Hole 801C Research Articles

Biometric analysis of the Maastrichtian Arkhangelskiella group in the Indian Ocean (ODP Hole 762C): Taxonomy and evolution.

Biometric analysis of the Maastrichtian Arkhangelskiella group in the Indian Ocean (ODP Hole 762C): Taxonomy and evolution.

Early accretion and prolonged carbonation of the Pacific Ocean's oldest crust

Abstract Newly formed oceanic crust is altered by seawater and carbonated at low temperatures over poorly defined periods of time. We applied in situ U-Pb dating to investigate 28 carbonate veins from Ocean Drilling Program Hole 801C, which is situated in the oldest Jurassic-age oceanic crust preserved in the western Pacific Ocean. Our results indicate that Pacific Ocean crust began accreting at 192 ± 6 Ma, which is ~25 m.y. earlier than previously recognized. Carbonation peaked at 171 ± 5 Ma and continued at a low rate for more than ~65 m.y. after accretion. Jurassic carbonation rates varied over ~10 m.y. timescales but encompassed a range similar to that observed today. These data suggest that carbonation rates are relatively insensitive to changes in atmospheric CO2, but confirm the longevity of seafloor alteration as a critical control in global volatile cycling.

Reconstructing Eocene Eastern Indian Ocean Dynamics Using Ocean‐Drilling Stratigraphic Records

AbstractThe Eocene Epoch corresponds to the runup toward the Greenhouse to Icehouse Cenozoic transition. To fully appreciate this climate evolution, detailed and accurate age‐depth models are required. While much progress has been made recently in the field of Eocene astrochronology, the construction of unambiguous Eocene astronomical timescales (ATS) is hampered by lithologically undetected hiatuses, the scarcity of carbonate‐rich marine successions, and conflicting cyclostratigraphies. In this study, we present an orbital‐scale cyclostratigraphy for Ocean Drilling Program (ODP) Hole 762C, and we reconstruct Eastern Indian Ocean dynamics. This reconstruction is based on two ocean‐drilling Eocene sequences: ODP Hole 762C and International Ocean Discovery Program (IODP) Site U1514. Our eccentricity‐based cyclostratigraphy for Hole 762C is integrated with existing bio and magnetostratigraphies and constitutes the most precise available chronology for this legacy site. The Hole 762C stratigraphy is combined with the existing Site U1514 age‐depth model to obtain a high‐resolution Eocene ATS for the Eastern Indian Ocean. We apply sedimentary noise modeling to obtain new insights in benthic turbulence at both sites. Despite the significant difference in paleo‐waterdepth, noise levels at both sites carry a 1.2‐Myr obliquity amplitude imprint. We interpret the sedimentary noise at Hole 762C, on a submarine plateau, in terms of sea‐level change. The sedimentary noise at U1514, by contrary, is interpreted to be modulated by bottom current intensity as this site represents a deep‐sea basinal environment. We conclude that, despite very similar astronomical signatures, the mechanistic pathways between astronomical forcing and sedimentary response were radically different at these two sites.

Low-temperature oceanic crust alteration and the isotopic budgets of potassium and magnesium in seawater

Low-temperature (<100°C) alteration of oceanic crust plays an important role in determining the chemical composition of the oceans. Although a major sink of seawater potassium, little is known about the effects of low-temperature basalt alteration on the potassium isotopic composition of seawater (δ41K∼0‰), which is ∼0.50‰ enriched relative to bulk silicate Earth (BSE, δ41K= -0.54‰). Here, we present a suite of isotopic systems (δ41K, δ26Mg, δ7Li, 87Sr/86Sr) and major/minor elements in bulk rock, veins and mineral separates from the upper volcanic section of Cretaceous (Troodos ophiolite) and Jurassic (Ocean Drilling Program Hole 801C) oceanic crust. We use these data to estimate the K isotopic fractionation associated with low-temperature oceanic crust alteration and provide new constraints on the role of this process in the global geochemical cycles of Mg and K in seawater. We find that hydrothermally altered basalts from the Troodos ophiolite and ODP Hole 801C, most of which are enriched in K relative to the unaltered glass compositions, have δ41K values both higher and lower than BSE, ranging from +0.01‰ to -1.07‰ (n=83) and +0.04‰ to -0.88‰ (n=17), respectively. Average δ41K values of bulk-rock samples from Troodos and Hole 801C are indistinguishable from each other at ∼-0.50‰, indicating that low-temperature basalt alteration is a sink of 39K from seawater, and explaining, in part, why seawater has a higher 41K/39K than BSE. In contrast to K, average δ26Mg values for both Troodos (∼0.00‰) and Hole 801C (∼0.20‰) indicate that altered oceanic crust (AOC) is a sink of 26Mg from seawater, likely contributing to the light δ26Mg composition of seawater (∼-0.8‰) relative to BSE (∼-0.2‰). We observe isotopically heavy δ26Mg values in basalt samples characterized by small to no changes in bulk Mg content, consistent with extensive isotopic exchange of Mg between seawater and oceanic crust during low-temperature oceanic crust alteration. Finally, we find that variability in δ7Li and δ41K across three sites in the Troodos ophiolite can be explained by different styles of alteration that appear to be related to the timing of sedimentation and its effects on chemical and isotopic exchange between seawater and oceanic crust.

