Distribution Of Groundwater Research Articles

Combined geophysical approach as a tool to identify spatial groundwater aquifer distribution in structurally complex area. Case study of Kasserine aquifer system (central Tunisia)

Many countries are facing water resource scarcity. The Kasserine region in central Tunisia, is characterized with semi-arid climate and it is one of the most affected areas by drought in the country. Groundwater constitutes the main resource for drinking and irrigation water in Kasserine region. The groundwater aquifer levels are very structured, in this geologically complex zone, and their geometry needs to be well characterized. The present study aims to identify the geometry and the distribution of Campanian to Quaternary main aquifers in the Kasserine hydrogeological basin.In this study, we adopted a combined geophysical approach; we analyzed and interpreted gravity and seismic existent data in addition to acquiring conventional vertical electrical soundings. The gravity data analysis and mapping revealed that the study area is structured in numerous geological blocks. It highlighted the existence of two major negative gravity anomalies associated with the Megdoudech basin and the Kasserine graben. The gravity maps illustrated the role of the NW-SE Kasserine major Fault in the block structuring. The seismic reflection sections have emphasized the same structuring of the basins. They have exposed the fault network responsible for the compartmentalization of geological structures and which plays an important role in the hydrodynamics of the aquifer system in the region. The geoelectrical investigation highlighted the existence of three aquifer units: the sandy to sandy-clay levels of the Plio-Quaternary in the Kasserine graben, the sandstones of the middle Miocene with an average resistivity of 75 Ω m profiled at different depths, and the Campanian limestones with high resistivities in the Kasserine plateau.This combined approach is proven to be very useful to understand groundwater distribution in such geologically complex zones. The results will help the decision makers to ensure the safe management of groundwater resources especially in semi-arid and arid regions.

Uncharted water conflicts ahead: mapping the scenario space for Germany in the year 2050

IntroductionIn recent years, conflicts surrounding the use, distribution, and governance of surface water and groundwater in Germany have gained prominence in the media, on the political agenda, and in research. Increasing effects of climate change, such as heatwaves and drought but also extreme rain events and flooding, are considered to become more prominent and pressing in the future by different societal actors. However, it remains highly uncertain if and what type of conflicts related to water quantity Germany might actually face in the future (and how they will be framed). This paper addresses one dimension of this uncertainty—namely the future context uncertainty of possible resource and water governance conflicts. Our research contributes to an improved understanding of the uncertainty concerning future climatic, natural, land use related, political, economic, and other societal contexts that could impact water conflicts.MethodWe ask: What are possible coherent context scenarios for Germany in the year 2050, and how are they expected to influence future water conflicts? In an expert-based process, we apply a qualitative and systematic method of systems analysis, cross-impact balances (CIB). With CIB, we build internally consistent scenarios of possible futures and map the future scenario space.Results and discussionDiversity mapping with a new CIB web application of the ScenarioWizard reveals that the scenario space is rather large and diverse. The identified scenario space of n = 355 internally consistent scenarios spans four most diverse scenarios “Polycrisis,” “Economy and agriculture in crisis,” “Growth through adaptation to climate change,” and “Sustainable transformation.” Depending on the development of future contexts, the risk for future water resource and governance conflicts may unfold in various ways. We conclude that our scenario analysis provides a useful base for research and practice to address the context uncertainty of water conflicts in Germany. Our results can be used for risk assessment, to define societal framework assumptions for societal-hydrological modeling, and to develop robust and adaptive strategies and policies.

Fluoride and nitrogen contamination and potential health risks in the groundwater of a typical agricultural region

ABSTRACT Fluoride and nitrogen contamination is a global concern and has been a serious problem in agricultural areas. This study aims to identify the source of fluoride and nitrogen in the groundwater and assess groundwater quality and human health risks in the Guanzhong Plain, northwest China. The results showed that the concentrations were 0.15–4.74 mg/L for F−, 0.02–89.89 mg/L for NO3−-N, and BDL-2.40 mg/L for NH4+-N in groundwater. Distinct area-dependent distributions of fluoride and nitrogen were observed in the study region. Higher F− and NO3−-N concentrations in groundwater were detected in the northern part, and higher NH4+-N levels were observed in the southern part. Water–rock interaction and agricultural activities were the controlling factors for fluoride and nitrogen distribution in groundwater. About 80% of samples are considered to have good water quality with a Water Quality Index (WQI) < 100. Exposure to fluoride and nitrogen through drinking should require more attention. The total non-carcinogenic risks through oral ingestion of groundwater were 0.22–3.19 for adults and 0.51–7.44 for children, respectively. The order of pollutants in the groundwater in terms of their hazard to residents was F− > NH4+-N > NO3−-N > NO2−-N. The findings of this study could provide more insights into groundwater management.

