High Environmental Footprint Research Articles

Transforming meat waste into sustainable corneal keratoplasty models.

With a rapidly global population, there is a critical need to enhance food production and waste management. This necessity is driving opportunities for sustainable integrated food chains committed to biovalorization and circular bioeconomic practices. One approach that aligns with this vision relies on sustainable tissue engineering, which offers opportunities to leverage food systems in the search for natural biomaterials from agricultural waste. In this perspective, we propose utilizing common meat waste sources, often associated with a high environmental footprint, to develop tissue graft models. These models reduce agricultural waste, decrease the reliance on animal testing, and support both biovalorization and medical innovation. Specifically, we explore a unique approach to generate corneal transplantation models completely from discarded components of the meat food chain, using the eyes and bladders. This strategy involves creating keratoplasty models by reseeding the decellularized extracellular matrix (dECM), encompassing three major corneal regions: the epithelium, stroma, and endothelium. Interestingly, these scaffolds can be recellularized with cellular lineages derived from stem niches harvested from urine. This approach integrates waste management with regenerative medicine, fostering sustainable advancements in tissue engineering.

A scalability-centric perspective on global human development within environmental limits

The Human Development Index (HDI) positions Global North countries as development benchmarks, overlooking their high environmental footprints. This perspective poses a dilemma: global adoption of Northern lifestyles risks surpassing planetary biophysical limits, while non-adoption risks perpetuating developmental inequality. The Planetary Pressures adjusted-HDI (PHDI) from the United Nations Development Program (UNDP)’s 2020 Report aimed to incorporate environmental pressures into the assessment of human development. However, countries ranking highest on the PHDI also exhibit considerable environmental footprints, limiting the PHDI’s utility as a sustainability metric. Our study introduces a revised metric emphasizing “scalability” as a pivotal facet of sustainability. Scalability, in our context, refers to the theoretical possibility of scaling a country’s historical developmental trajectory to the entire global population without exceeding planetary biophysical limits rendered in absolute terms. This emphasis on historicity and absolute environmental performance distinguishes our approach from the PHDI. Our results highlight Panama, Costa Rica, Sri Lanka, Peru, and Albania as having achieved high social progress with low environmental costs or high levels of scalable development. This signals that substantial social progress can be achieved globally without overstepping biophysical limits. Nonetheless, simple projections indicate that the environmental footprints of these countries may scale unsustainably in the future if current trends persist. This study underscores the continued need to prioritize scalability in the future and recommends shifting the narrative to countries that exemplify scalable development to provide strategic insights to the Global South.

The energy transition paradox: How lithium extraction puts pressure on environment, society, and politics

Lithium-ion batteries are essential for Europe's renewable energy transition. By 2030, the EU will need 18 times more lithium, and by 2050, 60 times more. For that reason, Europe aims to increase domestic sourcing and achieve nearly full self-sufficiency by 2030. However, lithium mining has a high environmental footprint and can have severe social impacts. This research examines the socio-environmental implications of lithium mining for the EU energy transition and identifies leverage points that alleviate tension between justice and security. The Social, Technological, Economic, Environmental, and Political framework was used to systematically gather insights from experts representing various stakeholders on these issues. Subsequently, these insights were compiled into a fuzzy-cognitive map, creating a system-based overview and allow construction and comparison of four scenarios examining the future of lithium and its impacts on the environment and local communities in Europe. This reveals the importance of good governance to avoid issues of corruption and geopolitical tensions with a potential adverse impact on society and environment. However, governance alone is insufficient to mitigate negative impacts. A circular economy, where lithium is recovered from used batteries, is most favorable, reducing the demand for new material and the negative impacts of mining. This holistic overview stresses the need for increased government involvement, stakeholder alignment, and dealing with corruption as vital aspects in mitigating the negative socio-environmental impacts of lithium mining.