Magnesium isotopic composition of altered oceanic crust and the global Mg cycle

To investigate the behavior of Mg isotopes during low-temperature alteration of oceanic crust and to further understand its role in the global Mg cycle, we measured the Mg isotopic compositions (25Mg/24Mg and 26Mg/24Mg) of a set of samples of altered oceanic crust (AOC) recovered from the Ocean Drilling Program Hole 801C, the reference site for old crust (∼170 Ma) subducting in the Pacific. The measured δ26Mg values range from −1.70‰ to 0.21‰, deviating from that of pristine oceanic basalts (−0.25 ± 0.07‰). Composite samples of volcanoclastic breccia that have experienced relatively intense alteration have larger variation in δ26Mg values (−1.01‰ to 0.15‰) than composite samples of massive basaltic flows (−0.53‰ to −0.04‰), indicating significant Mg isotope fractionation during low-temperature alteration of the oceanic crust. Moreover, the upper off-axis basement has on average lower δ26Mg values (−1.70‰ to −0.04‰) than the lower on-axis basement (−0.16‰ to 0.21‰). These findings, combined with the co-variations between MgO content and FeO∗/CaO ratio and between δ26Mg and FeO∗/CaO ratio, suggest that formation of Mg-bearing minerals (i.e., saponite and calcite) during low-temperature alteration of the oceanic crust accounts for the highly variable δ26Mg of AOC. Early formation of saponite under anoxic condition preferentially takes up heavy Mg isotopes and accounts for Mg enrichment and relatively high δ26Mg in the on-axis basement. Subsequent precipitation of carbonates results in the dilution of Mg and relatively low δ26Mg in the off-axis basement. In addition, accumulation of carbonate-rich interflow sediments in the upper basement may contribute further to the low δ26Mg. A weighted average δ26Mg value of 0.00 ± 0.09‰ is estimated for the AOC at Site 801, implying that low-temperature alteration of oceanic crust drives the ocean to a lighter Mg isotopic composition, and thus requires additional carbonate precipitation to maintain a steady-state Mg isotopic composition of seawater. A mass balance calculation suggests that the Mg output flux due to low-temperature alteration of the oceanic crust equals ∼12% of the annual Mg riverine input, indicating that AOC is a significant sink of Mg in seawater. Our study further highlights that recycling of AOC with highly variable δ26Mg along with overlying marine sediments into the mantle through subduction may generate Mg isotopic heterogeneity in the mantle at small scales.

Lower Maastrichtian cyclostratigraphy of the Bidart section (Basque Country, SW France): A remarkable record of precessional forcing

Cyclostratigraphic analysis of the Maastrichtian limestone–marl alternations of Bidart (SW France) allows the hypothesis of orbital control on lithological cycles to be evaluated. Magnetic susceptibility (MS), oxygen and carbon isotope measurements, sampled at a high resolution, are analyzed using various cyclostratigraphic tools. A statistically significant orbital signal is detected, with a remarkable record of the precession corresponding to the limestone–marl couplets. This well expressed orbital forcing allows the building of a relative cyclostratigraphic time scale for the MS and δ13C records based on the 100kyr eccentricity cycle. The total duration of the section is estimated at 1.44±0.22Myr. Correlation based on calcareous nannofossil biostratigraphy and comparison of the scaled Bidart δ13C record to the astronomically calibrated δ13C signal of ODP Hole 762C shows that the studied section extends from −71.5 to −70Ma, covering the upper part of Chron C32n.1n and 2/3 of Chron C31r. Oxygen isotope data suggest a 2°C cooling of sea-surface temperatures during the studied interval. When placed on the long-term δ18O trend of the Bidart section, this interval is here recognized as the onset of the early Maastrichtian cooling event. With its excellent record of the precessional forcing, the Bidart section, along with other sections of the Basque Country, is a useful tool for the refinement of the Maastrichtian timescale.

