Fires pose significant risks, leading to loss of life, property, and cultural heritage. Conventional fire protection materials encounter challenges in efficiency and intelligent monitoring, compounded by secondary hazards such as falls and impacts. Hence, there's increasing demand for innovative protective materials that combine robust mechanics, fire suppression, and advanced detection. In this study, we explore the use of reduced graphene oxide (rGO)-modified 3D spacer fabrics as a reinforcing phase within a polyvinyl alcohol (PVA)/glycerol organohydrogel (OHG) matrix, forming a novel 3D fabric-reinforced anisotropic composite OHG. This multifunctional composite OHG exhibits outstanding mechanical strength, environmental stability, enhanced flame retardancy, and smart sensing properties. The integration of fabric reinforcement significantly improves the OHG's compressive and impact resistance. The composite OHG's anisotropic structure, in conjunction with the OHG matrix, greatly enhances flame retardancy, while its dual electronic and ionic conductivities improve overall electrical performance. This synergy enables real-time compression monitoring with high sensitivity and stability, facilitated by a Bluetooth module for wireless impact event recording. Furthermore, the composite OHG's anisotropic thermal conductivity enables a thermoelectric effect, leading to self-powered fire alarm systems. This pioneering approach introduces multifunctional smart OHG composite with synergistic capabilities, offering novel prospects for advanced protection and smart firefighting applications.
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