A sustainable deposition method for diamond-like nanocomposite coatings – Insights into the evolution of atomic structure and properties

A sustainable deposition method for diamond-like nanocomposite coatings – Insights into the evolution of atomic structure and properties

Macrosynthetic fibers as replacement of conventional steel reinforcement for concrete of partition walls

AbstractConventional reinforced concrete for building partition walls has proven numerous advantages (in terms for instance of acoustic performance and robustness) with respect to other existing alternatives. However, its use leads to high material consumption and environmental footprint together with time‐consuming processes for placing steel reinforcement. To reduce time‐consuming processes and carbon footprint, the replacement of ordinary steel reinforcement by structural macrofibers is envisioned as a suitable solution due to: (1) the acceptance of fiber reinforced concrete (FRC) for structural applications in various guidelines (as Annex L of FprEN 1992‐1‐1:2023, draft for future Eurocode 2) and (2) the fact that the amounts of fibers necessary to reach the required mechanical performance of the FRC for crack control are expected to be economically competitive. Additionally, within the spectra of types of macrofibers capable of efficiently reinforce concrete, macrosynthetic fibers (MSFs) were considered in this research due to their benefits in terms of durability performance and reduced environmental impact (potential to use cements with lower clinker content and reduced thickness of elements). Aiming at confirming both the constructability, casting procedure and structural performance of macrosynthetic fiber reinforced concrete (MSFRC) partition walls, these walls were constructed in a real building in Switzerland. In this article, the design process is presented as well as the associated MSFRC material and structural experimental programmes, conducted both in laboratory and on‐site. In addition, several FEM‐modeling considerations as well as quality control and construction aspects observed during the implementation process are raised. Finally, for reference purposes, a first approach to the economic and environmental impact (CO2eq‐based) of such MSFRC walls is presented.

Comparative assessment of methane emissions from the manure of Mexican Creole Hairless Pigs and Commercial Pigs fed the same diet

AbstractPig production contributes significantly to the high environmental footprint of the livestock sector. Therefore, in this framework, a transition toward more sustainable production is essential. Local natural livestock resources, such as Mexican Creole Hairless Pigs, provide a good opportunity to achieve sustainable pig production. In the present study, a first approximation to compare the carbon emissions of Mexican Creole Hairless Pig manure from Commercial Pig manure is presented. Under the same feeding and housing conditions, the specific methane emissions of both Mexican Creole Hairless Pigs and Commercial Pigs manure were determined experimentally at room temperature. In addition, specific methane production kinetics was modeled using the Gompertz equation to estimate the specific methane production rate. The methane emission factors for Mexican Creole Hairless Pig manure (0.33 ± 0.02 kg[CO2‐eq]/LU per day) were half those of Commercial Pig manure (0.7 ± 0.04 kg[CO2‐eq]/LU per day), and biochemical manure analysis suggested that Mexican Creole Hairless Pigs had better digestibility of the diet. In general, due to physiological factors such as food intake rate and gut microbiota development, which could influence the fat and fiber digestibility of Creole genotypes, pig genotype should be included as an additional factor to estimate greenhouse gas emissions from pig manure. The production of Mexican Creole Hairless Pigs in an extensive local system is therefore an attractive option for developing new sustainable markets.

Wheat flour-derived amyloid fibrils for efficient removal of organic dyes from contaminated water

Amyloid fibrils derived from different proteins have been proved as a promising material for adsorption of various pollutants from wastewater, which showed advantages of low cost and eco-friendliness. However, most of the amyloid fibrils derived from animal-based proteins with high environmental footprint, while more sustainable amyloid fibrils derived from plant materials are desirable. In this study, a plant-derived amyloid fibril was extracted from the commonly used wheat flour with a simple and scalable protein purification and fibrillization process. Interestingly, the amyloid fibrils showed good adsorption capacity towards typical organic dyes (Eosin Y (EY) and Congo red (CR)) from contaminated water. Adsorption kinetic analysis indicated the adsorption process to EY or CR by wheat flour amyloid well fitted with a pseudo-second-order model. The adsorption also followed a Langmuir isothermal model with adsorption capacities of 333 mg/g and 138 mg/g towards CR and EY, respectively. This work demonstrated the feasibility to utilize the plant-based amyloid fibril for organic dyes removal from contaminated water, which provided an affordable, sustainable and scalable tool for organic dyes removal from wastewater.Graphical

