There are significantly toxic Cu contaminants in seasonal frozen soil areas under industrial production and mineral exploitation. However, the hydration reactions of mainstream alkaline curing agents such as cement are disturbed by the solidification and thawing of moisture, and their solidification/stabilization is ineffective to heavy metals. Therefore, there is an urgent requirement to optimize the use of current curing agents to improve the solidification/stabilization (S/S) effect of Cu contaminants in seasonal frozen soil areas. In this study, the Epoxy resin (EP) with excellent waterproofing and frost resistance was incorporated into artificially prepared Cu-contaminated soil to maintain a steady engineering application strength and inhibit the outward diffusion of toxic Cu contaminants under freeze-thaw cycles. The freeze-thaw resistance of EP-cured Cu-contaminated soil and the feasibility of EP remediation technology have been investigated, including mechanical properties, environmental effects and microstructure. The decline in mechanical strength and the increment in Cu leaching during freeze-thaw cycles are effectively suppressed by the remediation of EP. Even after 8 freeze-thaw cycles, there is merely a mechanical strength decline of 5%, solely a secondary Cu leaching of 4.74mg/L, and astonishingly a leachable index of 11.70 in the specimens with 12% EP dosage. The expansion phenomenon of pores and clay fractures under freeze-thaw cycles were gradually alleviated after incorporation of EP. The above results demonstrate the Cu-contaminated seasonal frozen soil remedied by EP are high-strength, basically non-toxic, and environmentally friendly material which are suitable for in-situ stabilization/solidification in seasonal frozen soil areas.
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