Homogeneous Field Research Articles

Additive Manufacturing of Grid Reservoir-Integrated Anodes for Dendrite-Free, Safe, and Ultra-Low Voltage Zinc-Ion Batteries.

This work reports a novel 3D printed grid reservoir-integrated mesoporous carbon coordinatedsilicon oxycarbide hybrid composite (3DP-MPC-SiOC) to establish the zincophile interphase for controlling the dendrite formation. The customized 3D printed grid patterned structure inhibits Zn dendrite growth and achieves long-term stability with reduced voltage polarization due to homogeneous electric field distribution. The hybrid composite consisting of SiOC interpenetrated within carbon constructs a high zinc nucleation interphase, hence promoting uniform Zn2+ deposition and enhancing ionic diffusion with dendrite-free growth and a reduced nucleation energy barrier. As a result, the 3DP-MPC-SiOC@Zn symmetrical cell affords a highly reversible Zn plating/stripping and dendrite-free structure over 198h with an ultra-low voltage polarization. These inspiring performances endow the 3DP anode with a 3DP-VO cathode as a full battery, which shows a retention capacity of 78.8mAhg-1 (Coulombic efficiency: 94.04%) at 0.1Ag-1 and a large energy density of 41Whkg-1 at a power density of 1.2Wkg-1 (based on the total mass of electrode) after 120 cycles. This newly developed 3D printing of hybrid composite as an electrode is straightforward and scalable and provides a novel concept for realizing dendrite-free and stable rechargeable Zn-ion batteries.

Fat Suppression in Distal Extremity 3-T MRI Using Spectral Heterogeneity Adaptive Radiofrequency Pulses.

Background Conventional chemical shift selective (CHESS) fat suppression may fail in distal extremity MRI due to sensitivity to field inhomogeneities. Purpose To develop a patient-specific fat-suppression method for distal extremity 3-T MRI by exploiting the spectral heterogeneity adaptive radiofrequency pulse (SHARP) technique and to compare it to fat suppression with CHESS. Materials and Methods SHARP uses the routinely acquired frequency spectrum at MRI calibration to adapt the frequency range and time-bandwidth product of the fat-suppression pulse. In this prospective study, fat suppression by SHARP was assessed by numerical simulations, phantom experiments, and imaging in 15 asymptomatic participants who underwent ankle, foot, and hand (in superman and hand-by-the-side positions) MRI using SHARP, CHESS, and reference standard (short-tau inversion recovery or Dixon) techniques. Three readers ranked the MRI scans from 1 (best) to 3 (worst) regarding fat-suppression homogeneity. The added value of SHARP was defined as the difference between the proportions of images where SHARP outranked CHESS and where CHESS outranked SHARP. Friedman, Wilcoxon signed rank, and χ2 tests were used to compare in vivo data. Results At numerical simulations, SHARP showed 0% water and 62%-70% fat suppression, whereas CHESS showed 2% water and 57% fat suppression. Phantom data demonstrated lower fat-suppression inhomogeneity indexes with Dixon (1.0%) and SHARP (2.4%) compared with CHESS (10.7%). In 15 participants (mean age, 38.5 years ± 12.8 [SD]; six female participants), mean ranking by readers of fat homogeneity in the reference technique (ankle, foot, hand in superman position, and hand-by-the-side position: 1.02, 1.02, 1.03, and 1.06, respectively) was higher than those with SHARP (1.39, 1.46, 1.50, and 1.66, respectively), which were higher than those with CHESS (1.64, 1.80, 1.61, and 1.80, respectively) (all P < .001). The added value of SHARP was highest for images in the foot (389 of 1158; 33.6%; P < .001 vs other joints), followed by the ankle (247 of 971 [25%]; P < .001 vs both hand positions), and lowest for hand-by-the-side and hand in superman positions (158 of 1223; [13%] and 133 of 1193 [11%], respectively; P = .18). Conclusion SHARP provided more homogeneous fat suppression than CHESS. © RSNA, 2024 Supplemental material is available for this article.

