Improved Energy Resolution Research Articles

A WISER way for simulating the performance of gratings.

Soft X-ray monochromators for synchrotron radiation sources have been continuously developed over the years, improving energy resolution and stability. Great effort has been made in improving the surface quality of the optics involved, reaching values permitting diffraction-limited images. Still, one problem has not been solved, nor fully understood, yet: groove placing errors. Nowadays, these are one of the major factors responsible for resolving the power reduction of diffraction-gratings-based X-ray monochromators. Despite decades of use of gratings, there is not yet a universally established method for predicting and simulating the effect of groove placing errors on monochromator performance. This is especially important in the new scenario of high-coherent X-ray sources, i.e. diffraction-limited storage rings and free-electron lasers. To address this problem, in this article an approach based on WISER (Wavefront propagatIon Simulation codE libRary) is presented. WISER is a physical optics simulation package, also available in the user-friendly Orange Synchrotron Radiation Suite - OASYS. Even though it was originally conceived to assess the focusing performance of X-ray mirrors in the presence of height defects, it perfectly simulates the performance of a periodic (or quasi-periodic) structure like a diffraction grating. In this article, the way to use WISER and its application to a specific case, e.g. the design of a monochromator for the upgrade of a beamline at the Advanced Light Source, are shown. A simple rule for estimating how well the grooves are placed on a grating, based on calculation of the Strehl ratio, is also presented.

A new class of variable-radii diffraction optics for high-resolution x-ray spectroscopy at the National Ignition Facility (invited).

A new class of crystal shapes has been developed for x-ray spectroscopy of point-like or small (a few mm) emission sources. These optics allow for dramatic improvement in both achievable energy resolution and total throughput of the spectrometer as compared with traditional designs. This class of crystal shapes, collectively referred to as the Variable-Radii Spiral (VR-Spiral), utilize crystal shapes in which both the major and minor radii are variable. A crystal using this novel VR-Spiral shape has now been fabricated for high-resolution Extended X-ray Absorption Fine Structure (EXAFS) experiments targeting the Pb-L3 (13.0keV) absorption edge at the National Ignition Facility. The performance of this crystal has been characterized in the laboratory using a microfocus x-ray source, showing that high-resolution high-throughput EXAFS spectra can be acquired using this geometry. Importantly, these successful tests show that the complex three-dimensional crystal shape is manufacturable with the required precision needed to realize the expected performance of better than 5eV energy resolution while using a 30mm high crystal. An improved generalized mathematical form for VR-Spiral shapes is also presented allowing improved optimization as compared to the first sinusoidal-spiral based design. This new formulation allows VR-Spiral spectrometers to be designed at any magnification with optimized energy resolution at all energies within the spectrometer bandwidth.

Development of a magnetic shield for 20-inch microchannel plate photomultiplier tubes

A newly developed 20-inch photomultiplier tube with good timing response and improved energy resolution uses a microchannel plate instead of traditional dynodes. Thin flexible sheets of high-permeability iron-based amorphous alloy foils encased in thin polyethylene terephthalate layers are used to shield the photomultiplier tube from the geomagnetic field. The work reported in this paper shows that the detection efficiency is increased by 87% on average with the help of this magnetic shield, and the number of secondary electrons is reduced by a factor of 2 for 20-inch MCP-PMT at LHAASO-WCDA.

Proton-Induced Activation of New Scintillator Materials: SrI, GAGG, CLLB, CLLBC, TLYC, CLYC-7

