Ionic Polarization Research Articles

Modeling Europium (II/III) ion solvation in the LiCl-KCl eutectic mixture with polarizable force fields

The solvation processes of Europium (II/III) ions within the molten salt eutectic mixture, 3LiCl-2KCl, are investigated over temperatures ranging from 673 K to 1173 K. New polarizable ion force fields are proposed to model Europium ions in a molten salt eutectic mixture with a goal of accurately capturing the underlying physics in the solutions. In contrast to rigid-ion models, the polarizable Drude model with an adjusted WBK (Wang-Buckingham) force field significantly improves predictions for diffusion coefficients, the average diffusion activation energy, and changes in excess ion chemical potential and partial molar entropy, producing good agreement with experimental measurements.

Enhancing photocatalytic performance of covalent organic frameworks via ionic polarization

Covalent organic frameworks have emerged as a thriving family in the realm of photocatalysis recently, yet with concerns about their high exciton dissociation energy and sluggish charge transfer. Herein, a strategy to enhance the built-in electric field of series β-keto-enamine-based covalent organic frameworks by ionic polarization method is proposed. The ionic polarization is achieved through a distinctive post-synthetic quaternization reaction which can endow the covalent organic frameworks with separated charge centers comprising cationic skeleton and iodide counter-anions. The stronger built-in electric field generated between their cationic framework and iodide anions promotes charge transfer and exciton dissociation efficiency. Moreover, the introduced iodide anions not only serve as reaction centers with lowered H* formation energy barrier, but also act as electron extractant suppressing the recombination of electron-hole pairs. Therefore, the photocatalytic performance of the covalent organic frameworks shows notable improvement, among which the CH3I-TpPa-1 can deliver an high H2 production rate up to 9.21 mmol g−1 h−1 without any co-catalysts, representing a 42-fold increase compared to TpPa-1, being comparable to or possibly exceeding the current covalent organic framework photocatalysts with the addition of Pt co-catalysts.

Evaluation of ion recombination and polarity effect on photon depth dose measurements using mini- and micro-ion chamber.

To investigate the effect of ion recombination ( ) and polarity ( ) correction factors on percentage depth dose (PDD) curves for three ion chambers, using flat and flattening filter free (FFF) beams, across different broad field sizes. A method to assess these effects and their corresponding corrections is proposed. and were evaluated following the IAEA TRS-398 protocol for three ion chambers: PTW Semiflex-3D-31021, PinPoint-3D-31022, and Semiflex-31010. PDD measurements were acquired from dmax to 32cm depth at four voltages (±400V or±300V, and±100V) for field sizes 4×4, 10×10, 20×20, and 40×40 cm2. The values were computed after the correction at each applied voltage. This study aimed to assess the variation of the factors along scanning depths for different field sizes, to evaluate the need for correcting the scanning data. was independent of depth and field size for Semiflex-3D, while it presented an increasing value with depth for the PinPoint-3D. increased with dose rate, i.e., decreased with depth. The variation of this perturbation effect over the PDD range was about 0.1% for flat beams with all three ion chambers. With FFF beams, it was around 0.3% with PinPoint-3D, and 0.8% for 10FFF with Semiflex-3D. A second-order polynomial fit can be determined to directly correct the raw data scanned along the beam axis for both and . can significantly affect the PDD scanning measurements in FFF beams acquired with Semiflex-3D. An error close to 1% at large depths could be present, meaning an error of less than 0.3% relative to the dose at the depth of dmax.

Investigating the effect of finite ionic size and solvent polarization on induced charge electro-osmosis around a perfectly polarizable cylinder

Many industrially relevant microfluidic applications use concentrated solutions of macro-molecular solutes dissolved in polar solvents like water, which are typically deployed at high voltages. In this study, we investigate the effect of finite ionic sizes and solvent polarization on induced charge electro-osmotic flow around a perfectly polarizable cylinder, at high electric field strengths and ionic concentrations. The flow is actuated by means of a direct current electric field, and the step response of various flow parameters are studied numerically. Finite ionic sizes, defined through a steric factor ν, are modeled using the modified Poisson–Nernst–Planck model. Additionally, a field-dependent permittivity, characterized by a solvent polarization number A, accounts for molecular re-orientation effects. Our findings reveal an ion-size modulated decrement in charge concentration in the electrical double layer and an augmentation in the electric field. Remarkably, the resulting flow velocities increase with ion size. Solvent polarization, on the other hand, results in a marked reduction in flow velocities. Steric effects, however, dominate over a large range of parameter space (applied voltage and bulk ionic concentration) as compared to solvent polarization. Finally, we demonstrate that unequal ionic sizes result in flow asymmetries at the steady-state, thereby generating net electro-phoretic motion of suspended particles.

