Icehouse Climate Research Articles

Zinc isotope perspective on global carbon cycling during the onset of the late Paleozoic icehouse

The onset of the late Paleozoic icehouse coincided with a large global carbon-cycle perturbation (represented by the mid-Tournaisian carbon isotope excursion [TICE]), although the underlying cause of this isotopic event remains uncertain. Zinc (Zn), an essential micronutrient for plankton, has an isotopic composition (δ66Zn) in seawater that is sensitive to subtle fluctuations in marine carbon (C) cycling. Here, we investigated C cycling during the TICE using paired carbonate δ66Zn-δ13C and organic δ13C records from two widely spaced sections in South China. These records reveal coupling between δ66Zn and δ13C over an ∼4 m.y. interval in the form of two positive excursions (Peaks I and II) separated by a negative shift (interpeak). Peak I is attributed to enhanced marine primary productivity (MPP), which was stimulated by increased micronutrient supply linked to enhanced silicate weathering and/or upwelling. The interpeak may record oxidation of remobilized organic matter from continental shelves exposed by glacio-eustatic sea-level fall, which, in turn, promoted MPP again and resulted in Peak II. Thus, the TICE records complex climate−carbon cycle feedbacks that may have led to large-scale organic carbon burial and driven stepwise cooling, marking the onset of a sustained late Paleozoic icehouse climate.

Eccentricity control on fluvial sedimentation in the tropics during the Middle-Late Pennsylvanian icehouse (∼306–314 Ma, Upper Silesian Basin)

Far-field effects of the Late Paleozoic glaciation (∼340–260 Ma) recorded in well-dated stratigraphic intervals of the Pangea can be instrumental in detecting the short-term variability of icehouse climate and deconvolving the climate mechanisms. This study examines the Cracow Sandstone Series (CS), which provides a snapshot of the Middle to Late Pennsylvanian (∼306–314 Ma) fluvial sedimentation in the eastern equatorial Pangea (Upper Silesian Basin, ∼2°N paleolatitude). Spectral estimates of borehole lithological data suggest predominant ∼100-kyr eccentricity pacing of coal-bearing fluvial cycles and persistence of this pattern across the onset of Late Pennsylvanian aridification. The immediate climatic and depositional controls involve changes in seasonal precipitation along the Intertropical Convergence Zone and resulting fluctuations in sediment input. The prominence of eccentricity pacing and suppression of precession-scale variability in the fluvial environment contrasts with the frequency spectra of seasonal insolation series – an issue comparable to the “100-kyr problem” of the Late Pleistocene. The traditional explanation considers the eccentricity component being imposed as a far-field response to glaciation, analogous to the Pleistocene carbon-cycle feedback. Here we propose an alternative possibility that calls upon time-integrated insolation at the equator and the role of semi-annual wet/dry cyclicity in transferring variance from precession-scale insolation changes to the modulating eccentricity term. Autogenic processes in the fluvial system might have participated in “shredding” the precessional and semi-precessional signals. The alternative scenario is decoupled from high-latitude climate and would imply a muted climate sensitivity of the eastern equatorial Pangea to glaciation. The individual options cannot be evaluated with the Upper Silesian data alone, but offer testable hypotheses, potentially helpful in revealing the short-term structure of glaciation and climate teleconnections during the Late Paleozoic.

Atmospheric oxygenation as a potential trigger for climate cooling

Secular changes in atmospheric CO2 and consequent global climate variations, are commonly attributed to global outgassing and the efficiency of silicate weathering, which may have been linked to mountain formation, land/arc distribution, and plant colonization through geological time. Although oxidative weathering has been shown to exert a significant role in the propagation of weathering fronts through the oxidation of Fe-bearing minerals, the influence of atmospheric O2 concentration (pO2) on silicate weathering, CO2 consumption, and global climate has not been thoroughly evaluated. This study presents a numerical model aimed at estimating the effects of pO2 on the climate, considering the influence of pO2 on the regolith thickness and thus weathering duration of granitic domains. Our model simulations reveal that an increase in weathering efficiency, through deeper penetration of the oxidative weathering front in the granitic regolith, would independently introduce a steady-state climate cooling of up to ∼8 °C, in step with one-order of magnitude rise in pO2. This temperature change may have repeatedly initiated the runaway ice-albedo feedback, leading to global glacial events (e.g., Neoproterozoic Snowball Earth). Increasing granitic weathering efficiency caused by a substantial pO2 increase may also have contributed to the development of icehouse climate during the Phanerozoic.

