The kinetics of ethylene oligomerization and aromatization (OA) over ZSM-5 with different Si/Al ratios was modeled by applying single-event concept combined with Brönsted kinetic model to establish a quantitative acidity-activity relationship. The NH3 desorption activation energy was related to the activation energy of the OA reactions and heat of de/protonation based on linear free-energy theory by introducing γ and δ as kinetics parameters for assessing the sensitivity of the OA reactions to the acid strength. A total of 36 parameters was estimated for the subtype elementary steps in each kinetics model. A hybrid genetic optimization algorithm was generated to obtain the kinetics model parameters, where the model can efficiently and accurately fit the changes in the product distribution obtained with the three catalysts for products in the reaction network. The regressed kinetics model can predict the influence of zeolites with the same topology and different acidity on the product distribution.
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