Effects of Zn2+/Si4+ co-doping on the cation distribution, crystal structure, and microwave dielectric characteristics of spinel-structured MgAl2O4 ceramics

Investigating the relationship between the structure and dielectric properties of cation-mixed spinel ceramics is crucial for overcoming the limitations of conventional microwave materials. In this study, MgAl2-x(Zn0.5Si0.5)xO4 (x = 0, 0.02, 0.04, 0.06, and 0.08) ceramics were prepared by a solid-state reaction method. The co-substitution for Al with Zn2+/Si4+ induces Al3+ cations for preferential occupation of the 8a site in the oxygen tetrahedra, forming a solid-solution ceramic at x ≤ 0.06. Enhanced ionic diffusion and compressive stress contribute to a dense microstructure (ρ > 95%) with uniform grain-size distribution after heating at 1650 °C for 4 h. Raman and 27Al NMR spectra reveal a relationship between cation distribution and covalency, consistent with the results of Rietveld refinement. The increases in cation disorder and degree of inversion are accompanied by an enhanced covalency of the Al–O bonds, which reduces intrinsic dielectric loss. In addition, the combination of Shannon ion polarizability and bond valence theory suggests that the increases in permittivity (εr) and the temperature coefficient of resonant frequency (τf) are related to the high polarizability of the dopant ions and the abnormal polarizability derived from the decreasing bond valence of the Al2–O site. The sample at x = 0.06 exhibits a low εr of 8.31, high Q × f of 194,159 GHz (at ∼11.35 GHz), and τf of -30.8 ppm/°C, indicating superior microwave application prospects as compared with traditional Mg-Al spinel ceramics.

Borosilicate glass with low dielectric loss and low permittivity for 5G/6G electronic packaging applications

A phase-separated borosilicate glass, with a relative permittivity ranging from 3 to 3.5 and a loss tangent as low as 5.6 × 10−4, is presented for packaging applications for the next generation of mobile communications. Ionic polarizability for each borosilicate composition was calculated from the Clausius–Mossotti relationship for both the vitreous and crystalline structures, and the polarizability difference between the two is proportional to the dielectric loss. Small amounts of alkali modifier were added to improve the glass processability, and the loss tangent increased to the 1–7 × 10−3 range. The resulting glass is phase-separated, which has no impact in the millimeter-wave spectrum, as the wavelengths are considerably greater than the length scale of each immiscible phase.

High-performance PVdF-HFP/PEG-IL composites: The combined effects of PEG and ionic liquid on proton conductivity and dielectric characteristics

This study explores the influence of varying polyethylene glycol (PEG) concentrations on the properties of PVdF-HFP/PEG-IL polymer composites through comprehensive characterization techniques, including FTIR, SEM, TGA, DMA, XRD and the detailed assessments of proton conductivity, dielectric properties, and relaxation dynamics. In terms of conductivity, the addition of PEG markedly improves proton conductivity. The PVdF-HFP/PEG40-IL composite exhibits the highest conductivity, reaching 1.96 × 10⁻2 S/m at 1 MHz and 300 K, and increasing to 4.27 × 10⁻2 S/m at 420 K. Dielectric properties show that the dielectric constant (ε′) increases with PEG content at low frequencies but decreases at higher frequencies due to reduced ionic polarization. Notably, PVdF-HFP/PEG40-IL achieves a dielectric constant of 3.39 × 106 at 20 Hz, which decreases to 30.34 at 1 MHz. Dielectric loss (ε'') also rises with temperature, with PVdF-HFP/PEG40-IL demonstrating the highest dielectric loss, indicative of superior proton conduction and polarization capabilities. Relaxation dynamics, as evidenced by tanδ, reveal that relaxation time significantly decreases with both increased PEG content and temperature, dropping from 1.06 × 10⁻4 s to 2 × 10⁻6 s as PEG concentration increases from 10 % to 40 %. This reduction in relaxation time correlates with enhanced proton conductivity and faster dipole relaxation, indicating PEG effect as a plasticizer that reduces polymer viscosity and improves ion transport. In conclusion, incorporating PEG into PVdF-HFP-IL composites leads to substantial improvements in proton conductivity, dielectric properties, and relaxation dynamics. The results highlight the crucial role of PEG in optimizing the performance of polymer electrolyte composites, making them effective candidates for advanced energy storage and conversion applications.

