Increase In Water Content Research Articles

Influence of Water Concentration on the Water/Vapor/ Oil Separation Process in a Vacuum Oil Filter: Modelling and Simulation

The vacuum oil filter (VOF) is widely applied in the oil-water emulsion demulsification separation due to the phase separation by using vacuum evaporation; however, the micro-dynamic characteristics of oil, water and vapor three phases and the influencing factors of separation efficiency are rarely studied. Therefore, the fluid flow and phase separation characteristics of water-in-oil emulsions were numerically analysed by ANSYS software. The demulsification conditions of water/oil emulsion were simulated by using the two-fluid model and the water evaporation model, and the turbulence effect was considered by using the Reynolds stress model. The results show that the established model could provide a convenient way to study the effects of the different water concentrations in oil; the turbulence intensity in VOF increases with the increase of water concentration in oil; The separation efficiency has been influenced by the inlet water concentration reaching values between 20.65-22.62% in the center axis, while 33.18-42.24% in the plate column; the vapor concentration ranged from 0 - 23.64% in the center axis, while 0 - 41.02% in the plate column. The relative volume fraction of water concentration decay tending with the water concentration increases, and the water concentration has a great influence on the separation efficiency.

Constitutive model analysis of Chang'e-5 simulated lunar regolith solidified bodies under compression

China’s Chang'e-5 spacecraft successfully collected 1731 g of Lunar regolith and returned it to Earth on December 17, 2020. In this paper, Chang'e-5 simulated Lunar regolith is used as the main material to form stable and dense solid Lunar soil structures by adding different amounts of an inorganic curing agent and water. The internal morphology, failure morphology under uniaxial compression, and stress–strain relationship of the Lunar regolith solidified samples (L-R-S-Ss) are then investigated. The damage constitutive model of the Lunar regolith cured body is analyzed according to the stress–strain curves, with the following results found. (1) Scanning electron microscopy indicates that the L-R-S-Ss contain more microvoids and microfractures, which are the main factors that lead to destruction. (2) The uniaxial failure mode of the L-R-S-Ss is primarily split failure, with both vertical and oblique cracks, with the angle between the main crack and the vertical axis being less than 30°. (3) The content of the curing agent and the amount of water are important factors affecting the L-R-S-S strength. As the water content increases, the L-R-S-S compressive strength tends to decrease. The L-R-S-S strength increases with increasing amount of cementitious material. (4) A cubic polynomial and a rational fraction are used to fit the ascending and descending sections of the L-R-S-S stress–strain curves, respectively, and a piecewise constitutive model of the L-R-S-S specimens is proposed. The calculated results of the model are in good agreement with the experimental curves.

Initial soil moisture and soil texture control the impact of storm surges in coastal forests

Flooding and salinization triggered by storm surges threaten the survival of coastal forests. The forest root zone (top 40 cm of soil) is the most affected by surge flooding. Determining the effect of a storm surge on edaphic conditions is essential to estimate vegetation response. Pre-storm soil hydrology could mitigate or enhance the salinization effect, ultimately determining the resilience of the forest. Here we assess the influence of pre-storm soil water content and salinity on storm surge effects in coastal vegetated areas. A 1D model (HYDRUS-1D) is used to simulate saltwater infiltration from above through the unsaturated zone. Different water content and concentration scenarios, along with scenarios with variable storm surge salt concentration, storm surge height and storm surge flooding duration are considered. In soils characterized by silt and clay, the maximum salinized soil depth increases as water content increases, affecting the top 40 cm of soil, except for clay loam soil, for which only the top 20 cm are salinized. In sandy soils, the salinization process involves the entire soil column. The contribution of water content to salinization varies from 12 % to 30 % along the top 40 cm in fine soils. In fine soils, the storm-surge height also becomes relevant. A study case is presented to support the numerical results. Field data confirm that soil water content controls the salinization of the root zone in clay and silt soils. Overall, we conclude that the root zones of coastal forests with clay and silt soils and low water content are the most at risk during storm surges. These events have the potential to radically change edaphic conditions and affect ecosystems.