MRI susceptibility artefacts caused by orthodontic wire.

To evaluate magnetic susceptibility artefacts produced by orthodontic wires on MRI and the influence of wire properties and MRI image sequences on the magnitude of the artefact. Arch form orthodontic wires [four stainless steels (SS), one cobalt chromium (CC) alloy, 13 titanium (Ti) alloys] were embedded in a polyester phantom, and scanned using a 1.5-T superconducting magnet scanner with an eight-channel phased-array coil. All wires were scanned with T1-weighted spin echo (SE) and gradient echo (GRE) sequences according to the American Society for Testing and Materials (ASTM) F2119-07 standard. The phantom also scanned other eight sequences. Artefacts were measured using the ASTM F2119-07 definition and OsiriX software. Artefact volume was analysed according to metal composition, wire length, number of wires, wire thickness, and imaging sequence as factors. With SE/GRE, black/white artefacts volumes from all SS wires were significantly larger than those produced by CC and Ti wires (P < .01). With the GRE, the black artefacts volume was the highest with the SS wires. With the SE, the black artefacts volume was small, whereas white artefacts were noticeable. The cranio-caudal extent of the artefacts was significantly longer with SS wires (P < .01). Although a direct relationship of wire length, number of wires, and wire thickness with artefact volume was noted, these factors did not influence artefact extension in the cranio-caudal direction. Ferromagnetic/paramagnetic orthodontic wires create artefacts due to local alteration of magnetic field homogeneity. The SS-type wires produced the largest artefacts followed by CC and Ti.

Results of 2023 survey on the use of synthetic computed tomography for magnetic resonance Imaging-only radiotherapy: Current status and future steps

Background and purposeThe emergence of synthetic CT (sCT) in MR-guided radiotherapy (MRgRT) represents a significant advancement, supporting MR-only workflows and online treatment adaptation. However, the lack of consensus guidelines has led to varied practices. This study reports results from a 2023 ESTRO survey aimed at defining current practices in sCT development and use. Materials and methodsAn survey was distributed to ESTRO members, including 98 questions across four sections on sCT algorithm generation and usage. By June 2023, 100 centers participated. The survey revealed diverse clinical experiences and roles, with primary sCT use in the pelvis (60%), brain (15%), abdomen (11%), thorax (8%), and head-and-neck (6%). sCT was mostly used for conventional fractionation treatments (68%), photon SBRT (40%), and palliative cases (28%), with limited use in proton therapy (4%). ResultsConditional GANs and GANs were the most used neural network architectures, operating mainly on 1.5 T and 3 T MRI images. Less than half used paired images for training, and only 20% performed image selection. Key MR image quality parameters included magnetic field homogeneity and spatial integrity. Half of the respondents lacked a dedicated sCT-QA program, and many did not apply sanitychecks before calculation. Selection strategies included age, weight, and metal artifacts. A strong consensus (95%) emerged for vendor neutral guidelines. ConclusionThe survey highlights the need for expert-based, vendor-neutral guidelines to standardize sCT tools, metrics, and clinical protocols, ensuring effective sCT use in MR-guided radiotherapy.

Nonsequential double ionization of Ar in two-color inhomogeneous laser fields

With the classical ensemble method, we investigate the correlated electron dynamics in nonsequential double ionization (NSDI) of Ar in parallel two-color inhomogeneous laser fields with different inhomogeneity parameter ϵ. Numerical results show that at low laser intensities, the probability of NSDI is higher for two-color laser fields with a higher inhomogeneity parameter ϵ. At high laser intensities, however, the probability of NSDI decreases as ϵ increases. It is also shown that under low laser intensities, the two-color inhomogeneous laser fields drives the NSDI predominantly dominated by the RII channel, and the ratio of the RII channel increases as ϵ increases. More interestingly, an arc-like structure is found in the correlated electron momentum distributions for the two-color inhomogeneous laser fields. The underlying dynamics are revealed by tracing back to classical trajectories.

Coupled stack-up volume RF coils for low-field open MR imaging.

