In the early stage 5th generation mobile phone system, it is expected to use high frequencies up to the SHF band (3 to 30 GHz) [1]. Therefore new noise countermeasure material is necessary in this band [2]. In this paper, we studied M-type, Y-type and Z-type hexagonal ferrite fine particles in composite form with epoxy resin, to find candidate for this application through SEM observation, XRD, DC hysteresis loop, high frequency complex permeability, and conduction noise suppression effect on micro stripline(MSL).Preparation and properties of fine particles– While Sr and Ba hexagonal ferrite materials are known as permanent magnet materials, they are also useful as high frequency materials whose ferromagnetic resonance (FMR) frequency exceeds 20 GHz, which corresponds to the center frequency of noise suppression exceeds 20 GHz. Firstly we followed a known direction to reduce magneto-crystalline anisotropy by a 1 – 2 at% substitution of Fe3+ions by a combination of metal ions such as Co2+and Ti4+. Table Ishows list of test perticles; Z-type Ba 3 Zn 2−X Co x Fe 24 O 41 (x=1.25), Y-type Ba 2 Zn 2 Fe 12 O 22 , and M-type SrCo x Ti x Fe 2−x O 19 (x=1.4) [3]. The fired polycrystalline material was pulverized to obtain fine particles. The XRD pattern showed that the crystal structure is mainly composed of hexagonal crystals since the relative intensity and diffraction angle of the main diffraction peak agree with the values of the JCPDS database.Fabrication and properties of composite sheet– The fine particles were mixed with the epoxy resin at a volume ratio of about 50%. This mixed solution was dropped onto a polymer sheet and screen-printed with a metal squeegee to a certain thickness, then a composite sheet was obtained. On the premise of mounting the composite in the gap between the interposer substrate and the IC chip, the coating thickness was chosen as 50 ± 5 μm in total. The Y-type fine particles were almost flat in planar state even after grinding and the Z-type and M-type fine particles were close to spherical and randomly oriented, according to the SEM observation. The coercive force obtained from the DC magnetization curve is 8 to 9 Oe in a composite sheet of Y-type and Z-type fine particles (hereinafter referred to as Y-type sheet, etc.), which is smaller by one order of magnitude than the M-type sheet (90 Oe). Correspondingly, the maximum value of the relative imaginary part permeability was the maximum of 1.8 for the Y-type sheet, and it was 0.9 for the Z-type sheet, and 0.3 for the M-type sheet. As shown in Fig. 1, measured input loss ratio [4] $\mathrm {P}_{{\mathrm {loss}}}/ \mathrm {P}_{{\mathrm {in}}}=1- ( \vert \mathrm {s}_{11} \vert ^{2}+\vert \mathrm {s}_{21} \vert ^{2})$with a network analyzer (Agilent Technologies, Model N5244A) became the larger as the relative imaginary part magnetic permeability became higher. The measured $\mathrm {P}_{\mathrm {loss}}/ \mathrm {P}_{\mathrm {in}}$was as high as 0.21 at 6 GHz, which should correspond to more than 5 dB conduction noise suppression. This research was supported in part by the R&D program of the Radio Use, Ministry of Internal Affairs and Communications, and the Cooperative Research Project Program of the RIEC (H27-B05) Tohoku University.
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