Assessing human and environmental health in global diets from a perspective of economic growth

Assessing human and environmental health in global diets from a perspective of economic growth

Atmospheric leaching of Ni, Co, Cu, and Zn from sulfide tailings using various oxidants

The growing demand for nickel and cobalt increases the interest in extracting metals from secondary sources, such as flotation tailings. A preferential strategy for the processing of the complex and/or low-grade secondary sources may be material integration into existing primary processes. In this research, a robust sulfuric acid leaching treatment was studied for metal extraction from sulfidic flotation tailings (Ni 0.45 %, Co 0.80 %, Cu 0.20 %, Zn 0.58 %). The impact of leaching parameters on metals extraction was studied; oxygen gas (1–2 L/min), ferric ions (0.05–0.3 M), and hydrogen peroxide (0.5–0.8 M), temperature (30–90 °C), sulfuric acid concentration (0.2–2 M), and solid–liquid ratio (50–100 g/L). It was found that after 30-minutes 20.0 % of nickel, 5.6 % of cobalt, and 33.0 % of the main impurity iron were extracted using oxygen as oxidant. Increasing temperature and sulfuric acid concentration were shown to have a positive effect on extraction. Also, with the further addition of ferric ions, cobalt extraction could be slightly increased (from 6.2 % to 8.3 %) whereas both nickel and cobalt could be increased with hydrogen peroxide (nickel 22.9 %, cobalt 14.2 %). However, the use of H2O2 can be challenging due to its high environmental footprint as well as partial decomposition by ferric ions, increasing H2O2 consumption further. The results suggest that the mineralogy of the investigated tailings limited feasible metals extraction using atmospheric conditions up to ≈ 20 % for nickel and ≈ 10 % for cobalt, with nickel distributing stronger into non-refractory minerals while cobalt reported more to pyrite. For other base metals, zinc extraction from sphalerite was shown to be efficient (up to ≈ 90 %) whereas copper extraction was limited (up to ≈ 30 %). In future, such atmospheric sulfuric acid leaching may provide a robust recovery route for non-refractory minerals present in the tailings, while full valorization of sulfide tailings matrix will require higher intensity processing with technologies such as pressure oxidation (POX), concentrated chloride leaching, bioleaching, roasting-leaching or very fine milling of the raw material prior to atmospheric leaching.

Porous carbon-nanostructured electrocatalysts for zinc-air batteries: from materials design to applications.

Zinc-air batteries (ZABs) are pivotal in the evolution of sustainable energy storage solutions, distinguished by their high energy density and minimal environmental footprint. The oxygen electrode, which relies on sophisticated porous carbon materials, is critical to operational efficiency. This review scrutinizes oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) processes in ZABs through advanced porous carbon applications. It delves into innovative synthesis techniques such as templating, chemical vapor deposition, and self-assembly that tailor pore structures for peak performance. The interactions between catalytic sites and carbon nanostructures, which significantly boost electrochemical performance, are highlighted. The manuscript discusses future strategies for overcoming current challenges by advancing catalytic efficiency and electrode design, emphasizing the integration of nano-engineering and materials science to foster ZABs with superior energy capacity and adaptability. Additionally, the review projects how ongoing research into carbon material properties could unlock new applications in other energy systems, potentially broadening the scope of ZAB technology. This paper integrates recent advancements in porous carbon materials, offering pivotal insights for next-generation high-performance ZAB development.

