Textile Finishing Research Articles

Dyeing and Performance Testing of Chitosan-Modified Cotton Fabrics with Tea Polyphenols

Abstract Tea polyphenols are one of the primary components of tea leaves and possess various beneficial effects, including radiation resistance, detoxification, antioxidation, antibacterial properties, anti-aging effects, digestive support, anti-cancer properties, and immune system enhancement. This study focuses on utilizing tea polyphenols for the functional finishing of chitosan-modified cotton fabrics, with the aim of developing an environmentally friendly and efficient green functional finishing process. The analysis reveals that the optimal dyeing parameters for cotton fabrics modified with chitosan and using a mass fraction concentration of 3% tea polyphenols are as follows: a pH value of 7, temperature of 50°C, dyeing time of 60 minutes, and a tea polyphenol o.w.f concentration exceeding 6%. Under these processing conditions, the chitosan-modified cotton fabrics demonstrate excellent colorfastness to sunlight, water, and friction, all exceeding grade 4. Furthermore, they exhibit good antibacterial properties, UV protection, and odor resistance, making them highly practical.

Antimicrobial and UV protection finishing of cotton fabric with copper nanoparticles synthesized using S.cumini leaf extract

Antimicrobial and UV protection finishing of cotton fabric with copper nanoparticles synthesized using S.cumini leaf extract

Antibacterial finishing of compression fabrics based on Ti3C2Tx-APTES material

Patients with hyperplastic scarring need to wear compression garments for long periods of time during treatment with compression therapy. Compression garment fabrics (CGFs) are prone to bacterial growth during use, leading to patient infections. It is essential to apply antibacterial functional finishing to the CGFs. In this study, antibacterial CGFs based on Ti3C2Tx and amino-functionalized silane coupling agent (3-aminopropyl) triethoxysilane composite material (APTES) were prepared by dip-coating method. The binding mechanism between the Ti3C2Tx-APTES and the CGF was explored, and the antibacterial rate, wash fastness, and wearability of the antibacterial fabric were investigated. The addition of APTES resulted in the formation of covalent bonds between the CGF and the antibacterial agent. The unwashed CGF exhibited antibacterial rates of 99.9% against Staphylococcus aureus (S. aureus, AATCC 25922) and 99.76% against Escherichia coli (E. coli, AATCC 6538), respectively. The wash fastness of antibacterial CGF met industry standard AA level, and the wearability of the treated fabric could basically satisfy daily wear requirements. The Ti3C2TX-APTES antimicrobial CGF prepared in this study provides an effective solution for the development of antimicrobial fabrics for sports and medical applications.

Carbon Footprint for Jeans’ Circular Economy Model Using Bagasse

To date, clothing has been produced and disposed of in large quantities. It is also known that each process, from the procurement of raw materials to production, transportation, sales, laundry, and disposal, has a significant environmental impact. According to the Global Fashion Agenda, greenhouse gas (GHG) emissions from the fashion industry account for 4% of the global total. Therefore, apparel makers are shifting from a linear economy to a circular economy. For example, the Japanese start-up Curelabo Co., Ltd. (Okinawa, Japan) developed jeans (bagasse washi jeans) made from bagasse, which is a residual material derived from sugarcane after the extraction of cane juice. Furthermore, the use of improved dyeing reduces boiler fuel consumption and eliminates the need for detergents and acid. For disposal, the used jeans and their production waste are processed into biochar for carbon sequestration. In this study, we attempted to calculate GHG emissions using life cycle assessment (LCA) for the circular economy model developed by Curelabo Co., Ltd. GHG emissions from the production of bagasse washi jeans were 1.09 × 101 kg-CO2e. Dyeing, bleaching, and fabric finishing, known as the wet processes, were found to contribute a large proportion of GHG emissions due to their high energy consumption. Furthermore, the entire lifecycle of GHG emissions from bagasse washi jeans, including transport, sales, laundry, and disposal, were 1.53 × 101 kg-CO2e. First, the use of bagasse washi yarn for the weft reduced by 2.99 × 10−1 kg-CO2e compared with the use of conventional 100% bleached cotton yarn. Second, compared with conventional dyeing, GHG emissions from the improved dyeing process were reduced by 2.78 kg-CO2e. Third, the disposal of the used jeans and their production waste into biochar reduced GHG emissions by 9.01 × 10−1 kg-CO2e. Additionally, GHG emissions can be reduced by re-inputting waste in the paper-making process and by using liquefied natural gas as boiler fuel in the dyeing process.

