High Concentrations Of Manganese Research Articles

ANÁLISIS HIDROGEOQUÍMICO DE LA CALIDAD DE AGUAS SUPERFICIALES EN UNA ZONA MINERA EN EL FLANCO OESTE DE LA CORDILLERA OCCIDENTAL DE LOS ANDES

This study used the hydrogeochemical properties of surface waters surrounding a mining project in Peru to compare them with the environmental quality standards established in Supreme Decree 004-2017-MINAM, focusing on category 3 for vegetable irrigation and animal drinking. Physical-chemical, inorganic, microbiological and parasitic parameters were evaluated in lagoons and springs. The results determined the presence of slightly alkaline deposits with a pH of 9.59 and slightly acidic deposits with a pH of 5.33, as well as deposits with high content of iron, manganese, and zinc. To ensure the reliability of the chemical analysis, an ionic balance of the main dissolved cations and anions was performed. The Piper diagram determined the predominant calcic sulfate waters, as well as the presence of a calcic bicarbonate water deposit. On the other hand, the Stiff diagram determined sulfate (SO42-) as the predominant ion. This study concludes that the different stations comply with the environmental quality standards, although deposits with high levels of iron, manganese, and zinc were found in surface waters. Different treatments were determined to control pH levels and to decrease the amount of such ions present.

Pharmacognostic standardisation of the leaves of Costus afer Ker Gawl. (Zingiberaceae) and Palisota hirsuta (Thunb.) K. Schum. (Commelinaceae)

BackgroundMicrobes’ resistance to orthodox drugs and continued emergence of new infections call for search of new drugs that can mitigate such resistance and cure newly emerging infections. Despite the therapeutic importance of Costus afer and Palisota hirsuta, the detailed pharmacognostic characters of the two plants are still missing in the literature. Thus, this study evaluated the pharmacognostic characters of these plants and the antimicrobial activity of the plants’ methanol extract. Macroscopic, microscopic, fluorescence analysis, phytochemical screening, heavy metal analysis, proximate, antimicrobial assay and Gas Chromatography–Mass Spectrometry analyses were carried out on both plants.ResultsThe microscopic evaluation showed that the epidermal layer of Costus afer is hypostomatic with polygonal shaped epidermal cells and cyclotic stomata on abaxial layer while the epidermal layer of Palisota hirsuta leaf is amphistomatic, having polygonal shape epidermal cell, trichomes and paracytic stomata. The proximate analysis showed that both plants have a high carbohydrate content (C. afer: 59.13% and P. hirsuta: 68.28%) but a low crude fat content (C. afer: 1.867% and P. hirsuta: 0.233%). The heavy metal analysis revealed a high content of Manganese (266.80 mg/100 g) in Palisota hirsua, and a high content of iron (43.94 mg/100 g) in Costus afer. Both plants are free of lead. The phytochemical screening showed that both plants have saponins, tannins, flavonoids, alkaloids and cardiac glycosides. Alkaloids are the highest constituents in Costus afer (9.1%) and Palisota hirsuta (7.1%). The antimicrobial assay showed both plant extracts had the highest inhibitory effect on both bacteria and fungi at 100 mg/kg. Six compounds and 23 compounds were identified by GC–MS in C. afer and P. hirsuta, respectively. Methyl stearate (40.43%) and hexadecanoic acid, methyl ester (25.62%) were the prevailing constituents identified in C. afer and P. hirsuta, respectively.ConclusionThe pharmacognostic features of Costus afer and Palisota hirsuta shown in this study can be used to design a suitable monograph which would be useful in compilation of another edition of Nigeria Herbal Pharmacopoeial. The dominant compounds in both plants can serve as chemotaxonomic markers for correct identification of the two plants.

Optical and photoelectrical properties of low-concentration-Mn-doped CsPbBr3 nanocrystals

