Corrosion Inhibition Of Copper Research Articles

The Rubus fruticosus Leaf Extract as an Eco-Friendly Copper Corrosion Inhibitor

The Rubus fruticosus Leaf Extract as an Eco-Friendly Copper Corrosion Inhibitor

Improving the performance of silver coating deposited on copper through corrosion inhibitors

Immersion silver plating is an important surface finishing technique in the integrate circuit industry. However, it often results in silver coatings with poor compactness and adhesion due to the significant difference in potentials between silver and copper. The corrosion inhibitors of copper, rather than complexing agents of silver ions, were used to improve the immersion plated silver coating performance on copper. It was found the combined use of benzotriazole and imidazole could regulate the erosion rate of the copper substrate and improve the quality of the silver coating. The effects of different inhibitors concentrations on surface morphology, elemental composition, corrosion resistance, hardness, and conductivity of the silver coating were studied. The results indicated the optimal concentration of the combined inhibitors was 0.058 mol∙L-1, which enhanced the compactness, crystallinity, and overall performance of the silver coating by passivating the copper surface and regulating the silver deposition process.

Eco-friendly impact of a novel green Melilotus officinalis extract as a sustainable inhibitor to reduce acid corrosion of copper.

In this study, we deployed green Melilotus officinalis extract (MOE) as a corrosion inhibitor for copper. The anticorrosion properties of MOE for Cu in 1 M HNO3 were investigated by various experimental and numerical techniques, including potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and a weight loss (WL) method at different temperatures. Additionally, scanning electron microscopy (SEM) coupled with energy-dispersive X-ray analysis (EDX) and atomic force microscopy (AFM) were utilized to examine the surface morphology of Cu with and without the extract. By contrasting the inhibition effectiveness with and without the extract, the inhibition efficiency (% IE) was observed. The WL method revealed that 300 ppm of the extract had an IE of 93.8% for Cu immersed in one molar HNO3 solution. The MOE was classified as a mixed type according to the PDP study since it delayed both cathodic and anodic processes, with a cathodic predominance. At 25-45 °C, MOE's free adsorption energies were 23.1-21.5 kJ mol-1, showing that mixed-type adsorption occurred on the Cu surface. Additionally, the Langmuir adsorption isotherm and the adsorption data from the WL tests of MOE showed a good match. The extract could adsorb spontaneously onto the metal surface, according to the thermodynamic conditions. Analysis of the corrosion product using different techniques revealed that a protective layer had formed on the metal's surface. Hence, MOE had a good corrosive inhibitive effect on Cu in HNO3 solution. It turned out that all the methods used gave consistent results.

Evaluation of cactus mucilage as a green corrosion inhibitor for copper in sulfuric acid environment

This study investigates the corrosion inhibition performance of cactus mucilage for copper in 0.5 M H2SO4 solution. The cactus mucilage was extracted using a pure water extraction method and characterized using FTIR and GC-MS analyses. The inhibition efficiency was evaluated using potentiodynamic polarization and EIS techniques, while surface morphology was analyzed using SEM and AFM. The potentiodynamic polarization results revealed that cactus mucilage acts as a mixed-type inhibitor, with inhibition efficiency increasing from 78.6% at 100 mg L-1 to 94.5% at 600 mg L-1. The EIS measurements showed a significant increase in charge transfer resistance from 0.56 k? cm-2 in the uninhibited solution to 8.26 k? cm-2 with 600 mg L-1 cactus mucilage. The adsorption of cactus mucilage on the copper surface followed the Langmuir isotherm model, with a strong adsorption equilibrium constant of 23.6 × 103 M. Compared to other green inhibitors, cactus mucilage exhibited superior inhibition efficiency and sustainability advantages, making it a promising eco-friendly alternative for copper corrosion protection.

Diphenyl disulfide derivatives as high-efficiency corrosion inhibitors for copper in sulfuric acid: Experimental and theoretical studies

Three organic small molecules, namely Diphenyl disulfide (PDS), 4,4′-Dithiodianiline (DDA), and 4-Methylphenyl disulfide (MDS), were subjected to corrosion screening on copper substrates. Electrochemical testing revealed their corrosion efficacy, with MDS exhibiting the highest efficiency at 98.9 %. Investigation into MDS's corrosion mechanism attributed its superior performance to the presence of hydrophobic methyl groups, facilitating the formation of a denser molecular protective film on the copper surface. The adsorption of corrosion inhibitors on copper surfaces was investigated by Langmuir monolayer adsorption model and X-ray photoelectron spectroscopy. Theoretical calculations further elucidated the inhibitory mechanisms of these sulfurized compounds and the influence of different functional groups on corrosion efficiency. Specifically, the introduction of methyl groups enhanced MDS's ability to displace water molecules on the copper surface, thereby augmenting its corrosion inhibition potential. These findings align with the observations from electrochemical and surface analyses, affirming the efficacy of MDS in mitigating copper corrosion.