On greenhouse and icehouse climate regimes over the Phanerozoic

AbstractThroughout the Phanerozoic and more, the Earth has experienced cold and hot periods, which are typically associated with long‐lasting (hundreds of million years, Ma) greenhouse and icehouse climate regimes. Now, most published sea‐level curves report two main maxima in the Cretaceous and Ordovician superimposed on a multitude of short‐term fluctuations. The big humps are shown to be predominantly the results of the plate tectonic configuration, not icehouse and greenhouse regimes, suggesting that the small oscillations are related to continental ice variations. From this point of view, it can be inferred that polar ice caps are present almost all the time, and climate regime changes appear much more frequent and shorter than usually considered and are not well‐documented from glaciogenic deposits. Relying on short‐term oscillations, the volume of continental ice can be retrieved over the Phanerozoic.

The Pacific-North American teleconnection in the Cenozoic

The Pacific-North American teleconnection (PNA) is one of the most important atmospheric modes in the Northern Hemisphere in modern climate. Through the PNA teleconnection, climate variations in the tropical Pacific have significant impacts on North America. However, whether there existed the PNA-like mode in the deep-time climate and how it evolved remain unknown. Here, we study the evolution of the PNA in the past 70 million years, using simulation results with the fully coupled Community Earth System Model version 1.2.2 (CESM1.2.2). Our simulation results show that there existed a PNA-like mode (referred to as PNA in this study) in the Cenozoic, but with different strengths and pathways. The strengths of the PNA were weaker over 70–40 million years ago (Ma) than that of the present, while it is comparable to the present over 30–10 Ma. Diagnosis indicates that the weaker strengths and distorted pathways of the PNA before ∼40 Ma are due to weaker meridional temperature gradients in warmer climates, which causes weakened extratropical westerly jet and altered extratropical waveguide of planetary-scale stationary waves. After ∼40 Ma, Earth climate became much colder, entering into the icehouse climate. Thus, the PNA pattern is close to the present state.

Duration of Sturtian “Snowball Earth” glaciation linked to exceptionally low mid-ocean ridge outgassing

Abstract The Sturtian “Snowball Earth” glaciation (ca. 717–661 Ma) is regarded as the most extreme interval of icehouse climate in Earth’s history. The exact trigger and sustention mechanisms for this long-lived global glaciation remain obscure. The most widely debated causes are silicate weathering of the ca. 718 Ma Franklin large igneous province (LIP) and changes in the length and degassing of continental arcs. A new generation of two independent Neoproterozoic full-plate tectonic models now allows us to quantify the role of tectonics in initiating and sustaining the Sturtian glaciation. We find that continental arc length remains relatively constant from 850 Ma until the end of the glaciation in both models and is unlikely to play a role. The two plate motion models diverge in their predictions of the timing and progression of Rodinia break-up, ocean-basin age, ocean-basement depth, sea-level evolution, and mid-ocean ridge (MOR) carbon outflux. One model predicts MOR outflux and ocean basin volume–driven sea level lower than during the Late Cenozoic glaciation, while the other predicts outgassing and sea level exceeding those of the Late Cretaceous hothouse climate. The second model would preclude a major glaciation, while the first model implies that the trigger for the Sturtian glaciation could have been a combination of an extremely low MOR outflux (~9 Mt C/yr) and Franklin LIP weathering. Such minimal outflux could have maintained an icehouse state for 57 m.y. when silicate weathering was markedly reduced, with a gradual build-up of MOR CO2 in the atmosphere paired with terrestrial volcanism leading to its termination.

