Ionization Gauge Research Articles

A Cylindrical Triode Ultrahigh Vacuum Ionization Gauge with a Carbon Nanotube Cathode.

In this study, a cylindrical triode ultrahigh vacuum ionization gauge with a screen-printed carbon nanotube (CNT) electron source was developed, and its metrological performance in different gases was systematically investigated using an ultrahigh vacuum system. The resulting ionization gauge with a CNT cathode responded linearly to nitrogen, argon, and air pressures in the range from ~4.0 ± 1.0 × 10−7 to 6 × 10−4 Pa, which is the first reported CNT emitter-based ionization gauge whose lower limit of pressure measurement is lower than its hot cathode counterpart. In addition, the sensitivities of this novel gauge were ~0.05 Pa−1 for nitrogen, ~0.06 Pa−1 for argon, and ~0.04 Pa−1 for air, respectively. The trend of sensitivity with anode voltage, obtained by the experimental method, was roughly consistent with that gained through theoretical simulation. The advantages of the present sensor (including low power consumption for electron emissions, invisible to infrared light radiation and thermal radiation, high stability, etc.) mean that it has potential applications in space exploration.

The influence of palladium on the hydrogenation of acetylene on Ag(111).

We have used reflection absorption infrared spectroscopy (RAIRS) and temperature programmed reaction (TPR) to study the selective hydrogenation of acetylene on both a clean Ag(111) surface and on a Pd/Ag(111) single-atom-alloy surface. The partial hydrogenation of acetylene to ethylene is an important catalytic process that is often carried out using PdAg alloys. It is challenging to study the reaction with ultrahigh vacuum techniques because H2 does not dissociate on Ag(111), and while H2 will dissociate at Pd sites, H-atom spillover from Pd to Ag sites does not generally occur. We bypassed the H2 dissociation step by exposing the surfaces to atomic hydrogen generated by the hot filament of an ion gauge. We find that hydrogen atoms react with acetylene to produce adsorbed ethylene at 85 K, the lowest temperature studied. This is revealed by the appearance of a RAIRS peak at 950 cm-1 due to the out-of-plane wagging mode of adsorbed ethylene when acetylene is exposed to a surface on which H atoms are pre-adsorbed. The formation of both ethylene and ethane are detected with TPR, but no acetylene coupling products, such as benzene, were found. From quantitative analysis of the TPR results, the percent conversion and selectivities to ethylene and ethane were determined. Low coverages of Pd enhance the conversion but do so mainly by increasing ethane formation.

Thermionic Electron Beam Current and Accelerating Voltage Controller for Gas Ion Sources

Thermionic emission sources are key components of electron impact gas ion sources used in measuring instruments, such as mass spectrometers, ionization gauges, and apparatus for ionization cross-section measurements. The repeatability of the measurements taken with such instruments depends on the stability of the ion current, which is a function, among other things, of the electron beam current and electron accelerating voltage. In this paper, a laboratory thermionic electron beam current and accelerating voltage controller is presented, based on digital algorithm implementation. The average value of the percentage standard deviation of the emission current is 0.021%, and the maximum electron accelerating voltage change versus the emission current is smaller than 0.011% in the full operating range of the emission current. Its application as a trap current or emission current-regulated ion source power supply could be useful in many measuring instruments, such as in microelectromechanical system (MEMS) mass spectrometers as universal gas sensors, where a stable emission current and electron energy are needed.

Turbulence generated small-scale structures as PMWE formation mechanism: Results from a rocket campaign