The Landsat Data-Based Monitoring of Groundwater Depth and Its Influencing Factors in the Oasis Area of the Weigan River

Using the Weigan River oasis as the research area and based on Landsat and measured groundwater depth data, the temperature vegetation drought index (TVDI) was calculated, and the groundwater depth that was measured in the field was used to establish a groundwater level prediction model (R2 = 0.644). Groundwater distribution in the Weigan River oasis was monitored from 2007 to 2020, and the model was verified using data from September 2013 and June 2015. The results indicate the following: (1) From 2000 to 2015, the groundwater depth of the Weigan River oasis was increased in a fluctuating manner and increased from 2.80 m to 5.79 m, and these values fluctuated sharply with a range of change of 106.79%. (2) The correlation coefficient R2 between the measured and predicted water levels in the two periods is 0.67 and 0.61, and the verification effect is good. (3) In the period from 2007 to 2020, the groundwater depth in the irrigated area exhibited a declining trend, where it decreased from the northwest and northeast to the southwest and southeast. (4) In irrigated areas, the GDP, population, and grain yield exerted a greater impact on groundwater depth. However, precipitation and evaporation were not significantly correlated with groundwater depth.

Distribution and Co-Enrichment Factors of Arsenic and Fluoride in the Groundwater of the Plain Area of the Aksu River Basin, Xinjiang, PR China

The Aksu River Basin is located in the western region of the middle part of the southern foothills of the Tianshan Mountains and the northwestern edge of the Tarim Basin in Xinjiang, China. High-arsenic (As)/high-fluoride (F) groundwater is widely distributed in this area and is harmful to the life of local residents and to agricultural production. It is of great importance to understand the distribution and causes of As-F co-enrichment in the groundwater in this area. Based on the test results of 138 groundwater samples in the plain area of the Aksu River Basin, the hydrochemical characteristics of groundwater and the spatial distribution of As-F co-enrichment groundwater were analyzed under the following conditions: a single-structure phreatic aquifer (SSPA), a phreatic aquifer in a confined groundwater area (PACGA), a shallow confined aquifer (SCA), and a deep confined aquifer (DCA), all in a recharge area, transition area, and an evaporation area. The hydrogeochemical processes affecting the source, migration, and enrichment of As-F in the groundwater were revealed. The results showed that the chemical types of groundwater in the study area were mainly HCO3·SO4-Ca·Mg and SO4·Cl-Na·Mg. Horizontally, high-As-F groundwater was mainly distributed in the transition area and evaporation area in the middle and lower reaches of the Aksu River Basin. The area is close to the edge of the desert, where the groundwater runoff is sluggish and in an alkaline-reducing groundwater environment. Vertically, high-As groundwater was mainly distributed in the PACGA at a depth of 10–20 m and in the SCA at a depth of 80–100 m. High-F groundwater was mainly concentrated in the PACGA at a depth of 10–30 m and in the SCA at a depth of 80–100 m, and As-F co-enrichment groundwater was mainly concentrated in the PACGA at a depth of 10–20 m and in the SCA at a depth of 80–100 m. The hydrochemical characteristics of the groundwater in the Aksu River Basin were closely related to geological conditions, hydrogeological conditions, and the hydrochemical environment of the groundwater. As-F co-enriched groundwater was mainly affected by the combination of a small topographic gradient, a shallow groundwater burial depth, a weak reducing alkaline groundwater environment, strong evaporation and concentration, the weathering and dissolution of evaporated salt rock, and the alternating adsorption of cations.