Behaviour of wet clay due to off-road traffic loading

Abstract The presence of water in the soil can greatly affect the trafficability of off-roading vehicles, making it difficult to operate. As the water content increases, it can eventually lead to sinkage and immobility. Despite the relevance of this topic in many applications, such as military, agricultural, and earthmoving vehicles, the studies available on tire and moist soil interaction are limited. The numerical modeling of such a system is very challenging because it requires accounting for hydro-mechanical effects, large deformations, non-linear behavior, and complex interactions between the tire and the soil. This work contributes to the understanding of the behavior of moist clay under the influence of traffic loading. In particular, the preliminary results of numeric simulations to study the interaction between moist clay and a passing tire using physics-based techniques are presented. A great emphasis is given to the development of an accurate soil model that can capture the fundamental characteristics of moist clays in saturated conditions.

Highly selective alginate/CuO mixed matrix membranes for efficient dehydration pervaporation of various organic solvents

Pervaporation is an energy-efficient technique for dehydrating organic solvents from aqueous mixtures. To develop a highly selective pervaporation membrane with broad usage, we incorporated three types of CuO particles (solid CuO-S, sea urchin-like CuO-U, and porous CuO-P) into sodium alginate (Alg) for fabricating the Alg/CuO mixed matrix membranes (MMMs). The CuO syntheses and membrane preparation are simple and eco-friendly. The synthesized particles and membranes were systematically characterized. The improved hydrophilic feature of Alg/CuO MMMs was validated from the reduced water contact angle and higher water swelling ratio with increasing CuO wt%. When the Alg/CuO MMMs were applied to the pervaporation of 30 wt% water/isopropanol (IPA) at 25 ℃, both the permeation flux and separation factor were enhanced significantly compared to the pure Alg membrane. The separation efficiency followed the order of Alg/CuO-S MMMs < Alg/CuO-U MMMs < Alg/CuO-P MMMs, in good agreement with their water swelling tendency. The incorporation of 3 wt% porous CuO-P particles in MMM achieved the optimal dehydration efficacy (normalized total flux of 3.5 kg m-2h−1, separation factor of ca. 5000, and water purity of 99.96 wt%, with a stable performance over 168 h). A further larger loading wt% led to a decreased separation selectivity due to more void formation from particle aggregation. With an increase in feed temperature, both the permeation flux and separation factor were improved; however, the increase in feed water concentration deteriorated the separation selectivity while enhancing the flux. Furthermore, the high selectivity and broad applicability of Alg/3% CuO-P MMM were fruitfully demonstrated by exhibiting superior separation efficiencies in dehydrating various polar aprotic solvents compared with several membranes discussed in the literature.

Interindividual Variation in Gut Nitrergic Neuron Density Is Regulated By GDNF Levels and ETV1

The size and function of the enteric nervous system (ENS) can vary substantially between individuals. Because ENS function is involved in the etiology of a growing number of common human diseases, understanding mechanisms that regulate ENS variation is important. We analyzed RNAseq data from 41 normal adult human colon biopsies and single-cell RNA-seq data from human and mouse developing gut. To establish cause-consequence relationship we used alleles in mice that allow levels change of the candidate effector molecule in the comparable range to human samples. We used siRNA and primary neuronal cultures to define downstream molecular events and characterized gut functional changes in mice where molecular phenotypes paralleled findings in humans. We found that glial cell line-derived neurotrophic factor (GDNF) levels in the human colon vary about 5-fold and correlate strongly with nitrergic marker expression. In mice, we defined that GDNF levels are regulated via its 3' untranslated region (3' UTR) in the gastrointestinal tract and observed similar correlation between GDNF levels and nitrergic lineage development. We identified miR-9 and miR-133 as evolutionarily conserved candidates for negative regulation of GDNF expression in the gastrointestinal tract. Functionally, an increase in inhibitory nitrergic innervation results in an increase in gastrointestinal tract transit time, stool size, and water content accompanied with modestly reduced epithelial barrier function. Mechanistically, we found that GDNF levels regulate nitrergic lineage development via induction of transcription factor ETV1, corroborated by single-cell gene expression data in human and mouse developing enteric neurons. Our results reveal how normal variation in GDNF levels influence ENS size, composition, and gut function, suggesting a mechanism for well-known interindividual variation among those parameters.