Low-field open magnetic resonance imaging (MRI) systems, typically operating at magnetic field strengths below 1 Tesla, has greatly expanded the accessibility of MRI technology to meet a wide range of patient needs. However, the inherent challenges of low-field MRI, such as limited signal-to-noise ratios and limited availability of dedicated radiofrequency (RF) coils, have prompted the need for innovative coil designs that can improve imaging quality and diagnostic capabilities. In response to these challenges, we introduce the coupled stack-up volume coil, a novel RF coil design that addresses the shortcomings of conventional birdcage in the context of low-field open MRI. The proposed coupled stack-up volume coil design utilizes a unique architecture that optimizes both transmit/receive efficiency and RF field homogeneity and offers the advantage of a simple design and construction, making it a practical and feasible solution for low-field MRI applications. This paper presents a comprehensive exploration of the theoretical framework, design considerations, and experimental validation of this innovative coil design. We demonstrate the superior performance of the coupled stack-up volume coil in achieving 47.7% higher transmit/receive efficiency and 68% more uniform magnetic field distribution compared to traditional birdcage coils in electromagnetic simulations. Bench tests results show that the B1 field efficiency of coupled stack-up volume coil is 57.3% higher compared with that of conventional birdcage coil. The proposed coupled stack-up volume coil outperforms the conventional birdcage coil in terms of B1 efficiency, imaging coverage, and low-frequency operation capability. This design provides a robust and simple solution to low-field MR RF coil design.

FeSiBCCr bulk metallic glasses with excellent soft magnetic properties prepared using spark plasma sintering technology

Fe-based amorphous alloys have received much attention in the fields of electronics and electrical due to their excellent soft magnetic properties at high frequency. However, the controllable preparation of large-sized Fe-based bulk metallic glasses (BMGs) still faces numerous challenges. In this study, FeSiBCCr amorphous powders prepared by gas-water combined atomization were used as raw materials, and FeSiBCCr BMGs were prepared through spark plasma sintering (SPS) at different pressures. The microstructure, phase and magnetic properties of the compacts were systematically characterized using SEM, XRD, TEM, DSC, and VSM. The results showed that when the sintering pressure was 50 MPa, the slow densification process dominated by particle rearrangement at the initial densification process made the internal contact resistance of the compacts larger. This led to macroscopic inhomogeneous physical fields and severe local overheating during the later stages of sintering, causing the precipitation of α-(Fe, Si) and Fe3B phases. Although the material exhibited a relatively high saturation magnetization (Bs) of 1.08 ± 0.01 T, the low density and amorphous fraction resulted in a high coercivity (Hc) of 1060.8 ± 37.8 A·m-1. When the sintering pressure was increased to 250 MPa, the degree of particle densification significantly improved, and the temperature inhomogeneity was markedly suppressed due to reduced internal resistance. Thus, the prepared FeSiBCCr BMGs exhibited an extremely high density of 6.66 ± 0.06 g·cm-3 and excellent soft magnetic properties with Bs of 1.23 ± 0.01 T and Hc of 18.8 ± 1.8 A·m-1. This indicated that the FeSiBCCr BMGs prepared in this study exhibited broad application prospects in efficient electromagnetic conversion and advanced electronic devices.

Quantitative gradient recalled echo (qGRE) MRI enables in vivo measurement of pre-atrophic neurodegeneration in a mouse model of Alzheimer's disease