Cold climatic snaps during the Eocene-Oligocene transition in the central Tibetan Plateau: Implications for ice-induced sedimentary structures and isotope geochemistry

The Eocene-Oligocene transition was a time of major climate instability and a shift from an ice-free world to a predominant icehouse climate. Identifying the ancient glacial deposits and their associated sedimentary structures are of paramount significance for understanding the Earth's climate in the Cryogenian Period. Ice-induced sedimentary structures (IISS) are considered as types of primary structures preserved on surfaces and in upper parts of unconsolidated sediments by physical cryospheric processes of seasonal ice freezing and thawing, and therefore sensitive not only to climate, but also to paleogeography, hydrology, and type of environment. Despite the common occurrence of modern IISS in a wide variety of environments, from high-latitude regions to low-latitude areas of high altitude, available records from ancient geologic archives are scarce. Herein, we integrated sedimentological and geochemical proxies to study IISS and geochemical signals as reliable indicators of cold climate in an outstanding example of the Eocene-Oligocene interval from the Niubao Formation in the Lunpola Basin, central Tibet. Detailed field sedimentological, petrographic microscopic investigations, and bulk carbonate oxygen (δ18Ocarb) and carbon (δ13Ccarb) isotope geochemistry were conducted in this lacustrine succession. Seven sets of IISS are represented by ice crystal marks, frozen cracks, ice-frozen bubbles, ice-expanding laminae, ice-rafted debris (dropstones), ice water pea-like, and ice water pits. They are classified into three groups based on major deriving mechanisms: ice-related crystal marks, deformation-related ice structures, and gravitational fall IISS. Positive δ18Ocarb excursions at the Eocene-Oligocene transition provide evidence of a shift toward cold or near-freezing climatic snaps in response to global cooling episodes at this time. Integrating the paleogeomorphic scenario of central Tibet with the stratigraphically reported IISS and glendonite clusters, the results support that the Lunpola lake sustained cold or near-freezing conditions at Eocene-Oligocene transition. These findings provide one of the most comprehensive sedimentological and isotopic analyses of ancient IISS and a more direct spatial-temporal constraint for the regional climate system of central Tibet.

Phylogenetic relationships and historical biogeography of Otus species based on mitochondrial cytochrome b gene sequence

Abstract This study analyzed mitochondrial cytochrome b gene sequences to infer Otus species’ phylogenetic relationships and historical biogeography. The researchers used Maximum Parsimony and Maximum Likelihood methods to generate the phylogenetic trees. They constructed a Bayesian MCC Chronogram Tree to determine the Otus species’ age and speciation events. Paleoclimate and paleogeology maps were also used to correlate the branching out of Otus species with geological time periods and climatic conditions. The results showed five major clusters or clades for the core taxon group (Otus) and one for the sister group (Tyto). The Bayesian tree showed seven major clades for Otus, with the first speciation occurrence dating back to 21.54 mya during the Early Miocene epoch. Most of the core taxon species speciated during the Pliocene Period, with some exceptions. The paleoclimate data indicated that Otus clades branched out during the Icehouse climate state, with the first branching out occurring during the Coolhouse climatic state. The paleogeologic data revealed that the African and American (North and South) continents were already distinct and divided by the Atlantic Ocean during the first branching out of the Otus clade. The distribution areas of Otus species were also mapped using updated Wallace’s zoogeographic realms. Overall, this study provides a better understanding of the phylogenetic history of Otus species and their diversification in relation to geological and climatic events. However, the authors caution that all phylogenetic trees, evolutionary studies, and divergence time estimates should be considered hypotheses with significant uncertainty.

Contrasting response of sea-level change to orbital eccentricity in greenhouse and icehouse climates

