Hydrazinium Salts Research Articles

Diamagnetic Susceptibility of Hydrazinium (1 +) and Hydrazinium (2 +) Compounds

The diamagnetic susceptibilities of a number of solid hydrazinium salts have been determined by the Gouy method. The results have been compared with the diamagnetic susceptibilities of the corresponding alkali and ammonium salts. It has been confirmed that the relationship between the molar susceptibility of alkali, ammonium, and hydrazinium (1 +) halides and the effective atomic number of the cation is a periodic one. The diamagnetism of the hydrazinium (1 +) and hydrazinium (2 +) ions was estimated to be (− 20.3 ± 0.3) × 10−6emu/mole. The magnetic susceptibility of the hydrazinium (2 +) ion has been treated theoretically in the LCAO MO approximation and a good agreement with the observed susceptibility value of this ion has been found. A theoretical prediction about the diamagnetic anisotropy of the hydrazinium (2 +) ion was made. The values calculated by the Van Vleck method are about 30% smaller in the x and y directions as compared with the z one. Only a 10% difference was obtained by Pople's MO theory.

397. Hydrazine. Part III. The hydrazinium salts of complex fluoro-acids of tin, antimony, and bismuth

The first page of this article is displayed as the abstract.

Studies on Hydrazine. Solubility of Hydrazinium Salts in Mixed Solvents

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudies on Hydrazine. Solubility of Hydrazinium Salts in Mixed SolventsE. C. GilbertE. C. GilbertMore by E. C. Gilbert and E. H. HuffmanE. H. HuffmanMore by E. H. HuffmanCite this: J. Phys. Chem. 1932, 36, 11, 2789–2792Publication Date (Print):November 1, 1932Publication History Published online1 May 2002Published inissue 1 November 1932https://doi.org/10.1021/j150341a003RIGHTS & PERMISSIONSArticle Views139Altmetric-Citations2LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (190 KB) Get e-Alerts