Influence of the induced Na+/Cl- ionic polarization effects on multi-scale structures of maize starch during radio frequency heating.

Structural modification/unfolding of starch molecules can be improved by radio frequency (RF) treatment. This necessitates a better understanding of its action mechanism through rapid heating and dipolar/ionic molecular vibration effects. Native maize starch (NS) was subjected to RF heating in a NaCl solution to five target temperatures, and its effect on structural modifications was evaluated. Results showed that the conductivity, particle size distribution and zeta potential of RF heated starch increased with increasing temperature. RF energy had a significant effect on the vibration intensity of other skeleton modes. No new chemical bonds/groups were formed in the starch even though there was the effect of sodium/chloride ions with the added vibration intensity of the ions and the dipolar rotation movements resulted in changes in the disordered and/or ordered structures. The RF treatment at 70 °C had the highest energy (10.4 kJ) of inter-strand hydrogen bond, crystallinity (36.6 %) and trough viscosity (2480 cp), but had the lowest crystallite dimension (13.7 nm), full width at half maximum (14.4) of peak at 480 cm-1, and breakdown (534 cp) and setback (784 cp) viscosities based on X-ray diffraction, Fourier transform infrared, and Raman and RVA observations.

Innovative Anode Design to Enhance Both Volumetric and Gravimetric Energy Densities of LiCoO2||Graphite Pouch Cells

AbstractThe ratio of the anode (negative electrode) and cathode (positive electrode) areal capacities (N/P ratio), is an important parameter for Lithium‐ion batteries. Considering the manufacturing tolerance and battery safety, almost all of the batteries keep the N/P ratio > 1. Deviating from this ratio can lead to lithium precipitation on the anode surface, which poses significant risks. Here, by using a gradient structured graphite (Gr) anode, a new design concept is proposed that the N/P ratio could be less than 1, which can effectively achieve higher energy density without sacrificing the battery safety. This is achieved by incorporating a small quantity of silver (Ag) nanoparticles into the bottom layer of the anode (Gr‐Agx), which effectively modulates the concentration polarization of lithium ions along the thickness of the electrode. Moreover, the volumetric energy density of 4 Ah LiCoO2||Gr‐Ag0.5 (N/P = 0.8) pouch cell increases by 14.5% compared with LiCoO2||Gr (N/P = 1.1). Furthermore, the universal applicability and efficacy of the N/P < 1 design paradigm in LiFePO4||Gr cells are validated.

Effect of binary ion substitution on the crystal structure and microwave dielectric properties of MgTa2O6 ceramics

AbstractMg1/3A11/3A21/3Ta2O6 ceramics (where A1 and A2 represent Co, Ni, or Zn) were prepared using the solid‐phase reaction route. The results of X‐ray diffraction and Raman tests showed that (Co1/2Ni1/2)2+, (Co1/ 2Zn1/2)2+, and (Ni1/2Zn1/2)2+ ions replaced Mg2+ ions in the lattice of MgTa2O6, resulting in the formation of a pure tri‐rutile structure. All three complex ions could significantly reduce the sintering temperature of the ceramics (by 150°C–200°C) and could broaden the sintering window. The large deviation (48.8%–69.2%) between the porosity corrected relative permittivity εr‐corr. and the theoretical relative permittivity εr‐theo. might be due to the overestimation of the ionic polarizability of Ta5+ by Shannon. (Co1/2Ni1/2)2+ has the most significant effect of increasing the bond energy of ceramic A–O bonds, reducing the τf value from 51 to 36 ppm/°C. In addition, the mechanisms affecting their dielectric properties are discussed based on bond ionicity (fi), full width at half maximum (FWHM) of Raman peak, and bond energy (E). Mg1/3Co1/3Ni1/3Ta2O6 ceramic sintered at 1350°C have the most excellent microwave dielectric properties: εr = 26.8, Q × f = 86,000 GHz, and τf = 36 ppm/°C.