Paleointensity results from the Jurassic: New constraints from submarine basaltic glasses of ODP Site 801C

Tholeiite of the oldest oceanic crust was drilled during ODP Legs 129 and 185 at Hole 801C in the western Pacific. Fresh appearing submarine basaltic glass (SBG) was recovered from the tholeiites (∼167 Ma) which has been shown to be nearly ideal for determining absolute paleointensity. Paleointensities of the younger, off‐axis, alkalic basalts (∼160 Ma), overlying the tholeiites, had been studied earlier. Here we report results from the older tholeiitic (on‐axis) sequence. We subjected a total of 73 specimens from 17 cooling units to absolute paleointensity experiments. Of these, 30 specimens and six cooling unit averages met our strictest reliability criteria, yielding an average of 11.9 ± 3.9 μT. The bulk of evidence suggests a paleolatitude of the site of 14°S (with an uncertainty of 10°). This translates the intensity to a value for the virtual axial dipole moment of 28 ZAm2, slightly lower than values determined from the plagioclase crystals in the three cooling units of the younger alkalic basalts overlying the tholeiites (Tarduno &amp; Cottrell, 2005). Our value is low when compared to the long‐term median value of the field of 42 ZAm2. Our results and those of the published literature therefore support the contention of a low magnetic field strength in the Jurassic (average of 28 ± 14 ZAm2;N = 138 individual estimates), as initially suggested by Prévot et al. (1990). Our interpretation of the body of available data argue for low field strengths for the entire Jurassic extending into the early Cretaceous.

Santonian–Campanian planktonic foraminifera from Tanzania, Shatsky Rise and Exmouth Plateau: Species depth ecology and paleoceanographic inferences

Abstract The Santonian–Campanian interval is of particular interest as it encompasses a cooling trend after the Late Cretaceous greenhouse maximum warmth of the Turonian as well as a possibly related major faunal turnover among planktonic foraminifera. The recovery of pristinely preserved planktonic foraminifera from Santonian–Campanian sequences in southeastern Tanzania allows examination of faunal changes and documentation of species-specific stable isotope (δ 13 C and δ 18 O) signatures. These isotopic data are ideal for inferring species paleoecological preferences and for tracing major paleoceanographic changes. This study reports the first δ 18 O and δ 13 C data generated on “glassy” specimens of Marginotruncana coronata , M. undulata , M. marginata , and M. pseudolinneiana and Sigalia carpatica . Additional results from Shatsky Rise (Ocean Drilling Program Leg 198, Hole 1210B) and Exmouth Plateau (ODP Leg 122, Hole 762C) provide geographic control on species habitat preferences and paleoceanographic context. Isotopic analyses suggest that double-keeled species, including Globotruncana bulloides , Contusotruncana fornicata , C. plummerae and probably marginotruncanids, inhabited the surface mixed layer, whereas the biserial Gublerina rajagopalani was a permanent thermocline dweller. Thus, our study confirms recent suggestions that the depth-distribution models based on shell morphology and analogies with modern taxa are not applicable. At all the examined localities, changes in planktonic foraminiferal assemblages are used to define several ecological intervals, each one characterized by a distinctive taxonomic composition and/or increasing/decreasing species diversity. Combined geochemical and paleontological observations suggest that, by the middle–late Campanian, a stratified upper water column developed in Tanzania while less stratified and/or mesotrophic conditions prevailed at Shatsky Rise and Exmouth Plateau.