Simultaneous measurements of rocket-borne and ground-based instruments in a common volume were performed from Andøya, Norway (69° N, 16° E) in frame of the recent PMWE-project, devoted to clarify the formation mechanism behind polar mesosphere winter echoes (PMWE). This article focuses on measurements of April, 13th 2018. Despite low solar activity, we observe several radar echoes, giving the launch criterion. Combining precise in-situ ionization gauge and wave propagation measurements with ground-based radar measurements on 53.5 and 3.17 MHz, as well as lidar, we were able to measure key parameters of PMWE formation. Carefully analyzing the atmospheric background (i.e., temperature, viscosity, Brunt-Väisälä frequency, and scale heights of electron and neutral density), deriving turbulence parameters by means of radar and rocket, as well as estimating particle sizes of meteor smoke particles (MSP), we got a deep insight into the physical processes behind the PMWE phenomenon. Measurements clearly show that the coherent structures in refractive index variations (forming PMWE) are accompanied by neutral air turbulence, which is reflected in small-scale structures (down to some meters) of neutral and electron density. We analyze and discuss the temporal development of the radar echos by means of spectral width and wind measurements. We show that the behavior of the structures under investigation together with the atmospheric background is consistent with the interpretation, that PMWE were created by turbulence. Furthermore, it becomes clear that charged Meteor Smoke Particles (MSP) and background electron density can only enhance SNR, while turbulence is a prerequisite for their formation.

Pyroelectric lithium niobate electron emission-based ion-pump

This work presents a compact ion-pump that utilizes pyroelectricity for ionization of ambient molecules. The pyroelectric ionization is realized by heating a lithium niobate (LiNbO3) crystal with low voltage resistive heating (10 V drive voltage, 0.5 W Joule heating) to generate a high voltage across the poled surface of the crystal. Pyroelectrically generated electrons from the polarized surface of the crystal are accelerated using an electric field generated by both the crystal and external titanium (Ti) electrodes biased at ±300 V, which results in the ionization of molecules in the chamber. The low collector current in the pA range ensures that the power consumed due to ionization current is lower than the LiNbO3 heating power. The ionized gas molecules are accelerated toward the Ti collector electrodes where they are implanted owing to large acceleration produced by the collector electrodes. The system is configured as a sputter pump for gettering ions to reduce chamber pressure from the baseline value of 1.4 μTorr with just the external pump to 1.1 μTorr by incorporating the LiNbO3 pump. The proof-of-concept of the pyroelectric pumping mechanism is demonstrated using a 140 cm3 stainless steel vacuum chamber, with supplementary turbomolecular and diaphragm pumps and demonstrates that a 50 s thermal cycling of the crystal is optimal for the ion-pump. Pumping action was measured with a Pirani gauge and a hot cathode ion gauge. Analytical modeling and experimental results for pumping speed calculations showed a good match during high-pressure pumping.

Refining the cold atom pressure standard

In our previous work (Shen et al 2020 Metrologia 57 025015; Booth et al 2019 New J. Phys. 21 102001), we have reported the first primary quantum pressure standard based on the loss rate of cold rubidium atoms from a magnetic trap. We have shown that this standard is self-calibrating. That is, the single parameter required to quantify the pressure or particle flux impinging on the sensor atoms, , can be determined experimentally. In this paper, we refine our procedure to extract the trap loss rate coefficient by expressing the measured trap loss rate of the rubidium atoms as a convolution of the universal loss rate expression from Shen et al (2020 Metrologia 57 025015) and Booth et al (2019 New J. Phys. 21 102001) with the energy distribution of the rubidium atoms in the trap. We report improved values for 87Rb–X (X = He, Ar, Xe, H2, N2, and CO2) collision pairs. All are systematically higher than our previously reported values, although the differences are less than 2%. The calibration factor of an ionization gauge for nitrogen obtained using the cold atom standard, i g = 0.950 (19), agrees with the value obtained by NIST, i g = 0.940 (26) calibrated against their orifice flow standard.

Lidar Observations of Instability and Estimates of Vertical Eddy Diffusivity Induced by Gravity Wave Breaking in the Arctic Mesosphere

AbstractOn the night of 18–19 October 2018, sodium resonance lidar measurements show the presence of overturning in the mesospheric sodium layer. Two independent tracers, sodium mixing ratio and potential temperature, derived from resonance and Rayleigh lidar measurements, reveal that vertical spreading of the sodium mixing ratio contours and a layer of convective instability coincide with this overturning. Analysis of lidar measurements also reveals the presence of gravity waves that propagate upward, are saturated, and dissipate at the height of the convective instability. The vertical spreading is analyzed in terms of turbulent diffusive transport using a model based on material continuity of sodium. Estimates of the turbulent eddy diffusion coefficient, K, and energy dissipation rate, ε are derived from the transport model. The energy dissipated by the gravity waves is also calculated and found to be sufficient to generate the turbulence. We consider three other examples of overturning, instability and spreading on the nights of: 17–18 February 2009, 25–26 January 2015, and 8–9 October 2018. For all four events we find that the values of K (∼1,000 m2/s) are larger and the values of ε (∼10–100 mW/kg) are of similar magnitude to those values typically reported by ionization gauge measurements. These examples also reveal that higher levels of turbulent mixing are consistently found in regions of lower stability.