Doping of cesium lead bromide (CsPbBr3) perovskite nanocrystals offers effective control of their optical and optoelectrical properties, leading to possibilities of several new applications. Herein, cesium lead bromide perovskite nanocrystals are synthesized with doping of a low concentration of manganese (Mn) into the perovskite lattice using manganese (II) chloride (MnCl2) as a precursor. The shift in X-ray diffraction peaks toward higher angles indicates that manganese as a dopant is present inside the cesium lead bromide lattice. A change in the manganese (II) chloride precursor concentration from 5 to 10 mmol results in an increment in the atomic percentage of manganese from 0.3 to 0.5% in the cesium lead bromide crystal. Doping of a low concentration of manganese (0.3 at.%) into cesium lead bromide results in enhancement of green emission, while doping with a higher concentration of manganese (0.5 at.%) results in blue emission. The band gap of cesium lead bromide nanocrystals increases from 2.31 to 2.53 eV with an increase in the concentration of manganese. The dark and photoelectrical conductivity of cesium lead bromide nanocrystals is improved in the case of doping with a low concentration (0.3 at.%) of manganese. The ratio of photocurrent against dark current is found to be ∼182 in manganese-doped cesium lead bromide crystal film as compared with ∼101 for undoped cesium lead bromide crystal film. Doping with a low concentration of manganese improves the overall electrical and photoelectrical conductivity of cesium lead bromide perovskite nanocrystals.

Facilitation of phosphorus acquisition by Banksia attenuata allows Adenanthos cygnorum (Proteaceae) to extend its range into severely phosphorus-impoverished habitats

Abstract Background and aims In extremely low-phosphorus (P) environments, most Proteaceae exude carboxylates from cluster roots. These carboxylates mobilise inorganic P which leads to a relatively high leaf manganese concentration ([Mn]). However, we found that Adenanthos cygnorum (Proteaceae) in a low-P habitat did not invariably have a high leaf [Mn] in south-western Australia. We aimed to explore how A. cygnorum acquires P in severely P-impoverished habitats. Methods We determined soil P concentrations and leaf [Mn] of A. cygnorum growing within 1 m and more than 10 m away from other large Proteaceae. We also grew plants in a glasshouse to determine its root carboxylate exudation and rhizosheath phosphatase activity. Results Adenanthos cygnorum did not produce functional cluster roots. It depended on carboxylates released by a P-mobilising neighbour, Banksia attenuata (Proteaceae), to acquire P when growing in severely P-impoverished soil (< 8 mg P kg− 1 dry soil). In slightly less P-impoverished soil (> 11 mg P kg− 1 dry soil), phosphatases released by A. cygnorum hydrolysed sufficient organic P that was relatively mobile. Conclusion The reliance on facilitation of P acquisition in A cygnorum depended strongly on location. We demonstrated the exudation of phosphatases, which mobilise inorganic P; this P was adequate for growth when there was sufficient organic P in soil. Facilitation of P acquisition by B. attenuata allowed A. cygnorum to extend its range into severely P-impoverished habitats where it cannot exist without facilitation. This knowledge provides a better understanding of the diversity of P-acquisition strategies in severely P-impoverished environments.

Removing Mn, Cu and Fe from Real Wastewaters with Macrophytes: Reviewing the Relationship between Environmental Factors and Plants' Uptake Capacity.

Heavy metal pollution creates environmental health concerns. Among these, iron (Fe), copper (Cu) and manganese (Mn) are commonly found in aquatic environments due to the release of wastewaters. Phytoremediation in hydroponics uses macrophytes to treat contaminated environments, and this is influenced by environmental factors. However, the relationship between these factors and the removal of Fe, Cu and Mn by macrophytes is not known. Therefore, a meta-analysis serves to determine the correlations between environmental factors and the removal of these metals in real wastewater by macrophytes, as well as to identify the role of different aquatic forms of macrophytes in phytoremediation. Emergent macrophytes had higher concentrations of manganese in their tissues, and higher bioconcentrations factor of iron and manganese than floating plants. Regardless of the biotope, higher concentrations of Fe and Cu decreased the ability of plants to bioconcentrate them. The correlations among exposure time, pH, dissolved oxygen, nitrogen, phosphorus, photoperiod and metal phytoremediation by plants were also found. It can be concluded that the emergent macrophytes showed better performance in terms of the removal of Fe, Cu and Mn, and that the significant correlations between environmental factors and removal vary with the type of metal and the environmental factor analyzed.

Erosion Resistance of Cast Steel and Spheroidal Graphite Cast Iron with a High-Manganese Content in Molten Aluminum Alloys

Erosion Resistance of Cast Steel and Spheroidal Graphite Cast Iron with a High-Manganese Content in Molten Aluminum Alloys

ВЛИЯНИЕ РЕЖИМОВ СИНТЕЗА НА ЭЛЕКТРОХИМИЧЕСКИЕ ХАРАКТЕРИСТИКИ КОМПОЗИТОВ НА ОСНОВЕ МНОГОСТЕННЫХ УГЛЕРОДНЫХ НАНОТРУБОК И ОКСИДА МАРГАНЦА, ЛЕГИРОВАННОГО ОКСИДОМ СЕРЕБРА