Optimization of Ball Milling Parameters for Efficient Copper Slag Valorization

Optimization of Ball Milling Parameters for Efficient Copper Slag Valorization

Upcycling glass wool and spodumene tailings in building ceramics from kaolinitic and illitic clay

With concerns related to the high cost and environmental footprint of energy, reducing the sintering temperature in the ceramic industry remains a key challenge. This study investigates the effect of glass wool waste on the sintering properties of kaolinitic and illitic clays, two types of clay commonly used in the ceramic industry. Both clays were substituted with 20 and 40 wt% glass wool, and the effect on sintering at 850, 950, and 1050 °C was investigated. The properties of the sintered materials were assessed with several techniques, including X-ray diffraction, scanning electron microscopy, bulk density, water absorption, dilatometry, and compressive and flexural strength. The water absorption of the prepared ceramics varied from 0 to 30 %, while compressive and flexural strength were in the ranges of 10–60 MPa and 2–15 MPa, respectively, depending on the glass wool content and sintering temperature. The addition of glass wool induced more glass formation, microstructure densification, and higher firing shrinkage at lower temperatures, which contributed to an increase of more than 100 % strength at 850 °C. The addition of 10–20 parts spodumene tailings was observed to mitigate the firing shrinkage at 950 °C with no significant effect on the mechanical properties.

Evaluation of Wastewater Coagulation/Flocculation with Chitosan from Shrimp Exoskeletons Waste and Aluminum Sulfate

Intensive use of water, growing cities, and lack of wastewater treatment are some factors increasing hydric stress worldwide. Coagulation/flocculation is one of the preferred treatments for wastewater. However, aluminum salts are traditionally used in this process. This coagulant has a high environmental footprint and residual aluminum in wastewater is a public health concern. The preparation and use of chitosan as a coagulant aid in coagulation/flocculation with aluminum sulfate were investigated. The ef fect of the order of addition of coagulants (aluminum sulfate followed by chitosan, or chitosan followed by aluminum sulfate), dose of the coagulants, pH, and slow mixing velocity for flocculation were studied. It was found that the removal of total suspended solids (TSS) with aluminum sulfate was relatively unaf fected by pH (aluminum sulfate dose of 100 mg L-1 at pH of 5 units achieved 94% removal of TSS and at pH of 8.2 units 89% removal of TSS), whereas with chitosan was highly af fected (chitosan dose of 180 mg L-1 at pH of 4 units achieved 96% removal of TSS and at pH of 8.2 units 25% removal of TSS). In the coagulation/flocculation experiments where both coagulants were used, it was found that the order of coagulant addition and pH of wastewater have a statistically significant ef fect (P-value < 0.05) on the removal of TSS. Higher removal of TSS was achieved when aluminum sulfate was added followed by chitosan at a wastewater pH of 5 units. Chitosan can be ef fectively used to reduce the use of aluminum salts in wastewater treatment. However, it is necessary to optimize the preparation of this coagulant and investigate other factors, such as variation in the wastewater quality, that can af fect the robustness of the process.

Battery metal recycling by flash Joule heating.

The staggering accumulation of end-of-life lithium-ion batteries (LIBs) and the growing scarcity of battery metal sources have triggered an urgent call for an effective recycling strategy. However, it is challenging to reclaim these metals with both high efficiency and low environmental footprint. We use here a pulsed dc flash Joule heating (FJH) strategy that heats the black mass, the combined anode and cathode, to >2100 kelvin within seconds, leading to ~1000-fold increase in subsequent leaching kinetics. There are high recovery yields of all the battery metals, regardless of their chemistries, using even diluted acids like 0.01 M HCl, thereby lessening the secondary waste stream. The ultrafast high temperature achieves thermal decomposition of the passivated solid electrolyte interphase and valence state reduction of the hard-to-dissolve metal compounds while mitigating diffusional loss of volatile metals. Life cycle analysis versus present recycling methods shows that FJH significantly reduces the environmental footprint of spent LIB processing while turning it into an economically attractive process.