In recent years, a number of new scintillator materials with improved energy resolution for gamma-ray detectors have become commercially available for use in terrestrial-based homeland security applications, and some are being incorporated into instrumentation for space. Unlike terrestrial applications, the harsh environment of space—in particular, energetic trapped particles, cosmic rays, and neutrons—often activates these materials, and any improvement in sensitivity as a result of improved energy resolution could be offset by the additional background due to activation. The purpose of this work was to measure potential backgrounds due to trapped and cosmic-ray proton-induced activation in the new materials: SrI₂:Eu (SrI), ⁷Li-enriched Cs₂LiYCl₆:Ce (CLYC-7), Cs₂LiLaBr₆:Ce (CLLB), Cs₂LiLa(Br,Cl)₆:Ce (CLLBC), Tl₂LiYCl₆:Ce (TLYC), and Gd₃(Al,Ga)₅O₁₂:Ce (GAGG). Using a large-diameter 64-MeV proton beam, detectors were irradiated with a total dose of 100 rad (Si), roughly equivalent to the annual dose in a typical low earth orbit. Measurements were made with a single 100% relative efficiency high-purity germanium (HPGe) (0.05–3 MeV) and the irradiated detector. Two multichannel analyzers (MCAs) operating in the event mode were used to collect the data. Time-tagged events were processed into various spectral integration times for analysis, and characteristic gamma-ray energies and decay times were used to identify activation products. Most of the identified activation products were the result of (p, xn) reactions, with a few exceptions. This work identifies the primary radioisotopes generated by energetic proton activation in six different scintillator materials.

Enhancing the detection sensitivity of a high-resolution β − γ coincidence spectrometer

A high-resolution β − γ coincidence spectrometry system has been set-up and calibrated at the UK CTBT Radionuclide Laboratory (known as GBL15) at AWE. The system has been configured specifically to measure the signatures of radioxenon isotopes that can be indicative of a nuclear explosion. The high purity germanium (HPGe) and PIPSBox detectors have been placed in an ultra-low-background lead shield to reduce the background count-rate and new software allows the combination of signals from four detectors (two HPGe detectors and two silicon-based detectors) to cover a larger solid angle. Measurements of samples of radioxenon isotopes are used to realise an improved detection efficiency and background acquisitions have demonstrated the achievable detection limits to reach 1.3 mBq for 133Xe and ≤0.3 mBq for the metastable isomers 131mXe and 133mXe. Due to the improved energy resolution in both photon and electron detectors, the detection sensitivity remains high in the presence of interfering signals from other radioxenon isotopes, such as those that may be present due to the significant levels of atmospheric radioxenon in parts of the world. This paper summarises the detector setup, efficiency calibration measurements and determination of the limits of detection. This work demonstrates the benefits of high-resolution coincidence detector systems for re-measurement of samples from the CTBT International Monitoring System (IMS) – improved detectability of metastable isomers 131mXe and 133mXe in the presence of 133Xe, compared to the current laboratory system.

Using Deep Learning Algorithms to Improve Energy Resolution in the Semileptonic Decays

The neutrino closure method can be used to obtain the decay kinematics with one missing final state particle (ν) in semileptonic decays. Its solution should give the square of the invariant mass of the lv system (q2) and momentum (P) of the decayed mother particle in semileptonic decay process. However, the resolution obtained by solving two-solution problems with existing algorithms is limited. We propose a new method based on deep learning to improve the resolution of the two key physical quantities when processing Large Hadron Collider beauty (LHCb) experimental data. Resolution of q2 (P) can be improved evenly 1.7% (8.2%) by regression algorithm and 2.7% (9.6%) by classification algorithm compared to linear regression algorithm. The resolution improvements using the new method will benefit the studies on semileptonic decays in hardon collider experiments. Moreover, the new method can be applied to other decays with a missing particle in the final state.

Advances in ultrahigh-energy resolution EELS: phonons, infrared plasmons and strongly coupled modes.

Nowadays, sub-50 meV atom-wide electron probes are routinely produced for electron energy loss spectroscopy in transmission electron microscopes due to monochromator technology advances. We review how gradual improvements in energy resolution enabled the study of very low-energy excitations such as lattice phonons, molecular vibrations, infrared plasmons and strongly coupled hybrid modes in nanomaterials. Starting with the theoretical framework needed to treat inelastic electron scattering from phonons in solids, we illustrate contributions in detecting optical surface phonons in photonic structures. We discuss phonon mapping capabilities in real and reciprocal space, and the localized phonon response near nano-/atomic-scale structural features. We also survey the progress of aloof spectroscopy in studying vibrations in organic materials and applications in measuring local temperature and photonic density of states in single nanostructures using phonon scattering. We then turn towards studies on infrared plasmons in metals and semiconductors. Spectroscopy analyses now extend towards probing extremely complex broadband platforms, the effects of defects and nanogaps, and some far-reaching investigations towards uncovering plasmon lifetime and 3D photonic density of states. In doped semiconductors, we review research on the use of the electron probe to correlate local doping concentration and atomic-scale defects with the plasmonic response. Finally, we discuss advances in studying strong coupling phenomena in plasmon-exciton and plasmon-phonon systems. Overall, the wealth of information gained extends our knowledge about nanomaterial properties and elementary excitations, illustrating the powerful capabilities of high-energy resolution scanning transmission electron microscopy-electron energy loss spectrometry.