Robust methods are needed for preclinical evaluation of novel Alzheimer Disease (AD) therapies to accelerate drug discovery. Quantitative Gradient Recalled Echo (qGRE) MRI has shown promise to provide insight into neurodegeneration in AD prior to atrophy development in humans, highlighting areas of low neuronal density. In this study a novel qGRE method (20 echoes, TE=2-40ms) is shown to non-invasively measure the longitudinal neuronal loss in the hippocampus of a mouse model of AD tauopathy Tg4510.Tg4510 (n=10) and wild type (WT, n=6) mice underwent MRI (7T field strength) at 3-7 months old. 3D qGRE approach was used to generate brain-specific R2* maps free of magnetic field inhomogeneity artifacts. Light-sheet microscopy of the brains stained with NeuN and MBP served to visualize neuronal nuclei and myelin content respectively.Significant decrease in NeuN staining between 3mo and 5mo was observed in the hippocampus of Tg4510, validating the mouse AD model.Longitudinal analysis showed clear decreases in R2* metric of qGRE signal in the Tg4510 mice hippocampus undergoing neurodegeneration between 3 and 5 months old. Histogram analysis revealed an upward trend in patterns of low R2* value (Dark Matter, DM), and broadening of R2* distribution. These were quantified as significant increase in both DM Volume Fraction (DMVF) and R2* Standard Deviation (SD) in Tg4510 mice (p=0.004/p=0.016 DMVF/SD) but not in WT controls (p>0.25). Further monotonical increase was also observed in both metrics in time. A significant negative correlation was observed between the DMVF and myelin content (p=0.01, r=-0.76), suggesting sensitivity of the technique to the loss of myelinated axons.The presented qGRE technique, validated by histological measurements, can be readily applied as in vivo tool in preclinical models of neurodegeneration for pharmacodynamics and mechanism of action assessment.

Nonlinear modulation of dispersive fast magnetosonic waves in an inhomogeneous rotating solar low-β magnetoplasma

Abstract We study the modulation of fast magnetosonic waves (MSWs) in rotating inhomogeneous low-β magnetoplasmas with the effects of gravitation and the Coriolis force. By employing the standard multiple-scale reductive perturbation technique (RPT), we derive a nonlinear Schrödinger (NLS) equation that governs the evolution of slowly varying MSW envelopes. The fast MSW becomes dispersive by the effects of the Coriolis force in the fluid motion, and the magnetic field and density inhomogeneity effects favor the Jeans instability in self-gravitating plasmas in a larger domain of the wave number (k, below the Jeans critical wave number, kJ) than homogeneous plasmas. The relative influence of the Jeans frequency (ωJ, associated with the gravitational force) and the angular frequency (Ω0, relating to the Coriolis force) on the Jeans carrier MSW mode and the modulational instability (MI) of the MSW envelope is studied. We show that the MSW envelope (corresponding to the unstable carrier Jeans mode with ωJ &gt; 2Ω0 and k &lt; kJ) is always unstable against the plane wave perturbation with no cut-offs for growth rates. In contrast, the stable Jeans mode with ωJ &gt; 2Ω0 but k &gt; kJ manifests either modulational stability or MI having a finite growth rate before being cut off. We find an enhancement of the MI growth rate by the influence of magnetic field or density inhomogeneity. The case with constant gravity force (other than the self-gravity) perpendicular to the magnetic field is also briefly discussed to show that the fast magnetosonic carrier mode is always unstable, giving MI of slowly varying envelopes with no cut-offs for the growth rates. Possible applications of MI in solar plasmas, such as those in the X-ray corona, are also briefly discussed.&amp;#xD;

AAPM Task Group Report 325: MRI static magnetic field homogeneity measurement and evaluation procedures - Guidance and resources.

Measurement of static magnetic field (B0) homogeneity is an essential component of routine MRI system evaluation. This report summarizes the work of AAPM Task Group (TG) 325 on vendor-specific methods of B0 homogeneity measurement and evaluation. TG 325 was charged with producing a set of detailed, step-by-step instructions to implement B0 homogeneity measurement methods discussed in the American College of Radiology (ACR) MRI Quality Control Manual using specific makes and models of MRI scanners. The TG produced such instructions for as many approaches as was relevant and practical on six currently available vendor platforms including details of software/tools, settings, phantoms, and other experimental details needed for a reproducible protocol. Because edits to these instructions may need to be made as vendors enter and exit the market and change available tools, interfaces, and access levels over time, the step-by-step instructions are published as a living document on the AAPM website. This summary document provides an introduction to B0 homogeneity testing in MRI and several of the common methods for its measurement and evaluation. A living document on the AAPM website provides vendor-specific step-by-step instructions for performing these tests to facilitate accurate and reproducible B0 homogeneity evaluation on a routine basis.