In this work, promising electrode materials for asymmetric supercapacitors based on multiwalled carbon nanotubes and manganese oxide doped with silver oxide were obtained and studied. To form the composites, the method of exposure of carbon material in an aqueous solution of potassium permanganate with the addition of silver nitrate in various quantities was used. It has been established that an increase in the amount of silver nitrate during the formation of the composite leads to an increase in the mass loading of the composite with both silver oxide and manganese oxide, which provides higher electrochemical characteristics of the material. The maximum specific capacity of the composite with a high content of manganese and silver was about 146 and 65 F/g at discharge current densities of 0.1 and 1.0 A/g, respectively. The high capacitive characteristics of the composite are ensured by a combination of the electrochemical activity of manganese oxide and the low electrical resistance of silver oxide.

An investigation of the seasonal relationships between meteorological factors, water quality, and sporadic cases of Legionnaires' disease in Washington, DC.

Since the discovery of Legionnaires' disease (LD), limited progress has been made in understanding the epidemiology of sporadic cases of LD. Outbreaks have confirmed that air conditioning and potable water systems can be sources of community-acquired LD. However, studying the association between water quality and LD incidence has been challenging due to the heterogeneity of water systems across large geographic areas. Furthermore, although seasonal trends in incidence have been linked to increased rainfall and temperatures, the large geographic units have posed similar difficulties. To address this issue, a retrospective ecological study was conducted in Washington, DC, from 2001 to 2019. The study identified aseasonal pattern of LD incidence, with the majority of cases occurring between June and December, peaking in August, October, and November. Increased temperature was found to be associated with LD incidence. In surface water, higher concentrations of manganese, iron, and strontium were positively associated with LD, while aluminum and orthophosphate showed a negative association. Intreatment plant water, higher concentrations of total organic carbon, aluminum, barium, and chlorine were positively associated with LD, while strontium, zinc, and orthophosphate showed a negative association. The results for orthophosphates and turbidity were inconclusive, indicating the need for further research.

Manganese Constituent in Stainless Steels Oxidized in Oxygen Containing Water Vapor at 800 °C: High Temperature Oxidation and Volatilization

Many industrial operations, such as solid oxide fuel cells (SOFCs) or combustion processes, have water vapor environments. Stainless steel was applied as part of these applications at high temperatures. The present work investigates high and low manganese content stainless steel that oxidized in an oxygen-containing 5% water vapor at 800 °C. SEM and EDX were performed to analyze oxide formation and ICP-OES was used to detect the volatile species that evaporated from steel surfaces. The results show that manganese in steel increases spallation and reduces Cr volatilization rates in high Mn stainless steel. The average Cr volatilization of high Mn samples is 0.09 × 10-11 g cm-2 s-1, which is about 14 times lower than the ones (1.25 × 10-11 g cm-2 s-1), while Fe and Mn volatilization rates increase by 10 and 62 times, respectively.

Biomass partitioning and ionomics of Macadamia with high manganese and low phosphorus concentrations.

Knowledge of the ionome of plant organs helps us understand a plant's nutritional status. However, the ionome of Macadamia (Proteaceae), which is an important nut-producing tree, remains unknown. We aimed to characterise the allocation of biomass and nutrient-partitioning patterns in three macadamia genotypes. We excavated 15 productive trees (three cultivars at 21years of age; two cultivars at 16years of age) in an orchard. Biomass, nutrient concentrations, and contents of roots, stems, branches, and leaves were analysed. Dry weight of roots, stems, branches and leaves accounted for 14-20%, 19-30%, 36-52%, and 12-18% of total plant weight, respectively. No significant difference was found in the total biomass among the cultivars at the same age. Compared with most crop plants, macadamia had low phosphorus (P) concentrations in all organs (<1gkg-1 ), and low leaf zinc (Zn) concentration (8mgkg-1 ). In contrast, macadamia accumulated large amounts of manganese (Mn), with a 20-fold higher leaf Mn concentration than what is considered sufficient for crop plants. Leaves exhibited the highest nutrient concentrations, except for iron and Zn, which exhibited the highest concentrations in roots. The organ-specific ionomics of Macadamia is characterised by low P and high Mn concentrations, associated with adaptation to P-impoverished habitats.