Quantitative experimental study on the apparent contact angle of unsaturated loess and its application in soil–water characteristics curve modeling

AbstractAdvancing and receding water contact angles, often denoted as the maximum and minimum apparent water contact angles, are crucial parameters reflecting a soil's water holding capacity. These parameters play an important role in establishing theoretical soil–water characteristic curves (SWCCs) for unsaturated soils. However, pre‐assuming constant advancing and receding contact angles during soil wetting and drying processes may be erroneous due to their close correlations with the water content and void ratio. To address this research gap, systematic laboratory measurements were conducted on a loess with different void ratios and water contents. Apparent water contact angles were acquired using an axisymmetric drop shape analyzer, enabling a comprehensive dataset. Analysis of variance was employed to assess the statistically significant differences between void ratios and water contents. The results reveal a significant increase in the observed water contact angle as the void ratio decreases and a decrease with increasing water content. Although both the void ratio and water content influence the water contact angle, the latter has a more pronounced effect. The relationship between the receding water contact angle and water content/void ratio is observed to be linear. The identification of this linear relationship offers insights into the fitting of the SWCC for loess across varying void ratios. This study serves to enhance theoretical methodologies, particularly in the adaptation of contact angles, thus facilitating the development of more precise SWCC models.

Experimental study on deformation characteristics of seasonal subgrade soil under dynamic load.

In Northwest China, the highway infrastructure often faces challenges due to the widespread presence of subgrade soil. This soil undergoes significant changes in performance under cyclic loading and freeze-thaw cycles. To effectively design and construct highways in these regions, it is crucial to understand the impact of various factors on the deformation characteristics and mechanical properties of subgrade soil. This study aims to investigate the influence of freeze-thaw cycles, water content, confining pressure, and loading rate on the deformation behavior and mechanical properties of subgrade soil under cyclic loading conditions. Experimental tests were conducted to analyze the deformation characteristics and mechanical properties of the subgrade soil. The test results revealed the following: 1) Dynamic loading leads to a noticeable decrease in the strength of subgrade soil, resulting in a softening effect on the stress-strain curve. The cumulative strain of the soil is positively correlated with the number of freeze-thaw cycles and water content, while negatively correlated with confining pressure. The final cumulative strain remains below 1%. 2) The failure stress of subgrade soil decreases exponentially with an increase in freeze-thaw cycles, dropping from 224.52 kPa to 196.76 kPa. 3) An increase in water content linearly decreases the failure stress of subgrade soil, ranging from 377.1 kPa to 151.5 kPa. 4) Confining pressure exhibits a linearly increasing relationship with the failure stress of subgrade soil, ranging from 151.6 kPa to 274.5 kPa. 5) The failure stress of subgrade soil demonstrates a linear increase with the loading rate, ranging from 200.46 kPa to 210.62 kPa. These findings provide valuable insights for the design and construction of highways in seasonal frozen areas. They also offer guidance for preventing and mitigating subgrade freeze-thaw issues in the future.

Experimental study on characterization of resilient modulus and prediction model of saline aeolian sand

The dynamic resilience characteristics of aeolian sand subgrade are influenced by salt content and water content, exhibiting significant stress dependence and anisotropy. The resilient modulus(MR) of aeolian sand represents the stress-strain nonlinearity under cyclic loading, serving as an important parameter for the design of aeolian sand subgrade in desert areas. In order to investigate the variation of MR of aeolian sand subgrade with salt content and water content under traffic loading, as well as the MR characteristics under these conditions, three types of aeolian sand samples with varying water content and four sulphate contents were prepared. The variation of MR of aeolian sand under different confining pressures and deviator stress levels, as well as the influences of water content and salt content, was studied through indoor dynamic triaxial testing. Based on the pattern of the fitting parameters of the benchmark model, a prediction model suitable for the MR of aeolian sand was constructed. The results indicate a rise in aeolian sand's MR with increasing deviator stress and confining pressure, with confining pressure having a more significant impact than deviator stress. With the increase in water content, the MR of aeolian sand decreases nonlinearly, and with the increase in salt content, it exhibits a wave-shaped trend of "increasing-decreasing-increasing," which is related to the dissolution state of sodium sulfate in the soil. Based on the experimental results, a prediction model of the MR of aeolian sand was established, derived from the benchmark model, which can reflect the influence of salt content and water content on the MR, introducing them as variables within the model.