Reduction of green-gap effect for light-emitting diodes using InGaN-ZnGeN2-InGaN/GaN type-II MQW

In this work, the design of two multiple-quantum-wells (MQWs) green LEDs are investigated − (i) LED A with standard InGaN/GaN type I band alignment quantum wells (QWs), and (ii) LED B with InGaN-ZnGeN2-InGaN/GaN type II band alignment QWs. Using numerical program we obtain energy band diagram, carrier concentration, electric field, electroluminescence spectra and radiative-recombination-rate (RRR). Owing to presence of strong polarization field and compositional inhomogeneity in InGaN/GaN heterostructure, it is hard to obtain the high efficiency in wavelength of 500–600 nm, termed as ‘green-gap’ effect. Introduction of InGaN-ZnGeN2-InGaN QWs reduces the piezoelectric polarization field and enhances overlapping between electron-hole wave functions thereby increasing RRR. Moreover, holes are distributed uniformly in all QWs in the active region of LED that leads to improved emission efficiency. The proposed device, LED B exhibits 710 % more output optical power and less wall-plug efficiency droop is only 3.1 % in contrast to 82.4 % in LED A.

Towards shorter composite 180° refocusing pulses for NMR

Novel composite 180° pulses are designed for use in nuclear magnetic resonance (NMR) and verified experimentally using solution-state 1H NMR spectroscopy. Rather than being constructed from 180° pulses (as in much recent work), the new composite pulses are constructed from 90° pulses, with the aim of finding sequences that are shorter overall than existing equivalents. The primary (but not exclusive) focus is on composite pulses that are dual compensated – simultaneously broadband with respect to both inhomogeneity of the radiofrequency field and resonance offset – and have antisymmetric phase schemes, such that they can be used to form spin echoes without the introduction of a phase error. In particular, a new antisymmetric dual-compensated refocusing pulse is presented that is constructed from ten 90° pulses, equivalent to just five 180° pulses.

Comparison of test-retest reproducibility of DESPOT and 3D-QALAS for water T 1 and T 2 mapping.

Relaxometry, specifically T 1 and T 2 mapping, has become an essential technique for assessing the properties of biological tissues related to various physiological and pathological conditions. Many techniques are being used to estimate T 1 and T 2 relaxation times, ranging from the traditional inversion or saturation recovery and spin-echo sequences to more advanced methods. Choosing the appropriate method for a specific application is critical since the precision and accuracy of T 1 and T 2 measurements are influenced by a variety of factors including the pulse sequence and its parameters, the inherent properties of the tissue being examined, the MRI hardware, and the image reconstruction. The aim of this study is to evaluate and compare the test-retest reproducibility of two advanced MRI relaxometry techniques (Driven Equilibrium Single Pulse Observation of T 1 and T 2, DESPOT, and 3D Quantification using an interleaved Look-Locker acquisition Sequence with a T 2 preparation pulse, QALAS), for T 1 and T 2 mapping in a healthy volunteer cohort. 10 healthy volunteers underwent brain MRI at 1.3 mm3 isotropic resolution, acquiring DESPOT and QALAS data (~11.8 and ~5 minutes duration, including field maps, respectively), test-retest with subject repositioning, on a 3.0 Tesla Philips Ingenia Elition scanner. To reconstruct the T 1 and T 2 maps, we used an equation-based algorithm for DESPOT and a dictionary-based algorithm that incorporates inversion efficiency and B 1 -field inhomogeneity for QALAS. The test-retest reproducibility was assessed using the coefficient of variation (CoV), intraclass correlation coefficient (ICC) and Bland-Altman plots. Our results indicate that both the DESPOT and QALAS techniques demonstrate good levels of test-retest reproducibility for T 1 and T 2 mapping across the brain. Higher whole-brain voxel-to-voxel ICCs are observed in QALAS for T 1 (0.84 ± 0.039) and in DESPOT for T 2 (0.897 ± 0.029). The Bland-Altman plots show smaller bias and variability of T 1 estimates for QALAS (mean of -0.02 s, and upper and lower limits of -0.14 and 0.11 s, 95% CI) than for DESPOT (mean of -0.02 s, and limits of -0.31 and 0.27 s). QALAS also showed less variability (mean 1.08 ms, limits -1.88 to 4.04 ms) for T 2 compared to DESPOT (mean of 2.56 ms, and limits -17.29 to 22.41 ms). The within-subject CoVs for QALAS range from 0.6% (T 2 in CSF) to 5.8% (T 2 in GM), while for DESPOT they range from 2.1% (T 2 in CSF) to 6.7% (T 2 in GM). The between-subject CoVs for QALAS range from 2.5% (T 2 in GM) to 12% (T 2 in CSF), and for DESPOT they range from 3.7% (T 2 in WM) to 9.3% (T 2 in CSF). Overall, QALAS demonstrated better reproducibility for T 1 and T 2 measurements than DESPOT, in addition to reduced acquisition time.

