Laser Heating Research Articles

Localized Heating Assisted Laser Shock Peening without Coating Enhances Mechanical Properties of Ti6Al4V Alloys

Room-temperature laser shock peening without coating (RT-LSPwoC) is the mainstream method for surface strengthening, yet it induces tensile residual stress on the surface during rapid heating and cooling. Warm LSPwoC, combining the benefits of dynamic strain aging and LSPwoC, exhibits higher performance than RT-LSPwoC. However, overall high-temperature is time- and resource-consuming, and it is prone to causing thermal stress relaxation during processing, making it unsuitable for large-scale applications. In this paper, a novel localized heating assisted LSPwoC (LHA-LSPwoC) method, utilizing a continuous wave laser for local heating, is proposed. Additionally, the deep physics-informed neural network model, embedded with physical formulas, is designed for process optimization. It enables rapid and accurate responses for an extensive number of cases (40 cases with an average deviation below 1%), overcoming the drawbacks of traditional numerical simulations that are time-consuming and difficult to efficiently handle numerous cases. Compared to RT-LSPwoC, LHA-LSPwoC samples have higher dislocation density and higher grain refinement, demonstrating higher hardness and residual stress, particularly superior fatigue performance. The mechanism of LHA-LSPwoC is discussed, and thermally coupled finite element simulations and molecular dynamics calculations are conducted to provide theoretical support. The proposed method is cost-effective and flexible, showing outstanding potential for industrial applications.

Piezothermoelastic interaction in piezoelectric rods induced by a timed laser pulse without energy dissipation

The main aim of this article is to study the piezo-thermoelastic interaction in piezoelectric rods without energy dissipation due to a laser heat source with a timed pulse. Laplace transforms are used to represent the analytical solutions in the transformations domain. The governing equations of piezo-thermoelasticity in the Green and Naghdi model (GNII model without energy dissipation) in the presence of a laser heat source with a timed pulse are solved exactly in the Laplace domain, calculating the temperature, the stress, the displacement, and the electric potential. Numerical Laplace inversion is then used to find the general solution of the variables under study, which are then graphically shown.

Transient behavior of thermocapillary convection in thin liquid film exposed to step laser heating

Temporally developing thermocapillary convection induced by step laser heating of a thin liquid film has been studied numerically. Computations are performed using the commercial software STAR CCM+ version 2022.1. The liquid film of silicone oil (high Prandtl number fluid) is 60 mm in diameter and 3 mm in thickness. Flow characteristics related to surface velocity and surface temperature have been studied. Validation of the computations is achieved for the surface velocity, the velocity along thickness and the surface temperature through comparison with PIV and IR camera measurements. The laser-beam with a carbon dioxide gas laser (10.4 μm in wavelength) is used for heating. It is found that the temporally developing profile of surface velocity shows two local velocity peaks (uS1 and uS2) at two radial locations (rS1 and rS2) respectively. The first peak, uS1, appearing due to the steep temperature gradient generated by laser-beam heating and its radial position, rS1, do not change noticeably with time. On the other hand, the second peak, uS2, travels radially outwards with decreasing magnitude in a self-propelling manner until its radial position, rS2, approaches an asymptotic maximum. Detailed analysis of the coupling among radial temperature gradient, local pressure variation and local convective acceleration near the second peak reveals that hydrothermal mechanisms are responsible for self-propelling travel of uS2. The transient behaviors of both primary and secondary velocity peaks are found to depend on the fluid viscosity and the laser-beam settings

Photothermally‐Engineered Crystallization of GAP‐Se Bulk Chalcogenide Nanocomposites toward the Realization of 3D Gradient Refractive Index Profiles

AbstractTailorability of a medium's optical properties, specifically refractive index and dispersion, is key to enabling compact optical designs. Chalcogenide glasses (ChGs) are widely used for infrared (IR) imaging applications, and the development of gradient refractive index (GRIN) optics. This work extends efforts to create and characterize 3D GRIN profiles in bulk multi‐component Ge‐As‐Pb‐Se (GAP‐Se) ChGs through spatially selective conversion of commercial glass to glass ceramic. This work extends prior efforts on bulk and film lab‐scale glass media, to that of a commercially produced material with improved optical homogeneity. Laser‐induced crystallization upon heat treatment results in the formation of high index Pb‐containing crystals that contribute to an increase in the nanocomposite's resulting effective refractive index, neff. The material's induced crystallinity imparted via laser exposure and heat treatment using metrology tools such as refractometry, X‐ray diffraction, FTIR, and TEM are studied. The resulting material response is quantified which is shown to be modulated via laser dose in both lateral and for the first time, axial directions enabling the first demonstration of a true, 3D GRIN profile. By comparing these outcomes to prior radial GRIN structures, the promise of these media as candidate materials for infrared systems.