Low-density granite-based geopolymer for well cementing: The role of burnt lime in enhancing early strength

In the pursuit of sustainable solutions within the oil and gas industry, the environmental and mechanical limitations of Ordinary Portland Cement (OPC) have led to the evaluation of more sustainable alternative materials for oilwell cementing applications. Particularly in shallow-depth cementing operations, where low-density slurries are essential to prevent formation breakdown, current solutions fall short in balancing environmental impact with the industry's performance requirements. Geopolymers, known for their reduced carbon footprint and comparable mechanical properties, have been seen as a promising alternative. However, increasing water content to lower the slurry density remains a challenge for geopolymers due to the weakening effect and prolonged reaction. The specific role of burnt lime (CaO) has the potential to enhance the early strength of low-density geopolymers yet remains under-explored for this particular case. This study aims to fill this gap by examining the effects of two different reactivities of CaO on a low-density granite-based geopolymer at low temperatures and investigate the potential of CaO to enhance the early strength of low-density geopolymers, aiming to provide a sustainable alternative to traditional cementing materials in oil well operation. The investigation consists of viscosity measurements, pumpability tests, and compressive strength evaluations. Additionally, isothermal calorimetry, TGA, XRD, and SEM were conducted to gain a deeper understanding of the behavior of each sample. Supplementary tests were conducted to evaluate the effect of varying CaO concentrations and the impact of mud contamination on the performance of low-density geopolymers. The investigation revealed that calcium oxide did not significantly impact the initial viscosity of the slurry however, it affects gelation and rate of the reaction. Short-term strength was shown to be affected by CaO at two different temperatures, yet negligible effects were seen in the long-term period for geopolymers with a high water-to-solid ratio. The findings suggest that CaO can significantly enhance the early strength of geopolymers, which are crucial properties for cementing operations in oil and gas wells. This could contribute to accelerate the possibility of geopolymers as a viable sustainable replacement for Portland cement especially in shallow and low-temperature well-cementing applications.

Experimental study on freezing temperature and its influencing factors of loess contaminated by heavy metals

This paper attempts to reveal the freezing temperature and its influencing factors of heavy metal-contaminated loess by adopting two cooling methods: fast and slow grading. As a result, Lanzhou loess was used as an experimental material to make polluted soil with varying heavy metal concentrations and initial water content. The pollutant elements included Zn, Ni, Cu, Cr, Cd, and Pb. The findings demonstrate that: 1) The slow cooling rate causes supercooling, jumping, and a progressive decrease in the temperature of the polluted soil. Different cooling methods have no obvious effect on freezing temperature. Furthermore, the freezing temperature of contaminated soil varies depending on its water content. The impact of increasing water content on freezing temperature is not evident; 2) The freezing temperature of loess decreases with the increase of heavy metal ion content. The freezing temperature of loess polluted by Zn, Ni and Cd ions decreased linearly with the increase of ion content. The influence of cations on the freezing temperature of loess is as follows: Zn2+> Ni2+> Cd2+> Cr3+> Pb2+> Cu2+. The influence order of anions is Cl− > SO42−; 3) The freezing temperature of loess containing heavy metal ions is about equal to the freezing temperature of the corresponding heavy metal solution plus the freezing temperature of loess itself. The freezing temperature of heavy metal-polluted loess follows the temperature superposition principle.