Novel spin-lock time sampling strategies for improved reproducibility in quantitative T1ρ mapping.

This study aimed to optimize the sampling of spin-lock times (TSLs) in quantitative T1ρ mapping for improved reproducibility. Two new TSL sampling schemes were proposed: (i) reproducibility-guided random sampling (RRS) and (ii) reproducibility-guided optimal sampling (ROS). They were compared to the existing linear sampling (LS) and precision-guided sampling (PS) schemes for T1ρ reproducibility through numerical simulations, phantom experiments, and volunteer studies. Each study evaluated the four sampling schemes with three commonly used T1ρ preparations based on composite and balanced spin-locking. Additionally, the phantom and volunteer studies investigated the impact of B0 and B1 field inhomogeneities on T1ρ reproducibility, respectively. The reproducibility was assessed using the coefficient of variation (CoV) by repeating the T1ρ measurements eight times for phantom experiments and five times for volunteer studies. Numerical simulations resulted in lower mean CoVs for the proposed RRS (1.74%) and ROS (0.68%) compared to LS (2.93%) and PS (3.68%). In the phantom study, the mean CoVs were also lower for RRS (2.7%) and ROS (2.6%) compared to LS (4.1%) and PS (3.1%). Furthermore, the mean CoVs of the proposed RRS and ROS were statistically lower (P < 0.001) compared to existing LS and PS schemes at a B1 offset of 20%. In the volunteer study, consistently lower mean CoVs were observed in bilateral thigh muscles for RRS (9.3%) and ROS (9.2%) compared to LS (10.9%) and PS (10.2%), and the difference was more prominent at B0 offsets higher than 50 Hz. The proposed sampling schemes improve the reproducibility of quantitative T1ρ mapping by optimizing the selection of TSLs. This improvement is especially beneficial for longitudinal studies that track and monitor disease progression and treatment response.

Anti-Swelling Microporous Membrane for High-Capacity and Long-Life Zn-I2 Batteries.

Zinc-iodine (Zn-I2) batteries are gaining popularity due to cost-effectiveness and ease of manufacturing. However, challenges like polyiodide shuttle effect and Zn dendrite growth hinder their practical application. Here, we report a cation exchange membrane to simultaneously prevent the polyiodide shuttle effect and regulate Zn2+ deposition. Comprised of rigid polymers, this membrane shows superior swelling resistance and ion selectivity compared to commercial Nafion. The resulting Zn-I2 battery exhibits a high Coulombic efficiency of 99.4 % and low self-discharge rate of 4.47 % after 48 h rest. By directing a uniform Zn2+ flux, the membrane promotes a homogeneous electric field, resulting in a dendrite-free Zn surface. Moreover, its microporous structure enables pre-adsorption of additional active materials prior to battery assembly, boosting battery capacity to 287 mAh g-1 at 0.1 A g-1. At 2 A g-1, the battery exhibits a steady running for 10,000 cycles with capacity retention up to 96.1 %, demonstrating high durability of the membrane. The practicality of the membrane is validated via a high-loading (35 mg cm-2) pouch cell with impressive cycling stability, paving a way for membrane design towards advanced Zn-I2 batteries.