Climate-controlled changes in eustatic sea level (ESL) are linked to transfers of water between ocean and land, thus offering a rare insight into the past hydrological cycle. In this study, we examine the timing and phase of Milankovitch-scale ESL cycles in the peak Cretaceous greenhouse, the early Turonian (∼93–94 million years, Myr, ago). A high-resolution astronomical framework established for the Bohemian Cretaceous Basin (central Europe) suggests a ∼400-kyr pace and a distinct asymmetry of interpreted ESL cycles. The rising limbs of ESL change constitute only 20–30 % of the cycle, and are encased entirely within the falling phase of the 405-kyr eccentricity; the intervening ESL falls (≤6 m in magnitude) are more protracted, starting within 70 kyr prior to the eccentricity minima and culminating ∼60 kyr after the 405-kyr eccentricity maxima. Despite similarities to the sawtooth shape of ∼100-kyr glacioeustatic oscillations of the Late Pleistocene, the time scales and phasing are unparalleled in the Pleistocene icehouse. A similar, 405-kyr pace is found in ice-volume variations of the early Miocene, but the timing of glacioeustatic change relative to eccentricity forcing is incompatible with the phase of greenhouse sea-level oscillations. The phasing points to major differences in the geographic location and insolation sensitivity of the key hydrological reservoirs under icehouse and greenhouse regimes. The inferred structure of greenhouse eustasy points to low- or middle-latitude water storage, likely aquifers, that charge (expand) with rising seasonality variations and discharge (contract) with declining seasonality amplitudes on the 405-kyr scale. The net volume of water transferred on these time scales is within 2.2 × 106 km3, equivalent to ≤10 % of the present-day storage in the uppermost 2 km of continental crust; potential additive interference with steric eustasy, proportionally relevant during greenhouse regimes, could reduce the volumes required for continental storage.

Coal-derived rates of atmospheric dust deposition during the Jurassic-Cretaceous greenhouse periods

The study of dust deposition records in geological history is of great significance to the study of paleoclimate evolution during deep periods. Because dust can directly influence the biochemical processes and climate evolution of the Earth. However, the absence of quantitative data on dust limits the systematic and comprehensive study of paleoclimate evolution during deep periods. Prior to the Quaternary period, most quantitative studies on atmospheric dust have focused on the Permian era. However, in the entire Mesozoic era, there are still no quantitative data available on atmospheric dust deposition rates. We utilized the average concentration of inorganic matter in coal from the Jurassic and Cretaceous periods to depict the dust concentration and corresponding dust deposition rate in the atmospheric system during these periods. We also conducted a correlation analysis using the distribution of arid source areas. The results show that the values of ash concentration and dust deposition rates are higher near the arid provenance and lower far away from it. Furthermore, in this study, we have compared the latitudinal variation gradient of dust deposition rates under the icehouse and greenhouse climates by using the end of the Permian and Quaternary as representatives of icehouse climate and the Jurassic and Cretaceous periods as representatives of the greenhouse climate. Our findings indicate that there is a higher ash concentration, dust deposition rate, and dust deposition rate variation gradient in the air under the icehouse climate, while there is a lower ash concentration, dust deposition rate, and dust deposition rate gradient in the air under the greenhouse climate. We have also discussed the dust sources during the Mesozoic period, as well as the differences in ash data under greenhouse and icehouse conditions. This provides a strong basis for studying the atmospheric environment after the modern climate entered the ice age.

A time-space window between Eocene karst bauxite genesis and the first molasse deposition in the Dinaric Foreland Basin in the North Dalmatia, Croatia

Karst bauxite deposits in the North Dalmatian piggyback basin (NDPGB) are a part of the Mediterranean bauxite belt, which is the largest European bauxite deposit zone; however, there is a general lack of information regarding the genesis, age, and precursor of the bauxite deposits in this region. In this study, we combined detrital zircon U–Pb geochronology with compositional, mineralogical, and morphological data from four bauxite locations in the NDPGB to provide a new palaeogeographical and palaeoenvironmental evolution model for the Lutetian–Rupelian timeframe of the NDPGB. The Eocene climatic conditions began with the Palaeocene–Eocene Thermal Maximum event (∼56 Ma), followed by the Early Eocene Climatic Optimum (∼49 Ma) and Middle Eocene Climatic Optimum (∼40 Ma), and were completed as a cooling trend culminating around the Eocene/Oligocene boundary (∼34 Ma), with a shift towards an icehouse climate. These events were coeval with the continuous drift of the African continent towards Eurasia and the subsequent closure of the western part of the former Neo-Tethys Ocean associated with massive volcanic activity. Based on the bauxite deposits of the NDPGB, Early Eocene limestones formed in the last phase of the long-lasting Adriatic Carbonate Platform. The Middle Eocene orogenic activity resulted in an elevation in this area. High average temperatures, accelerated hydrological cycles and precipitation, and intensive continental weathering with increased volcanic carbon input resulted in favourable conditions for the development of karst bauxites at this time. Further Upper Eocene tectonic deformation of the NDPGB area resulted in the development of bauxite traps and enabled redeposition of the initial bauxite material. Subsequently, the bauxite deposits were covered with clastic carbonate molasse derived from the intensive erosion of the young Dinaric orogeny. The implications of this study are as follows. First, it provides new information on the timing of bauxitisation in the area by providing the first radiometric zircon geochronology, which refined and restricted the time window for bauxite formation in this region. Additionally, our results provide a new perspective on the possibility of aeolian precursors in karst bauxite formation and provide new constraints on the first tectonic marks of the initial Dinaric orogeny.

