Forearc Peridotites Research Articles

Petrogenesis of ultramafic rocks from the Neoproterozoic Bou Azzer Ophiolite (Morocco): new insights into a long-standing geodynamic question

ABSTRACT The Neoproterozoic Bou Azzer Ophiolite, located in the Pan-African orogen of the Anti-Atlas, Morocco, exposes a well-preserved mantle section of the ophiolitic sequence. Although ultramafic rocks are the most common rock types in the sequence, they have received less attention in previous studies. In this work, we investigate the petrogenesis of these ultramafic rocks in detail, including their petrology, mineralogy, and whole rock geochemistry. The mineral assemblages are mainly formed by antigorite with minor lizardite, chlorite, and accessory Cr-spinel. The only preserved primary mantle mineral is Cr-spinel, which shows unaltered cores with Cr# between 0.61 and 0.71 and alteration rims to ferrian chromite and magnetite. Whole rock analyses indicate almost total serpentinization and, locally, strong carbonation (mass loss of ignition between 11.94 and 22.20 wt%). The non-carbonated samples preserve protolith signatures, with decreased MgO/SiO2 suggesting metasomatic processes related to serpentinization. Immobile trace elements compare well with fore-arc peridotites, while melting modelling indicates intense and polyphasic melting events. We propose polyphase melting in a subduction-initiation setting, with a first stage of 14–23% anhydrous melting, forming fore-arc basalts, and a second stage of 15–25% melting with 1 wt% H2O, forming boninites. The Bou Azzer ultramafic rocks represent the fore-arc region of a supra-subduction zone, challenging previous interpretations that suggested a back-arc position.

Gold and sulfide-bearing listvenite in the mantle section of the Tays ophiolite in the Arabian Shield, Saudi Arabia

The mantle section of the Late Neoproterozoic Tays ophiolite in the Arabian Shield consists principally of thoroughly serpentinized peridotite with characteristics typical of depleted mantle protoliths from a fore-arc environment. The serpentinite is altered along shear zones and thrust planes to gold-bearing listvenite bodies of various sizes. These bodies are divided into carbonate listvenite and silica‑carbonate listvenite; they may be dyke-like or lenticular in form, and are yellowish-brown, reddish-brown, or greyish in outcrop. Carbonate listvenite expresses schistose deformation fabrics concordant to fabric in the host serpentinite, whereas silica‑carbonate listvenite is undeformed at field scale and contains a generation of undeformed minerals at thin-section scale. Silica‑carbonate listvenite contains Cr-rich muscovite (fuchsite) and base-metal sulfides and is enriched in Zn, Pb, Cu, Ag, and Au along with SiO2. The transformation of serpentinite along shear zones to different types of listvenite reflects successive episodes of fluid-mediated metasomatism. Carbonate listvenite develops first, driven by infiltration of CO2–bearing fluids during serpentinization of the original fore-arc peridotite. Silica‑carbonate listvenite marks a later episode associated with infiltration of K-bearing, SiO2-saturated fluids released during emplacement of the ophiolite. Listvenitization in the Tays serpentinite concentrated gold in sub-economic to economic extents, with concentrations increasing from host serpentinite (2–4 ng/g) to carbonate listvenite (267–937 ng/g) to silica‑carbonate listvenite (1717–3324 ng/g).

Melting processes, cooling rates, and tectonic settings of the Neo-Tethyan mantle: the in-situ mineral chemical record

Peridotites in the Yarlung Zangbo ophiolite (YZO) have the potential to elaborate the mantle dynamics that operated below the Neo-Tethyan oceanic crust. Here, we measured major and trace element concentrations of minerals (e.g., clinopyroxene, orthopyroxene, olivine, and spinel) in YZO harzburgites and lherzolites to trace the origin and evolution of the YZO. The rare earth element (REE) patterns of clinopyroxenes in lherzolites and harzburgites plot within the field of abyssal and forearc peridotites, respectively, indicating that the latter experienced a higher degree of partial melting. Based on the relative extents of light (LREE) and heavy (HREE) REE depletions in clinopyroxene, we classified the lherzolites into two groups (I and II). The group I clinopyroxenes are depleted in HREEs and enriched in LREEs and MREEs compared to those of group II. Meanwhile, the REE patterns of harzburgite clinopyroxenes are identical to that of group II, although they display lower REE concentrations. Models based on REE abundances in clinopyroxene suggest that group I lherzolites experienced ~8–11% partial melting in the spinel domain, whereas group II lherzolites formed after 5% melting in the garnet domain followed by 6–9% and 9–16% partial melting in the spinel domain, respectively. These high degrees of melting may suggest that the harzburgites formed in a supra-subduction zone (SSZ) setting. Surprisingly, the REE-in-two-pyroxenes thermometer (TREE) shows that the YZO peridotites record high-temperature cooling at 991–1218 °C which is lower than the conditions below mid-oceanic ridges (MORs), but compatible with recent reports of high closure temperatures in forearc environments. Furthermore, our TREE results constrain the cooling rate of the YZO peridotites to ~0.01–0.5 °C/yr, overlapping with rates reported for SSZ, MOR, and abyssal peridotites. By integrating the petrological, geochemical, and thermal features, we tentatively interpret the group I lherzolites accreted in an Early Cretaceous forearc during subduction initiation, whereas the group II lherzolites and the harzburgites formed by further melting of the earlier lherzolites in a SSZ setting.