Astronomical calibration of upper Campanian–Maastrichtian carbon isotope events and calcareous plankton biostratigraphy in the Indian Ocean (ODP Hole 762C): Implication for the age of the Campanian–Maastrichtian boundary

An integrated framework of magnetostratigraphy, calcareous microfossil bio-events, cyclostratigraphy and δ13C stratigraphy is established for the upper Campanian–Maastrichtian of ODP Hole 762C (Exmouth Plateau, Northwestern Australian margin). Bulk-carbonate δ13C events and nannofossil bio-events have been recorded and plotted against magnetostratigraphy, and provided absolute ages using the results of the cyclostratigraphic study and the recent astronomical calibration of the Maastrichtian. Thirteen carbon-isotope events and 40 nannofossil bio-events are recognized and calibrated with cyclostratigraphy, as well as 14 previously published foraminifer events, thus constituting a solid basis for large-scale correlations. Results show that this site is characterized by a nearly continuous sedimentation from the upper Campanian to the K-Pg boundary, except for a 500kyr gap in magnetochron C31n. Correlation of the age-calibrated δ13C profile of ODP Hole 762C to the δ13C profile of the Tercis les Bains section, Global Stratotype Section and Point of the Campanian–Maastrichtian boundary (CMB), allowed a precise recognition and dating of this stage boundary at 72.15±0.05Ma. This accounts for a total duration of 6.15±0.05Ma for the Maastrichtian stage. Correlation of the boundary level with northwest Germany shows that the CMB as defined at the GSSP is ~800kyr younger than the CMB as defined by Belemnite zonation in the Boreal realm. ODP Hole 762C is the first section to bear at the same time an excellent recovery of sediments throughout the upper Campanian–Maastrichtian, a precise and well-defined magnetostratigraphy, a high-resolution record of carbon isotope events and calcareous plankton biostratigraphy, and a cyclostratigraphic study tied to the La2010a astronomical solution. This section is thus proposed as an excellent reference for the upper Campanian–Maastrichtian in the Indian Ocean.

A record of the extraterrestrial 3He flux through the Late Cretaceous

Late Cretaceous (100–73Ma) pelagic limestones were measured for helium concentration and isotopic composition to characterize the interplanetary dust flux using 3He as a tracer. In the Bottaccione section near Gubbio, Italy, three intervals of elevated 3He concentration were detected: K1 in the Campanian stage at ∼79Ma, K2 in the Santonian stage at ∼85Ma, and K3 in the Turonian stage at ∼91Ma. All three of these episodes are associated with high 3He/4He and 3He/non-carbonate ratios, consistent with their derivation from an enhanced extraterrestrial 3He flux rather than decreased carbonate sedimentation or dissolution. While K2 is modest in magnitude and duration and thus is of limited significance, K1 and K3 are each identified by a few myr interval with an ∼4-fold enhancement in mean 3He flux compared with pre-event levels. Samples from ODP Hole 762C in the Indian Ocean spanning both K2 and K3 (93–83Ma) confirm the presence of a peak in the Turonian stage, suggesting that K3 is a global event. The K1 and K3 3He events are similar in most respects to the two peaks previously detected in the Cenozoic, suggesting a similar origin. These have been attributed to a major asteroid collision in the Late Miocene and to a shower of either comets or asteroids in the Late Eocene. Based on the age and temporal evolution of K1, we suggest that it most likely records the collision which produced the Baptistina asteroid family independently dated at ∼80Ma. The K3 event is less easily explained. It is characterized by an unusually spiky and erratic temporal progression, suggesting an unusual abundance of very 3He rich particles not previously seen in the sedimentary 3He record. We suggest this episode arises either from a comet shower or from an asteroid shower possibly associated with dust-producing lunar impacts.

Eocene biogeochronology and magnetostratigraphic revision of ODP Hole 762C, Exmouth Plateau (northwest Australian Shelf)

We present a chronostratigraphic model for the Eocene from ODP Leg 122 Hole 762C (northwest Australian shelf), integrating calcareous nannofossil data with previously published planktonic foraminiferal data, magnetostratigraphy and stable isotopic data. This ~240m thick interval extends from magnetic polarity Chron C25r to Chron C15r, and nannofossil zones CP6/7 to CP16a (NP7/8-NP21). Examination of the calcareous nannofossil biostratigraphy showed several potential hiatuses within this stratigraphic section at Hole 762C. The presence of these hiatuses was supported by cross-correlation of planktonic foraminiferal P-zones, magnetostratigraphic reversals and δ13C and δ18O isotopic excursions. These biostratigraphic and isotopic data were used to re-evaluate the original magnetostratigraphy, and this revised framework was integrated into a new age model. The original depositional model from Leg 122 proposed a continuous section with relatively low sedimentation rates in the Lutetian and basal Ypresian (&lt; 1.0cm/ky); however, our results suggest that sedimentation rates were relatively high but that the section is interrupted by four hiatuses, each ~1-2 myr in duration. This new age model allowed revision of sedimentation rates at Hole 762C. These revised rates are used to estimate the ages of calcareous nannofossil bioevents, which are compared to several additional, globally distributed localities.