The detection efficiency study of NaI(Tl) scintillation detector with the different numbers of SiPMs

SiPMs are generally coupled into whole columns in gamma energy spectrum measurement, but the relationship between the distribution of whole SiPM columns and the energy resolution of the measured energy spectra is rarely reported. In this work, ∅ 3 × 3 inch NaI scintillator is placed on an 8 × 8 SiPM array, and the energy resolution of the 137Cs peak at 662 keV corresponding to the γ-ray is selected as a reference. Each SiPM is switched to explore the influence of the number of SiPM arrays, distribution position, and reflective layer on the energy resolution of SiPMs. Results show that without coupling, the energy resolution is greatly improved when the number of SiPMs ranges from 4 to 32. However, after 32 slices (the area covered by SiPMs relative to the scintillator reaches 25.9%), the improvement in energy resolution and total pulse count is not obvious. In addition, the position of SiPMs relative to the scintillator does not exert much impact on the energy resolution. Results also indicate that by adding a reflective film (ESR), the energy resolution of the tested group increases by 10.38% on average. This work can provide a reference for the design and application of miniaturized SiPM gamma spectrometers.

Improving the characterization of fusion in a MuSIC detector by spatial localization

Multi-Sampling Ionization Chambers (MuSIC) provide an efficient means of measuring nuclear reactions with low beam rates (< 106 pps). However, in comparison to thin-target measurements, prior measurements using MuSIC detectors all manifest fusion excitation functions with wide error bars in the energy dimension. This uncertainty limits the applicability of these devices in measuring near and sub-barrier fusion cross-sections. Key to overcoming this limitation is spatial localization of the fusion in the detector. By comparing the measured ionization in the MuSIC detector with accurate energy loss calculations the position of the fusion in the detector is determined. The analysis not only provides the desired improvement in energy resolution, but it also allows extraction of the atomic number of the evaporation residues following fusion. The effectiveness of this approach is demonstrated for 18O+12C measured with MuSIC@Indiana.

Bias-voltage dependent operational characteristics of a fully spectroscopic pixelated cadmium telluride detector system within an experimental benchtop x-ray fluorescence imaging setup

Commercially available fully spectroscopic pixelated cadmium telluride (CdTe) detector systems have been adopted lately for benchtop x-ray fluorescence (XRF) imaging/computed tomography (XFCT) of objects containing metal nanoprobes such as gold nanoparticles (GNPs). To date, however, some important characteristics of such detector systems under typical operating conditions of benchtop XRF/XFCT imaging systems are not well known. One important but poorly studied characteristic is the effect of detector bias-voltage on photon counting efficiency, energy resolution, and the resulting material detection limit. In this work, therefore, we investigated these characteristics for a commercial pixelated detector system adopting a 1-mm-thick CdTe sensor (0.25-mm pixel-pitch), known as HEXITEC, incorporated into an experimental benchtop cone-beam XFCT system with parallel-hole detector collimation. The detector system, operated at different bias-voltages, was used to acquire the gold XRF/Compton spectra from 1.0 wt% GNP-loaded phantom irradiated with 125 kVp x-rays filtered by 1.8-mm Tin. At each bias-voltage, the gold XRF signal, and the full-width-at-half-maximum at gold Kα 2 XRF peak (∼67 keV) provided photon counting efficiency and energy resolution, respectively. Under the current experimental conditions, the detector photon counting efficiency and energy resolution improved with increasing bias-voltage by ∼41 and ∼29% at −300V; ∼54 and ∼35% at −500V, respectively, when compared to those at −100V. Consequently, the GNP detection limit improved by ∼26% at −300V and ∼30% at −500V. Furthermore, the homogeneity of per-pixel energy resolution within the collimated detector area improved by ∼34% at −300V and ∼54% at −500V. These results suggested the gradual improvements in the detector performance with increasing bias-voltage up to −500V. However, at and beyond −550V, there were no discernible improvements in photon counting efficiency and energy resolution. Thus, the bias-voltage range of −500 to −550V was found optimal under the current experimental conditions that are considered typical of benchtop XRF/XFCT imaging tasks.