Tribological properties of diamond-like carbon films lubricated with water-emulsified engine oil

In this work, the tribological properties of two diamond-like carbon (DLC) films were investigated at different temperatures using water-engine oil emulsions as lubricants, considering emerging fuel systems such as hydrogen and ammonia. The results revealed that the friction coefficient of a-C film raised with the increasing water content at 80 °C. The friction coefficient of a-C:H film initially raised and then decreased with varying water fractions at different temperatures. Elevated temperature exacerbated the wear of both DLC films at high water contents. The most significant wear was observed for a-C film at 80 °C and a-C:H film at 50 °C. The a-C:H film exhibited more sensitive wear characteristics to water content than the a-C film. Surface analysis indicated that water-engine oil emulsions prevented the formation of phosphate tribo-film on steel friction pair for two DLC films but promoted the tribo-oxidation of steel pair sliding contact with a-C film, especially at higher temperatures. Distinct reactivities of two DLC films towards water molecules could affect the adsorption of lubricants on DLC surfaces, leading to their different friction and wear behavior. It suggests that the water-caused emulsification of lubricating oil will be a pivotal consideration in tribological applications of DLC films in future internal combustion engines.

Stability of Pure Biodiesel (B100), Biodiesel Mixture (B40), and Petroleum Diesel (B0) Due to Storage

Biodiesel is produced from synthetic ester compounds of vegetable and animal oils through a process of refining, bleaching, degumming, transesterification, and esterification. The quality and characteristics of the fuel are greatly influenced by the storage. The purpose of this research is to determine and analyze the effect of storage conditions on the physical and chemical changes of biodiesel (B100), biodiesel blend (B40), and petro diesel (B0). Experiment was conducted by storage fuels using glass bottle for 35 days arranged into four conditions based on cap and wrapping using aluminum foil, namely P1 (with cap, with wrapping), P2 (with cap, no wrapping), P3 (no cap, with wrapping), and P4 (no cap, no wrapping). Results showed that fuel quality decreases due to storage indicated by an increase in water content, density, acid number, and color parameters, as well as a decrease in the specific calorific value of all fuels. The condition of the storage container affected the changes the quality parameters. Based on its impact on fuel quality decline, the order of storage container conditions from the best is P1 (with cap, with wrap) &gt; P2 (with cap, no wrap) &gt; P3 (no cap, with wrap) &gt; P4 (no cap, no wrap). Keywords: Biodiesel, Biodiesel blend (B40), Diesel fuel, Stability, Storage time.

Experimental study on the shear characteristics of frozen soil‐concrete interface under the constant normal stiffness

AbstractThe interaction between the structure and soil is a crucial factor in infrastructure stabilization in cold region engineering, both transversely and vertically. During interface deformation, the transverse action is reflected in the change of constraints, including normal stiffness, normal stress, and normal volume, while the vertical action is reflected in the change of shear properties. However, the study of different transverse constraints is not systematic, especially considering the normal stiffness and shear properties at different hydrothermal states. This study investigated the shear behavior of the interface between concrete and frozen soil under different normal stiffness, temperature, and water content using the interface direct shear test under temperature‐controlled conditions. The results show that with the increase in temperature and water content, the initial shear stiffness of the interface shear stress‐shear displacement curve gradually increases, and the interface shear strength gradually increases. Different normal stiffnesses have a small effect on the morphology of the interfacial shear stress‐shear displacement curve but significantly affect the peak shear strength. The peak shear strength increases significantly with the increase of normal stiffness, and this trend is more obvious with the decrease in temperature. The corresponding interfacial cohesion and friction angle also increases with the increase in normal stiffness.

Mechanical properties of teguline clay pellet mixtures during continuous oedometric compression