A novel corrosion inhibitor for copper in sulfuric acid media: Complexation of iodide ions with Benincasa Hispida leaf extract

In the context of green and low-carbon development, the rapid development of industry brings the problem of metal corrosion costs increase, metal corrosion protection methods are of great concern. Extracts from Benincasa hispida leaves (BHLE), which were obtained through pressurised liquid extraction, were employed as a inhibitor for copper corrosion in 0.5 M H2SO4. Their composition and anti-corrosion properties were subsequently analyzed and evaluated. The electrochemical analysis results indicated that BHLE functions as a cathodic-type corrosion inhibitor. The anti-corrosion performance intensifies with the increase in concentration but diminishes gradually as the temperature rises, when the concentration of BHLE is 400 mg/L, the corrosion inhibition efficiency can reach 91.82 %, when the concentration of added potassium iodide reaches 16 mg/L the slow-release efficiency of the compounded corrosion inhibitor reaches 96.92 %. The addition of I− strengthens the inhibition efficiency through the adsorption form dominated by competitive adsorption. The adsorption of BHLE onto the surface of copper follows the Langmuir monolayer adsorption model.

Experimental and Computational Insights into the Effects of -NH2 and -Cl Functional Groups on the Copper Corrosion Inhibition by Benzotriazole

The influences of -NH2 and -Cl groups on the copper corrosion inhibition in 0.5 M H2SO4 solution by benzotriazole were studied using experimental methods and density functional theory calculations. Mass loss tests, potentiodynamic polarization, and surface morphology analyses revealed notable differences: while unmodified benzotriazole showed an inhibition efficiency of 76.6%, the -Cl derivative increased this to 87.6%, whereas the -NH2 derivative dropped it to 61.0% at the concentration of 5 × 10−4 M. Density functional theory calculations indicated these differences are not due to electronic properties or inhibitor-copper interaction energies but rather to the inhibitor’s influence on the oxygen reduction reaction, especially O2 and H2O adsorption. The -NH2 group formed strong hydrogen bonds with O2 and H2O, reducing oxygen reduction inhibition, while the -Cl group repelled O2, resulting in enhanced inhibition. Free energy analysis of the oxygen reduction reaction supported these findings. These new insights into benzotriazole derivatives’ copper corrosion inhibition mechanisms offer valuable guidance for developing next-generation corrosion inhibitors.

Novel Schiff base derivatives: Enhanced corrosion protection for copper in NaCl solutions – Electrochemical insights and theoretical analysis

This study investigates the corrosion inhibition properties of two recently synthesized Schiff bases, namely 4-bromo-2-(((2-((2-hydroxyethyl)amino)ethyl)imino)methyl)phenol (BHA) and phenyl-2-(((2-((2-hydroxyethyl)amino)ethyl)imino)methyl)phenol (PHA), for copper in a 3.5 wt% NaCl solution. The novelty of this work lies in the use of these Schiff bases, which have not been previously studied in this context, thereby providing new insights into their potential as effective copper corrosion inhibitors. The inhibition performance of the Schiff bases was evaluated using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The potentiodynamic polarization results demonstrated high corrosion inhibition efficiencies of 85.16 % for PHA and 82.78 % for BHA at a concentration of 1 mM, indicating a mixed-type inhibition process with cathodic predominance. The adsorption of these inhibitors on the copper surface was found to follow the Langmuir adsorption isotherm, and the adsorption constants (Kads) and Gibbs free energies (ΔG*ads) were calculated. Quantum chemical calculations, in conjunction with Monte Carlo (MC) and molecular dynamics (MD) simulations, provided further insight into the adsorption mechanisms and supported experimental findings, thus offering a comprehensive understanding of the inhibitors’ efficacy.