Plasmonic photothermal photodynamic therapy in mice with colorectal cancer

The need for searching for new methods of antitumor therapy is due to the sharp increase in morbidity and mortality from cancer, as well as because of the fact that conventional chemo- and radiotherapy are often insufficiently effective owing to the development of tumor cells resistance. Plasmonic photothermal therapy (PPT) is a method based on tumor hyperthermia by laser heating of metal nanoparticles with plasmon resonance properties.

Balanced truncation model reduction for laser heating wafer model in frequency restricted domain

Modeling and simulating laser heating phenomena are crucial for optimizing manufacturing processes and ensuring high-quality final products. A major challenge in semiconductor manufacturing is achieving accurate, real-time temperature control during wafer heating. To reduce the computational burden of complex mathematical models, low-dimensional reduced models can be employed. In this paper, we develop a mathematical model for laser heating in silicon wafers. For model reduction, we use the balanced truncation method, considering both frequency-unrestricted and restricted cases. Additionally, the rational Krylov subspace method is applied to solve high-dimensional sparse matrix equations. To gain key physical insights, we use the COMSOL Multiphysics package. Finally, some numerical experiments are conducted using MATLAB to validate the proposed approach.

Single‐Mode Excited Thermally‐Responsive Multicolor Emissions of High Entropy Upconversion Perovskite Halides for Anticounterfeiting

AbstractThis work presents a novel and highly secure anticounterfeiting strategy based on high entropy upconversion perovskite halides with thermally responsive multicolor emissions excited by a single laser. The perovskite halides are doped with rare earth cations and oxygen anions simultaneously and form the high entropy crystal structure by using a solid‐state reaction method. The color‐shifting emissions stem from luminescent kinetics transformation from energy transfer upconversion at low temperature to excited state absorption at high temperature. The multicolor emissions can also be trigged by the 975 nm laser heating effect. The results indicate the great potential of the high entropy upconversion perovskites for anticounterfeiting applications with a convenient recognition method.

Level-Set Method Based Predictive Modeling to Track the Evolution of Surface During Pulsed Laser Surface Melting

Abstract The objective of this study is to investigate the evolution of surface geometry during pulsed laser surface melting (pLSM) via level-set method-based interface tracking numerical framework. Existing models to track surface geometry are inaccurate and computationally expensive. Therefore, they have limited use in gaining understanding of the surface evolution during pLSM. A numerical model, integrating the level-set approach, fluid flow, and heat transfer dynamics, is detailed in this paper. The multi-phase numerical model achieves accurate tracking of interface for a single pulse by implementing the volumetric laser heat source on the moving interface by modifying Beer–Lambert's law. The accuracy of the single pulse model is confirmed by comparing its peak-to-valley height (PVH) to the experimental data. The deviation in PVH is limited to about 15%, with a maximum root mean square error of ∼0.24 µm, highlighting the model's reliability. Additionally, the evolved surface of a single pulse from the model is replicated over an area with dedicated overlaps to generate the predicted textured surface with reasonable accuracy. Some inaccuracies in the predicted surface roughness values were observed because the textures were generated based on a single pulse geometry computed on an initially flat surface. Nonetheless, the results highlight a significant development in numerical frameworks for pLSM and can be used as a tool to gain deeper insights into the process and for process optimization.

Label-Free Raman Probing of the Intrinsic Electric Field for High-Efficiency Screening of Electricity-Producing Bacteria at the Single-Cell Level.