Using Biofacies Analysis of a Tertiary Algal Reef (Pinnacle Reef - Middle Eocene IIA), at Burton Guyot (IODP Site U1376) to Determine Transition from Greenhouse to Icehouse

Twenty-five samples were collected at 30 cm intervals from the studied cored interval within the limestone unit (AII) reported at IODP Site U1376 on Burton Guyot. The purpose of this research is to examine and identify the coral and algae suites in the studied core concerning sea level fluctuation during the Eocene time. This reef is isolated by being between two volcanic units in the Southwest Pacific Ocean. Eleven biofacies units have been established based on the fabric of the grains. The biofacies units are as follows; Algal-coral grainstone, foraminiferal algal-coral grainstone (Alabaminabed), foraminiferal algal-coral packstone to grainstone (Heterostegina bed), algal-coral grainstone, foraminiferal algal boundstone, foraminiferal algal grainstone (Lagena bed), foraminiferal algal grainstone (Cibicidoides micrus-bed), foraminiferal algal boundstone to grainstone, foraminiferal algal-coral grainstone, algal echionoidal packstone, and foraminiferal algal coral wacke-packstone. This is the first study to use both algae and coral in differentiating the units mentioned above. The only coralline red algae recognized in the samples is Lithothamnion camarasae. This species is a good indicator of the warm climatic conditions during the middle-late Eocene. The only species of coral found in these units is Isopora togianensis, a scleractinian reef builder. The high percentage of algae compared to coral indicates a climatic change from a greenhouse to an icehouse climate. The faunal trend during this time also indicates a tectonic change.

Seafloor hydrothermal systems control long-term changes in seawater [Li+]: Evidence from fluid inclusions.

Secular variations in the major ion chemistry and isotopic composition of seawater on multimillion-year time scales are well documented, but the causes of these changes are debated. Fluid inclusions in marine halite indicate that the Li concentration in seawater [Li+]SW declined sevenfold over the past 150 million years (Ma) from ~184 μmol/kg H2O at 150 Ma ago to 27 μmol/kg H2O today. Modeling of the lithium geochemical cycle shows that the decrease in [Li+]SW was controlled chiefly by long-term decreases in ocean crust production rates and mid-ocean ridge and ridge flank hydrothermal fluxes without requiring changes in continental weathering fluxes. The decrease in [Li+]SW parallels the 150 Ma increase in seawater Mg2+/Ca2+ and 87Sr/86Sr, and the change from calcite to aragonite seas, KCl to MgSO4 evaporites, and greenhouse to icehouse climates, all of which point to the importance of plate tectonic activity in regulating the composition of Earth's hydrosphere and atmosphere.