Origin of the Mussau Trench in the Western Pacific: Geochemical and mineralogical constraints from basalts and serpentinized peridotites

The Mussau Trench is apparently an incipient subduction zone. However, petrologic and geochemical evidence for the nature and origin of the Mussau Trench is lacking. We present the first mineralogical and geochemical analyses of basalts and serpentinized peridotites from the Mussau Trench. All sampled Mussau Trench basalts yield MORB-like trace-element patterns and lack the geochemical characteristics of typical arc lavas. The Dupal-type isotopic compositions of the MORB-like lavas confirm that the overriding plate shows more affiliation to the Caroline Plate than to the Pacific Plate. The Mussau Trench could have formed along a pre-existing transform fault in the Caroline Plate. Peridotites from the Mussau Trench are highly serpentinized and can be divided into two groups. Group I peridotites have low MgO/SiO2 ratios and contain talc and quartz, suggesting that they were metasomatized by SiO2-rich fluids. Group II peridotites have higher Al2O3/SiO2 ratios at a given MgO/SiO2 ratio and rarely contain talc or quartz. The peridotites in the Mussau Trench differ from typical fore-arc peridotites in the Mariana Trench; for example, the Mussau peridotites are less depleted in trace elements and have lower spinel Cr# (<0.6) than those from the Mariana Trench, suggesting that they originated in the lithosphere of the Caroline plate. The temperatures (<688 °C) and pressures (<7.3 kbar) estimated using amphibole compositions (dominantly edenite and pargasite) suggest that the peridotites were serpentinized by high-temperature slab-derived fluids. Although the limited plate convergence at the Mussau Trench was insufficient to cause arc magmatism, subducted slab-derived fluids caused serpentinization of the overriding lithospheric mantle in an infant subduction channel. Therefore, the serpentinized peridotites and basalts in the Mussau Trench provide important information on the marks and processes of intra-oceanic subduction initiation.

Mineral and whole-rock geochemistry of high-Al podiform chromitites in the Fizh Massif of the Cretaceous Oman ophiolite: origin of hydrous N-MORB melts in a nascent forearc setting

The Oman ophiolite is one of the largest and best exposed ophiolites in the world and has &gt;450 chromitite deposits. We report here a newly identified chromitite deposit in the Wadi Rajmi, Oman. This deposit occurs within a dunitic envelope, which is surrounded by harzburgite, and consists of both massive and disseminated chromitite types. The Rajmi peridotites represent depleted upper mantle rocks that underwent &gt;20% partial melting and experienced metasomatism by melts and fluids derived from a subducting slab. They demonstrate geochemical affinities similar to those of the Izu–Bonin–Mariana forearc peridotites, supporting their formation in a forearc environment. The Rajmi chromitites have low Cr# values and are classified as high-Al chromitites. They have geochemical compositions comparable with those of chromitites crystallized from mid-ocean ridge basalt (MORB)-type melts. However, the chromites in these high-Al chromitites contain various silicate inclusions (e.g. amphiboles and micas), indicating the hydrous and atypical MORB nature of their parental magmas. Combined with the mineralogical and geochemical characteristics of the country rocks, we posit that the parental melts of the Rajmi high-Al chromitites have a MORB-like affinity derived from partial melting of a nascent forearc mantle. Supplementary material: The whole-rock and mineral data of the Rajmi harzburgites, dunites and chromitites are available at https://doi.org/10.6084/m9.figshare.c.6795689 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

Fluid‐Mantle Interaction Along the Mariana Convergent Margin

AbstractActive serpentinite mud volcanoes in the forearc region of the Izu‐Bonin‐Mariana system represent an excellent natural laboratory for studying the geochemical processes along convergent plate margins and the associated forearc. During IODP Expedition 366, serpentinite mud with lithic clasts from the underlying forearc crust and mantle as well as from the subducting Pacific Plate was recovered. Ultramafic clasts from Fantangisña Seamount reveal very high degrees of serpentinization with mesh and bastite textures as well as development of late lizardite and chrysotile veins, which suggests serpentinization temperatures below 200°C. On the other hand, recovered harzburgites and, on occasion, dunites from Asùt Tesoru Seamount show a well‐preserved primary assemblage with low degrees of serpentinization and forearc peridotite characteristics. Fine‐grained antigorite associating with lizardite has been identified throughout the serpentine mud matrix, suggesting an alteration temperature of c. 340°C. Furthermore, alteration conditions during rodingitization point to temperatures of at least 228°C, estimated via chlorite geothermometry. Additionally, a rare ophicarbonate clast containing andraditic as well as Cr‐rich hydrogarnets from Asút Tesoru Seamount indicates crystallization temperatures of at least 230°C. Hence, a trend of lower temperature of serpentinization and higher degree of alteration closer to the trench. The detailed characterization of the fluid‐rock alteration conditions as well as fluids composition and transport permits a better constraining of the fluid–rock interactions and related mass transfers within subduction zones and during ascent of serpentinite fault gouge within mud volcano conduits and in mudflows after their emplacement on the flanks of the edifices.