Strong Metal‐Support Interaction Triggered by Molten Salts

AbstractStrong metal‐support interaction (SMSI) plays a vital role in tuning the geometric and electronic structures of metal species. Generally, a high‐temperature treatment (>500 °C) in reducing atmosphere is required for constructing SMSI, which may induce the sintering of metal species. Herein, we use molten salts as the reaction media to trigger the formation of high‐intensity SMSI at reduced temperatures. The strong ionic polarization of the molten salt promotes the breakage of Ti−O bonds in the TiO2 support, and hence decreases the energy barrier for the formation of interfacial bonds. Consequently, a high‐intensity SMSI state is achieved in TiO2 supported Ir nanoclusters, evidenced by a large number of Ir−Ti bonds at the interface, at a low temperature of 350 °C. Moreover, this method is applicable for triggering SMSI in various supported metal catalysts with different oxide supports including CeO2 and SnO2. This newly developed SMSI construction methodology opens a new avenue and holds significant potential for engineering advanced supported metal catalysts toward a broad range of applications.

Strong Metal-Support Interaction Triggered by Molten Salts.

Strong metal-support interaction (SMSI) plays a vital role in tuning the geometric and electronic structures of metal species. Generally, a high-temperature treatment (>500 °C) in reducing atmosphere is required for constructing SMSI, which may induce the sintering of metal species. Herein, we use molten salts as the reaction media to trigger the formation of high-intensity SMSI at reduced temperatures. The strong ionic polarization of the molten salt promotes the breakage of Ti-O bonds in the TiO2 support, and hence decreases the energy barrier for the formation of interfacial bonds. Consequently, a high-intensity SMSI state is achieved in TiO2 supported Ir nanoclusters, evidenced by a large number of Ir-Ti bonds at the interface, at a low temperature of 350 °C. Moreover, this method is applicable for triggering SMSI in various supported metal catalysts with different oxide supports including CeO2 and SnO2. This newly developed SMSI construction methodology opens a new avenue and holds significant potential for engineering advanced supported metal catalysts toward a broad range of applications.

A Series of Ultra-low Permittivity ALaP4O12 (A = Li, Na, K) Metaphosphate Microwave Dielectric Ceramics for Ultra-wideband Dielectric Resonant Antenna Application.

The employment of ultra-low permittivity materials in the configuration of antennas has been demonstrated to augment the antenna bandwidth and diminish signal delay effectively. This study presents three ultra-low permittivity metaphosphate microwave dielectric ceramics (MWDCs). The ALaP4O12 (A = Li, Na, K) metaphosphate ceramics, which all belong to the monoclinic crystal system, exhibit extremely low permittivity (εr ≈ 5) and excellent quality factor (Q·f > 10,000 GHz) at a low sintering temperature (T < 950 °C). Terahertz time-domain spectroscopy indicates that the εr of ALaP4O12 at terahertz frequencies is comparable to that observed in the microwave band and its value remains stable over an extensive frequency range. Furthermore, the relationship between the crystal structure and the dielectric properties of ALaP4O12 has been analyzed through the lens of chemical bond theory. The highest Q·f value observed for LiLaP4O12 can be attributed to the high chemical bond strength and stability of its crystal structure. The lowest ionic polarizability per unit volume is exhibited by NaLaP4O12, which results in the lowest pore-corrected permittivity. The thermal expansion of the chemical bonds within KLaP4O12 is considerable, resulting in the highest coefficient of thermal expansion. Finally, the performance of a LiLaP4O12-based dielectric resonator antenna (DRA) excited by slot-coupled microstrip lines was designed and optimized by using different ceramic radius-to-height (RH) ratios. It was found that when the RH ratio of DRA reached 1.85, both the fundamental mode (HEM11δ) and the higher-order mode (HEM12δ) of DRA were simultaneously excited. The two modes overlap significantly, resulting in an ultra-wideband (UWB) of 46.8% (bandwidth = 7.93 GHz). Concurrently, the maximum radiation efficiency and gain of the DRA, obtained from the simulation, are 97.9% and 7.92 dBi, respectively. The findings of this study may inform the investigation of ultra-low permittivity phosphorus-based MWDCs and UWB DRAs.