Neutron detection efficiency of the Neutron dEtector with Xn Tracking (NEXT)

An efficient neutron detection system with good energy resolution is required to correctly characterize decays of neutron-rich nuclei where β-delayed neutron emission is a dominant decay mode. The Neutron dEtector with Xn Tracking (NEXT) has been designed to measure β-delayed neutron emitters. By segmenting the detector along the neutron flight path, NEXT reduces the associated uncertainties in neutron time-of-flight measurements, improving energy resolution while maintaining detection efficiency. Detector prototypes are comprised of optically separated segments of a neutron-gamma discriminating plastic scintillator coupled to position-sensitive photomultiplier tubes. The first performance studies of this detector showed that high intrinsic neutron detection efficiency could be achieved while retaining good energy resolution. The results from the efficiency measurements using neutrons from direct reactions are presented.

Fast Energy Dependent Scatter Correction for List-Mode PET Data.

Improvements in energy resolution of modern positron emission tomography (PET) detectors have created opportunities to implement energy-based scatter correction algorithms. Here, we use the energy information of auxiliary windows to estimate the scatter component. Our method is directly implemented in an iterative reconstruction algorithm, generating a scatter-corrected image without the need for sinograms. The purpose was to implement a fast energy-based scatter correction method on list-mode PET data, when it was not possible to use an attenuation map as a practical approach for the scatter degradation. The proposed method was evaluated using Monte Carlo simulations of various digital phantoms. It accurately estimated the scatter fraction distribution, and improved the image contrast in the simulated studied cases. We conclude that the proposed scatter correction method could effectively correct the scattered events, including multiple scatters and those originated in sources outside the field of view.

Investigation on method of reducing surface leakage current of the CdZnTe photoconductive detector with MSM structure

The surface leakage current (SLC) of CdZnTe is an important factor affecting detection performance. In this work, we established a two-dimensional model of metal-semiconductor-metal (MSM) structured CdZnTe with a low-resistance layer on the surface. The composition of SLC and the distribution of the internal electric field are analyzed by simulation. The study found that the change of electrode size will change the contribution of SLC from cathode, anode and side surfaces. With the increase of electrode size, the contribution of SLC to total leakage current decreases gradually, and the internal electric field distribution becomes more uniform. According to the conclusions of simulation, we have proposed a simple and accurate method to estimate the bulk resistivity and SLC of CdZnTe. In addition, combined with a series of experiments, we have also summarized several methods which can reduce the contribution of the SLC in MSM structured CdZnTe detector in order to improve energy resolution.

Advanced inorganic halide ceramic scintillators

Research in ceramic scintillators has steadily progressed alongside the research in bulk single crystal scintillator growth. As interest in faster scintillation material production with lower cost increases, more research on scintillating ceramics is needed. Research targeting optimization of optically transparent ceramics that can rival bulk-grown crystals grown may lower cost, increase yield, increase volume, and improve energy resolution in applications and systems currently using sodium iodide and alike. Ceramic scintillators that are dense (>5 g/cm3), have high effective Z (>60), are bright (>40,000 photons/MeV), and are not sensitive to moisture as well as those that can be handled without protection are desired. Ultra-fast ceramic materials are also of interest. This paper presents an equipment design and technique to produce inorganic halide ceramic scintillators Cs2HfCl6 (CHC) and Tl2HfCl6 (THC). Improvements and optimization of CHC and THC ceramic scintillator fabrication are gauged by monitoring the energy resolution and peak position of 137Cs full energy peak at 662 keV. With a 1-inch diameter CHC ceramic scintillator, energy resolution of 5.4% (FWHM) and light yield of 20,700 ph/MeV are achieved, while with a 16-mm diameter THC ceramic scintillator, energy resolution of 5.1% (FWHM) and light yield of 27,800 ph/MeV are achieved. Decay times of 0.6 microseconds (21%) and 3.0 microseconds (79%) are measured for CHC and 0.3 microseconds (13%) and 1.0 microseconds (87%) for THC. Both ceramic CHC and THC scintillators have similarly good proportionality data when compared to their single crystal counterparts.