The water-poor and reduced mantle beneath the Neo-Tethys Ocean: Tectonic setting of the western Yarlung-Tsangpo ophiolites

Water contents and deformation behaviors of minerals in mantle peridotites are diagnostic features to distinguish the physical conditions between mid-ocean ridges and subduction zones, which could serve as effective indicators for discriminating the tectonic setting of ophiolites. In this study, we report a systematic dataset of petrology, geochemistry, water contents and deformation behaviors for the mantle peridotites from the Cuobuzha ophiolite in the western Yarlung-Tsangpo suture zone (YTSZ), southern Tibet, to provide new insights into the long-standing debate for the tectonic setting of ophiolites therein. Geochemical data revealed that the Cuobuzha mantle peridotites experienced low to moderate degrees of partial melting (∼10–15%), although some harzburgites have been intensively modified by late-stage melt-rock interactions. The Cuobuzha peridotites, on the other hand, are characterized by low orthopyroxene water contents (46–95 wt ppm in average), clear olivine crystallographic preferred orientations of A- and E-types, and low oxygen fugacity (logfO2, QFM −2.55 to −0.81, where QFM means quartz-magnetite-fayalite buffer), thus indicative of the occurrence of high-temperature, water-depleted, and reduced mantle in this ophiolite. The features above of the Cuobuzha mantle peridotites are quite similar to those of abyssal peridotites at modern mid-ocean ridges and systematically different from the relatively refractory, water-rich, and oxidized characteristics typical of forearc peridotites in suprasubduction zones. Based on the data from this study and a compiled dataset for other ophiolites from the western YTSZ, we revealed that mantle peridotites with a water-poor and reduced nature are common in these ophiolites, thus providing strong evidence supporting for their origination from a mid-ocean ridge of a mature ocean basin. From the perspective of mantle peridotites, the ophiolites in the western YTSZ now geographically distributed in two branches (i.e., the northern and southern sub-belts) might have formed in a single ocean basin of the Neo-Tethys and were dismembered by late-stage tectonic events to their current locations.

Geochemistry and Mineralogy of Peridotites and Chromitites from Zhaheba Ophiolite Complex, Eastern Junggar, NW China: Implications for the Tectonic Environment and Genesis

The Zhaheba ophiolite is an ocean relic of the Zhaheba-Aermantai oceanic slab, a branch of the early Paleozoic Paleo-Asian Ocean. The peridotites consist mainly of harzburgite, lherzolite and minor dunite, chromitite. This study describes the whole-rock geochemistry and mineral chemistry of the Zhaheba peridotite and chromitite for the purpose of constraining their tectonic environment and genesis. The major oxides and the trace element concentrations of the peridotites are comparable with abyssal peridotite, but fall outside the field of SSZ (suprasubduction zone) peridotite and the fore-arc peridotite. The massive chromites belong to the high-Cr group, with an average Cr# (Cr/(Cr + Al)) atomic ratio) value of chromian spinel of 0.77, whereas the average Mg# value is 0.60. The disseminated chromites give a lower concentration of Cr2O3 (38.96–42.15 wt.%, average 40.35 wt.%) and lower Cr# values (0.50–0.56, average 0.53), but slightly higher contents of MgO (13.23 wt.%) and Mg# (0.61) than the massive chromites. In the diagrams of Cr#-Mg#, NiO-Cr# and TiO2-Cr#, the massive chromites fall in the field of boninite, and the disseminated chromite in the peridotite plot fall in the field of abyssal peridotite and mid-oceanic ridge basalt (MORB). The massive chromitites, with high-Cr, display a boninite affinity, whereas the disseminated chromite plot in the high-Al and abyssal peridotite type field may be generated by the extension of the Zhaheba ocean in the MOR environment then experienced deep subduction and exhumation. The calculated degrees of partial melting for the massive chromites are 21%−22%, and for the disseminated chromites in peridotites the degrees are 17%−18%. The calculated values of fO2 for the massive chromites range from −1.44 to +0.20, and the values for the disseminated chromites range from −0.32 to +0.18. The inferred parental melt composition for massive chromitite falls in the field of boninite in an arc setting, whereas the disseminated chromite in peridotites are in the field of a MORB setting. This indicates that the parental magmas of the former were more refractory than the latter. A two-stage evolution model for the chromites was proposed, in which disseminated chromites were first formed in an MOR environment and then modified by later-stage melts and fluids, and formed massive chromites were formed in an SSZ setting during intra-oceanic subduction.