Characterizing fabric crease recovery through sequential image analysis

Abstract Crease recovery is the ability of a fabric to revert to its original condition after deformation or folding. This recovery process is intricately linked to several fabric properties, including fiber content, yarn structure, weave, fabric finish, and mechanical treatments. Based on the dynamic nature of crease recovery, this paper employs sequential image analysis to track the velocity of fabric crease recovery at different positions and extract simple metrics for measuring fabric shape retention. In each image, the contour of the creased sample is detected, and the contour is modeled by a Gaussian function to calculate its barycenter. The barycenter of a crease is the point in space where the mass of the crease is concentrated, reflecting the shape and position of the crease. During the recovery process, the translation of the barycenter of the creased sample can be determined from the sequential images, leading to the calculation of crease's recovery velocity. Experimental results demonstrate a linear relationship between the barycentric velocity and logarithmic time. The slope of the resulting fit line, designated as the crease coefficient k, serves as a singular metric for assessing the fabric's shape retention following the release of the crease. This methodology is benchmarked against traditional fabric crease behavior tests, including the draping coefficient, bending length, and crease recovery angle. It demonstrates that the crease coefficient k offers greater reliability and accuracy across tests on 10 diverse fabric samples, which varied in terms of fiber content, weave, yarn size, and density.

Construction of fully bio‐based flame retardant and antibacterial coating on polyester fabric with chitosan and ammonium phytate

AbstractIn this work, a flame retardant and antibacterial coating was constructed on the surface of polyester (PET) fabric by a simple layer‐by‐layer self‐assembly method based on chitosan (CS) and ammonium phytate (APA). The introduction of the coating significantly improved the flame retardant, anti‐dripping, and antibacterial properties of PET fabrics. The PET fabric that has been treated exhibits a limiting oxygen index of 34.6%. During the vertical flame test, it forms an expanded char layer, reduces the damage length to 3.4 cm, and produces no molten drops. The cone calorimeter test results revealed that the peak heat release rate of the treated PET fabric decreased by 62.0%. Additionally, the finished PET fabric has significant antibacterial properties against Escherichia coli, a slight increase in tensile breaking strength, and a slight decrease in whiteness index. This study presents a fully bio‐based, simple, and effective method for flame retardant, anti‐dripping, and antibacterial finishing of PET fabrics.

Eco friendly functional finishes of polyester fabric using keratin from wool and feather wastes

This research showcases the use of hydrothermally extracted solutions from poultry feathers and wool as eco-friendly and versatile textile finishes. These solutions, derived from waste biomass containing the keratin biopolymer, were obtained through environmentally conscious hydrothermal degradation processes. Initially, the study focused on analysing the chemical parameters and properties of both dialysed and non-dialysed solutions extracted from feathers and wool. The investigation tracked primarily the presence of keratin within these solutions. Upon application to polyester textiles as the reference material, the presence of these solutions on the fabric surface was confirmed successfully. A thorough physicochemical analysis of the treated textiles involved various analytical techniques. These encompassed surface composition analysis via X-ray Photoelectron Spectroscopy (XPS) and Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), assessment of wettability through Contact Angle measurements, determination of surface charge using surface zeta potential, and examination of the thermal and flame-retardant properties via Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), and calorimetric tests. In addition, the colour, UV radiation transmission and antioxidant activity were evaluated using standard tests.The remarkable effects of the treatment have been observed in the exceptional antioxidative action, fire resistance, UV protection and enhanced hydrophilicity of these innovative multifunctional textiles. This approach holds significant implications across research, economics and society, enriching Material Science by deepening the understanding of materials and their multifaceted properties. Moreover, it promotes resource efficiency, opens new sustainable textile market prospects, and contributes to social impact by supporting environmental sustainability, engaging communities and ensuring health and safety benefits.