Identification of the base of the lower-to-middle Campanian Globotruncana ventricosa Zone: Comments on reliability and global correlations

The reliability of the first appearance datum of Globotruncana ventricosa as biozonal marker for the Campanian is discussed. The taxonomy and species concept of G. ventricosa and of Globotruncana tricarinata, that has been either regarded as junior synonym of Globotruncana linneiana or of G. ventricosa, are examined to avoid misidentifications, and one species is here formally described as new, Globotruncana neotricarinata nov. sp. The tropical and subtropical planktic foraminiferal assemblages from the Bottaccione section (Gubbio, Italy), from Deep Sea Drillig Project (DSDP) Site 146 (Caribbean Sea, central Atlantic Ocean), and from Ocean Drilling Program (ODP) Hole 1210B (Shatsky Rise, northwestern Pacific Ocean) are analyzed for the presence of biostratigraphic markers. Lowest and highest occurrence data have been checked in thin sections and washed residues in the Bottaccione section. The comparative biostratigraphic analysis of the planktic foraminiferal distribution highlights: 1) the absence of G. ventricosa at the stratigraphic level at which it is supposed to first occur in the Tethyan area, 2) the presence of transitional specimens resembling G. ventricosa and thus erroneously used to identify the base of the G. ventricosa Zone, 3) the presence of a good sequence of bioevents that appear to be promising for regional and global correlations such as the appearance of Globotruncanita atlantica, Contusotruncana plummerae and the disappearance of Hendersonites carinatus. The correlation potential of these bioevents has been verified across latitudes by studying the Campanian planktic foraminiferal assemblage in pelagic sediments drilled on coastal Tanzania (western Indian Ocean), and at the deep-sea ODP Hole 762C (Exmouth Plateau, western Indian Ocean), that were located at 30°S and 47°S in the Late Cretaceous, respectively. Besides the known diachronous first appearance of G. ventricosa in the Southern Ocean sites, results confirm the difficulty in using G. ventricosa as zonal marker in the tropical and subtropical areas, and the validity of the first appearance datum of C. plummerae for regional and global correlations.

Hf‐Nd input flux in the Izu‐Mariana subduction zone and recycling of subducted material in the mantle

In subduction zones, two major mass fluxes compete: the input flux of altered oceanic crust and sediments subducted into the mantle and the output flux of magma that forms the volcanic arc. While the composition and the amount of material erupted along volcanic arcs are relatively well known, the chemical and isotopic composition of the subducted material (altered oceanic crust and sediments) is poorly constrained and is an important factor in the mass balance calculation. Ocean Drilling Program Leg 185 in the Western Pacific used systematic sampling of the altered basaltic basement and sediment pile and the creation of composite mixtures to quantify the total chemical flux subducted at the Izu‐Mariana margin. Here, we report Hf and Nd isotopic compositions of materials recovered from this Leg. The Hf and Nd isotopic compositions of altered basalts from Hole 801C are indistinguishable from those of recent unaltered Pacific mid‐ocean ridge basalt, suggesting that hydrothermal alteration had no effect on either isotopic systems. The complete Site 1149 sedimentary pile has a weighted average ɛNd of −5.9 and ɛHf of +4.4, values similar to those of Fe‐Mn crusts and nodules. Therefore, the Hf and Nd isotopic compositions of the sediments collected at Site 1149 indicate minimal contributions from continental detrital material to the rare earth elements and high field strength elements. However, the Hf isotopic budget of the oldest sediments is more influenced by continental material than the younger sediments, despite the large distances to continental masses 130 Ma ago. In the Izu subduction zone, we calculate a sedimentary input of less than about 2% in the volcanic lava source. In contrast, at least 85% of the sedimentary Nd and Hf are recycled into the mantle to affect its general composition. Assuming that sediments have been recycled in a similar manner into the mantle for millions of years, large chemical heterogeneities must be produced in the mantle. In addition, the depletion of the mantle due to the extraction of continental crust must be partly counterbalanced by the injection of vast quantities of enriched sedimentary material.