Sedimentary facies and carbon isotopes of the Upper Carboniferous to Lower Permian in South China: Implications for icehouse to greenhouse transition

The Late Paleozoic Ice Age (LPIA) is the so far longest-last icehouse climate state during the Phanerozoic, and recorded a complete transition from icehouse to greenhouse climate state since the occurrence of vascular plants and complex terrestrial ecosystem. Therefore, integrated studies on the icehouse-greenhouse transition of the LPIA are critical to understanding the driver and mechanism of the deep-time paleoclimate system, particularly in an icehouse climate state. However, frequent subaerial exposures and stratigraphic discontinuities in low-latitude areas due to glacio-eustatic changes from the Pennsylvanian (Late Carboniferous) to Cisuralian (Early Permian) potentially altered the primary δ13C signals, which hampered a valid global correlation. Here, three carbonate slope successions (Naqing, Shanglong, and Narao) in the Luodian Basin, South China Block, were selected for detailed sedimentology and high-resolution carbonate δ13C study. The variation of δ13C is compared with the sedimentary characteristics and can be correlated with global glacial events and atmospheric pCO2 during the apex and deglaciation period of the LPIA. It suggests that δ13C of the Luodian Basin can potentially represent the global mean δ13C of the seawater dissolved inorganic carbon and provide a reference for the future study on global carbon cycling.

Paleoecology and evolutionary response of planktonic foraminifera to the mid-Pliocene Warm Period and Plio-Pleistocene bipolar ice sheet expansion

Abstract. The Pliocene-Recent is associated with many important climatic and paleoceanographic changes, which have shaped the biotic and abiotic nature of the modern world. The closure of the Central American Seaway and the development and intensification of Northern Hemisphere ice sheets had profound global impacts on the latitudinal and vertical structure of the oceans, triggering the extinction and radiation of many marine groups. In particular, marine calcifying planktonic foraminifera, which are highly sensitive to water column structure, exhibited a series of extinctions as global temperatures fell. By analyzing high-resolution (∼ 5 kyr) sedimentary records from the Eastern Equatorial Pacific Ocean, complemented with global records from the novel Triton dataset, we document the biotic changes in this microfossil group, within which three species displayed isochronous co-extinction, and species with cold-water affinity increased in dominance as meridional temperature gradients steepened. We suggest that these changes were associated with the terminal stages of the closure of the Central American Seaway, where following the sustained warmth of the mid-Pliocene Warm Period, bipolar ice sheet expansion initiated a world in which cold- and deep-dwelling species became increasingly more successful. Such global-scale paleoecological and macroevolutionary variations between the Pliocene and the modern icehouse climate would suggest significant deviations from pre-industrial baselines within modern and future marine plankton communities as anthropogenic climate forcing continues.

Faunal evolution under the background of the Cenozoic greenhouse and icehouse climate

地球上的生命演化，到新生代生态体系已经接近今天的世界。随着造礁生物的出现并孕育了大量海洋生物，特别是鱼类占据了今天脊椎动物分类多样性的半数以上，现代的生物圈与水圈的关系更加密切。新生代显著的全球性气候事件对生态系统产生了巨大的影响，哺乳动物在此环境背景下经历了由古老类群为主向现代类群为主的转变，而鱼类区系在多样性组成和地理分布上更加趋近今天的面貌。新生代冰室-温室气候频繁转换，虽然中间有过多次小幅升温事件，但整体是一个降温的趋势。古新世/始新世界线代表了哺乳动物进化的一个重要时期，其气候环境背景是55.8 Ma的全球平均气温比今天高8°C；湿润的气候条件导致哺乳动物向北迁徙，而许多哺乳动物的目，包括灵长目、奇蹄目和偶蹄目等在此事件之后很快出现，并依靠高纬度地区的陆桥迅速扩散。2.6 Ma全球气温第一次下降到低于今天的水平，导致海水大量结冰，海平面大幅度下降，白令海峡露出海面成为联通北美和欧亚大陆的桥梁，促进了两个大陆之间的动物交流。水循环不仅影响到全球动物区系的演变，也与生物资源的安全和人类的未来发展息息相关。

Devonian to Carboniferous continental-scale carbonate turnover in Western Laurentia (North America): upwelling or climate cooling?

