Microfluidic chips represent visualization-enabled miniaturized analytical platforms that serve as powerful investigative tools for multiscale process characterization, enabling multiscale analysis from pore-level processes to macroscopic system behaviors. These systems provide high-resolution insights into fluid–rock interactions within geological formations, where multiphase flow dynamics and biogeochemical processes fundamentally control hydrocarbon recovery efficiency and subsurface storage performance. At the microscale, fluid–solid interfacial phenomena dictate multiphase displacement mechanisms across diverse lithologies, while microfluidic platforms accurately replicate subsurface flow conditions in hydrocarbon reservoirs, coal seams, and gas-bearing formations through geometrically constrained microenvironments. This review systematically examines the technological implementation of microfluidic chips in subsurface reservoir engineering, specifically categorized into four strategic areas: geological carbon sequestration, underground hydrogen storage, gas hydrate/coalbed methane extraction, and enhanced oil recovery. Across these applications, microfluidic systems primarily function to decode immiscible fluid displacement physics under reservoir-relevant conditions. Systematic investigations have identified critical governing factors including interfacial wettability, viscosity contrast, injection dynamics (flow rate/pressure), thermodynamic conditions, pore-throat geometry, surface morphology, reservoir heterogeneity, and microbial mediation. Integration of these microscale findings enhances predictive capabilities in macroscopic simulations such as core flooding experiments and reservoir-scale flow modeling, ultimately advancing strategic optimization of energy resource management and environmental sustainability at engineering-relevant scales. Meanwhile, microchips face challenges such as scale mismatch and limited material performance in actual geological simulations. In the future, technological innovation in the field of energy geology can be promoted by developing high-performance chip materials and establishing multiscale coupling experimental platforms.
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