Enhancement of second-order vortex harmonics in epsilon-near-zero materials

When a spatially-inhomogeneous vortex laser field irradiating an epsilon-near-zero (ENZ) material is theoretically investigated, second-order vortex harmonics occur due to the symmetry breaking from the field spatial-inhomogeneity. Their signal intensity is sensitive to three factors: the ENZ field enhancing ratio, the ENZ material thickness, and the field inhomogeneity degree. Their competition supports a high conversion efficiency of around 10−6 for second-order harmonics from the incident fundamental laser field under an optimum thickness of ENZ materials.

ЕЛЕКТРИЧНЕ ПОЛЕ НАПІВПРОВІДНОГО ЕКРАНА СИЛОВОГО КАБЕЛЮ З ПОЛІМЕРНОЮ ІЗОЛЯЦІЄЮ З УРАХУВАННЯМ СТРУКТУРНИХ НЕОДНОРІДНОСТЕЙ

The non-homogeneous electric field distributions in the cross-linked polyethylene insulation of 330 kV power cable with multi-conductor core depending on the electrical conductivity and thickness of the semiconducting screen as well as at different frequency of applied voltage (from 50 to 104 Hz) are studied by finite-element analysis. As shown, taking into account the periodic structure of core surface, the electrical conductivity of the material of internal semiconducting screen should exceed 10–6 S/m and its thickness should be at least 1.5 mm in order to obtain the uniform electric field in the basic insulation of the cable at the boundary with the screen. The paper also considers the effect of various types of the surface and volumetric defects in the semiconducting screen on the electric field inhomogeneity in cable insulation. It is shown that the defects in the screen can lead to a significant increase of the electric field in the local zones of their location (up to 5 times as compared to the field without defects) and therefore contribute to the formation and development of treeing structures in the insulation. The revealed results explain the reasons for the micro- and macro-level degradation of power cable insulation and confirm the need to ensure the uniform structure, smooth surface of both semiconducting screen and core during the technological process of manufacturing the power cables with cross-linked polyethylene insulation. References 23, figures 8, table 1.

Void Evolution on the Li-Solid Electrolyte Interface in Solid-State Batteries: A Parametric Study Under Varied Mechanical and Electrochemical Conditions

Void growth during the plating and stripping process is an important interfacial phenomenon that hinders the development of Li-metal solid-state batteries (SSBs) because it can potentially result in inter-component delamination or growth of Li dendrites. Behind the void growth is the complex interaction between electrochemistry and mechanics. Voids usually grow from micro- or nanoscale initial imperfections on the Li-solid electrolyte (SE) interface. It is, therefore, important to analyze the stress concentration at the initial void tips, which largely determines the growth/shrinking of the void as well as the consequent changes in the internal resistance and overall battery efficiency. Recently, the development of in situ operando experimental technology has enabled the electro-chemo-mechanical characterization of the void growth phenomenon on the Li-SE interface. In this study, we explore how voids in SSBs evolve with a multi-physics model in COMSOL Multiphysics. Based on this model, we perform a systematic parametric study in the space of the mechanical stack pressure and the applied current density. The simulation results show different deformation patterns and potential failure mechanisms under different combination of stack pressure and current density. To better understand the phenomena, we develop an analytical solution to understand the void deformation induced by the inhomogeneous Li-ion concentration field under stack pressure. This analytical approach offers a complementary and intuitive perspective on the mechanical aspect of our simulation findings. By combining the simulation and analytical solutions, we depict a phase diagram, in which we identify the “safe zone” that will not result in void growth. The new insights of this research hold the promise of guiding the development of stabilized SSB interfaces.