The Devonian to Carboniferous (DC) transition coincided with a green-to-ice house climatic shift, anoxia, disappearance of lower latitude carbonate banks, and turnover from warm-to-cool water carbonate factories. In western Laurentia, the switch to carbonate factories dominated by cool-water biota was contemporaneous with a tectonically driven palaeogeographic change. To investigate this depositional shift and infer the relative impact of climate vs tectonics, a continental-scale sedimentological and geochemical study was conducted on twelve stratigraphic sections of DC strata from western Canada to southern Nevada (USA). The spatial–temporal distribution of microfacies records the turnover from [i] a Famennian lime mud-rich, shallow warm-water carbonate ramp with low sedimentation rates, mesotrophic conditions and tabular geometry to [ii] Tournaisian to Viséan lime mud-depleted and grainstone dominated cool-water carbonate ramp with anomalous high sedimentation rates, oligotrophic conditions and a pronounced slope. Positive excursions of δ18Ocarb (+ 2‰ V-PDB) and δ13Ccarb (+ 4‰ V-PDB) of Lower Mississippian carbonates likely correspond to the first cooling peak of the Carboniferous-Permian icehouse climate, following carbon withdrawal during black shale deposition during the late Famennian and early Tournaisian. However, late Tournaisian return of photozoan elements and their persistence throughout the Viséan suggests that warmer surface water existed, revealing a decoupling of the lower latitude ocean and the atmosphere. Shoaling of the thermocline was likely a result of cold-water upwelling along an open coast, as the Antler orogen no longer provided an oceanic obstruction to the west. This study shows that carbonate platforms are more susceptible to regional changes than global shifts.

Ca2+] and [SO[formula omitted]] in Phanerozoic and terminal Proterozoic seawater from fluid inclusions in halite: The significance of Ca-SO4 crossover points

Chemical analyses of 2,618 (1,640 new and 978 published) fluid inclusions in marine halite were used to define paleoseawater [Ca2+] and [SO2−4] over the past 550 million years (Myr). Three types of fluid inclusion brine chemistries were recognized based on measured [Ca2+] and [SO2−4]: (1) SO4-rich with [SO2−4] ≫ [Ca2+]; (2) Ca-rich with [Ca2+] ≫ [SO2−4]; and (3) Ca-SO4 crossover points with [Ca2+] ≈ [SO2−4]. The SO4-rich and Ca-rich fluid inclusion chemistries oscillated twice in the terminal Proterozoic and Phanerozoic. Transitions between SO4-rich and Ca-rich seas, here called “Ca2+−SO42−crossover points” occurred four times: terminal Proterozoic–Early Cambrian (544–515 Ma), Late Pennsylvanian (309–305 Ma), Triassic–Jurassic boundary (∼200 Ma), and Eocene–Oligocene (36–34 Ma). New fluid inclusion analyses using laser ablation-inductively coupled plasma-mass spectrometry better defined the [Ca2+] and [SO2−4] in seawater at the Late Pennsylvanian and Eocene–Oligocene crossover points and the timing of the Triassic–Jurassic crossover point. Crossover points coincide with shifts in seawater Mg2+/Ca2+ ratios, the mineralogies of marine non-skeletal carbonates and shell building organisms (aragonite vs. calcite) and potash evaporites (MgSO4 vs. KCl types). Phanerozoic and terminal Proterozoic trends in seawater [Ca2+] and [SO2−4] also coincide with supercontinent breakup, dispersal, and assembly cycles, greenhouse–icehouse climates, and modeled atmospheric pCO2. Paleoseawater [Ca2+] and [SO2−4] were calculated from the fluid inclusion data using the assumption that the [Ca2+] × [SO2−4] ranged from 150 to 450 mmolal2, which is 0.5–1.5 times the [Ca2+] = 11 × [SO2−4] = 29 product in modern seawater (319 mmolal2). Two additional end-member scenarios, independent of the [Ca2+] × [SO2−4] = 150–450 mmolal2 assumption, were tested using constraints from fluid inclusion [Ca] and [SO4]: (1) constant [SO2−4] = 29 mmolal as in modern seawater, and variable [Ca2+], and (2) constant [Ca2+] = 11 mmolal as in modern seawater and variable [SO2−4]. Mg2+/Ca2+ ratios calculated from the three scenarios were compared to independent data on the Mg2+/Ca2+ ratios from skeletal carbonates (echinoderms and corals) and mid-ocean ridge flank calcite veins. Constant [Ca2+] of 11 mmolal is unlikely because this relatively low concentration generated unreasonably low seawater [SO2−4] during most of the past 550 Myr and high Mg2+/Ca2+ ratios compared to independent data. Constant [SO2−4] of 29 mmolal produced unreasonably high seawater [Ca2+] and lower Mg2+/Ca2+ ratios than those derived from fluid inclusions, echinoderms, corals, and calcite veins. Variable [Ca2+] and [SO2−4] showed the best agreement with the Mg2+/Ca2+ ratios derived from fluid inclusions, echinoderms, corals, and calcite veins.