Development of a design for an ionisation vacuum gauge suitable as a reference standard

The EURAMET EMPIR project “16NRM05 - Ion gauge” aims to develop an ionisation vacuum gauge suitable as a reference vacuum standard. In such a gauge the electron trajectories and their kinetic energy inside the ionisation volume should be well defined and stable. In the search for a suitable design, a series of simulations on different ionisation gauge concepts that have the potential to meet stringent stability requirements have been carried out. Different software packages were used for this purpose. This paper focuses on the design aspects and the performance of the different ionisation gauge concepts that have been investigated by simulation. Parameters such as ionisation gauge sensitivity, ion collection efficiency and electron transmission efficiency, have been determined as a function of emission current, pressure and electron source alignment.

Symmetry breaking of plasma induced by pressure in PIG ion source

In this work, we use the COMSOL software to study the discharge characteristics of argon in the Penning ion gauge (PIG) ion source driven by DC voltage and based on a two-dimensional fluid model. The distribution of the electron density under different pressures is investigated. Our results indicate that, although the ion source has the symmetric geometry structure, the distribution of the electron density will lose the symmetry due to the change of pressures.

A simulation study of argon discharge in PIG ion source with axial magnetic field

In this study, we used a two-dimensional fluid model to investigate the argon discharge in Penning ion gauge (PIG) ion source influenced by magnetic field and the structure of ion source. Under fixed anode voltage U and pressure P, the relationships between the axial magnetic field, the structure parameter K, which is the ratio of the distance of two cathodes and the diameter of the anode tube, and the electron density are obtained. For fixed magnetic field B=0.01 T and pressure P=0.5 Torr, the electron density along the central axis has the maximal value when K=0.8. With fixed K=0.8 and P=1 Torr, the maximal electron density was found when B=0.1 T. Our results imply that there are optimal values for magnetic field and K which induce the maximal plasma density.

Time stability characterization of quadrupole mass spectrometers

• Time stability of eight QMSs was investigated over 2-years period. • Stability of sensitivity of Faraday cup detector and SEM gain for He and N 2 . • Stability of peak position and peak width of He and N 2 . • Stability of minimum detectable partial pressure for He. • Measurements were carried out according to ISO TS 20175:2018. This study focuses on the time stability of different metrological characteristics of quadrupole mass spectrometers (QMSs). Investigated parameters were the sensitivity, when using a Faraday cup as a detector, the peak position, the peak width, the gain of a secondary electron multiplier, and the minimum detectable partial pressure. Eight different commercial QMSs were investigated at seven national metrology institutes under three different nominal calibration pressures of 5 × 10 −6 Pa, 5 × 10 −5 Pa, and 5 × 10 −4 Pa for N 2 and He. The measurements were carried out using a periodicity of approximately 3 months for a total duration of 2 years. Sensitivity calibrations were conducted either through a comparison method using calibrated ionization gauges or by applying a primary vacuum calibration system. In the case of ionization gauges, they were periodically recalibrated to ensure their stability and traceability to a primary pressure standard.