The fabrication of high-performance microbial fuel cells requires the evaluation of the activity of electrochemically active bacteria. However, this is challenging because of the time-consuming nature of biofilm formation and the invasive nature of labeling. To address this issue, we developed a fast, label-free, single-cell Raman spectroscopic method. This method involves investigating the "pure" linear Stark effect of endogenous CO in the silent region of biological samples, which allows for probing the intrinsic electric field in the outer-membrane cytochromes of live bacterial cells. We found that reduced outer-membrane cytochromes can generate an additional intrinsic electric field equivalent to an applied potential of +0.29 V. We also found that the higher the electrical activity of the cell, the larger the generated electric field. This was also reflected in the output current of the constructed microbial fuel cells. Raman spectroscopy was employed to facilitate the assessment of electrochemical activity at the single-cell level in highly-diluted bacterial samples. After analysis, inactive bacteria were ablated by laser heating, and 20 active cells were cultured for further testing. The rapid and high-throughput probing of the intrinsic electric field offers a promising platform for high-efficiency screening of electrochemically active bacterial cells for bioenergetic and photosynthetic research.

Quantum Coherence Control at Temperatures up to 1400 K.

Coherent quantum control at high temperatures is important for expanding the quantum world and is useful for applying quantum technologies to realistic environments. Quantum control of spins in diamond has been demonstrated near 1000 K, with the spins polarized and read out at room temperature and controlled at elevated temperatures by rapid heating and cooling. Further increase of the working temperature is challenging due to fast spin relaxation in comparison with the heating and cooling rates. Here we significantly improve the heating and cooling rates by using reduced graphene oxide as the laser absorber and heat drain and hence realize coherent quantum operation at up to 1400 K, which is higher than the Curie temperatures of all known materials. This work facilitates the use of diamond sensors to study a wide range of magnetic effects in the high-temperature regime, such as thermoremanent magnetism and magnetic shape memory effects.

Analytical model for laser cutting in porous media

Laser cutting in porous media presents both challenges and opportunities for various applications. Laser cutting requires a deep understanding of heat transfer, materials, and laser physics, and can involve nonlinear and transient effects. There is a lack of literature regarding modelling laser cutting in porous media. Using conservation of energy principle, an analytical model has been developed to calculate the total laser power required to cut a porous media without the need for complex numerical simulations.The model incorporates a new correlation for calculating waste power due to heat transfer into the surrounding during laser cutting as well as modifications to the energy balance equation to incorporate the effect of porosity and fluid saturation.The model has been validated with experimental data of cutting porous media (carbonate rock) and corroborated well. Model validation showed around 10 % accuracy for fluid saturated rock samples and around 17 % accuracy for dry rock samples. Also it has been observed that the level of accuracy improves with lower Peclet number (i.e. lower cutting speed).The proposed analytical model has been used to examine the effect of Peclet number, porosity, fluid saturation, rock type and material thickness on laser cutting performance. The methodology described in this article can be used as a guideline to calculate laser power requirements and size the laser equipment at an early stage prior to the manufacturing process.

Research on thermal runaway and gas generation characteristics of NCM811 high energy density lithium-ion batteries under different triggering methods

Safety concerns, including thermal runaway and gas generation, present significant challenges for high-energy-density lithium-ion batteries. Thermal abuse, a common trigger for thermal runaway, can be induced by various methods, including heating rods, coils, plates, and lasers. This study compares the impacts of three heating techniques—heating rods, coils, and plates—on thermal runaway and gas generation in a commercially used NCM811 lithium-ion battery, which has a high energy density of 280.24 Wh/kg (the latest cylindrical 46950 model). The study found that the heating coil was the most effective, triggering thermal runaway more quickly and at a higher temperature than the heating plate and rod. Gas production analysis revealed that the heating coil method generated significantly more gas, particularly CO2, than the other methods. The concentrations of gases produced during thermal runaway (CO, CO2, H2, and CH4) varied by heating method, with the heating coil leading to a more complete battery reaction. The safety evaluation highlighted the hazardous nature of the heating rod method, which produced the widest flammable gas concentration range and the highest explosion risk among the tested heating methods. This study provides critical insights into heating techniques in lithium-ion battery thermal runaway scenarios and offers valuable data for improving safety measures in energy storage systems.

In-situ, real-time monitoring of thermo-mechanical properties of biological tissues undergoing laser heating and ablation.