Black Cumin Seed Extract as Copper Corrosion Inhibitor in H2SO4 1M: An Experimental and Theoretical Study

Experimental corrosion tests and theoretical calculation were conduct to investigate the corrosion inhibition mechanism of black cumin seed extract for copper in 1 M H2SO4 solution. Electrochemical testing using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) method showed that BCS adsorbed to form a protective layer on the copper surface with high inhibition efficiency at 500 ppm concentration (73,35%). Increasing the BCS concentration up to 500 ppm causes the charge transfer resistance increase in the EIS measurement, while the corrosion current density measured by PDP decreases. The values of charge transfer resistance and corrosion current density at 500 ppm BCS are respectively 3687 .cm2 and 2.86 μA.cm-2. The BCS is a mixed inhibitor (anodic and cathodic) that adsorbs physically on the copper surface and obey the Langmuir isothermal adsorption model. Quantum chemical calculation and molecular dynamic simulation show that the studied BCS molecules adsorb strongly on the copper surface with parallel orientation mode. The methyl linoleate (MLIN) molecules from BCS produce the most stable adsorption energy of the other studied compound molecules as a result of molecular dynamic simulation.

Corrosion Inhibition and Adsorption Behaviour of Centrosema pubescens Leaf Extract for Copper in HCl Solution

Study’s Excerpt In this study, Centrosema pubescens leaf extract (CPE) has been confirmed as eco-friendly and efficient green inhibitor for copper corrosion in hydrochloric acid. Detailed thermodynamic analysis, revealed that CPE adsorption follows a Freundlich isotherm model. SEM-EDX and FTIR characterizations confirmed the formation of a protective layer confirming the potentials of the plant extracts in sustainable corrosion prevention. Full Abstract The anti-corrosion behaviour of Centrosema pubescens leaf extract (CPE) on copper in 1.5 M hydrochloric acid was investigated using weight loss method at different temperatures, followed with scanning electron microscopy (SEM) surface characterization connected with energy dispersive X-ray spectroscopy (EDX). The Fourier transform infrared spectrum of CPE was obtained. CPE inhibition effectiveness depends on the temperature and its concentration. CPE restrains the copper corrosion with 94.26 % inhibition efficiency at 1.0 g/L of CPE and at 303 K. For the CPE-inhibited system, a higher activation energy (Ea) value (range of 31.09 to 38.70 kJmol-1) compared to 20.34 kJmol-1 of the blank solution was obtained. The reaction process is spontaneous and endo thermic, as indicated by the ΔH, ΔS and ΔG values calculated. CPE adsorption behaviour fitted best into Freundlich isotherm.

Corrosion Inhibition of Copper by Pisum sativum Peel Extracts in NaCl Solution: Phytochemical Analysis and DFT Study

Corrosion Inhibition of Copper by Pisum sativum Peel Extracts in NaCl Solution: Phytochemical Analysis and DFT Study

Evaluation of Artichoke Extract as a Corrosion Inhibitor for Copper and OL45 in Aggressive Environments

Abstract Metal corrosion is a significant issue in areas such as transport, construction, or production, with effects on equipment productivity, user safety, and finally, the costs related to the replacement of affected components. Research in recent years has focused on the discovery of substances capable of significantly reducing the corrosion rate of metals and alloys with a minimal impact on the environment. A promising category of green corrosion inhibitors represents active components from natural extracts. Corrosion experiments have been focused on the use of artichoke (Cynara scolymus) stem extract as a corrosion inhibitor for copper and mild steels such as OL45 in H2SO4 0.5 mol L-1 and NaCl 3.5% environments. The electrochemical behaviour of the active components in the artichoke extract was studied using cyclic voltammetry on Pt electrode, and their inhibitory effect has been demonstrated by using electrochemical techniques such as linear voltammetry at a speed of 1 mV s-1 and chronoamperometry method in the absence, respectively, presence of 1, 2, 4, and 8 g L-1 extract. The variation of parameters such as corrosion potential Ecorr, corrosion current icorr, and impedance values with increasing concentrations shows that the artichoke extract greatly reduces the corrosion rate. To complement the corrosion studies carried out, quantum chemical calculations were performed by using the B3LYP/6-31G* basis set, and the descriptors EHOMO, ELUMO, dipole moment, ionization energy, and molecular hardness substantiated the inhibitory effect. Considering artichoke extract components, this study presents a potential prospect for using natural extracts in anti-corrosion protection as well as an ecological alternative to standard corrosion inhibitors.