Significance of Casein and it’s Applications in the manufacture and finishing of various textiles

Significance of Casein and it’s Applications in the manufacture and finishing of various textiles

Essential Oils in Medical Textile Finishing

Essential Oils in Medical Textile Finishing

Literature review on artificial intelligence in dyeing and finishing processes

The finishing process in the textile sector is recognized as one of the most complex. This complexity arises from the diversity of structures, the multiple steps involved, the use of complex machinery, the variety of materials, chemicals and dyes, and the need to combine creativity and precision. Therefore, it is crucial to have tools that can improve efficiency, flexibility, and decision-making in this complex area. This literature review aims to provide relevant information on the use of digital engineering in the field of textile finishing. In this review, we used a systematic literature review methodology to examine how digital engineering is applied in the dyeing and finishing process. The data for this study was collected from reputed databases such as Science Direct, IEEE Xplore, Textile Research Journal and Google Scholar. We used the Prisma framework to select relevant articles, which led to the exclusive inclusion of journal articles in our literature review. A comprehensive framework has been developed to understand the impacts of using digital engineering. The approach presented in this framework provides a comprehensive and highly effective approach to addressing the complex challenges associated with ambiguity, modifications and subtleties frequently observed in the ennobling process. The results of various studies explored different aspects, such as properties of textile materials, chemicals and dyes, performance of finishing machines, organizational performance of finishing companies, as well as health concerns and safety at work. Although these studies have provided valuable solutions, they unfortunately remain insufficient to meet the requirements of the finishing process, which remains a complex area characterized by uncertainties, variations, and subtleties inherent to the practice. This particularity of each dyed and finished product promotes an environment conducive to experimentation and continued research.

Low temperature carbonization, smoke suppression and durable flame retardancy of cotton fabric spray-assisted coated by phosphorus nitrogen silicon composite system

To solve the problems of flammability, smoldering, smoking and flame retardant durability of cotton fabric, flame retardant fininshing was executed using spray assisted self-assembly method, and P/N/Si synergistic flame retardant system was constructed by polyethylene imine (PEI), phytic acid (PA) and 3-aminopropyltriethoxysilane (APTES). Cotton cellulose carbonized at low temperature prompting by PA catalytic effect, and this cooperated with PEI thermal decomposition to endow cotton fabric with flame retardancy and smoking suppression by reducing its pyrolysis rate at high temperature and lessening combustible products. Meanwhile APTES as silane coupling agent further improved its flame retardant durability and smoke suppression effect. The synchronous thermal analysis results indicate that cotton fabrics treated by PA/PEI/APTES composite system present significant low-temperature carbonization trend, and their initial decomposition temperatures advance by 46.5℃-75.9℃. Moreover, they form 4.6 %-44.9 % aromatic structure char through dehydration and carbonization reactions during the low-temperature carbonization process, improving their thermal stability at high temperature, and their after-flame and smoldering phenomena disappear. The damaged length of treated fabric with five layers reduces to 5.0 cm, its limiting oxygen index reaches 33.7 %, and it presents excellent flame retardant durability and smoke suppression effect. This low-temperature carbonization mechanism possesses importantly innovative significance for the flame retardant finishing of cotton fabric, and it not only more actively guides the selection of flame retardants to make them match with the material required, but provides a new thinking method for flame retardant material research in the future.

Investigation of water and carbon footprint reductions employing best available techniques in the textile sector

This study includes a new approach in terms of connecting best available technique (BAT) selection/decision to water and carbon footprint evaluations in addition to economical and environmental performance criteria. This new approach was applied to an integrated textile facility mainly employing cotton fabric finishing and printing-dyeing. After potential implementation of selected 12 BATs, the reduction potentials in the existing water/carbon footprints were calculated. The blue water, grey water and total water footprint values of the facility were found to be 126, 837 and 963 L/kg product, respectively. The total carbon footprint value of the facility was found to be 7.011 kg CO2eq/kg product, and most of this comes from steam use. The optimization of resin regeneration frequency/duration and washing-rinsing steps in the water softening system via online hardness sensors provides 20–30% reductions in blue water footprint values. It was calculated that when BATs from 1 to 7 together are implemented in the facility, an average of 68.5% reduction in the total water footprint could be achieved. Alternatively, when BATs 1–5 and 8 are implemented, such reduction is 45.6%, highlighting the effectiveness of the selected BATs. BAT 9 exhibited the highest reduction in total carbon footprints due to the fact that it is related to minimization of energy losses. If all selected BATs are to be implemented in the facility, a reduction of 1.179 kg CO2eq/kg product could be achieved in the total carbon footprint, corresponding to 16.8% reduction. Significant reductions in energy consumption could be achieved through techniques/applications such as isolation of hot surfaces, reducing reprocesses by improving dyehouse-laboratory coordination, optimizing recipes and applying correct dyeing techniques at once, making lighting systems efficient, process modifications/optimizations in pre-treatment and final finishing processes, and reducing water consumption in processes requiring hot water. This study indicated that selection and application of BATs in industries should be coupled with water/carbon footprint evaluations.