Augmentation of Halide Vacancy Rectification through Copper Ion Polarization in Nonsubstituted Porphyrin for Printable Carbon-Based Perovskite Solar Cells

Augmentation of Halide Vacancy Rectification through Copper Ion Polarization in Nonsubstituted Porphyrin for Printable Carbon-Based Perovskite Solar Cells

Design and Fabrication of a C-Band Patch Antenna with Low Loss BaM4Si5O17 Microwave Dielectric Ceramics.

Single-phase BaM4Si5O17 (M = Yb, Er, Y, Ho) ceramics have been investigated for their crystal structures, microwave dielectric properties, flexural strength, and potential applications in dielectric antennas. Rietveld refinement and TEM analysis revealed that the BaM4Si5O17 ceramics exhibit a monoclinic structure (space groups: P21/m). The εr of the BaM4Si5O17 ceramics was dominated by ionic polarizability and ρrel. The Q × f values were considerably larger at BaM4Si5O17 (M = Yb and Y) ceramics with the high Utotal and low intrinsic dielectric loss. The τf values were controlled by the MO6 octahedron distortion and -VBa. The flexural strength was mainly dominated by pores and average grain size and reached the maximum value (156 MPa) at BaY4Si5O17 ceramic with small average gain sizes and high relative density. Additionally, a patch antenna was fabricated using high-performance BaY4Si5O17 ceramic characterized by a εr value of 9.02, a Q × f value of 60620 at 12.30 GHz, and a τf value of -37.65 ppm/°C. This design achieved a high simulated radiation efficiency of 82.70% and a gain of 5.60 dBi at 6.97 GHz. indicating potential applications of BaY4Si5O17 ceramic because of its low dielectric loss and high flexural strength.

Nonlinear dielectric response and conductivity characteristics of epoxy resin in high voltage AC electric field

Abstract High-voltage dielectric and AC conduction behaviors of epoxy resin (EP) insulation are beneficial for the design and application of solid-state power electronic devices. This study investigates the nonlinear dielectric response and AC conduction characteristics of EP. The dielectric relaxation characteristics, including permittivity and AC conductivity of the EP samples, were investigated using high-voltage dielectric spectroscopy and the ionic polarization model. The results demonstrate a nonlinear increase in the relative permittivity and AC conductivity concerning the AC electric field. The increase in AC conduction under a high-frequency electric field is attributed to the reduction in the threshold field for charge injection caused by elevated temperatures. Considering the dielectric response and carrier hopping, it is evident that the nonlinear dielectric response of EP primarily originates from the ionic process under high electric fields. Ionic polarization, in conjunction with ion-hopping conduction, enhances the dielectric loss at high frequencies and electric fields, thereby facilitating the nonlinear conversion of AC conduction. The equivalent free volume is likely to increase in high-frequency fields. This phenomenon leads to an increase in AC conduction and even dielectric breakdown. This study offers a pivotal theoretical framework for the design and application of high-frequency insulation.

Application of the flexible and polarisable hydration ion model to study Th(IV) aqueous solutions

Th(IV) hydration in aqueous solution is studied by means of molecular dynamics simulations based on a polarisable Th(IV)- H 2 O interaction potential developed in the framework of the hydrated ion concept. Molecular Dynamics (MD) simulations provide as the only in-solution representative motif the ennea-aqua ion, [ Th ( H 2 O ) 9 ] 4 + , with first shell water molecules at an average distance of 2.47 Å from the ion, in accordance with most of the experimental estimates. A well-defined second hydration shell is also identified, hosting ca. 19 solvent molecules at 4.65 Å. Non-structural aspects of the Th(IV) hydration phenomenon, such hydration enthalpy and ion diffusion are well reproduced by the simulation results. The analysis of the O-Th-O angle distribution suggests that the capped square antiprism arrangement prevails over the trigonal tricapped prism. The well-balanced definition of the ion–water and water–water interactions in such a demanding ion neighbourhood is confirmed by the EXAFS and XANES spectroscopies. The theoretical spectra, computed from the MD trajectory, are in fine agreement with some of the experimentally recorded. The sensitivity of the XAS spectroscopy to structural changes confirms how the presented potential manages in a proper way the response of the water molecules to the highly polarising electric field generated by the tetravalent ion.

Mechanisms of enhanced performance in Zr4+/Ta5+ codoped rutile-TiO2 ceramics via broadband dielectric spectroscopy.

