Quantitative measurements of the apparent rate of reaction of wood rods undergoing fast pyrolysis by contact with a hot spinning steel disc are reported. The variations in the apparent volatilization rate and in the thickness of the reacting layer were studied as a function of disc velocity, rod diameter, contact pressure and disc temperature. The results show that the rate of reaction is mainly limited by heat transfer outside and inside the wood (ablation conditions). The external heat transfer coefficient, studied as a function of contact pressure, is much more important than the heat transfer coefficient calculated on the basis of simple radiation transfer. The conclusion is that fast pyrolysis of wood in the ablation regime can be observed if two necessary conditions are fulfilled : high available heat flux and efficient removal of the primary products of the reaction.
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