PEM water electrolysis is a promising technology for renewable hydrogen production. However, improving the performance and efficiency of PEM water electrolyzers requires a thorough understanding of the properties and behavior of their components. Here we present a robust and effective method for determining the sheet resistance of porous electrodes commonly used in technologies such as PEM water electrolyzers. For this, a new analysis method was developed that relies on industrial printed circuit boards, allowing resistance measurements at ten different length scales ranging from 250 µm to 2500 µm and a 1D mapping of the resistance at each length scale. The sheet resistance of a commercially available reference material is characterized in order to validate the method, and the impact of compression force on the probe-sample contact is demonstrated. Furthermore, the sheet resistance of commonly used PEM water electrolyzer components is investigated. This includes the discussion of the gas diffusion layer, porous transport layer, and catalyst layers coated onto a membrane. Besides, by using an image processing-based method, the thickness distribution of the catalyst layers can be obtained and is correlated with the electrical in-plane resistivity. The results indicate that the sheet resistance is a more relevant parameter than the in-plane electrical resistivity to characterize catalyst layers. We will present a ranking of different PEM water electrolyzer components according to their sheet resistance for both anode and cathode catalyst layers. Acknowledgement This project has received funding from the European Union's Horizon 2020 research and innovation programme under the PROMET-H2 grant agreement No 862253.
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