Rationale for alternative water sources for mining regions with high environmental footprint on the example of Levikha village of the Sverdlovsk region

Introduction. Mine drainage has always been one of the main threats to the hydrosphere of mining areas, both during and after active mining. The most common method of mine water neutralization is associated with the slaked lime. On the abandoned Levikha copper-sulphide mine territory (Sverdlovsk region), acid mine drainage discharge reaches 3,000 m³/day. To neutralize acid waters, more than 400 m³/day of water with a neutral pH is required (to produce the slaked lime). Due to the worn out state of water pipe from the river Tagil, heavy losses, and frequent accidents, the neutralization station receives no more than half of the required amount of water. As a result, the neutralization technology is violated, acid mine drainage is not properly cleaned, the regulatory requirements for wastewater are not achieved, and sulfate waters with increased mineralization and metal concentrations are discharged into the river Tagil. Research objective is to substantiate the possibility of finding sources of drinking, household and process water supply for Levikha village and acid mine drainage neutralization stations by applying groundwater. Methods of research include a comprehensive approach containing research results analysis and field and laboratory research data processing. Results and discussion. Promising areas have been identified representing private catchment areas of potential water intakes with the most favorable conditions for underground runoff. A combination of the following factors was the criterion for promising areas and load points: favorable geological and tectonic conditions (the presence of tectonic faults); groundwater inflow testing results (relatively high specific flow rates of wells); geomorphological position (confinement to low relief areas, location near surface sources of groundwater recharge); hydrochemical sampling data (satisfactory chemical composition of groundwater); sanitary and hygienic situation (absence of potential sources of pollution in the local catchment area). Conclusions. The total resources of the five promising sites are 1,340 m3 /day, including 282 m3 /day for drinking purposes. Exploration and development of promising areas no. II (favorable geological and tectonic conditions within it are confirmed by the groundwater inflow testing results) and no. III (favorable sanitary and hygienic conditions) seem to be the most reasonable. These sites might cover half of the village water needs for drinking and household purposes.

Alternative Fuels Substitution in Cement Industries for Improved Energy Efficiency and Sustainability

The conventional energy source in cement industries is fossil fuels, mainly coal, which has a high environmental footprint. On average, energy expenditures account for 40% of the overall production costs per ton of cement. Reducing both the environmental impact and economic expenditure involves incorporating alternative energy sources (fuels) such as biomass, solid-derived fuel (SDF), refuse-derived fuel (RDF) etc. However, within cement plants, the substitution of conventional fossil fuels with alternative fuels poses several challenges due to the difficulty in incorporating additional fuel-saving techniques. Typically, an additional 3000 MJ of electricity per ton of clinker is required. One of the most effective solutions to this is thermal optimization through co-processing and pre-processing, which makes it possible to implement additional fossil-fuel-saving techniques. In developing nations such as Togo, waste-management systems rely on co-processing in cement factories through a waste-to-energy relationship. Also, there are some old cement plants with low-efficiency, multi-stage preheaters without pre-calciners, reciprocating huge coolers, low-efficiency motors etc., which still operate and need to be made environmentally sustainable. However, compared to modern kilns which can have up to 95% of energy recovery from waste, an old suspension preheater kiln can recover only up to 60% of its heat energy depending on the cooler type, and due to the lack of a bypass and combustion chamber (pre-calciner). This research paper evaluated the performance of a cement plant incorporating AF and presents the procedures and recommendations to optimize AF substitution in cement plants. To achieve this, a comparative performance study was carried out by assessing the alternative fuel characteristics and the equipment performance before and after the incorporation of the alternative fuel. Data were collected on the optimum substitution ratio, pre-processing and co-processing performance, raw-meal design and economic analysis. Results indicated that the cost to be covered per ton of waste input is €10.9 for solid-derived fuel (SDF), €15 for refuse-derived fuel (RDF), and that the co-processing cost optimization for the cement plant could have a cost saving of up to 7.81€/GJ. In conclusion, it is recommended that appropriate kiln and alternative-fuel models be created for forecasting production based on various AF.

Life Cycle Assessment of Coastal Enhanced Weathering for Carbon Dioxide Removal from Air.