Analysis of defects and non-metallic inclusions distribution in high-strength TWIP steel Fe-25Mn-12Al-1.5C after electroslag remelting

TWIP steels belong to the list of the most innovative materials of our time due to the combination of a high mechanical characteristics level and low density. The most high-strength alloys usually contain about 25-30 wt. % manganese and about 10 wt. % aluminum. Production of such steels is complicated by the peculiarities of their chemical composition. Due to the high content of manganese and aluminum, they are prone to components liquation by density, have a greater number of shrinkage defects and an increased number of sulfides, nitrides and oxides non-metallic impurities. This determines the use of effective refining methods, which include electroslag remelting (ESR). The paper shows a comparison of Fe-25Mn-12Al-1.5C alloy structure, type and amount of non-metallic inclusions after induction melting and after refining electroslag remelting. Electron microscopy of the samples and local chemical analysis of the phases showed a large number of non-metallic inclusions — sulfides, phosphides, and oxynitrides. After refining process, it was shown that electroslag remelting contributes to a noticeable decrease of nitrogen and sulfur content, and as the result — it lowers the number of related of non-metallic inclusions. However, it seems to be an insufficiently effective method of refining materials like TWIP-steels. Relatively large size of the non-metallic inclusions, low phosphides refining ability and the crystallization conditions under which a directionally crystallized structure forms, may be noticed among the disadvantages of the ESR method. It was also established that in crystallizer zones, close to the bottom and walls, metal refines worse than its central volumes. Upper part of the ingot has shrinkage and sub-shrinkage zones enriched with gas-shrinkage defects, so it can be called a problem zone. In general, it is shown that the ESR method is not capable to solve a problem of refining high-manganese TWIP steels with a high aluminum content to the required extent.

Изучение марганецокисляющих микроорганизмов, выделенных из микробоценозов высокомагнитных почв

From the stand point of the possible use of microorganisms in water purification biotechnologies, studying microorganisms capable of removing dangerous pollutants such as heavy metals from the aquatic environment is of great importance. Microbial screening was conducted on isolates from microbiocenoses of highly magnetic soils of the city Mednogorsk (Orenburg region, Russia), to assess their resistance to manganese (II) ions. The objects of this research were nine strains of manganese-oxidizing microorganisms and two strains of iron-oxidizing microorganisms: Bacillus megaterium 69.3 and B. megaterium 69.5. It was observed that, most of the studied microorganisms were characterized by increased resistance to manganese (II) ions when grown on an agar medium. Maximum resistance to Mn (II) was observed in microbial strains: 55.2 and B. megaterium 69.5. The maximum tolerant concentration (MTC) of Mn (II) for these microorganisms was 300 and 350 mmol/L; the minimum inhibitory concentration (MIC) was 350 and 450 mmol/L, respectively. When studying the growth of the two microbial strains: 55.2 and B. megaterium 69.5 in liquid media for 5 days. It was discovered that, when cultured in a selective medium, microbial resistance of the strains to Mn (II) was higher compared to when cultured in a nutrient LB medium. The results showed high resistance of microorganisms to a range of Mn (II) concentrations: from 0,5 to 250 mmol/L in a liquid medium. Maximum growth of the studied microbial strains was observed at Mn (II) concentration of 10 mmol/L. These microbial strains with high resistance to Mn (II) open up the prospect of their practical use for biotechnological purposes involving the purification of drinking and wastewater from high manganese content.

WATER QUALITY OF SMALL RIVERS IN THE PRIPYAT BASIN: ENVIRONMENTAL AND FISHERY ASSESSMENT

The study of anthropogenic causes of the deterioration of the state of small rivers is the first step towards their conservation and restoration, improving the human environment as a whole. The aim of the study is the fishery and environmental assessment of water quality of small rivers in the Pripyat River basin (the area of right-bank tributaries in the middle part of the river) within the Rivne region in the northern-west region of Ukraine. The initial data for the assessment have been the results of monitoring (27 physical and chemical indicators) during 2010–2018. The assessment by the integral ecological index (Ie) has shown that the rivers belonged to the II quality class in terms of average values and were characterized as “clean” and “clean enough”. According to the worst values, the rivers belonged to the II-III quality classes and were characterized as “fairly clean” – “slightly polluted” – “moderately polluted”. The best water quality by the Ie index was established for the Zhabichi River within the urban-type settlement of Demydivka. Water quality of the Ustia River below the runoff of the cities of Rivne and Zdolbuniv has corresponded to IV-V classes i.e. was "dirty" and "very dirty" (high content of phosphates, nitrogen compounds, copper, manganese, and zinc). In terms of trophic state, the water of the rivers is mesotrophic (according to average values) and eutrophic (according to the worst values), except for the part of the Ustia River below the runoff of the city of Rivne, where the water is polytrophic. The rivers have failed to meet water quality standards for fishery water use by COD, BOD5, and heavy metals content (Cu, Mn, Fe, Zn).