Eco-friendly shrink-resist finishing of wool through synergistic effect of disulfide bond reducing agent and papain

The environmental benefits of utilizing protease as a biocatalyst for wool shrink-resist finishing have been widely recognized. However, the efficacy of individual protease treatment is unsatisfactory due to its incapability towards the outermost cuticle layer of wool fibers that contains hydrophobic fatty acids. In order to weaken the structural integrity of the highly cross-linked scales and promote the enzymatic anti-felting, sodium sulfite and tris (2-carboxyethyl) phosphine hydrochloride (TCEP) were employed in combination with papain, respectively, aiming at obtaining a low shrinkage without unacceptable fiber damages. Based on the synergistic effect of papain and TCEP, the edges of wool scales were slightly destroyed by the reduction of disulfide bonds, accompanied by enzymatic hydrolysis of the keratin component. Through the controlled reduction and hydrolysis of wool scales, satisfactory anti-felting result was achieved without causing severe damage to the fiber interiors. In the presence of 0.25 g/L TCEP and 25 U/mL papain, the area shrinkage of wool fabric decreased to approximately 6 %, with a low strength loss of less than 8 %. Meanwhile, the dyeing behavior of the wool fabric under low-temperature conditions was dramatically improved, leading to decreased energy consumption during production. The present work provides an alternative for eco-friendly finishing of wool fabrics, which can be applied commercially.

Eco-Dyeing and Functional Finishing of Cotton Fabric Using a Natural Colour Derived From Lotus Seed: Enhanced Fastness Properties with Chitosan

Medicinal plant-based dyeing introduces vibrant colours alongside antibacterial and anti-odor properties, fostering sustainability. Innovations include mass sampling for consistent pigment production. Furthermore, lotus seedpods, rich in bioactive compounds, exhibit potential in diverse fields. Chitosan, a biopolymer derived from chitin, boasts versatility in drug delivery systems, wound healing, and antimicrobial applications. This experimental inquiry delves into the dyeability and antimicrobial efficacy of cotton fabric subjected to treatment with chitosan and dyed using Lotus seeds. The investigation encompasses varied parameters such as dye concentration, duration, and temperature for fabric dyeing. The study elucidates the aqueous extraction methodology for dye from Lotus seeds, the chitosan-based mordanting techniques. Standardized assessments are utilized to gauge colour fastness characteristics, encompassing washing, rubbing, and perspiration fastness, along with assessing the antimicrobial attributes of the treated cotton fabric. The study indicates that the application of chitosan-treated cotton fabric enhances dye intensity and overall dyeing quality, consequently improving the colour fastness property of washing, rubbing, and perspiration. Additionally, the treated cotton fabric exhibits significant antimicrobial activity against common bacteria, highlighting the potential of Lotus seed-derived colourants and chitosan mordant in the development of sustainable and antimicrobial textiles. The future scope lies in optimizing the integration of Lotus seed-derived colourants and chitosan mordant for enhanced sustainability and antimicrobial efficacy in textile applications, leveraging advancements in dyeing technology and antimicrobial formulation techniques.

The impact of DOPO‐derived phosphoramides containing triazine moieties on the flame retardancy and smoke suppression properties of waterborne polyurethane

AbstractWaterborne polyurethane (WPU), which is a novel and environmentally friendly variety of polyurethane, replaces organic solvents with water. It has been extensively utilized in diverse fields encompassing coatings, textile finishing, building decoration, adhesives, plastic chemistry, and others. However, WPU is inherently flammable and releases a significant amount of smoke production during the combustion process. This research presents an original fire‐resistant Waterborne Polyurethane (WPU) with a newly‐integrated flame‐retardant component comprising a triazine phosphoramidate segment derived from 9,10‐dihydro‐9‐oxo‐10‐phosphaphenanthrene‐10‐oxide (DOPO) within its primary structure. In comparison to pure WPU, the limiting oxygen index (LOI) of flame‐retardant WPU (FRWPU) increased from 19.6% to 29.2%. In UL‐94 testing, the FRWPU film achieved a V‐0 rating with only 6% retarding component. Additionally, in cone calorimetry tests, Total Heat Release (THR), peak Heat Release Rate (pHRR), Total Smoke Production (TSP), Smoke Production Rate (SPR), and peak Carbon Monoxide Production Rate (pCOP) are decreased by 27.7%, 16.2%, 64.6%, 61.3%, and 77.8%, respectively. The greater degree of graphitization observed in the residual carbon substantially impeded heat exchange and the emission of smoke during combustion. Flame‐retardant intermediate segments greatly improved the FRWPUs' ability to suppress smoke and remain flame‐retardant. The creation and formulation of aqueous polyurethanes that are flame‐retardant can benefit greatly from the insights and references offered by this research.