Re–Os results from ODP Site 801: Evidence for extensive Re uptake during alteration of oceanic crust

Re and Os concentrations and Os isotopic ratios were determined for composite samples prepared from volcanoclastics (VCL) and basaltic flows (FLO) from Jurassic oceanic crust (Ocean Drilling Program Leg 185, Site 801 in the western Pacific), with the aim of determining the effect of seafloor weathering on the Re–Os budget. A supercomposite sample, prepared from a proportionate mixture of the various composite powders, served to represent the average composition of the altered oceanic crust [Kelley, K.A., Plank, T., Ludden, J. and Staudigel, H., (2003). Composition of altered oceanic crust at ODP Sites 801 and 1149, Geochem. Geophys. Geosyst. 4(6) 8910, doi:10.1029/2002GC000435.]. Re contents vary from 0.2 to 1.3 ng g − 1 , and from 2.2 to 3.1 ng g − 1 in the VCL and FLO composites respectively. Os contents vary from 0.005 to 0.047 ng g − 1 in the VCL, and from 0.008 to 0.027 ng g − 1 in the FLO composites. The FLO composites have much higher Re/Os ratios and thus have more radiogenic Os compositions ( 187Os/ 188Os = 1.38 to 8.48) than the VCL composites ( 187Os/ 188Os = 0.32 to 4.40). The VCL composite from the upper section of the crust shows evidence for substantial Re loss and Os uptake, consistent with oxidative weathering processes. However, Re uptake during weathering processes under more reducing conditions, evident in the FLO samples from throughout the section and to a lesser extent in the lower VCL samples, more than compensates for this Re loss in the upper VCL. Os concentrations were essentially unchanged by these reductive processes. Model age calculations suggest that Re uptake continued for tens of millions of years after crust formation. Abundant secondary pyrite is found throughout the altered Hole 801C crust in zones of restricted seawater flow, and this may have accommodated an important part of the input Re. The Re content of the supercomposite (∼ 2.2 ng g − 1 ) is about 1 ng g − 1 higher than would be expected on the basis of its Yb content. If the results from Hole 801C are typical, they suggest that the Re concentration of at least the upper part of the oceanic crust may be nearly doubled during seafloor alteration. Such large extents of Re uptake would have a significant effect on the oceanic Re budget. Furthermore, assuming that they survive passage through the subduction zone, these elevated Re contents would greatly decrease the proportion of subducted oceanic crust required in the source region to explain the radiogenic Os compositions of many ocean island basalts.

Origin of the Pacific Jurassic quiet zone

Understanding the marine magnetic anomaly record is critical for constructing realistic geodynamo models of global geomagnetic field, polarity reversal mechanisms, and long-term geomagnetic field behavior. One of the least understood portions of the marine magnetic anomaly record is also the oldest part of the record, the Jurassic quiet zone (JQZ), where anomalies become weak and difficult to correlate. The reason for the existence of the JQZ is unclear. It has been suggested that the JQZ is a true polarity superchron, similar to the Cretaceous normal superchron. Continental magnetostratigraphic studies have suggested that the JQZ is a period of rapid polarity reversal, of low field intensity, or both. We show results of a deep-tow survey of Pacific Jurassic crust that confirms the existence of magnetic anomalies within the JQZ. We tie Ocean Drilling Program Hole 801C (167.4 Ma) into the record and show that seafloor-spreading magnetic anomalies are present around the hole and extend to 170 Ma crust. We find a rise in reversal rate with increasing age with reversal rates over 10 rev/m.y. at 160 Ma and at 167 Ma. Anomaly amplitudes decrease in the record from 155 Ma until 162 Ma, where low-amplitude anomalies are difficult to correlate. Prior to 167 Ma, anomalies regain amplitude and remain strong until the end of our record at 170 Ma. The JQZ thus appears to be a combination of low-amplitude magnetic anomalies combined with rapid field fluctuations, which could be due to either intensity or polarity changes.