Surface potential measurements of a polymer film following primary ion gun irradiation for ToF-SIMS analysis of insulator using a Kelvin probe and the observation of effects from the vacuum gauge

When an insulator sample is analyzed via time-of-flight secondary ion mass spectrometry (ToF-SIMS), charges accumulate on the sample surface due to the primary ion beam. These local surface charges and surface potentials cause many problems during analysis. A Kelvin probe was used to measure the surface potentials of the insulator sample. The surface potential induced on the surface of the sample and its temporal change was measured following the irradiation of the gas cluster ion beam. It was confirmed that the estimated surface potential value is affected by the high vacuum gauge, and there is an inflow of charges that possess polarities opposite to that of the surface potential. The amount of current flowing from the high vacuum gauge was calculated using the surface potential data that was measured. The amount of charge flowing onto the surface of the insulator was varied from several tens of fA to several fA, which was depended on its vacuum degree and position of high vacuum ion gauge. Additionally, neutralization of surface charges by the neutral gas effect was also weakly observed. This leaked current from the high vacuum gauges is likely to have a small but lasting impact on the ToF-SIMS insulator analysis.

Realization of a universal quantum pressure standard

We report the realization of the first cold-atom primary standard. This standard is based on a universal law governing quantum diffractive collisions between particles that allows an experimental determination of the velocity averaged total collision cross section, the only parameter required to quantify the pressure or flux of particles given a sensor particle collision rate measurement. Using an ensemble of 87Rb sensor atoms, we show that this new quantum pressure standard can be applied to gases of both atomic (He, Ar, and Xe) and molecular species (, , and ), surpassing the scope of existing orifice flow pressure standards. We verify the accuracy of this new standard using an ionization gauge (IG) calibrated for N2 by an orifice flow standard. The gauge calibration factors determined by the cold atom and orifice flow standards differ by less than 0.5% and, thus, agree within their uncertainties of 2% and 2.8% respectively. Using this standard, we evaluate the response of two different IGs to a variety of different gas species and report variations of up to 20% for their measured calibration factors. We also observe a non-linear response of the IG readings for CO2 gas. Finally, we demonstrate the use of a magneto-optical trap (MOT) as a transfer standard to extend the measurement range by a factor of 100 to include pressures up to P ~ 10−5 Pa.

Design and analysis of the cold cathode ion source for 200 MeV superconducting cyclotron

SC200 is a superconducting isochronous cyclotron which generates 200 MeV, 400 nA proton beam for particle therapy. The cold-cathode-type Penning ion gauge (PIG) ion source for the internal ion source of SC200 has been selected as an alternative and preliminary designed. In this paper, design of ion source and test bench are demonstrated. Currently, the properties of ion source have been simulated for a variety of electric field and magnetic field distributions. The secondary electron emission in electromagnetic field has been simulated. It provides reference for the optimization design of arc chamber. In addition, the sample of cold-cathode-type ion source has been tested on the test bench and extracted beam intensity has been measured over 200 μA.

Universality of quantum diffractive collisions and the quantum pressure standard

This work demonstrates that quantum diffractive collisions are governed by a universal law characterized by a single parameter that can be determined experimentally. Specifically, we report a quantitative form of the universal, cumulative energy distribution transferred to initially stationary sensor particles by quantum diffractive collisions. The characteristic energy scale corresponds to the localization length associated with the collision-induced quantum measurement, and the shape of the universal function is determined only by the analytic form of the interaction potential at long range. Using cold 87Rb sensor atoms confined in a magnetic trap, we observe experimentally , the universal function specific to van der Waals collisions, and use it to realize a self-defining particle pressure sensor that can be used for any ambient gas. This provides the first primary and quantum definition of the Pascal, applicable to any species and therefore represents a fundamental advance for vacuum and pressure metrology. The quantum pressure standard realized here is compared with a state-of-the-art orifice flow standard transferred by an ionization gauge calibrated for N2. The pressure measurements agree at the 0.5% level.

Atomic-Scale View of the Oxidation and Reduction of Supported Ultrathin FeO Islands.

By means of scanning tunneling microscopy (STM) measurements, we studied in situ the oxidation and reduction of FeO bilayer islands on Au(111) by oxygen (O2) and hydrogen (H2), respectively. The FeO islands respond very dynamically toward O2, with the coordinatively unsaturated ferrous (CUF) sites at the island edges being essential for O2 dissociation and O atom incorporation. An STM movie obtained during oxidation reveals how further O2 molecules can dissociate after the consumption of all initially existing CUF sites through the formation of new CUF sites. In contrast, we found that H2 molecules only dissociate when vibrationally excited through the ion gauge and only at the basal plane of FeO islands, implying that the CUF sites are not relevant for H2 dissociation. Our STM results reveal how excess O atoms are incorporated and released in O2 and H2 and thus shed light onto the stability of inverse catalysts during a catalyzed reaction.