Effects of human and tectonic activities on groundwater in the upper Yellow River terraces of the loess Plateau

Terraces of the Yellow River are among the most crucial geomorphological landforms pertaining to human survival on the Loess Plateau. After more than half a century of surface flood irrigation, rapid rises in groundwater levels have led to frequent geological disasters, causing a rapid short-term evolution of Yellow River terraces, and an increasingly serious contradiction between this rapid evolution and human survival. However, the process by which water transfers through the thick loess vadose zone and causes a rapid groundwater response within months or years remains controversial. Using the Heitai platform of Yellow River terrace IV as an example, we found, on the basis of regional geological surveys, that at least 112 tectonically-induced cracks have developed in this area. We contend that the superimposed effects of earthquake ground motions from historical and ancient earthquakes since the Late Pleistocene have driven the development of such densely distributed cracks in the loess layer. These cracks, together with a series of fault planes generated by NE-directed extrusive stress at the regional scale, constitute a potential network of preferential channels for water transport within the Heitai platform. Combined with the results of a large-scale in situ ponding test and electrical resistivity tomography, we found that this network of cracks helps to establish catchment areas within the loess layer, thereby increasing soil saturation at a more extensive spatial scale, which may then increase the overall movement velocity of the wetting front. We semi-quantified the efficiency of the crack network in enhancing the recharge of surface water to groundwater, and suggested that the impact of human and tectonic activities substantially shortens the response time of groundwater to surface water, with the reduced time far exceeding one order of magnitude. The results of a field investigation of structural traces and terrace groundwater after the Ms 6.2 Jishishan earthquake on 18 December 2023 further emphasize that a causal mechanism of human and tectonic activities leading to the rapid short-term evolution of groundwater distribution patterns may be universally applicable to all Yellow River terraces on the Loess Plateau. This study mitigates the long-standing controversy concerning the mode of surface water infiltration, including piston flow and preferential flow, and the infiltration medium by which rapid surface water recharge to groundwater occurs in loess areas over short time periods.

Controls on regional sulphate distribution in shallow groundwater in the western Canadian Interior Plains

Sulphate (SO4), predominantly derived from sulphur (S)-bearing glacial sediments distributed widely across the Canadian Interior Plains, contributes to high groundwater salinity and can be detrimental to riparian and dry-land ecosystems, agricultural production, and water use. While previous researchers investigated SO4 distribution and dynamics in shallow groundwater at local scales (<1500 km2), we examine SO4 occurrence in groundwater at larger scales, and to depths of ∼150 m, considering variations in geology, glacial history, climate, and geochemical and hydrogeological settings in the Canadian province of Alberta. Sulphate concentrations in groundwater vary considerably, with 15 % of 139,130 samples above the 500 mg/L Canadian drinking water aesthetic objective. Analysis of δ34SSO4 and δ18OSO4 from 179 wells throughout Alberta shows SO4 is dominantly derived from oxidation of S-bearing material. At this large scale, marine shale bedrock subcrops, glacial ice flow directions, and climate control SO4 distribution. Groundwater contains less SO4 (<200 mg/L) in western Alberta compared to the east due to a lack of S-bearing bedrock, higher groundwater recharge rates, thinner glacial sediments, and increased groundwater circulation. Focusing on a region in south-central Alberta (Red Deer area), hydrogeological characteristics relating to SO4 formation, recharge, permeability, hydraulic gradient, and travel time are included in a principal component analysis to identify six groundwater groups at varying stages of evolution and SO4 concentrations depending on their hydrogeological setting. Low SO4 concentrations are associated with areas of high recharge, where SO4 has been leached from the sediments, or with more evolved bedrock groundwater where SO4 has been reduced or was recharged in pre-glacial times. High SO4 concentrations are found in areas of lower recharge and permeability, where flushing occurs more slowly. Combining the Red Deer area and province-wide analyses, we identify seven regions across Alberta with characteristic distribution and controls on SO4 occurrence in shallow groundwater.