Downhole magnetic measurements of ODP Hole 801C: Implications for Pacific oceanic crust and magnetic field behavior in the Middle Jurassic

Downhole horizontal and vertical magnetic field measurements within the 474 m thick Jurassic crustal section drilled at ODP Hole 801C in the western Pacific show anomalies that are “in phase,” indicating that this site formed in the southern hemisphere and moved across the paleoequator to its present location at 18.6°N. The inclination computed from the horizontal and vertical anomaly logging data varies significantly downhole and can be explained by progressive rotation of the lava sequence as it is buried during accretion. This is compatible with the observed dips in the Formation Micro Scanner (FMS) data, which show up to 42° of rotation toward the fossil spreading axis. We restore the magnetic inclination to prerotated values and obtain an estimated pretilt inclination of 39.9° ± 6.6°, corresponding to a paleolatitude of 22.7° ± 5°S. The magnetic logging data document six polarity units within the drilled volcanic extrusive crust. The upper 132 m thick logged section of lavas contains four polarity units, which apparently formed 7 Myr after the formation of the underlying basement. The lower 212 m logged section of the hole is reversely magnetized with an intervening normal polarity zone. More than one reversal downhole would indicate a rapid reversal rate given the time it takes to form the extrusive section of oceanic crust: ∼45,000 years at a fast spreading rate of 66 km/Myr. Previous results from a contemporaneous section in Spain suggest rapid reversals throughout the late Bajocian–early Bathonian Stage (170–165 Ma). Nevertheless, the complicated formation history prevents quantification of the geomagnetic reversal rate for the 801C crustal section.

The interpretation of thermal neutron properties in ocean floor volcanics

Abstract Using near-complete chemical analyses, computed thermal absorption cross-section values (σ) are calculated for ocean-floor basalts from ODP Holes 896a and 1179D. Comparison with nuclear measurement of σ, demonstrates that this computational method is valid and clarifies the interpretation of σ in ocean-floor basalts. Boron, lithium and the rare-earth elements are important controls on the σ-values, and, of these, the distribution of the rare-earth elements is controlled by primary magmatic processes, whereas the distribution of boron and lithium is strongly influenced by secondary low-temperature alteration processes. Consequently, computed σ-values can be used to discriminate between various basalt types and to identify areas of secondary alteration. Following calibration of the ‘fresh basalt’ signature, it is possible to interpret log derived neutron absorption measurements of a sample (Σ-values), which, when integrated with other log responses, allow the distribution of alteration within a drilled section to be mapped. Examples from ODP Hole 801C demonstrate the potential of this technique.

Middle Campanian–lowermost Maastrichtian nannofossil and foraminiferal biostratigraphy of the northwestern Australian margin

The middle–late Campanian was marked by an increase in the bioprovinciality of calcareous microfossil assemblages into distinct Tethyan, Transitional, and Austral Provinces that persisted to the end of the Maastrichtian. The northwestern Australian margin belonged to the Transitional Province and the absence of key Tethyan marker species such as Radotruncana calcarata and Gansserina gansseri has led petroleum companies operating in the area to use the locally developed KCCM integrated calcareous microfossil zonation scheme. The KCCM zonation is a composite scheme comprising calcareous nannofossil (KCN), planktonic foraminiferal (KPF) and benthonic foraminiferal (KBF) zones. This paper presents the definitions and revisions of Zones KCCM8–19, from the highest occurrence (HO) of Aspidolithus parcus constrictus to the lowest occurrence (LO) of Ceratolithoides aculeus, and builds on our previous early–late Maastrichtian study. The presence of a middle–upper Campanian disconformity is confirmed by microfossil evidence from the Vulcan Sub-basin, Exmouth and Wombat plateaus, and the Southern Carnarvon Platform. In the Vulcan Sub-basin and on the Exmouth Plateau (ODP Hole 762C) the hiatus extends from slightly above the LO of common Rugoglobigerina rugosa to above the LO of Quadrum gothicum. On the Wombat Plateau (ODP Hole 761B) it spans from above the LO of Heterohelix semicostata to above the LO of Quadrum gothicum; and in the Southern Carnarvon Platform the disconformity has its longest duration from above the HO of Heterohelix semicostata to above the LO of Quadrum sissinghii. A significant revision of the events which define Zones KCCM18 and 19 was necessary owing to the observation that the LO of Ceratolithoides aculeus occurs below the HOs of Archaeoglobigerina cretacea and Stensioeina granulata incondita and the LO of common Rugoglobigerina rugosa. In the original zonation these events were considered to be coincident.