Designand expected performance of a variable-radii sinusoidal spiral x-ray spectrometer for the National Ignition Facility.

A novel high-resolution x-ray spectrometer for point-like emission sources has been developed using a crystal shape having both a variable major and a variable minor radius of curvature. This variable-radii sinusoidal spiral spectrometer (VR-Spiral) allows three common spectrometer designgoals to be achieved simultaneously: 1. reduction of aberrations and improved spectral (energy) resolution, 2. reduction of source size broadening, and 3. use of large crystals to improve total throughput. The VR-Spiral concept and its application to practical spectrometer designare described in detail. This concept is then used to designa spectrometer for an extreme extended x-ray absorption fine structure experiment at the National Ignition Facility looking at the Pb L3 absorption edge at 13.0352 keV. The expected performance of this VR-Spiral spectrometer, both in terms of energy resolution and spatial resolution, is evaluated through the use of a newly developed raytracing tool, xicsrt. Finally, the expected performance of the VR-Spiral concept is compared to that of spectrometers based on conventional toroidal and variable-radii toroidal crystal geometries showing a greatly improved energy resolution.

Impact of improved energy resolution on DUNE sensitivity to neutrino non-standard interactions

The full physics potential of the next-generation Deep Underground Neutrino Experiment (DUNE) is still being explored. In particular, there have been some recent studies on the possibility of improving DUNE’s neutrino energy reconstruction. The main motivation is that a better determination of the neutrino energy in an event-by-event basis will translate into an improved measurement of the Dirac C P phase and other neutrino oscillation parameters. To further motivate studies and improvements on the neutrino energy reconstruction, we evaluate the impact of energy resolution at DUNE on an illustrative new physics scenario, viz. non-standard interactions (NSI) of neutrinos with matter. We show that a better energy resolution in comparison to the ones given in the DUNE conceptual and technical design reports may significantly enhance the experimental sensitivity to NSI, particularly when degeneracies are present. While a better reconstruction of the first oscillation peak helps disentangling standard C P effects from those coming from NSIs, we find that the second oscillation peak also plays a nontrivial role in improving DUNE’s sensitivity.

Quaternary Semiconductor Cd1−xZnxTe1−ySey for High-Resolution, Room-Temperature Gamma-Ray Detection

The application of Cd0.9Zn0.1Te (CZT) single crystals, the primary choice for high-resolution, room-temperature compact gamma-ray detectors in the field of medical imaging and homeland security for the past three decades, is limited by the high cost of production and maintenance due to low detector grade crystal growth yield. The recent advent of its quaternary successor, Cd0.9Zn0.1Te1−ySey (CZTS), has exhibited remarkable crystal growth yield above 90% compared to that of ~33% for CZT. The inclusion of Se in appropriate stoichiometry in the CZT matrix is responsible for reducing the concentration of sub-grain boundary (SGB) networks which greatly enhances the compositional homogeneity and growth yield. SGB networks also host defect centers responsible for charge trapping, hence their reduced concentration ensures minimized charge trapping. Indeed, CZTS single crystals have shown remarkable improvement in electron charge transport properties and energy resolution over CZT detectors. However, our studies have found that the overall charge transport in CZTS is still limited by the hole trapping. In this article, we systematically review the advances in the CZTS growth techniques, its performance as room-temperature radiation detector, and the role of defects and their passivation studies needed to improve the performance of CZTS detectors further.