A complex network analysis of groundwater wells in and around the Doñana Natural Space, Spain

This paper proposes the use of Complex Network Analysis tools to study the spatial distribution and temporal evolution of groundwater abstraction wells within a region of interest. To that end a weighted undirected network connecting wells within a certain distance was built. The edge weights take into account the distance between the wells as well as their corresponding abstraction volumes. In addition to the conventional complex network metrics, two specific abstraction-based centrality indexes are proposed, based on the total impact of a groundwater abstraction well on its surrounding wells and on the total impact of surrounding wells on a specific location. The proposed approach has been applied to the area of the Doñana Natural Space, one of the most important wetlands in Europe. The topology of the network reveals a large number of small, disconnected components and a few large components. This is reflected also in the degree distribution, which follows a Power Law distribution. The network has a large average clustering coefficient, a small average path length and a low level of centralisation. Global and average local network efficiency are also high. The network is assortative in terms of degree-degree and strength-strength correlations. Eigenvector centrality of the nodes reveals the location of influential wells.

Comparison of groundwater distribution, exchange and storage between cropland and forestland over the past 115 years

ABSTRACT Using the US Geological Survey groundwater model, we compared spatial distribution, flow exchange, and storage of groundwater between cropland and forestland in the Upper Yazoo River Watershed, Mississippi, from 1900 to 2014. Under normal climate, average groundwater head declined 2.7 m in cropland but only 1 m in forestland over the 115 years. The average groundwater flow from forestland to cropland surpassed the reverse flow by a factor of 238, owing to a higher elevation in forestland and intensive groundwater pumping in cropland. Cropland was a net groundwater sink while forestland was a net groundwater source under all climates. Our findings underscore the discernible impacts of climate changes on groundwater storage and suggest that afforestation in the region would be an alternative for saving groundwater resources and supplying more waters to croplands. This study offers valuable insights into groundwater supply planning not only in Mississippi but also in comparable situations worldwide.

Integration of geospatial techniques and analytical hierarchy process (AHP) ind demarcating groundwater potential zones in Lakhimpur district, Assam, India

Overexploitation and climate change have threatened the availability and sustenance of groundwater resources. A proper understanding of the regional distribution of groundwater is crucial to ensure long-term water security. The present study aims to identify the groundwater potential zones in the Lakhimpur district of Assam using the Analytical Hierarchy Process (AHP) in combination with geospatial technologies. The occurrence of groundwater in the region was determined by several factors including geomorphology, lithology, slope, distance from the river, drainage density, lineament density, rainfall, curvature, soil, land use, land cover, Normalized difference vegetation index (NDVI), and topographic wetness index (TWI). These factors organized as thematic layers were utilized to generate a groundwater potential zones (GWPZ) map in the GIS environment. The AHP, an effective decision-making technique, was adopted to assign weights to each thematic layer corresponding to their relative importance in influencing groundwater availability. The GWPZ map prepared using the weighted overlay techniques was categorized into three classes: good, moderate, and poor. The result revealed that the good potential zone comprises 1909.41 km2 (65.12%), moderate 1018.25 km2 (34.72%) and the poor zone comprises 4.22 km2 (0.14%) of the total geographical area. The obtained results of 73.33% (Overall accuracy), 0.708 (ROC-AUC), and 0.50 mbgl (groundwater level fluctuation) between pre-monsoon and post-monsoon prove that the model has performed satisfactorily in identifying groundwater potential zones. The findings provide a framework for the effective exploration and management of groundwater resources, ensuring their future availability in the region.

Evaluation of Groundwater Resources in the Middle and Lower Reaches of Songhua River Based on SWAT Model