Origin and evolution of Neoproterozoic metaophiolitic mantle rocks from the eastern Desert of Egypt: Implications for tectonic and metamorphic events in the Arabian-Nubian Shield

The mantle rocks from Kadaboura and Madara areas represent sections of dismembered ophiolitic complexes developed during the Neoproterozoic in the Eastern Desert of Egypt, which is located in the northwestern corner of the Arabian–Nubian Shield. The Kadaboura mantle rocks comprise serpentinites and serpentinized dunites, whereas those of the Madara consist of serpentinites and serpentinized pyroxenites.Despite the serpentinization of the studied mantle rocks, few relicts of primary chromite, olivine and pyroxene are preserved. Chromite is partly altered having unaltered Al-rich chromite cores surrounded by Fe-rich chromite and Cr-rich magnetite rims. The unaltered Al-rich chromite cores show compositions equilibrated at temperatures mostly below ~500-600°C, which is a temperature comparable to that estimated for primary chromite in greenschist up to lower amphibolite facies rocks. The high Cr# [100×Cr/(Cr+Al)= 47-76] of the unaltered chromite cores and the Mg-rich nature of the olivine relicts (Fo91–94) indicate that the studied mantle rocks were produced from a highly depleted mantle that experienced high degrees of melt extraction (mostly ~30-40%). This range of melt extraction resembles that estimated for supra-subduction zone peridotites, but higher than that in abyssal and passive margin peridotites. Furthermore, the clinopyroxene relicts show compositions comparable to those from the Mariana forearc peridotites. Bulk-rock geochemistry also reflects derivation from an extremely depleted and a highly refractory mantle source. Modelling of rare-earth elements suggests that the studied mantle rocks were possibly formed by the interaction of their highly depleted harzburgitic mantle precursors with subduction-related melts/fluids during their evolution in a fore-arc basin of the supra-subduction zone.The proposed geodynamic model suggests that the oceanic lithosphere generated during the seafloor spreading of the Mozambique Ocean was emplaced in the upper plate of the intra-oceanic subduction zone, in which the formely depleted Neoproterozoic mantle of the Arabian-Nubian Shield experienced mature phases of hydrous melting, extreme depletion and enrichment.

Arc signatures in abyssal peridotites and its implications

Investigating mass exchanges between the subduction zones and mid-ocean ridges provides essential clues to understanding recycling process and mantle convection in the Earth's mantle. In this study, we found evidence of recycled subduction signals in the abyssal peridotites from mid-ocean ridges through their extremely low bulk (Dy/Yb)N and bulk Al2O3, which could not be explained by normal decompression melting at mid-ocean ridges, but required a hydrous melting history. We show here that abyssal peridotites from the fast-spreading Pacific Oceanic Ridges (East-Pacific Rise and Pacific-Antarctic Ridge), to the ultraslow-spreading Southwest Indian Ridge and to the slow-spreading Mid-Atlantic Ridge, require increasing amount of slab-derived fluid in their mantle sources. Therefore, the subduction influence on abyssal peridotites is independent of the spreading rates of the overlying ridges. Locations, such as the Fifteen-Twenty Fracture Zone, the Rainbow Massif from the MAR and the Hess Deep from EPR, have abyssal peridotites overlap well with forearc peridotites, suggesting that the prominent characteristics of arc mantle wedge could be preserved in abyssal peridotites when the traveling distance or time is short for the recycled arc mantle migrating in the mantle convection flow. The well-preserved subduction-related signature in ridge areas that are relatively proximal to modern subduction zones imply that mass exchanges between the subduction zones and mid-ocean ridges may be more efficient than previously thought.

Relict abyssal mantle in a Caribbean forearc ophiolite (Villa Clara, central Cuba): petrogenetic and geodynamic implications

ABSTRACT The ophiolitic Villa Clara serpentinite-matrix mélange, central Cuba, forms part of the large ophiolitic belt of the Greater Antilles. The composition of ultramafic and mafic rocks allows classifying them into two main groups, revealing a complex multi-stage formation of oceanic lithosphere in varied tectonic settings: i) group 1 matches fertile MORB-like mantle typical of abyssal/transform fault peridotites, while ii) group 2 shows characteristics of refractory mantle-wedge forearc peridotites. These features are consistent with moderate extent of partial melting (4–8%) of depleted mantle at a mid-ocean ridge setting that created residual abyssal peridotite (group 1) and intense remelting (14–18%) of the latter in a forearc setting that created highly refractory peridotite (group 2). The elemental and isotopic characteristics of groups 1 and 2 serpentinites denote the influx of fluids evolved from the subducting slab. Mafic rocks appear as variably sized tectonic blocks within serpentinite that underwent variable alteration at low pressure. Immobile element concentrations allow identifying two main groups: i) group 1 is consistent with forearc basalts formed during the second stage of melting of (abyssal) peridotite, while ii) group 2 has a compositional pattern like island-arc tholeiitic basalts. A geodynamic evolution from abyssal to forearc settings is presented to explain the nature of the oceanic lithosphere of the Villa Clara ophiolitic bodies and ensuing serpentinization and mélange formation. This model may explain other ophiolitic bodies of the Caribbean arc in Cuba, Dominican Republic and Puerto Rico and elsewhere formed in abyssal/transform fault or forearc settings.