Clay pellet mixtures are generally compressed to improve their engineering performance. Deepening the comprehension of the mechanical properties of these mixtures in the complete compression process facilitates the benefit to the engineering design and their utilization. In this study, the effects of soil grain size distribution, water content and dry density on the mechanical properties and microstructure of Teguline clay pellet mixtures during a continuous oedometric compression process are explored. Three types of soil pellet mixtures, including mixture A (grain size ≤5 mm), mixture B (≤ 0.4 mm) and mixture C (2–5 mm), were prepared with different water contents of 7%, 8% and 12% respectively. Subsequently, continuous oedometeric compression was undertaken to explore their mechanical behaviours of the soil pellet mixtures. After that, the microstropic structures of the compacted pellet mixtures were investigated using mercury intrusion porosimetry (MIP). The results indicated that mixture A has a minimal initial packing density of pellet mixtures, while mixture C has a maximum one at the initial compression stage. After completion of compression, the compression curves of the pellet mixtures tended to converge uniformity at a semilogarithm coordinate as the vertical stress increased. All of the compression curves presented a concave shape at the plastic compression stage, which is significantly influenced by grain size distribution and water content. In contrast, the elastic compression and rebound behaviours are little affected by the grain size distribution and water content. As far as the microstructure is concerned, compacted samples prepared by mixture A or C presented a unimodal pore structure, while those by mixture B showcased a bimodal pore structure. In comparison with the unimodal pore distribution of the undisturbed stiff clay, the compacted samples displayed a pseudo-unimodal pore distribution because the inter-aggregate pores still existed. A double tangent method was proposed to determine the delimiting pore diameter of the pseudo-unimodal pore distribution curves and found that the delimiting pore diameter decreased with the increase of dry density and water content. Moreover, the inflexion point for the pore diameter of compacted samples prepared by coarse soil was larger than that of fine soil. Combining this work with previous research, it was found that the high compression of coarse soil easily causes the pseudo-unimodal shape, which is also impacted by water content and particle properties. This work could help deepen the understanding of the mechanical characteristics and microstructure of the stiff clay pellet mixtures during continuous oedometric compression.

Root tensile strength and suction-characteristic as indicators for screening species for slope stabilization in extreme climates

Root water potentials, essential for understanding drought tolerance and transpiration, can also influence root tensile strength, which is valuable for selecting plants for slope stabilization and erosion control in extreme wet and dry climates. This study investigated the relationships between root suction, water content, diameter and tensile strength of Cnidoscolus aconitifolius and Bougainvillea glabra to explore their potential for slope stabilization. Both species showed an increase in root water content and a decrease in suction with larger root diameter, despite their inherent difference in the tensile strength and suction relationship. The tensile strength versus suction plots clearly showed that Bougainvillea glabra can sustain higher load as root suction increases and is likely to perform better in extremely dry condition than Cnidoscolus aconitifolius. Observation of field performance indicated that this is the case which warrants further study on root suction for selecting species in stabilization of slopes in extreme climates.

Rising damp in heritage sites under urban expansion: A comprehensive case study of the Jinsha Earthen Site

Rising damp poses a significant threat to cultural heritage, yet its dynamics within actual heritage sites remain inadequately understood, particularly regarding its evolution and the impact of urbanization. The Jinsha Site, an earthen site from the Shang periods, is primarily composed of silt, with a layer of sand beneath and pebbles at the bottom, making it susceptible to rising damp. This study investigates the Jinsha Site as a case, monitoring soil water content and electrical conductivity, tracking changes in groundwater, precipitation, and river water levels, and investigating the relationship between urbanization and rising damp. The study aims to understand the process, causes, and influencing factors of rising damp and evaluate previous preservation strategies. The findings indicate that groundwater level in the sand layer trigger dampness, whereas the pebble layer exhibits dryness. Urban construction from 2006 to 2013 and 2014–2017 caused fluctuating groundwater levels, leading to repeated transitions between dryness and dampness at the site. Rainfall and river levels have negligible effect; even rainfall exceeding 100 mm (frequency <0.0056) only raises groundwater levels by approximately 1 m and increases water content by less than 2 % for a brief duration, typically less than half a month. The 2022 groundwater pumping strategy effectively maintained levels beneath the pebble layer (506 m), decreasing moisture by 12.71 % and conductivity by 0.27 dS/m. This study reflects on previous protection effortsand offers evidence-based strategies for heritage conservation amidst urban expansion.