The Microstructure and Tensile Properties of New High-Manganese Low-Activation Austenitic Steel

Using X-ray diffraction, scanning and transmission electron microscopy, the microstructure of a new low-activation chromium-manganese austenitic steel with a high content of manganese and strong carbide-forming elements is studied. Its structure, dislocation character and particle composition are detailed. The processes taking place in the steel under cold-rolling deformation are described. It is shown that the mechanical properties of the new high-manganese steel revealed by testing at 20 and 650 °C are comparable with those of well-known analogs or exceed them. Relying on the structural studies, this is attributed to the dispersion and substructural strengthening. Better plastic properties of the steel are associated with the twinning-induced plasticity effect. It is shown that the steel fracture after tension at the test temperatures is mainly ductile dimple transcrystalline with the elements of ductile intercrystalline fracture (at 20 °C), while at 650 °C the signs of the latter disappear. The low-activation chromium-manganese austenitic steels characterized by increased austenite stability are thought to be promising structural materials for nuclear power engineering.

Proximate composition and characterization of the vitamins and minerals of dandelion (Taraxacum officinale) from the Middle Doce River region – Minas Gerais, Brazil

This study aimed to determine the chemical composition and the vitamin, carotenoid, and mineral profile in dandelion (Taraxacum officinale) collected from the Middle Doce River region (Médio Rio Doce) in the state of Minas Gerais, Brazil. To accomplish this, the physicochemical parameters, such as titratable acidity, pH, and soluble solids were determined, in addition to the evaluation of the plants’ proximate composition (moisture, ash, proteins, dietary fibers, and lipids). The vitamin E, carotenoids and vitamin C were determined by HPLC and the minerals were analysed by inductively coupled plasma atomic emission spectrometry. The T. officinale samples presented a low content of macronutrients, a total energy value of 27.88 kcal.100 g−1 FW, a high fiber content (3.7 g.100 g−1 FW), low levels of total vitamin E (43.67 μg.100 g−1 FW), total carotenoids of 11.95 g.100 g−1 FW, and did not present vitamin C in detectable levels. The mineral analysis revealed a high concentration of iron, manganese, copper, zinc, and selenium, and small amounts or traces of aluminium, cadmium, nickel, and chromium. In conclusion, T. officinale was shown to be an important source of nutrients, especially fiber, iron and manganese.

Catalytic Behavior of Ag-Mn Catalyst for Efficient Toluene Removal at Low Temperature: Effect of Redox Property

Ag-Mn bimetallic catalysts were prepared by liquid-phase redox method and discussed their synergistic effect on the catalytic oxidation of toluene. The activity order of the catalysts was: Ag-Mn > Mn > Ag-Mn-R > Mn-R. The addition of Ag caused some K+ to be substituted over Ag-Mn, which resulted in the collapse of the structure, and led to more lattice defects and increased the active species. Furthermore, the Ag-Mn catalyst contained a large amount of Mn4+ and Olatt species, the best low-temperature reducibility and the lowest oxygen desorption temperature. After the reduction treatment, the high-valent manganese ions decreased, and the lattice oxygen concentration was greatly reduced. Besides, the high concentration of high valence manganese, easily released lattice oxygen and oxidized silver of Ag-Mn could contribute to the superior catalytic performance. The mechanism followed by toluene → benzoate → benzoquinone → manganese carbonate → CO2 + H2O.

The Heat Treatment of Pink Zoisite

Natural pink zoisites owe their color to a high concentration of manganese paired with low concentrations of other coloring elements such as vanadium or titanium. Upon conventional heating, such stones typically suffer from the reduction of Mn3+ to the colorless Mn2+ species alongside the destruction of the brownish yellow color that is related to titanium. We have processed manganese containing zoisites under the high pressure of pure oxygen which allowed the manganese to remain oxidized, while the brownish yellow color component was still successfully removed. Depending on the vanadium level, the treated gems show a pink to purplish pink color. Detection of this treatment is not easy as the temperature is too low to result in a change in internal features, but a combination of UV-Vis-NIR spectroscopy and trace element chemistry provided by LA-ICP-MS give evidence of such treatment.