Coastal enhanced weathering (CEW) is a carbon dioxide removal (CDR) approach whereby crushed silicate minerals are spread in coastal zones to be naturally weathered by waves and tidal currents, releasing alkalinity and removing atmospheric carbon dioxide (CO2). Olivine has been proposed as a candidate mineral due to its abundance and high CO2 uptake potential. A life cycle assessment (LCA) of silt-sized (10 μm) olivine revealed that CEW's life-cycle carbon emissions and total environmental footprint, i.e., carbon and environmental penalty, amount to around 51 kg CO2eq and 3.2 Ecopoint (Pt) units per tonne of captured atmospheric CO2, respectively, and these will be recaptured within a few months. Smaller particle sizes dissolve and uptake atmospheric CO2 even faster; however, their high carbon and environmental footprints (e.g., 223 kg CO2eq and 10.6 Pt tCO2-1, respectively, for 1 μm olivine), engineering challenges in comminution and transportation, and possible environmental stresses (e.g., airborne and/or silt pollution) might restrict their applicability. Alternatively, larger particle sizes exhibit lower footprints (e.g., 14.2 kg CO2eq tCO2-1 and 1.6 Pt tCO2-1, respectively, for 1000 μm olivine) and could be incorporated in coastal zone management schemes, thus possibly crediting CEW with avoided emissions. However, they dissolve much slower, requiring 5 and 37 years before the 1000 μm olivine becomes carbon and environmental net negative, respectively. The differences between the carbon and environmental penalties highlight the need for using multi-issue life cycle impact assessment methods rather than focusing on carbon balances alone. When CEW's full environmental profile was considered, it was identified that fossil fuel-dependent electricity for olivine comminution is the main environmental hotspot, followed by nickel releases, which may have a large impact on marine ecotoxicity. Results were also sensitive to transportation means and distance. Renewable energy and low-nickel olivine can minimize CEW's carbon and environmental profile.

The greening of IT use: the impact of environmental concerns on the use of internet systems

PurposeInternet use has a high environmental footprint that is often overlooked by end users. This paper contributes to limiting the negative environmental footprint of Information Technology (IT) use by understanding the relationship between environmental concerns and use of IT amongst users who are aware of the environmental footprint of IT use. Second, the paper argues that taking environmental concerns into account in technology acceptance studies is relevant, even in studies concerning ordinary IT (i.e. IT not commonly classified as “green” technology).Design/methodology/approachThe authors conduct two vignette-based surveys in two different countries: the USA and Belgium. Partial least squares structural equation modeling (PLS-SEM) is used to analyse the effect of environmental concerns on the intention to use the webcam during online meetings and binary logistic regression is used to analyse the relationship between environmental concerns and reported actual use of webcams.FindingsThe higher the respondents' environmental concerns, the higher their intention to use internet systems in a more environmentally responsible way, provided the respondents are aware of the environmental footprint of internet system use. Moreover, the higher the respondents’ environmental concerns, the more likely they are to use internet systems in a more environmentally responsible way.Originality/valueThis study is the first to distinguish “Greening of IT Use” from “Greening of IT” and “Greening by IT” and to show that environmental concerns has an impact on the way end users (intend to) use internet systems, provided the users are aware of the environmental footprint of that use.

Resource use efficiencies, environmental footprints and net ecosystem economic benefit of direct-seeded double-season rice in central China

Resource use efficiencies, environmental footprints and net ecosystem economic benefit of direct-seeded double-season rice in central China

High‐performance concrete with fine recycled concrete aggregate: Experimental assessment

AbstractHigh‐performance concrete (HPC) is a cement‐based material with excellent properties and durability which determines high‐level structural utilization. However, the necessity of high‐quality natural resources such as quartz powder and sand and a high amount of cement and silica fume and reinforcement by fibers causes a high environmental footprint and costs. One of the possible ways to reduce the environmental footprint and cost of the HPC/UHPC is to replace the powder or sand with secondary raw materials. In this study, the two types and three fractions of fine recycled concrete aggregate (fRCA) are used as supplementary materials in HPC. The reference mixture is based on the UHPC mixture without reinforcement to find out the influence of aggregate replacement. The properties of fresh and hardened concrete are examined. The results show a slight decline of mechanical properties however the autogenous shrinkage decrease with the replacement of natural aggregate by fRCA, which shows the possibilities of natural resources savings and thus leads to a lower environmental footprint of concrete structures as a contribution to the solution of sustainable development goals set by the United Nations in 2015 as an action plan up to 2030.