Exploring an Electrochemical Batch Reactor for Nutrient Recovery from Wastewater: Continuum Modeling Analysis of Hydrodynamics and Tertiary Current Distribution

Advancing electrochemical reactors for nutrient recovery from wastewater requires an integration of continuum modeling alongside experimental investigations to appropriately capture transport effects on electrode performance. This continuum modeling approach facilitates the comprehensive evaluation and optimization of electrochemical reactor performance, especially with respect to intricate phenomena that may be challenging to observe solely through experimentation. The optimization process not only enhances the efficacy of existing batch reactors but also lays the foundation for designing and scaling up continuous electrochemical reactors for nutrient recovery [1].A key transport phenomenon in electrochemistry is hydrodynamics because flow dynamics around electrodes dictate mass transport magnitude and uniformity, thereby impacting current distribution, efficiency, and electrolytic energy consumption during electrolysis. Achieving homogeneous velocity fields while avoiding undesirable flow features is essential to prevent non-uniform potential and current density distributions along the electrodes, mitigating side reactions and ensuring the overall efficacy of the electrochemical processes [2].In this study, a two-dimensional model of an electrochemical batch reactor was developed using COMSOL Multiphysics software to investigate reactor hydrodynamics, electrochemical reactions, and mass transfer of species. Employing the finite element method, the model incorporated the k-epsilon turbulence model for hydrodynamics simulation, widely used in literature for simulating fluid flow and mixing behavior [3]. Electrochemical reactions at the cathode (oxygen reduction) were modeled using the Butler-Volmer equation, while the Tafel equation was applied at the anode (hydrogen evolution). Boundary conditions were a grounded counter electrode (anode) and a potential of -1.1 vs Ag/AgCl(sat.) applied to the working electrode (cathode). Fick's second law diffusion-convective equation was employed to model the mass transfer of species, including hydroxide and oxygen.Preliminary findings indicate that while impellers contribute to turbulence and affect local conditions around electrodes, the impact on the backside of the modeled electrodes is relatively weak (Figure 1). This observation may adversely influence mass transfer rates and electrochemical reactions, underscoring the significance of integrating these results with electrochemical reactions for a comprehensive understanding of reactor behavior. Additional results will be presented at the meeting.

Deep learning-based pseudo-CT synthesis from zero echo time MR sequences of the pelvis

ObjectivesTo generate pseudo-CT (pCT) images of the pelvis from zero echo time (ZTE) MR sequences and compare them to conventional CT.MethodsNinety-one patients were prospectively scanned with CT and MRI including ZTE sequences of the pelvis. Eleven ZTE image volumes were excluded due to implants and severe B1 field inhomogeneity. Out of the 80 data sets, 60 were used to train and update a deep learning (DL) model for pCT image synthesis from ZTE sequences while the remaining 20 cases were selected as an evaluation cohort. CT and pCT images were assessed qualitatively and quantitatively by two readers.ResultsMean pCT ratings of qualitative parameters were good to perfect (2–3 on a 4-point scale). Overall intermodality agreement between CT and pCT was good (ICC = 0.88 (95% CI: 0.85–0.90); p < 0.001) with excellent interreader agreements for pCT (ICC = 0.91 (95% CI: 0.88–0.93); p < 0.001). Most geometrical measurements did not show any significant difference between CT and pCT measurements (p > 0.05) with the exception of transverse pelvic diameter measurements and lateral center-edge angle measurements (p = 0.001 and p = 0.002, respectively). Image quality and tissue differentiation in CT and pCT were similar without significant differences between CT and pCT CNRs (all p > 0.05).ConclusionsUsing a DL-based algorithm, it is possible to synthesize pCT images of the pelvis from ZTE sequences. The pCT images showed high bone depiction quality and accurate geometrical measurements compared to conventional CT.Critical relevance statementpCT images generated from MR sequences allow for high accuracy in evaluating bone without the need for radiation exposure. Radiological applications are broad and include assessment of inflammatory and degenerative bone disease or preoperative planning studies.Key PointspCT, based on DL-reconstructed ZTE MR images, may be comparable with true CT images.Overall, the intermodality agreement between CT and pCT was good with excellent interreader agreements for pCT.Geometrical measurements and tissue differentiation were similar in CT and pCT images.Graphical