Aliovalent dopant codoped rutile-TiO2 materials have garnered attention due to their excellent performance properties, characterized by low loss tangent (tanδ), high dielectric permittivity (ε'), and stable ε' over a broad temperature range. This performance is primarily due to the electron-pinned defect-dipoles (EPDDs) of the complex defects [Formula: see text]Ti3+-[Formula: see text]Ti3+BTi. Notably, the excellent dielectric properties in ZrxTa2.5%Ti0.975-xO2 (Zr-TTO) ceramics can be achieved using the traditional mixed oxide method without the EPDDs, due to the absence of A3+ (acceptor doping ions). Instead, the existence of localized free electrons and oxygen vacancies ([Formula: see text]) in Zr-TTO structures, due to doping ions and the sintering process, was confirmed by X-ray photoelectron and Raman spectroscopies. These ceramics exhibited ε'~ 2 × 104 and tanδ < 0.03 at 1kHz and 25°C in the 2.5-10%Zr-TTO samples. Moreover, all ceramics demonstrated a maximum ε' change (∆ε') of less than ±15% over the temperature range suitable for X7R and X8R type ceramic capacitors. Significantly, the change in ε' related to relative humility was calculated to be less than ±0.5% over the range of 50-95% RH, indicating the environmental stability of the dielectric properties, which is essential for capacitor applications. Investigations suggested that at least four mechanisms contributed to this system: the intrinsic effect of ionic polarization, Ti4+ · e- -[Formula: see text]- Ti4+ · e- and Ti4+ · e- - [Formula: see text] defects, interfacial polarization at insulating grain boundaries, and non-Ohmic contact between the surface sample and the metal electrode.

Dielectric Relaxation, Electrical Conductivity, Dielectric Permittivity, and Correlated Barrier Hopping Conduction Mechanism Analysis in Ag Doped Bi2S3 at Low Temperatures

AbstractPure and 6% Ag doped bismuth sulfide (Bi2S3) were synthesized via solid‐state reaction method at 500 °C. The X‐ray diffraction method confirmed the orthorhombic phase with average crystallite size ∼25 nm and average lattice strain ∼0.5% and ∼0.6% for pure and 6% Ag doped Bi2S3. The scanning electron microscope (SEM) images confirmed nanobelt morphology. A direct bandgap of ∼3.3 and ∼3.4 eV for pure and doped Bi2S3 was estimated using UV–vis spectroscopy, respectively. AC measurements were performed from 200 Hz to 2 MHz at temperature 223–298 K. Investigation of Nyquist plots of 6% Ag doped Bi2S3 nanobelts suggested space‐charge‐dependent behavior and indicated an negative temperature coefficient of resistance (NTCR). AC conductivity adhered to Jonscher's power law in which the decreasing trend of s‐parameter with increasing temperature indicates correlated barrier hopping conduction mechanism. From this model, hopping distance (∼10−9–10−11 m) and density of states (∼1022–1023 eV−1 cm−3) were estimated. The dielectric permittivity exhibited dispersion at low frequencies due to the combined effect of electronic, ionic, and interfacial polarizations. Presence of two semicircular arcs in the complex modulus analysis suggested the presence of both grain and grain‐boundary effects.

Achieving ultra-high energy storage performance in simple systems through minimal element substitution

Dielectric capacitors are essential components of modern advanced electronic devices and power systems based on their ultra-fast charging and discharging speeds and supreme power densities. Nevertheless, how to comprehensively boost their energy storage density and storage efficiency is still an insurmountable challenge. Here, we report a simple micro-chemical polarizability modulation strategy that enables SrTiO3-based dielectric materials to achieve excellent energy storage properties. The energy density and energy efficiency are increased to as high as 76 J∙cm−3 and 72 % from 0.4 J∙cm−3 and 46.7 % of pure STO, respectively, which is the largest value in micro-substitution (less than 3 %). Our results show that the introduction of trace amounts of elements with high ionic polarizabilities (Mn, V) facilitates the increase of chemical disorder and the formation of stable and highly dynamic polar nanoregions (PNRs), which reduces the hysteresis of the polarization switching and improves the polarization at the breakdown field strength, synergistically fostering the energy storage performance. The results of X-ray photoelectron spectroscopy and scanning electron microscopy reveal that the micro-substitution of Mn and V promote the reduction of oxygen vacancies and grain size, improving the breakdown resistance and stability of the capacitor. This present approach is expected to be widely used in the development of high-performance dielectrics.