Geochemistry of Waziristan Ophiolite Complex, Pakistan: Implications for Petrogenesis and Tectonic Setting

The Waziristan ophiolite complex (WOC), a segment of paleo-suture zone between the Indo-Pakistan plate to the south-east and the Afghan microplate to the north-west, is primarily composed of serpentinized dunites and serpentinites after harzburgites, crosscut by pyroxenites. The crustal portion dominantly comprises basalts and dolerites, with less abundant plagiogranites. Whole-rock XRF and trace element ICP-MS analyses were undertaken to determine the degree of melt extraction and subsequent geochemical depletion or enrichment of peridotite protoliths. The investigated peridotites are extremely refractory and show high Mg# values (0.88–0.92), low Al2O3 (0.19–0.96 wt%), total alkali values (0.02 &lt; Na2O + K2O ≤ 0.20 wt%), CaO (0.04–0.73 wt%), and TiO2 (0.001–0.017 wt%), but are rich in Cr (up to 3550 ppm) and Ni (up to 2340 ppm). Bulk REE modelling suggests that Waziristan peridotites underwent a high degree (15%–25% melting) of melt extraction in the closed system of spinel-bearing peridotite facies at shallow depths above a subduction zone and, in their chemistry (Sc, REE, Al2O3, and MgO), resemble Izu-Bonin-Mariana (IBM) forearc peridotites. Their U-shaped REE patterns and trace elements resemble peridotites derived from supra-subduction zone (SSZ) settings, especially a forearc setting, and also reflect metasomatism by slab-derived fluids. The ultramafic rocks preserve depletion in REE content (0.03 &lt; ΣREECN &lt; 0.60), indicating the highly depleted nature of refractory peridotites. The basalts (Mg#, 0.48-0.68) are similar in composition to typical boninite and show low to moderate MgO (6.2–13.0 wt%), low total alkali content (0.01–4.45 wt%) and TiO2 (0.13–0.17 wt%), but are higher in Al2O3 (≈11.9 wt%). They show a sub-alkaline affinity and possess geochemical signatures that are transitional from island arc basalt (IAB) magmas to boninitic magmas due to the changes from an extensional to a compressional regime during the initiation of subduction. These geochemical signatures suggest the formation of basalts from melts, resulting from the re-melting of the depleted mantle during intra-oceanic subduction initiation. The higher Th/Nb and V/Ti ratios of the studied basalts further confirm their generation in an SSZ setting characterized by subduction-derived fluids under higher oxidizing conditions. The mafic-ultramafic rocks of the WOC were, therefore, likely formed during intra-oceanic subduction initiation (forearc spreading) in the SSZ setting; they were exhumed along a thrust fault, and obducted onto the forearc region as result of the collision between the Indian plate and the Afghan microplate.

Abyssal and forearc features of mantle peridotites in the Guleman ophiolite in SE Turkey

The mantle section of the Guleman ophiolite consists mainly of depleted harzburgite and dunite with some less depleted harzburgite, all of which contain economically significant chromitite. The depleted harzburgite and dunite are characterized by low average bulk Al2O3 (<0.85 wt%) and CaO (0.14–0.94 wt%) contents, high-Mg olivine (Fo = 90.8–93.8) and orthopyroxene (Mg# = 91.3–92.1) together with moderately high-Cr spinel (Cr# = 54.1–67.6). The less depleted harzburgite (sample EG30) contains higher bulk Al2O3 (1.84 wt%) and CaO (2.15 wt%) contents, slightly lower-Mg olivine (Fo = 90.4) and orthopyroxene (Mg# = 90.4) together with lower-Cr spinel (Cr# = 17.9) and clinopyroxene with high Al2O3 (2.79 wt%) and similar TiO2 (0.05 wt%) contents. The 187Os/188Os isotopic ratios of the Guleman peridotites are 0.12589, 0.12736 and 0.13352, coupled with 187Re/188Os ratios of 0.32822, 0.90743, and 1.48804, respectively, for the dunite and depleted harzburgite These data suggest that the Guleman peridotites were modified by melt metasomatism and/or Re addition. Petrographical and geochemical results reveal that mantle peridotites experienced multi-stage melting and refertilization. In the first stage, abyssal peridotites were formed by ∼15% partial melting of an upwelling mantle at a mid-ocean ridge under anhydrous conditions, which was followed by the second stage of partial melting in a supra-subduction zone environment under hydrous conditions. In this later stage, forearc peridotites were formed with a total of 25–43% partial melting for the two episodes and then refertilized. However, some of the peridotites were unaffected (or less affected) by these later events. As a result, abyssal and forearc peridotites are both observed in the Guleman ophiolite.