Evolution of continental temperature seasonality from the Eocene greenhouse to the Oligocene icehouse –a model–data comparison

Abstract. At the junction of greenhouse and icehouse climate states, the Eocene–Oligocene Transition (EOT) is a key moment in Cenozoic climate history. While it is associated with severe extinctions and biodiversity turnovers on land, the role of terrestrial climate evolution remains poorly resolved, especially the associated changes in seasonality. Some paleobotanical and geochemical continental records in parts of the Northern Hemisphere suggest the EOT is associated with a marked cooling in winter, leading to the development of more pronounced seasons (i.e., an increase in the mean annual range of temperature, MATR). However, the MATR increase has been barely studied by climate models and large uncertainties remain on its origin, geographical extent and impact. In order to better understand and describe temperature seasonality changes between the middle Eocene and the early Oligocene, we use the Earth system model IPSL-CM5A2 and a set of simulations reconstructing the EOT through three major climate forcings: pCO2 decrease (1120, 840 and 560 ppm), the Antarctic ice-sheet (AIS) formation and the associated sea-level decrease. Our simulations suggest that pCO2 lowering alone is not sufficient to explain the seasonality evolution described by the data through the EOT but rather that the combined effects of pCO2, AIS formation and increased continentality provide the best data–model agreement. pCO2 decrease induces a zonal pattern with alternating increasing and decreasing seasonality bands particularly strong in the northern high latitudes (up to 8 ∘C MATR increase) due to sea-ice and surface albedo feedback. Conversely, the onset of the AIS is responsible for a more constant surface albedo yearly, which leads to a strong decrease in seasonality in the southern midlatitudes to high latitudes (>40∘ S). Finally, continental areas that emerged due to the sea-level lowering cause the largest increase in seasonality and explain most of the global heterogeneity in MATR changes (ΔMATR) patterns. The ΔMATR patterns we reconstruct are generally consistent with the variability of the EOT biotic crisis intensity across the Northern Hemisphere and provide insights on their underlying mechanisms.

Reassessment of ocean paleotemperatures during the Late Ordovician

Abstract The Late Ordovician is a paradox, with a greenhouse climate shifting to an icehouse climate during a time of presumably high CO2 levels. We used clumped isotope (Δ47) microanalysis of fossil brachiopod shells to determine paleotemperatures of North America (Cincinnati Arch) during the Katian (453–443 Ma). Microanalyses of fossil brachiopods yielded a right-skewed distribution of clumped isotope temperatures [T(Δ47)] ranging from 25 °C to 55 °C with a mode of 32 °C and a mean of 36 °C. To test the impact of Δ47 reordering (reequilibration of 13C-18O bonding) at burial temperatures on T(Δ47), we applied a Monte Carlo simulation to a Δ47 reordering model based on the burial history. Because the reordering simulation indicated partial reordering, we used the simulation results to back-calculate T(Δ47) and correct the reordering effect. Correcting for reordering decreased the mean T(Δ47) by only ~1 °C, to 35 °C, and did not change the mode (32 °C). These temperatures are lower than those of previous studies, but still suggest that the Late Ordovician climate of the Cincinnati Arch was warmer than the modern subtropical seas. However, carbonate facies in these strata argue for upwelling of cool water; thus, typical subtropical surface waters may have been as warm as 35 °C approaching the Hirnantian glaciation. Seawater δ18O values derived from back-calculated T(Δ47) and brachiopod δ18O values average −0.3‰ ± 0.6‰ relative to Vienna standard mean ocean water (VSMOW), consistent with the value expected for subtropical surface waters in a greenhouse Earth, assuming a constant seawater-δ18O model.