Effect of Conditions Simulating Practical Use on the Efficiency of an N-Halamine-Based Finish Applied to Medical Gown and Military Uniform Fabrics

Biocidal fabrics can reduce the transmission of pathogens caused by contaminated personal protective equipment (PPE). N-halamines are very effective and fast-acting biocides against bacteria and viruses. To explore the relevance of N-halamine compounds for use in PPE and operational clothing and equipment (OCE), this study investigates the impact of an N-halamine-based finish on the functional and aesthetic properties of fabrics used for medical gowns and military uniforms, and examines the effect of conditions simulating the PPE and OCE practical use on the N-halamine-based finish. It was observed that the presence of a water-repellent finish on the fabrics reduced the chlorine loading for the fabric made of hydrophilic fibers, whereas no effect was observed for the polyester fabric. No major effect of the finish application was measured on the fabric strength. In terms of the color, the gown fabric was strongly affected by the finish application and subsequent chlorination, whereas the effect on the military fabric was more limited. The treated fabrics remained within the requirements for Class 1 in terms of flammability. The results showed no impact of low chlorination temperature and different water quality levels on the chlorination efficiency. On the other hand, laundering, repeated abrasion, and exposure to UV radiation and perspiration simulating use conditions reduced the chlorine content in the fabric. These results provide some insight into the strengths and remaining challenges of N-halamine fabric finishes when considering practical applications for protective clothing.

An In Vitro Analysis of Antibacterial Property of Mikania micrantha Leaves Extract as a Textile Finish with Crosslinking Agent and Its Washing Efficacy

An In Vitro Analysis of Antibacterial Property of Mikania micrantha Leaves Extract as a Textile Finish with Crosslinking Agent and Its Washing Efficacy

Preparation and properties of highly efficient flame-retardant Lyocell fabrics: Mitigating the acidity effect of phytic acid on the mechanical properties under pad-dry-curing process finishing conditions

The pad-dry-curing process involves padding with finishing liquid, pre-drying, and high-temperature baking. It is widely used in the dyeing and finishing field. For the field of flame-retardant finishing of fabrics, the use of phytic acid (PA) as a raw material can be highly effective. However, the extreme acidity of PA can cause damage to cellulose-based fabrics under high-temperature conditions. The development of PAMA, a compound formed by reacting PA with maltitol, can effectively alleviate the damage of PA to fabrics at high temperatures. PAMA not only exhibits excellent flame-retardant properties by slowing down flame propagation but also helps mitigate the acidic damage to Lyocell fabrics during the pad-dry-curing process, including an increase in the limiting oxygen index (31.9 %), a reduction in peak heat release rate (55 %), and a substantial increase in breaking force retention compared with those of the sample using pure PA as a flame retardant (300 %). Overall, this research presents a promising approach to the development of environmentally friendly flame retardants for textiles, highlighting the importance of balancing effectiveness with fabrics.

Multifunctional finishing of cotton fabric using zinc oxide nanoparticles synthesized by bio-reduction method

Multifunctional finishing of cotton fabric using zinc oxide nanoparticles synthesized by bio-reduction method

Simple and facile fabrication of carboxymethylated cellulose nanofibrils one-side-coated cotton non-woven fabrics for beauty facial mask sheets

In this study, we developed eco-friendly beauty facial mask sheets with improved absorbency and performance using a simple textile finishing process. Carboxymethyl cellulose nanofibrils (c-CNFs) were bar-coated onto cotton non-woven fabrics (COFs), transforming them into sheet-shaped structures. The resulting sheets exhibited enhanced tensile strength, water absorption, and durability. The weight of the sheets increased proportionally with the amount of coated c-CNFs, while their thickness decreased due to compression during the process. The addition of c-CNFs improved absorption capabilities, despite the formation of a non-porous structure. Furthermore, the sheets demonstrated longer drying times, reduced friction coefficients, and improved mechanical properties. Cytotoxicity evaluation confirmed the biocompatibility of the sheets. This study highlights the feasibility of producing eco-friendly beauty facial mask sheets with enhanced performance through a simplified textile finishing process using c-CNFs, offering potential applications in the cosmetics industry.