Abstract Dion-Jacobson (DJ) perovskites have emerged as game-changers in the world of photovoltaics due to their unique combination of advantages like cost-effective fabrication, tailorable bandgap, and exceptional efficiency. Further, in this study, MXene contacts have been utilized with 2D-perovskites solar cells to leverage the advantages of both, leading to improved stability, superior charge transport, and adjustable energy bandgap without the occurrence of pinhole effects. To further tap into the immense potential of perovskites, this study explores the power of a triple-junction All DJ perovskite tandem solar cell (ADJT-PSC) architecture. This design captures a broader spectrum of sunlight, maximizing energy harvesting and unlocking new possibilities for photovoltaic devices. In this symphony of light and power, 1.5-pentamethylenediamine (PeDA) methylammonium lead iodide (PeDAMAPb2I7) (1.98 eV), PeDAMA5Pb6I19 (1.6 eV), CsLaTa2Se7 (1.1 eV) take as the absorber layers in the top, middle, and bottom subcells, respectively. Moreover, optimizing the thickness of each perovskite layer is crucial for maximizing efficiency. This study conducted a thorough analysis and identified the ideal 350 nm/550 nm/200 nm thicknesses for the top/middle/bottom layers, respectively. Furthermore, the study explored the art of doping variation in the electron and hole transport layers. By meticulously adjusting the doping levels, ADJT-PSC can achieve a maximum efficiency of 35%.
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