Secondary Metabolites and Mineral Elements of Manotes expansa and Aframomum alboviolaceum Leaves Collected in the Democratic Republic of Congo

Background and Aims: Manotes expansa Sol. ex Planch. and Aframomum alboviolaceum (Ridl.) Schum. are two plants belonging respectively to the family Connaraceae R.Br. and Zingiberaceae Martino widely used in traditional medicine for the treatment of eye diseases, fever, headaches, gastritis as well as asthma. The aim of the present study is the valorization of these two plants collected in the Democratic Republic of Congo by a quantitative and qualitative analysis of secondary metabolites and mineral elements in their leaves.&#x0D; Materials and Methods: The determination of secondary metabolites in the leaves of Manotes expansa and Aframomum alboviolaceum was carried out by UV-Visible spectrophotometry and X-ray fluorescence spectrophotometry for the identification and quantitative analysis of mineral elements.&#x0D; Results: The results showed that the leaves of these two plants are rich in phenolic compounds, i.e. 442.2 mgEqAG/g for the leaves of A. alboviolaceum, 370.64 mgEqAG/g for the red leaves and 282.64 mgEqAG/g green leaves of M. expansa. Although being part of the same plant, the red and green leaves of M. expansa presented a totally different phytochemical profile. The contents of condensed tannins, anthocyanins and flavonoids are respectively 0.3%, 0.68% and 3.29% for the leaves of A. alboviolaceum; 0.58%, 0.36% and 6.89% for the red leaves, and 0.65%, 0.26% and 7.55% for the green leaves of M. expansa. The mineral content in the leaves of both plants remains dominated by the high concentration of potassium (K), calcium (Ca), Magnesium (Mg), Manganese (Mn) and Iron (Fe).&#x0D; Conclusion: The high content of phenolic compounds and essential trace elements makes the leaves of M. expansa and A. alboviolaceum potential candidates to alleviate several health problems in Africa in general and particularly in the Democratic Republic of Congo.

Secondary Structures on the Friction Surface of Diamond-like Coating

Peculiarities of the formation of secondary structures on the surface of a diamond-like coating are studied on the example of a friction contact between a steel ball and a diamond-like coating. The friction surface was examined in various areas; the zone of wear products (the boundary of the friction track) and the original surface outside the friction area. It is shown that secondary structures with a high content of iron, nickel, manganese, chromium, and oxygen are characteristic of areas with the highest wear resistance. Such secondary structures are formed because of the intense interaction of the diamond-like coating with the steel of the ball during dry friction.

Congolese edible caterpillars, valuable sources of bioactive compounds with human health benefits

Insects are part of the regular diet of more than two billion people around the world and are not only delicacies. Insects provide great opportunities to replace meals but can have important additional benefits as well. In the Democratic Republic of the Congo (DRC), caterpillars are the most consumed insects, and they are consumed by more than 70% of the population throughout the year. The aim of this research was to report the microscopic features, mineral micronutrients, chromatographic fingerprints, antioxidant activities and peroxidase inhibition of edible Congolese caterpillars of the genusCinabra, Imbrasia andGonimbrasia from DRC. Microscopic analysis showed the presence of characteristic features, specific to each host plant of caterpillars, such as palisade cells, stomata, trichomes, sclereids, fibres, vessels, pollen and starch grains. Phytochemical screening by chromatographic techniques revealed the presence of phenolic acids, flavonoids and terpenes as major secondary metabolites. Elemental analysis on dry matter showed that studied caterpillars are insects containing significant amounts of micronutrients such as copper, magnesium, manganese, selenium and zinc.Gonimbrasia belina had the highest selenium, magnesium and zinc content (0.12 g/100 g, 0.17 g/100 g and 0.011 g/100 g, respectively) thanCirina forda, Cinabra hyperbius, Imbrasia truncata andImbrasia sp., C. forda andImbrasia sp. had the highest copper content (0.003 g/100 g).C. forda had the highest manganese content (0.006 g/100 g). All aqueous extracts displayed high radical-scavenging activities with IC50 values ranging from 10 to 80 μg/ml. Extracts showed the best cellular antioxidant activities on reactive oxygen species-induced chemiluminescence using L012 on human leucocytes 60 monocytes related to their IC50 values less than 0.5 μg/ml. In specific immuno-extraction followed by enzymatic detection of myeloperoxidase assay, all extracts of caterpillars exhibited a dose-dependent inhibitory effect on myeloperoxidase activity in the range concentrations of 1 to 20 μg/ml excepted extracts ofImbrasia epimethea,Imbrasia sp. andI. truncata. Our results showed that insects are not only valuable source of lipids, proteins and micronutrients such as selenium but also are sources of phytochemicals with therapeutic benefits.