The SWAT model primarily investigates sources of water pollution and conducts ecological assessments of surface water in contemporary hydrology and water resources research. To date, there have been limited accomplishments in the study of groundwater resources in China. The MODFLOW model currently primarily simulates groundwater levels and the migration of water quality, depending on the hydrological surface water data in the relevant area. This study aims to investigate the groundwater distribution characteristics of the middle and lower reaches of the Songhua River, a significant agricultural and grain production region in China. The research focuses on the middle and lower reaches of the Songhua River basin in Northeast China and employed the SWAT distributed hydrological model to simulate runoff. The monthly recorded runoff at Tongjiang Station in Jiamusi City was utilized to calibrate the model parameters. Consequently, the MODFLOW model was introduced to compare and assess the simulation outcomes of the SWAT model, ultimately ascertaining the distribution characteristics of shallow groundwater, groundwater recharge, recoverable volume, and groundwater levels in the Songhua River Basin. The findings indicate that: (1) The SWAT model demonstrates efficacy in the study region, achieving R2 and NS values of 0.81 and 0.76, respectively, thereby fulfilling the fundamental criteria for scientific research. The MODFLOW model exhibits strong performance in the study region, achieving a periodic R2 of 0.98 and a verification R2 of 0.97, with the discrepancy between simulated and actual groundwater levels confined to 0.6 m, thereby satisfying the criteria for scientific research. (2) In 2011, 2014, and 2016, the groundwater recharge in the middle and lower sections of the Songhua River was 24.33 × 108 m3, 30.79 × 108 m3, and 32.25 × 108 m3, respectively, aligning closely with the SWAT simulation results, while the average annual groundwater level depth was 8.17 m. (3) In the research area, groundwater recharging occurs primarily by atmospheric precipitation, while drainage predominantly transpires via groundwater as base flow, constituting 81.46%. Secondly, the recharge of shallow groundwater to deep aquifers is around 7.14%, with a minimal share attributed to vadose zone loss, constituting merely 2.1%. (4) From 2010 to 2016, the average groundwater runoff modulus of the middle and lower reaches of the Songhua River basin was 1.005 L/(s·km²), with a total recharge of 216.58 × 108 m3 and a total recoverable amount of 105.11 × 108 m3. The mean yearly supply was 25.11 × 108 m3. The total groundwater recharge was 26.54 × 108 m3 in the driest year (2011) and 33.25 × 108 m3 in the year of most ample water (2016).

Hydrochemical gradients driving extremophile distribution in saline and brine groundwater of southern Poland.

Extreme environments, such as highly saline ecosystems, are characterised by a limited presence of microbial communities capable of tolerating and thriving under these conditions. To better understand the limits of life and its chemical and microbiological drivers, highly saline and brine groundwaters of Na-Cl and Na-Ca-Cl types with notably diverse SO4 contents were sampled in water intakes and springs from sedimentary aquifers located in the Outer Carpathians and the Carpathian Foredeep basin and its basement in Poland. Chemical and microbiological methods were used to identify the composition of groundwaters, determine microbial diversity, and indicate processes controlling their distribution using multivariate statistical analyses. DNA sequencing targeting V3-V4 and V4-V5 gene regions revealed a predominance of Proteobacteriota, Methanobacteria, Methanomicrobia, and Nanoarchaea in most of the water samples, irrespective of their geological context. Despite the sample-size constraint, redundancy analysis employing a compositional approach to hydrochemical predictors identified Cl/SO4 and Cl/HCO3 ratios, and specific electrical conductivity, as key gradients shaping microbial communities, depending on the analysed gene regions. Analysis of functional groups revealed that methanogenesis, sulphate oxidation and reduction, and the nitrogen cycle define and distinguish the halotolerant communities in the samples. These communities are characterised by an inverse relationship between methanogens and sulphur-cycling microorganisms.

Hydrogeochemical properties, source provenance, distribution, and health risk of high fluoride groundwater: Geochemical control, and source apportionment

This study evaluated high fluoride (F−) levels, source distribution, provenance, health risk, and source apportionment in the groundwater of Sargodha, Pakistan. Therefore, 48 groundwater samples were collected and analyzed by ion-chromatography (DX-120, Dionex). The lowest concentration of F− was 0.1, and the highest was 5.8 mg/L in the aquifers. In this study, 43.76% of the samples had exceeded the World Health Organization's allowable limit of 1.5 mg/L. The hydrogeochemical facies in Na-rich and Ca-poor aquifers showed NaCl (66.6%), NaHCO3 (14.5%), mixed CaNaHCO3 (8.3%), CaCl2 (8.3%), mixed CaMgCl2 (2%), and CaHCO3 (2%) type water. Alkaline pH, high Na+, HCO3− concentrations, and poor Ca-aquifers promoted F− dissolution in aquifer. The significant positive correlations between Na⁺ and F− suggested cation exchange, where elevated Na⁺ occurs in Ca-poor aquifers. The cation exchange reduces the availability of Ca2+ would lead to higher F− concentrations. Meanwhile, the correlation between HCO₃- and F− indicates that carbonate minerals dissolution helps in increasing pH and HCO₃- as a result F− triggers in aquifers. Groundwater chemistry is primarily governed by the weathering of rock, water-rock interaction, ion-exchange, and mineral dissolution significantly control groundwater compositions. Cluster analysis (CA) determined three potential clusters: less polluted (10.4%), moderately polluted (39.5%), and severely polluted (50%) revealing fluoride toxicity and vulnerability in groundwater wells. Mineral phases showed undersaturation and saturation determining dissolution of minerals and precipitation of minerals in the aquifer. PCAMLR model determined that high fluoride groundwater takes its genesis from F-bearing minerals, ion exchange, rock-water interaction, and industrial, and agricultural practices. The health risk assessment model revealed that children are at higher risk to F− toxicity than adults. Thus, groundwater of the area is unsuitable for drinking, domestic, and agricultural needs.