Eco-friendly corrosion inhibition of copper in NaCl media using Perseana americana extract: Insights from quantum and electrochemical studies

Corrosion of copper in saline environments, particularly in 3.5% sodium chloride (NaCl) solutions, poses significant challenges across various industries, leading to substantial economic losses and safety concerns. Traditional corrosion inhibitors, often synthetic and toxic, raise environmental issues that necessitate the exploration of sustainable alternatives. This study investigates the use of Perseana americana extract (PAE) as an eco-friendly inhibitor for copper corrosion, demonstrating an impressive inhibition efficiency of 96.53% at an optimal concentration of 300 mg/L. Electrochemical assessments, including potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS), reveal that PAE functions as a mixed-type inhibitor, significantly reducing the corrosion current density (icorr) from 3.59 × 10⁻⁵ A/cm2 (without inhibitor) to 1.83 × 10⁻⁵ A/cm2 at 100 mg/L, and further to 0.12 × 10⁻⁵ A/cm2 at 300 mg/L. The adsorption behavior of PAE on the copper surface adheres to the Langmuir isotherm model, indicating monolayer adsorption with a Gibbs free energy of adsorption (ΔGads) of −18.84 kJ/mol, suggesting a predominantly physisorption mechanism. Additionally, Monte Carlo simulations confirm strong interactions between PAE molecules and the copper surface, with the highest adsorption energy recorded for phloretin at −3778.338 kcal/mol, highlighting the extract's potential as a green alternative to conventional inhibitors. This research underscores the viability of utilizing natural plant extracts for effective corrosion control, contributing to more sustainable practices in metal protection.

Expired drugs as vapor-phase corrosion inhibitors of copper in simulated marine atmospheric environment

Expired drugs as vapor-phase corrosion inhibitors of copper in simulated marine atmospheric environment

Corrosion inhibitors in H2O2 system slurry for Ru based barrier layer Cu interconnect chemical mechanical polishing and optimization

Ruthenium (Ru) has the advantages of low resistivity, high thermal stability, and good adhesion and wettability, making it an important solution for breaking through the 14 nm process as a new barrier layer material for multilayer copper interconnect. The purpose of copper (Cu) interconnect Ru-based barrier layer chemical mechanical polishing (CMP) is to obtain a highly flat surface, which not only includes the ideal Ru removal rate and selectivity of the Cu/Ru removal rate, but also inhibition of Cu corrosion. In this article, the corrosion inhibition mechanism of environmentally friendly and highly water-soluble inhibitor 5-methylthio-1 H-tetrazole (MTT) on Cu was studied. The inhibitory effect of MTT on Cu was analyzed through static etching rate testing, electrochemical experiments, and surface characterization. A systematic test was conducted on the planarization performance of the optimized polishing slurry. The corrosion inhibition mechanism of MTT on Cu was revealed through quantum chemical calculations and XPS testing. The experimental results show that the corrosion inhibitor MTT can effectively improve the surface quality of Cu. Quantum chemical calculations and experimental results indicate that MTT can be adsorbed on the surface of Cu through both physical and chemical methods, forming a dense passivation film, thereby inhibiting the corrosion of Cu. The optimized ratio of Ru-based barrier layer CMP polishing slurry was 5 wt% SiO2, 0.15 wt% H2O2, 20 mM ethylenediamine (EDA), 5 mM K4Fe(CN)6, and 2000 ppm MTT, resulted in the Cu/Ru removal rate selectivity of 1:1.18 and the Cu/Ru corrosion potential difference of 3 mV. The average correction values for dishing and erosion on the test pattern wafer of the Ru barrier layer were 355 Å and 280 Å, respectively. The results of this study indicate that MTT is an effective copper corrosion inhibitor in alkaline H2O2-based polishing slurry, providing meaningful references for Ru-based barrier layer copper interconnect CMP.