Experimental study of the effect of crude oil water content on boilover fire

When a tank experiences a boilover fire, oil droplets splash, heat release rate and flame height increase, posing significant hazards. Water is a necessary condition for boilover to occur, but current research mainly focuses on boilover caused by water layer, neglecting the influence of water content inherent in crude oil on boilover phenomena. In this study, crude oil with a water content ranging from 0.26 % to 3 % was utilized, and a series of boilover fire experiments were conducted by varying the presence or absence of a water layer and the initial oil thickness and by carrying out a series of boilover fire experiments focusing on the effect of water content on the boilover phenomenon. The results indicate that emulsified crude oil has a droplet micro-explosion phase during the stable combustion stage. When no water layer is present, the boilover process duration is brief, and the transient injection effect is notable, with boilover intensity increasing with water content. Upon adding a water layer, emulsified water abbreviates the boilover onset time, diminishes the combustion rate, and promotes the formation of the hot zone. The upper and lower limit values of the hot zone temperature decrease with increasing water content, while the temperature difference remains essentially unaffected, remaining constant at about 50 °C. Boilover intensity exhibits a nonlinear relationship with increasing water content, peaking at 2 % water content. The pre-boilover burned mass ratio remains relatively stable, maintained between 12 % and 15 % across all working conditions. Both the splash range and maximum heat flux increase with initial oil layer thickness but show no significant change with water content. Moreover, the safety distance corresponding to the heat radiation threshold exceeds the splash distance, indicating that heat radiation hazards predominate. The results of this paper will help provide guidance for fighting emulsified crude oil fires.

The Role of Water Content and Binder to Aggregate Ratio on the Performance of Metakaolin-Based Geopolymer Mortars

Geopolymers are in many applications a perfect alternative to standard cements, especially regarding the sustainable development of green building materials. This experimental study therefore deals with the investigation of different factors, such as the water content and the binder to aggregate ratio, and their influence on the workability of fresh mortar and its mechanical properties and porosity on different size scales. Although increasing the water content improved the workability and flow behaviour of the fresh mortar, at the same time, a reduction in compressive strength in particular and a lesser reduction in flexural strength could be demonstrated. This finding can be attributed to an increase in capillary porosity, as demonstrated by capillary water uptake and mercury intrusion porosimetry measurements. At the same time, the increasing water content led to an improved deaeration effect (low air void content) and to initial segregation (see the µXCT measurements). An alternative approach to enhance the compressive and flexural strengths of the mortar specimens is optimization of the binder to aggregate ratio from 1 to 0.25. This study paves the way for a comprehensive understanding of the underlying chemistry of the geopolymerization reaction and is crucial for the development of sustainable alternatives to cementitious systems.

Humidity-Controlling Ceramic Bricks: Enhancing Evaporative Cooling Efficiency to Mitigate Urban Heat Island Effect

Passive evaporative cooling technology using the building envelope is a crucial measure to mitigate the urban heat island effect. This study aims to enhance the cooling efficiency of the surface of enclosure structures by utilizing volcanic ash, potassium–sodium stone powder, and silica-based mesoporous oxide (SMO) as primary materials. These components are incorporated into the ceramic brick production process to create innovative humidity-controlling ceramic bricks (HCCTs). This study extensively investigates the impact of SMO and the amount of applied glaze on the physical and mechanical characteristics of these HCCTs. Additionally, it examines the water absorption and evaporative cooling properties of the studied materials under optimal substitution conditions. Numerical calculations are used to determine the heat and moisture transfer properties of HCCTs. The results indicate that incorporating 2% SMO and applying 70 g/m2 of glaze results in a moisture absorption capacity of 385 g/m2 and a moisture discharge capacity of 370 g/m2. These conditions also yield a notable flexural strength of 15.2 MPa. Importantly, the HCCTs exhibit significantly enhanced capillary water absorption and water retention capabilities. Increased water absorption reduces surface temperature by 2–3 °C, maintaining the evaporative cooling effect for 20 to 30 h. It is also found that the temperature of HCCTs decreases linearly with increasing water content and porosity, while the temperature difference gradually decreases with thickness. Water migration in HCCTs with greater thickness is notably influenced by gravity, with water moving from top to bottom. Therefore, it is recommended that brick thickness does not exceed 15 mm.