An investigation has been performed of the influence of contact stresses, which appear in the zone of friction of iron-manganese alloys with 16.9–40.5 wt % Mn, wear-resistant high-manganese austenitic steels, and carbon steel U13, on the phase composition, structure, and strengthening of surface layers of these materials under conditions of dry friction at small (0.03 and 0.07 m/s) sliding velocities, when the frictional heating of the surface layer of the samples is virtually absent. A quantitative estimation of the arising compressive contact stresses (pressures) has been carried out. It is shown that the value of the compressive contact stresses approximately corresponds to the values of microhardness measured on the friction surface of the materials investigated. These compressive contact stresses initiate the occurrence a γ-ɛ martensitic transformation in the iron-manganese alloys with 16–40% Mn, which is characterized by a negative volume effect, but impedes the development of the ɛ-α and γ-α martensite transformations (in austenitic steels) which occur with an increase in the specific volume. The stresses in question favor the formation of nanocrystalline structures in a thin (≤10 μm thick) surface layer of friction steels and alloys. The contact tensile stresses following the contact compressive stresses initiate the formation and propagation of microscopic cracks in the surface layer of the friction materials, and activate the development of martensitic ɛ-α and γ-α transformations in this layer. It is shown that the structural and phase transformations initiated by contact stresses exert a substantial effect on the microhardness, friction coefficient, and resistance to adhesive wear of the steels and alloys under study.
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