Hydrothermal alteration of upper oceanic crust formed at a fast-spreading ridge: mineral, chemical, and isotopic evidence from ODP Site 801

ODP Hole 801C penetrates >400 m into 170-Ma oceanic basement formed at a fast-spreading ridge. Most basalts are slightly (10–20%) recrystallized to saponite, calcite, minor celadonite and iron oxyhydroxides, and trace pyrite. Temperatures estimated from oxygen isotope data for secondary minerals are 5–100 °C, increasing downward. At the earliest stage, dark celadonitic alteration halos formed along fractures and celadonite, and quartz and chalcedony formed in veins from low-temperature (<100 °C) hydrothermal fluids. Iron oxyhydroxides subsequently formed in alteration halos along fractures where seawater circulated, and saponite and pyrite developed in the host rock and in zones of restricted seawater flow under more reducing conditions. Chemical changes include variably elevated K, Rb, Cs, and H 2O; local increases in Fe T, Ba, Th, and U; and local losses of Mg and Ni. Secondary carbonate veins have 87Sr/ 86Sr=0.706337–0.707046, and a negative correlation with δ 18O results from seawater–basalt interaction. Carbonates could have formed at any time since the formation of Site 801 crust. Variable δ 13C values (−11.2‰ to 2.9‰) reflect the incorporation of oxidized organic carbon from intercalated sediments and changes in the δ 13C of seawater over time. Compared to other oceanic basements, a major difference at Site 801 is the presence of two hydrothermal silica–iron deposits that formed from low-temperature hydrothermal fluids at the spreading axis. Basalts associated with these horizons are intensely altered (60–100%) to phyllosilicates, calcite, K-feldspar, and titanite; and exhibit large increases in K, Rb, Cs, Ba, H 2O, and CO 2, and losses of Fe T, Mn, Mg, Ca, Na, and Sr. These effects may be common in crust formed at fast-spreading rates, but are not ubiquitous. A second important difference is that the abundance of brown oxidation halos along fractures at Site 801 is an order of magnitude less than at some other sites (2% vs. 20–30%). Relatively smooth basement topography (<100 m) and high sedimentation rate (8 m/Ma) probably restricted the access of oxygenated seawater. Basement lithostratigraphy and early low-temperature hydrothermal alteration and mineral precipitation in fractures at the spreading axis controlled permeability and limited later flow of oxygenated seawater to restricted depth intervals.

Physical properties of upper oceanic crust: Ocean Drilling Program Hole 801C and the waning of hydrothermal circulation

The hydrologic evolution of oceanic crust, from vigorous hydrothermal circulation in young, permeable volcanic crust to reduced circulation in old, cooler crust, causes a corresponding evolution of geophysical properties. Ocean Drilling Program (ODP) Hole 801C, which obtained the world's oldest section of in situ, normal oceanic crust, provides the opportunity to examine relationships among hydrologic properties (porosity, permeability, fluid flow), crustal alteration, and geophysical properties, at both core plug and downhole log scales. Within these upper crustal basalts, fluid flux in zones with high porosity and associated high permeability fosters alteration, particularly hydration. Consequently, porosity is correlated with both permeability and a variety of hydration indicators. Porosity‐dependent alteration is also seen at the log scale: potassium enrichment is strongly proportional to porosity. We extend the crustal alteration patterns observed at Hole 801C to a global examination of how physical properties of upper oceanic crust change as a function of age based on global data sets of Deep Sea Drilling Project and ODP core physical properties and downhole logs. Increasing crustal age entails macroporosity reduction and large‐scale velocity increase, despite intergranular velocity decrease with little microporosity change. The changes in macroporosity and velocity are significant for pillows but minor for flows. Matrix densities provide the strongest demonstration of systematic age‐dependent alteration. On the basis of observed decreases in matrix density that are proportional to the logarithm of age, approximately half of all intergranular‐scale crustal alteration occurs after the first 10–15 Myr. Apparently, crustal alteration continues, at a decreasing rate, throughout the lifetime of oceanic crust.