In this work, Brillouin light-scattering spectroscopy and optical backscattering reflectometry (OBR) using Mg-silica-NP-doped distributed sensing fibers were employed for monitoring local GHz visco-elastic properties and surface temperature, respectively, during laser driven heating and ablation of chicken tissues. The spatial temperature distribution measured by OBR at various infrared laser heating powers and times was used to validate spatio-temporal local temperature variations modeled by the finite element method via solving Pennes' bioheat conduction equation. The reduction of viscosity and stiffness in chicken skin during its laser heating was attributed to water loss, protein denaturation and change in lipid phase behavior. These findings open avenues for the simultaneous real-time hybrid optical sensing of both viscoelasticity and local temperature in biological tissues undergoing denaturation and gelation during thermal ablation in clinical settings.

Gamma-ray back emission from nanowire array irradiated by ultra-intense relativistic laser pulse

A highly energetic photon is emitted via nonlinear inverse Compton scattering after an electron undergoes scattering with an ultra-intense relativistic laser pulse. In the laser-nanostructured interaction, gamma photons are emitted in different directions due to different electron heating mechanisms. However, the physics that leads to such gamma-photon emission directionality still requires further understanding. This paper shows that ∼53% of the photons emitted from the nanowires fall into the forward-directed cone, with ∼21% of the backward-emitted photons. Using the two-dimensional particle-in-cell simulations, we found that the backward-emitted photons are mainly ascribed to the j × B heating and reflux electrons. The direction of photon emission from the nanowire tip is in the direction of the ponderomotive force. Furthermore, we also demonstrate that the nanowire target attached to the supporting substrate helps to enhance forward photon emission and reduce emission from reflux electrons. Understanding the correlation between the laser heating mechanisms and the directionality of photon emission could provide insights into the generation of collimated gamma rays using nanowire targets for various applications.

Synthesis of Na3WH9 and Na3ReH8 Ternary Hydrides at High Pressures.

The Na-W-H and Na-Re-H ternary systems were studied in a diamond anvil cell through X-ray diffraction and Raman spectroscopy, supported by density functional theory and molecular dynamics calculations. Na3WH9 can be synthesized above 7.8 GPa and 1400 K, remaining stable between at least 0.1 and 42.1 GPa. The rhenium analogue Na3ReH8 can form at 10.1 GPa upon laser heating, being stable between at least 0.3 and 32.5 GPa. Na3WH9 and Na3ReH8 host [WH9]3- and [ReH8]3- anions, respectively, forming homoleptic 18-electron complexes in both cases. Both ternary hydrides show similar structural types and pressure dependent phase transitions. At the highest pressures they adopt a distorted fcc Heusler structure (Na3WH9-II' and Na3ReH8-II') while upon decompression the structure symmetrizes becoming fcc between ∼6.4 and 10 GPa for Na3WH9-II and at 17 GPa for Na3ReH8-II. On further pressure release, the fcc phases transform into variants of a (quasi-) hexagonal structure at ∼3 GPa, Na3WH9-I and Na3ReH8-I.

A Primary Study on the Applicability of Gel-Type Filler Materials to Root Pass Welds of the Thick Plate

Welding generally uses filler material to create deposited weld metal. Filler materials play a significant role in welding by providing the material needed to fill and form the joint. Existing filler materials are limited in the workspace and welding position and need help responding flexibly to welds of complex shapes. This study conducted primary research to develop a gel-type filler material with adhesion and flexibility that can cope with limited workspace and location. We attempted to provide a new approach to welding by mixing metal powder and binder to create a gel-type filler material. Root pass welding of thick plates was performed using a laser heat source. The bead appearance and cross-section of the weld zone were observed according to the type and composition of the metal powder, the binder content, and the method of synthesizing the metal powder. The physical characteristics of the weld were analyzed through observation of the hardness and microstructure of the weld.