High resolution x-ray emission spectrometer for multiple hard x-ray emission lines: Demonstration for Cu Kα and Kβ emissions.

We present a compact 3D printed x-ray emission spectrometer based on the von Hamos geometry that represents a significant upgrade to the existing von Hamos geometry-based miniature x-ray emission spectrometer (miniXES) [Mattern et al., Rev. Sci. Instrum. 83(2), 023901 (2012)]. The upgrades include the incorporation of a higher pixel density 500K detector for improved energy resolution and an enlarged sample area to accommodate a wider range of sample formats. The versatile spectrometer houses removable crystal holders that can be easily exchanged, as well as movable alignment eyelets that give flexibility in Bragg angle selection. Designed for ease of manufacture, all the components, except for the apertures, can be 3D printed and readily assembled. We describe its implementation in measurements of resonant and non-resonant Cu Kα and Kβ x-ray emission and report the theoretical and measured energy resolution and collected solid angle of the emission.

The response of thick (10 μm) AlInP x-ray and γ-ray detectors at up to 88 keV

The development of new x-ray and γ-ray spectrometers based on AlInP photodiodes with increased quantum detection efficiency and improved energy resolution is reported. The spectroscopic responses of two AlInP p+–i–n+ mesa photodiodes (10 μm i layer, the thickest so far reported) were investigated at photon energies from 4.95 to 88.03 keV; the detectors and preamplifier were operated at 30 °C. Energy resolutions (full width at half maximum) of 750 ± 40 eV and 850 ± 30 eV at 4.95 keV were achieved with the two detectors. The energy resolution deteriorated with increasing photon energy; this was in accordance with the increasing Fano noise with energy and suggested negligible incomplete charge collection noise across the photon energy range investigated. The measured voltage output of each spectrometer was found to be linear as a function of incident x-ray photon energy. The count rate (measured at 8.63 keV) was also found to linearly increase with incoming x-ray photon flux for the investigated spectrometers. These results, which were obtained using the thickest AlInP photodiodes produced so far, suggest that AlInP detectors are highly promising candidates for future uncooled x-ray and γ-ray spectrometers.

Properties of the 90° cylindrical energy analyzer with internal deceleration of the beam in real conditions of operation

To measure plasma potential in toroidal magnetically confined fusion plasma, the Heavy Ion Beam Diagnostic (HIBD) employs of the electrostatic energy analyzer. The 90° cylindrical energy analyzer (CEA) developed for the HIBD on the ISTTOK tokamak due to compactness and multislit operation capability, is characterized by large angular aberrations, if operated in conventional mode. A new operation regime was proposed based on numerical investigations, which demonstrated the efficiency of the 90°CEA operation in reducing angular aberrations via the deceleration of the ion beam inside analyzer, resulting also on an improved energy resolution. In this paper, the properties of the 90 ° CEA featuring with guard rings (GR) to shield the analyzer from the surrounding structures are investigated in the internal deceleration mode (ID-mode) for “centric” and “paracentric” injection geometries. The numerical simulations are conducted using SIMION code. Special attention is paid to uniformity of the beam image on detector plate, which is of importance in ion beam energy measurements by split-plate detector technique. The results confirm coupling of analyzer angle aberration properties with beam deceleration inside analyzer. For both “centric” and “paracentric” entrances the existence of the first-order focus in ID-mode is obtained. However, the first order focus ID-mode of 90°CEA with GR is characterized by heterogeneity of the image for the initially uniform beam, determined by modification of electric field inside analyzer. It is revealed that the energy dispersion of the initially monoenergetic ions due to chromatic-like aberration introduced by analyzer plays a contributive role in the beam image non-uniformity. From the beam energy measurements point of view, it is shown that the energy variation due to this chromatic aberration is of the second order of the analyzer intrinsic resolution. The results show that “centric” entrance in ID-mode is preferable as the image non-uniformity is less pronounced and can be effectively restored by manipulation of entrance slit dimensions and potentials on GR. It is concluded that besides detail preparatory numerical optimization, the beam image shape and uniformity control is essential, which can be realized with the dedicated multiple cell detection.