A hydrogeophysical conceptual model in the exploration of the "Las Sierras" aquifer: Case of Subwatershed III, southeast sector of Lake Managua, Nicaragua

This study proposes a hydrogeophysical conceptual model in a region southeast of Sub-basin III, which is part of the "Las Sierras" aquifer. The methodology employed combines geological data obtained from wells with geo-electric profiles, thus allowing a more precise representation of an underground valley hitherto unknown, primarily related to the materials of the Middle Las Sierras Group (TQps-M), identified as the main aquifer in the area. The delineation of hydrogeological units was carried out considering geological and geophysical conditions, providing valuable information to understand the distribution and behavior of groundwater in the region. The precise identification and delineation of hydrogeological units enable better management of groundwater resources in the region. This more detailed knowledge enables more effective strategies for the preservation and sustainability of local aquifers.

Paleo-climatic control on recharge and fresh-salt groundwater distribution in the Red River delta plain, Vietnam

Paleo-climatic induced sedimentation controls present-day recharge and the fresh-salt groundwater distribution in Quaternary delta systems. During sea-level highstands, marine clays with saline pore water were deposited and are interbedded with aquifers of coarse-grained sandy fluvial and shallow marine deposits, laid down during lowstands. The low-permeable marine layers may inhibit recent recharge to deeper aquifers, and thereby limit sustainable use of these freshwater resources. This phenomenon has been investigated in the Red River delta plain, using geophysical borehole logging, transient electromagnetic soundings, groundwater chemistry, stable isotope analysis and 3H and 14C dating of groundwater. Results reveal that marine saline pore water is still present in the Holocene marine clays, implying that fresh water has not entered the clays since their deposition. Therefore, recharge within the delta plain is not occurring and the deeper aquifers are hydraulically disconnected from the upper sandy layers. Today, recharge only occurs from the hinterland. Recharge during the last glacial period has flushed saline pore water from Pleistocene marine clays, but these clays were again affected by saline water during the Holocene transgression. The use of the groundwater resources in the delta plain must be adjusted to the present recharge to be sustainable.

Spatial distribution and hydrogeochemical processes of high iodine groundwater in the Hetao Basin, China

To understand the genesis and spatial distribution of high iodine groundwater in the Hetao Basin, 540 groundwater samples were analyzed for the chemistry and isotope. Total iodine concentrations in groundwater range from 1.32 to 2897 μg/L, with a mean value of 159.2 μg/L. The groundwater environment was mainly characterized by the weakly alkaline and reducing conditions, with the iodide as the main species of groundwater iodine. High iodine groundwater (I > 100 μg/L) was mainly distributed in shallow aquifers (< 30 m) of Hangjinhouqi near the Langshan Mountain and the discharge areas along the main drainage channels. The δ18O and δ2H values ranged from −12.09 ‰ to −3.99 ‰ and − 91.58 ‰ to −52.80 ‰, respectively, and the correlation between groundwater iodine and isotopes indicates the dominant role of evapotranspiration in the enrichment of iodine in the shallow groundwater with depth <30 m. It was further evidenced by the correlation between groundwater iodine and Cl/Br molar ratio, and significant contributions of climate factors identified from the random forest and XGBoost. Moreover, irrigation practices contribute to high iodine levels, with surface water used for irrigation containing up to 537.8 μg/L of iodine, which can be introduced into shallow aquifer directly. The iodine in irrigation water can be retained in the soil or shallow sediment, and later leach into groundwater under favorable conditions.