Genesis and evaluation of heavy minerals in black sands: A case study from the southern Eastern Desert of Egypt

Black sands in the southern Eastern Desert (SED) of Egypt contain substantial reserves of heavy minerals (up to 5 %), and are found mainly in three basins namely: Hodein, Ibib and Diit between Shalateen and Halayeeb cities. The heavy minerals in these black sands include ilmenite-leucoxene (31 %–44 %), magnetite (15–18 %), zircon (11–21 %), garnet and green silicates (11–15 %), rutile (6–12 %) and monazite (2–4 %). Cassiterite, thorite, uranothorite, gold, xenotime and chromian spinel are minor quantities (<1 %). Magnetite (FeO: 75–93.5 wt%) and ilmenite (TiO2: 42.7–56.9 wt%), hosting high Mn, V, Zr, Zn, Cr, Nb and Co, were probably derived from gabbroic rocks. The detrital chromian spinel composition (Cr#, 0.51–0.61; Mg#, 0.5–0.63; TiO2 < 1.0 wt%) and its morphology are similar to those of spinels in fore-arc peridotites from the SED of Egypt, suggesting dominance of fore-arc basins for peridotite emplacement. These basins were formed during arc-arc or arc-oceanic crust collision and encolsed ophiolites, gabbroic rocks and I-type granites as sources of the SED black sands. The studied garnets are mostly almandine in composition with few grossularite and spessartine; they might have been derived from I-type granites and gneisses sources. The rutile and monazite show enriched LREE relative to HREE, and display marked defeciency in Eu, suggesting highly fractionated granitic rocks as a main source. Two distinct types of zircon are recorded: radioactive (Hf: 1578–8770, Y: 319–1335, U: 36–114 and Th: 40–64 ppm) and non radioactive (Hf: 427, Y: 44, U: 2 and Th: 2 ppm); they were probably derived from different granitic sources. Compositions and P-T conditions (T: 655–970 °C, P: 1.18–9.53 kbar) of magmatic amphiboles are similar to those derived from I-type granitoids. Bulk analyses of the economic heavy mineral assemblages show significant concentrations of Fe (393 kg/ton), Zr (183 kg/ton) and Ti (129 kg/ton) with minor Cr (14 kg/ton), Ba (7 kg/ton), Hf (4.9 kg/ton), Th (up to 3.34 kg/ton) and U (0.29 kg/ton). The elevated contents of Th and U could be related to the occurrence of monazite and zircon with subordinate thorite, uranothorite and xenotime. The total REE contents of these bulk analyses range from 1 to 4 kg/ton, where LREEs form 80–90 % of total REEs. Monazite (ΣREEs: 443604 ppm on average), garnet, zicon (ΣREEs: 421 ppm) and rutile (ΣREEs: 309 ppm) are the main host of REEs in the investigated black sands. Tonnages of raw sands, to a depth of one meter, are estimated per 10 km2 in each basin, giving 18 million tons for Ibib basin and 19 million tons for both Diit and Hodein basins. Economic heavy minerals constitute 6–26 % of the total heavy minerals and around 1.0 % of total raw sands. Calculated reserves of these economic minerals, per 10 km2 of black sands, range from 0.1 million ton in Ibib and Hodein basins to 0.2 million ton in the Diit basin.

Mineralogy and geochemistry of serpentinized peridotites of the Northern Nubian Shield: The origin of compositionally banded olivine and implications for Neoproterozoic supra-subduction zone metasomatism

A sequence of Neoproterozoic ultramafic rocks — serpentinized peridotite, serpentinite, and clinopyroxenite — outcrop in Wadi El-Mireiwa in the south Eastern Desert of Egypt. They represent the mantle and lowermost crustal section of a fragmented ophiolite, emplaced by thrusting above metasedimentary rocks and an island arc assemblage and later intruded by a granite mass. In samples of the serpentinized peridotite, back-scattered electron images of olivine reveal banded zoning, defined by straight and parallel Mg-enriched (Fo ∼ 96) lamellae within typically magnesian host crystals (Fo ∼ 89). The presence of clinopyroxene, the relatively low whole-rock Mg# (∼88), the low NiO content of olivine (0.1–0.32 wt%), and the relatively high TiO2 content of fresh Cr-spinel (∼0.3 wt%) are all consistent with a cumulate origin for the serpentinized peridotite and serpentinites. On the other hand, some associated serpentinite has higher whole-rock Mg# (92) and low TiO2 in Cr-spinel (∼0.01 wt%), consistent with a residual origin by high-degree melt extraction in the fore-arc region of a supra-subduction zone (SSZ) environment. The formation of Mg-enriched bands in olivine is attributed to the enhancement of metasomatic Mg-Fe exchange with high-Mg/Fe2+ fluids along crystallographically-oriented subgrain boundaries produced by high strain-rate dislocation creep. Such high-Mg/Fe2+ fluid metasomatism also explains reverse zoning of MgO in Cr-spinel, whereas the low whole-rock concentrations of REE and other trace elements exclude a significant role for melt-rock interaction. The evidence for high-Mg/Fe2+ fluid metasomatism in this suite indicates that SSZ fluids and high fore-arc strain rates affect not only the mantle wedge but also overlying ultramafic cumulates. The oxygen fugacity [ΔlogƒO2(FMQ)] values calculated from unmetasomatized (+2.48 to +2.67) and metasomatized (+3.75 to +4.53) samples reflect the oxidized nature of Neoproterozoic SSZ magma and the even more oxidizing character of the metasomatic fluids. Banded zoning has also been recorded in olivine from Mariana fore-arc peridotite and Phanerozoic SSZ ophiolites; the Neoproterozoic Wadi El-Mireiwa case shows that rapid mantle flow has been a persistent feature of the tectonic environment where fore-arc ophiolites develop.