Design and characterization of Ion sources for CHIP-TRAP

At Central Michigan University, we are developing a high-precision Penning trap mass spectrometer (CHIP-TRAP) for precise mass measurements with stable and long-lived isotopes. Ions will be produced using external ion sources and then transported to the Penning trap at low energy using electrostatic ion optics. Ion sources that will be utilized with CHIP-TRAP include a laser ablation ion source (LAS) that has already been commissioned, and a low current Penning ion trap (PIT) source that is currently being developed. The LAS enables ion production from solid targets via ablation and ionization with a high-powered laser pulse. The PIT source is a novel Penning ionization gauge (PIG) type source, consisting of a 0.55 T NdFeB ring magnet, cylindrical Penning trap, and low current thermal electron emitter that enables ion production via electron impact ionization of gaseous samples. For both ion sources, small bunches of ∼100 – 1000 ions can be produced from a minimal sample of source material. The ion bunches are then transported along the CHIP-TRAP beamline, where time-of-flight mass filtering can be performed before they are captured in the CHIP-TRAP Penning traps.

Vacuum Pressure Measurement in Industrial Environments

SummaryHigh accuracy and reproducibility are the basis for outstanding product quality in the manufacturing of vacuum pressure gauges. Selective product and process controls supported by statistical process control (SPC) ensure success. Automated calibration processes traceable to the National Measuring Institute (NMI) are necessitated by the high product volume and the requirement for complete traceability. Even in industrial use under mostly non‐ideal surrounding conditions, the devices must deliver stable and accurate measured values in all production processes. Using the example of hot‐filament ionization gauges, it is shown how design modifications in the production process have reduced the measurement uncertainties of the devices from one generation to the next. In another example, the introduction of a second baffle in a capacitance diaphragm gauge, led to significant reductions in sensor drift.

The data acquisition and control system for the operation of ASDEX pressure gauge for the measurement of neutral pressure in ADITYA Tokamak

Bayard-Alpert (BA) type hot cathode ionisation gauge is widely used to measure neutral pressure precisely in vacuum system below 10−3 Torr pressure. Neutral pressure measurement in magnetic confinement fusion experiments is quite challenging for standard BA type gauge due to higher pressure limitation and its ionisation is affected by strong magnetic and electrical fields. To overcome the above limitations, a special hot cathode ionisation gauge, named ASDEX Pressure Gauge (APG) system was developed by G. Haas at the Max-Planck-Institute, Germany. The APG system can work in high magnetic field up to 6 T and high temperature plasma environment with broad pressure measurement range from 10−1 to 10−6 mbar with fast response (<10 msec) and good noise immunity.In the present work, we report the design and development of control and data acquisition of ASDEX Pressure Gauge (APG) for ADITYA Tokamak to measure real time neutral pressure during the high temperature plasma. The developed system can achieve synchronous control of gauge controller using General Purpose Interface Bus (GPIB) and data acquisition of ion emission current of gauge head using Peripheral Component Interconnect (PCI) based data acquisition module. Initially, the APG calibration with standard BA type hot cathode ionization gauge had been carried out using the test set-up of low magnetic field and ultrahigh vacuum system with gases like H2, Ar, He. For APG calibration for various pressure ranges of these gases, precise gas feed control system has been developed using controller based hardware and LabVIEW based software. After testing and calibration, the APG was installed on ADITYA tokamak and calibrated under high magnetic field of ADITYA. The developed APG control system is configurable for presenting the gauge parameters before the plasma discharge. During plasma discharge, the analog signal equivalent to neutral pressure is acquired in real-time using simultaneous sampling analog to digital converter (ADC) module. The acquired raw data and processed real time pressure can provide valuable neutral pressure/density information of Tokamak plasma.

Study on the Sensitivity of Fast Ionization Gauge in Mixture Gas of Hydrogen and Helium

Study on the Sensitivity of Fast Ionization Gauge in Mixture Gas of Hydrogen and Helium