Effects of grid resolution on regional modelled groundwater salinity and salt fluxes to surface water

Coastal fresh groundwaters face growing threats from rising withdrawals and climate change, with salinization of surface and groundwater as notable impacts. Recent developments in parallel variable-density modelling enable studying these threats at unexplored resolutions and extents. To improve the understanding of ground- and surface water salinization processes, we designed an experiment to measure how spatial resolution affects both groundwater salinity distribution and salt loads to surface waters. An existing parallelized coupled variable-density groundwater flow and salt transport (VD-GWT) model is applied to a region in the Netherlands whereby the surface water drainage network is parameterized at grid resolutions between 10 and 250 m. The results show a strong dependency between resolution and the salinity distribution in shallow groundwater while simulated salt loads are affected by imperfect flux scaling. The computational resources needed for this test suggest that regional high-resolution VD-GWT models are feasible using HPC environments, albeit not practical.

A review of groundwater iodine mobilization, and application of isotopes in high iodine groundwater.

Excessive intake of iodine will do harm to human health. In recent years, high iodine groundwater has become a global concern after high arsenic and high fluorine groundwater. A deep understanding of the environmental factors affecting iodine accumulation in groundwater and the mechanism of migration and transformation is the scientific prerequisite for effective prevention and control of iodine pollution in groundwater. The paper comprehensively investigated the relevant literature on iodine pollution of groundwater and summarized the present spatial distribution and hydrochemical characteristics of iodine-enriched groundwater. Environmental factors and hydrogeological conditions affecting iodine enrichment in aquifers are systematically summarized. An in-depth analysis of the hydrologic geochemistry, physical chemistry, biogeochemistry and human impacts of iodine transport and transformation in the surface environment was conducted, the results and conclusions in the field of high iodine groundwater research are summarized comprehensively and systematically. Stable isotope can be used as a powerful tool to track the sources of hydrochemical components, biogeochemistry processes, recharge sources and flow paths of groundwater in hydrogeological systems, to provide effective research methods and means for the study of high iodine groundwater system, anddeepen the understanding of the formation mechanism of high iodine groundwater, the application of isotopic technique in high iodine groundwater is also systematically summarized, which enriches the method and theory of high iodine groundwater research. This paper provides more scientific basis for the prevention and control of groundwater iodine pollution and the management of groundwater resources in water-scarce areas.

Nitrate trend reversal in Dutch dual-permeability chalk springs, evaluated by tritium-based groundwater travel time distributions

Historical use of fertilizer and manure on farmlands is known to have a lasting impact on ecosystems and water resources, but few studies assess the legacy of nitrate pollution on groundwater and surface water after farming applications were reduced. We studied the response of nitrate in spring water to a reduction of nitrogen fertilizer applications in agriculture realized since the mid-1980s. We assessed the travel time distribution of groundwater based on a time series of tritium measurements for 90 springs and small brooks that drain a dual porosity chalk aquifer. The travel time distributions were constrained using the tritium data in combination with time series of nitrate concentrations, applying a shape-free travel time distribution model. A clear trend reversal of nitrate concentrations was observed and simulated for springs with a large fraction of young water (< 30 years old) whereas the nitrate response in springs with relatively older water was attenuated and delayed. We conclude that obtaining a time series of tritium data helps to constrain age distributions of water that is discharged from dual permeability aquifers. The fraction of water aged <30 years was a meaningful parameter to distinguish between different types of springs. Nitrate trends in springs that drain large fractions of young water (> 0.6) show higher peak concentrations, shorter lag-time between leaching and outflow peaks and steeper declines after trend reversal, relative to trends in springs which are dominantly fed by older groundwater. The study thus shows that the nitrate legacy of groundwater systems is strongly determined by the range of their travel time distributions, and trend reversal in receiving springs and surface waters may appear within 10 to 15 years after measures to reduce nitrate losses from farming.

Heavy Metal Distribution and Health Risk Assessment in Groundwater and Surface Water of Karst Lead–Zinc Mine

Heavy Metal Distribution and Health Risk Assessment in Groundwater and Surface Water of Karst Lead–Zinc Mine