The heterogeneous mantle massif in south Tibetan ophiolites and its implication for the tectonic evolution of Neo-Tethys

Ophiolitic mantle peridotites show large variations in their geochemical compositions, which provide important information for the histories of mantle melting, melt metasomatism and prior melt depletion in the context of tectonic evolution of ancient oceans. Here we report new petrological and geochemical data for mantle peridotites from the Zhagabu ophiolite in south Tibet, which could represent fossil upper mantle of the Mesozoic Neo-Tethys oceanic lithosphere. The Zhagabu mantle peridotites, including spinel lherzolites and spinel harzburgites, have highly heterogeneous geochemical compositions, with whole-rock Al2O3 of 0.3–2.0 wt% and CaO of 0.3–2.2 wt%, and spinel Cr# [Cr/(Cr + Al)] of 0.21–0.74 and Mg# [Mg/(Mg + Fe2+)] of 0.44–0.74. The clinopyroxenes from the studied samples show extremely depletion in light rare earth element compositions, some of which however are elevated by post-melting melt-rock interactions. Spinel and clinopyroxene compositions collectively suggest that the Zhagabu mantle peridotites have experienced ~9–20% of fractional melting from a depleted mid-ocean ridge basalt mantle source. Trace element modeling of clinopyroxenes further indicates that some of the studied samples follow the refertilization-hydrous melting trends with variable fluid fluxes. Therefore, the heterogeneous compositions of the Zhagabu mantle peridotites are not comparable to those of either abyssal peridotites or forearc peridotites, but most probably record a dynamic transition from the anhydrous condition beneath the Neo-Tethyan mid-ocean ridge to the hydrous condition above the subducted slab. Considering that a forearc spreading is in contradiction with the low magma budget of Yarlung Zangbo ophiolites, the Neo-Tethyan subduction re-initiation was suggested to be achieved along oceanic detachment faults at ultraslow-spreading ridges. The Zhagabu mantle peridotites represent the very heterogeneous mantle massif in south Tibetan ophiolites, and provide an excellent window to investigate the complex mantle dynamics and tectonic evolution of the Neo-Tethys Ocean.

Ultramafic Rocks and Their Alteration Products From Northwestern Allaqi Province, Southeastern Desert, Egypt: Petrology, Mineralogy, and Geochemistry

The ophiolitic rocks, island arc metasediments, and granitic rocks are encountered in the study of the Allaqi province. The present study concentrated on ultramafic rocks and their various forms of hydrothermal alteration. Ophiolites commonly occur as dismembered rock sequences and have different types of hydrothermal alteration products. Ophiolites contain the essential type as serpentinites and talc-carbonate rocks, listwaenites, and amphibolites along shear zones and faults. Listwaenite is one of the most significant rocks in this area because it contains gold. The whole serpentinite rocks are affected by regional metamorphosis into greenschist facies. Geochemically, Neoproterozoic serpentinites fall into SSZ ophiolites, alpine-type peridotite, formed in the forearc peridotite tectonic environment. Regardless, the listwaenite and talc-carbonate rocks revealed that they trend to silica, carbonate, and talc. Listwaenites are classified into two types: carbonate-rich listwaenites and silica–carbonate-rich listwaenites. Magnetite, chromite, galena, and gold are the most typical ores recorded in this research.

Petrogenesis of the East Hoerba harzburgites, SW Tibet: Implications for melt stagnation in the lithospheric mantle of Neo-Tethys

In this study we present petrographic and compositional data for harzburgites from the eastern parts of the Hoerba Massif of the Yarlung-Zangbo Suture Zone (YZSZ), SW Tibet. These harzburgites are cross cut by semi-ductile mylonitic zones. The investigated rock samples contain aggregates of unstrained clinopyroxene with tapered edges. They also contain olivine with a high forsterite [Fo# = Mg/(Mg + Fe) × 100] content (89.3–91.8), orthopyroxene with a low Al 2 O 3 content (2.0–5.6 wt%), and clinopyroxene porphyroclasts with Cr 2 O 3 contents between 0.2 and 1.0 wt% and low lanthanide contents. Chromian spinel (Cr-spinel) in the East Hoerba harzburgites has low Cr# [100 × Cr/(Cr + Al)] and high Mg# [100 × Mg/(Mg + Fe)] values (23.7–39.2 and 62.2–76.3, respectively). These harzburgites have chondrite-normalized rare earth element (REE) patterns characterized by enrichments in the light (L-)REE and positive slopes from the middle to the heavy REE. Semi-quantitative geochemical modeling demonstrates that the bulk-rock compositions of the East Hoerba harzburgites differ from those of typical abyssal and forearc peridotites. Clinopyroxene trace element modeling suggests that the East Hoerba harzburgites initially underwent melting below a mature spreading center, followed by melting in the mantle wedge above a Cretaceous Neo-Tethyan subduction system. Enrichment of the harzburgite samples in LREE is interpreted as due to post-melting entrapment of small volumes of a LREE-rich melt in the lithospheric mantle. We suggest that the East Hoerba harzburgites are sub-oceanic peridotites that underwent melt depletion events and melt stagnation before their exhumation at the Neo-Tethyan seafloor. • The East Hoerba Massif is composed of variably depleted harzburgites. • They were formed from mantle depletion events and post-melting magma stagnation. • They were generated beneath a transitional arc–back-arc setting. • They do not represent fragments of old sub-continental lithospheric mantle.

