferred by aldehyde dehydrogenase (ALDH)1A1. The latter is the main stemness mediator via enhancing signaling pathways of Wnt/β-catenin, phosphatidylinositol 3-kinase/AKT, and hypoxia. Furthermore, ALDH1A1 mediates therapeutic resistance by inactivating drugs, stimulating the expression of drug efflux transporters, and detoxifying reactive radical species, thereby apoptosis arresting. Recent reports disclosed the potent and broad-spectrum anticancer activities of the unique nanocomplexes of diethyldithiocarbamate (DE, ALDH1A1 inhibitor) with ferrous oxide nanoparticles (FeO NPs) mainly conferred by inducing lipid peroxidation-dependent non-apoptotic pathways (iron accumulation-triggered ferroptosis), was reported. Accordingly, the anti-stemness activity of nanocomplexes (DE-FeO NPs) was investigated against human and mouse glioma stem cells (GSCs) and radioresistant GSCs (GSCs-RR). DE-FeO NPs exhibited the strongest growth inhibition effect on the treated human GSCs (MGG18 and JX39P), mouse GSCs (GS and PDGF-GSC) and their radioresistant cells (IC50 ≤ 70 and 161μg/mL, respectively). DE-FeO NPs also revealed a higher inhibitory impact than standard chemotherapy (temozolomide, TMZ) on self-renewal, cancer repopulation, chemoresistance, and radioresistance potentials. Besides, DE-FeO NPs surpassed TMZ regarding the effect on relative expression of all studied stemness genes, as well as relative p-AKT/AKT ratio in the treated MGG18, GS and their radioresistant (MGG18-RR and GS-RR). This potent anti-stemness influence is primarily attributed to ALDH1A1 inhibition and ferroptosis induction, as confirmed by significant elevation of cellular reactive oxygen species and lipid peroxidation with significant depletion of glutathione and glutathione peroxidase 4. DE-FeO NPs recorded the optimal LogP value for crossing the blood brain barrier. This in vitro novel study declared the potency of DE-FeO NPs for collapsing GSCs and GSCs-RR with improving their sensitivity to chemotherapy and radiotherapy, indicating that DE-FeO NPs may be a promising remedy for GBM. Glioma animal models will be needed for in-depth studies on its safe effectiveness.

In situ construction of iron-rich metal-organic frameworks on wool surface for enhanced flame retardancy and low smoke generation

The incorporation of metal-organic frameworks (MOFs) on textile materials to enhance flame retardancy is of interest and challenge. In this study, an iron-rich MOF (Fe-MOF) was constructed in situ on wool fabric surface through the alternating assembly of ferric metal salt and the carboxylic acid ligand 1,3,5-benzenetricarboxylic acid. The surface morphology, flame retardancy, smoke and heat release performance, thermal stability, and flame-retardant mechanism of the Fe-MOF coated wool fabric were investigated. Square-shaped crystals were observed on the coated wool fabric, indicating successful construction of Fe-MOF on the wool surface. The coated wool fabric with an add-on of 6.8% exhibited excellent flame retardancy, as evidenced by its self-extinguishing ability during the vertical burning test and a significantly enhanced limiting oxygen index of 32.6%. Moreover, the coated wool fabric demonstrated a remarkable reduction in heat and smoke production of 23.8% and 68.4%, respectively, indicating enhanced fire safety. The analysis of char residue, including thermal stability, surface morphology, iron content, and graphitization degree, supported the formation of ferric oxides as a protective layer, contributing to the improved flame retardancy of the Fe-MOF coated wool in the condensed phase. The in situ construction of Fe-MOF on wool macromolecules offers a promising and innovative approach for developing nonhalogen and nonphosphorus flame-retardant systems.