Amazarkan gold deposit: conditions of formation, sources of ore substance (Eastern Transbaikalia)

Relevance. The need to clarify the sources and conditions of formation of gold mineralisation of the Amarzakan gold deposit. The characteristic feature of the deposit is the spatial combination of gold mineralisation and small intrusions of the middle and basic composition of the Amudzhikan complex. Aim. Determination of physico-chemical conditions and nature of the source of the ore substance of the Amazarkan deposit. Methods. ICP-MS method and standard chemical analysis were used to determine the elemental composition of rocks. Sulfur isotope composition of sulfides was obtained using gas-source mass-spectrometry and fluid inclusions in quartz of ore veins were studied by traditional methods of thermobarogeochemistry and by FTIR spectroscopy at the Centre for Collective Use of Multi-element and Isotope Studies of the Siberian Branch of the Russian Academy of Sciences (Novosibirsk). The oxygen isotope composition was determined at the Geological Institute of the Siberian Branch of the Russian Academy of Sciences (Ulan-Ude) using the MIR 10-30 laser heating system with a 100-watt CO2 laser and a wavelength of 10.6 µm in the infrared region in the presence of BrF5 reagent. Results. The authors have established the spatial confinement of ore zones to Mesozoic dikes of the Amudzhikan complex (J2-3). The Eu/Sm and Eu/Eu* ratios in the dikes indicate fractionation of magmatic melts in the sources at the level of the lower continental crust and low degree of their differentiation. The character of REE distribution in the rocks of dikes of the Amudzhikan complex is similar to the distribution of REE in the ores of the deposit. Eu/Sm–Eu/Eu* figurative points of compositions of ore veins and granodiorites of the Amudzhikan complex form a single trend. Dykes of the Amuzhikan complex are characterized by increased Au content from 0.026 to 1.171 g/t. These data suggest a paragenetic link between Au mineralization and rocks of the Amudzhikan complex. Ore veins of productive stages of ore formation were formed at temperatures ranging from 125 to 410°C. The calculated S and O isotopic composition of the ore-forming fluid in equilibrium with pyrite and quartz, as well as the Co/Ni>1 ratio in the ores indicate the presence of a magmatic component in its composition.

In-process laser heating for mechanical strength improvement of FFF-printed PEEK

In-process laser heating for mechanical strength improvement of FFF-printed PEEK

Modeling the interaction between powder particles and laser heat sources

This study investigates the spheroidization of titanium Ti-6Al-4V powder particles using numerical models developed in Abaqus and OpenFOAM. Spherical particles are crucial in powder-based additive manufacturing due to their superior flowability, packing density, and mechanical properties, enhancing printing precision and the quality of final products. While conventional techniques such as gas atomization and plasma spheroidization have been extensively researched, the potential of laser spheroidization remains underexplored. To address this gap, detailed numerical analyses of laser spheroidization were conducted, modeling heat transfer from the laser to powder particles using a transient uncoupled heat transfer method with latent heat considerations, while particle deformation was simulated with a phase-fraction-based interface-capturing approach integrated with Navier-Stokes equations. The results, validated against analytical models, indicate that particles within the 20–80 μm range experience optimal spheroidization within a 0.005-second residence time under laser heating, with particles smaller than 30 μm reaching evaporation temperatures of 5,000°C, while larger particles reshape without evaporating under a typical heat flux of 94 MW/m2 (1.8 kW laser power). This study demonstrates that laser spheroidization of Ti-6Al-4V powder can potentially increase powder yield by 10%, offering higher power density and shorter melting times compared to plasma spheroidization, thus presenting a more efficient alternative for achieving spherical particles of specific sizes.

Rapid fabrication of gold microsphere arrays with stable deep-pressing anisotropic conductivity for advanced packaging

Smooth metal microspheres with uniform sizes are ideal for constructing particle-arrayed anisotropic conductive films (ACF), but synthesis is hindered by challenges in controlling anisotropic metal growth. Here, we present a positioned transient-emulsion self-assembly and laser-irradiation strategy to fabricate pure gold microsphere arrays with smooth surfaces and uniform sizes. The fabrication involves assembling gold nanoparticles into uniform colloidosomes within a pre-designed microhole array, followed by rapid transformation into well-defined microspheres through laser heating. The gold nanoparticles melt and merge in a layer-by-layer manner due to the finite skin depth of the laser, leading to a localized photothermal effect. This strategy circumvents anisotropic growth, enables tunable control of microsphere size and positioning, and is compatible with conventional lithography. Importantly, these pure gold microspheres exhibit stable conductivity under deep compression, offering promising applications in soldering micro-sized chips onto integrated circuits.