Petrogenesis of arc-related serpentinized peridotites (Egypt): Insights into Neoproterozoic mantle evolution beneath the Arabian-Nubian Shield

• Two ophiolitic peridotites in the SE Desert of Egypt provide a window into the Neoproterzoic mantle. • Geochemistry of peridotite and its mineral chemistry suggest an origin in the arc-related setting. • SED peridotites are refractory mantle residues (25–40% melting), like modern fore-arc peridotites. • Geochemical aspects of peridotite indicate changing from extension during subduction initiation. Korab Kansi and Abu Dahr Neoproterozoic ophiolitic peridotites in the Southern Eastern Desert (SED) of Egypt, are parts of the largest ophiolitic nappes in the Arabian-Nubian Shield. They mainly comprise refractory harzburgites with minor dunites that are commonly altered to serpentinites and talc carbonates. Olivine relics in serpentinized peridotites of the two complexes have olivines with high forsterite (Fo 90.6-92.2 ) and NiO (0.39 wt%) and low MnO (0. 13 wt%) contents, similar to those of mantle olivines. High Mg# (0.91–0.95) of orthopyroxene is consistent with that of depleted harzburgites. Primary spinel Cr# (0.55–0.75) and TiO 2 contents (<0.04 wt%) of the two peridotite complexes are similar to forearc peridotite spinels. The estimated degree of partial melting of Korab Kansi peridotites (25–40% melting) is slightly lower than that of Abu Dahr (30–40% melting), consistent with modern forearc peridotites. Korab Kansi peridotites exhibit lower oxygen fugacity (Δlog ƒO 2 , FMQ + 0.7 on average) and equilibrium temperature (610–710 °C) than those of Abu Dahr ( T , 750–900 °C at Δlog ƒO 2 , FMQ + 2.1), both suggesting subduction-modified peridotites. The low concentrations of incompatible elements, U-shaped REE patterns and high spinel Cr# of both peridotites indicate highly depleted mantle protoliths, reflecting multiple metasomatic and melting episodes in the mantle wedge. Enrichment of fluid mobile elements (e.g. B, Li, Th, U, Pb) relative to high-field strength elements (e.g. Nb, Ta, Ti, Zr) may reflect interaction between slab-derived fluids and peridotites. Calculated parental melts in equilibrium with Korab Kansi and Abu Dahr peridotite spinels have tholeiitic (MORB-like) and boninitic affinities, which were generated during proto-forearc spreading to a mature arc stage. Variations in melt compositions suggest a transitional setting from early proto-forearc spreading of mantle beneath Korab Kansi to the mature arc stage of Abu Dahr peridotites. Subduction initiation possibly started in the W and/or SW with proto-forearc spreading, and progressed to the E and/or NE where a mature arc stage with boninitic melts above an E- and/or SE-dipping subduction zone.

Peridotites with back-arc basin affinity exposed at the southwestern tip of the Mariana forearc

Peridotites at water depths of 3430 to 5999 m have been discovered using the submersible Shinkai6500 (dives 6K-1397 and 6K-1398) on the southwestern slope of the 139°E Ridge (11°12′N, 139°15′E), a small ridge at the southwesternmost tip of the Mariana forearc near the junction with the Yap Trench and Parece Vela Basin. The peridotites studied consist of 17 residual harzburgites and one dunite and show various textures with respect to their depths. Peridotites with coarse-grained (> 1 mm) textures were sampled from the shallowest part (3705–4042 m) of the dive area, and peridotites with fine-grained (< 0.5 mm) textures were sampled deeper (5996 m). Olivine crystal-fabrics vary with grain size, with (010)[100] A-type patterns for the coarse-grained peridotites, {0kl}[100] D-type patterns for the fine-grained peridotites, and various indistinct patterns in samples of variable grain sizes. Fine-grained peridotites with D-type olivine crystal-fabrics could result from deformation under relatively higher flow stresses, suggesting that a ductile shear zone in the lithospheric mantle could occur in the deepest part of 139°E Ridge. Spinel Cr# range from relatively low (0.36) to moderately high (up to 0.57), and correlate with Ti contents (0.07–0.45 wt.%). The trace element patterns of clinopyroxene similarly exhibit steepening slopes from the middle to the light REEs regardless of textural variations. These mineralogical and geochemical features would result from melt-rock interactions under conditions of relatively shallow lithospheric mantle, which are much more comparable with the Parece Vela Basin peridotites than the Mariana forearc peridotites. Consequently, the Parece Vela Basin mantle is more likely exposed on the inner slope of the westernmost Mariana Trench, presumably due to the collision of the Caroline Ridge.