Experimental and Computational Investigation of Salicylhydroxamic Acid as a Corrosion Inhibitor for Copper in Alkaline Solutions

Inhibitors, as indispensable components in chemical mechanical polishing (CMP) slurries, have a significant impact on inhibiting copper (Cu) corrosion and enhancing post-polishing surface quality. However, one of the major challenges in CMP lies in unraveling the microscopic corrosion inhibition mechanism of Cu. This work focuses on investigating the impact of an inhibitor, salicylhydroxamic acid (SHA), on the static etching rate (SER), electrochemical parameters, and surface morphology of Cu. The experimental findings demonstrate that SHA significantly decreases the SER and corrosion current density of Cu, while notably improving the Cu surface quality. The corrosion inhibition mechanisms of SHA on Cu are revealed through adsorption isotherm models, contact angle analysis, electrochemical impedance spectroscopy, and computational chemistry method. The benzene ring, oxime group, and O1 atom of SHA exhibit significant chemical reactivity, facilitating the preferential adsorption of SHA on Cu in a parallel orientation, thereby forming a hydrophobic protective film on the Cu surface. This process hinders the interaction between corrosive solutions and Cu, therefore SHA exhibits excellent corrosion inhibition performance on Cu. These findings hold great importance in gaining a deeper comprehension of the corrosion inhibition process of Cu, and provide guidance for designing more efficient inhibitors.

Synthesis, spectroscopic characterization of a new schiff base molecule, investigation as an efficient corrosion inhibitor for copper in sulfuric acid medium: combination of experimental and theoretical researches

A new Schiff base inhibitor known as “N, N’ carbonyl- Bis (para-hydroxy benzaldehyde imine)” has been synthesized and characterized by FTIR, NMR, and UV-Visible spectroscopy, the molecule was then assessed for its ability to prevent copper from corroding in a solution of 0.5 M H2SO4 using potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy SEM combined with energy dispersion spectroscopy EDX, and atomic force microscopy AFM. The tested inhibitor exhibits good copper corrosion inhibition performance in a 0.5 M H2SO4 solution. As inhibitor concentration rises, inhibition performance also rises, reaching a maximum inhibitory efficacy of around 84.76 ± 0.69% at 5.10−4 M. The inhibitor was adsorbable to the metal surface and followed the Langmuir isotherm. It has been done such that the addition of KI increased the inhibitory effectiveness, the mixed additives worked together. There is good agreement between the conclusions drawn from theoretical calculations using DFT and MD simulation and actual observations.

Characterization of Polyvinylpyrrolidone-2-Acrylamide-2-Methlypropansulphonic Acid Based Polymer as a Corrosion Inhibitor for Copper and Brass in Hydrochloric Acid

Characterization of Polyvinylpyrrolidone-2-Acrylamide-2-Methlypropansulphonic Acid Based Polymer as a Corrosion Inhibitor for Copper and Brass in Hydrochloric Acid

Experimental and computational explorations for the inhibitive performances of synthesized green surfactants against the corrosion of copper in nitric acid

The inhibitory characteristics of two recently synthesized biosurfactants based on amino acids, namely sodium N-hexadecyl glycine (I) and sodium N-hexadecyl valine (II), concerning copper corrosion in 1.0 M HNO3 were studied at variance of temperatures. FTIR analysis was utilized to identify the chemical structures of both synthesized biosurfactants. Various techniques were employed in this study. According to the results, the synthesized biosurfactants were played as proficient inhibitors for copper corrosion and their inhibition efficiencies (% IEs) were concentration- and structure-dependent with respect to them. At a concentration of 400 mg/L of the synthesized biosurfactants and at 298 K, the average% IE was found to be 90% for biosurfactant I and 85% for biosurfactant II. The gained higher% IEs were suggested to as a result of the potent adsorption of these biosurfactants on the surface of copper and the type of adsorption was discovered to be physical and followed Langmuir adsorption isotherm. The obtained findings signified that the synthesized biosurfactants exhibited mixed-type and interface-type inhibitors. The thermodynamic and kinetic parameters were assessed and discussed. Furthermore, the kinetics of corrosion of copper as well as its inhibition were also investigated. The density functional theory (DFT) and molecular dynamics (MD) simulations emphasized the inhibitory mechanism of the examined biosurfactants and proved the adsorption of the biosurfactants’ molecules on the copper surface. Theoretical modeling also demonstrated that the biosurfactant I exhibited a greater% IE compared to biosurfactant II. The experimental results gained from all employed measurements are largely reliable with each others and are in a good consistent with the theoretical studies signifying the validity of these results.

Exploring the Potential of a Green Synthesized Chromene Derivative as an Inhibitor for Copper Corrosion in Acidic Environments: A Combined Experimental and Theoretical Investigation

Exploring the Potential of a Green Synthesized Chromene Derivative as an Inhibitor for Copper Corrosion in Acidic Environments: A Combined Experimental and Theoretical Investigation