Femtosecond Laser Pulse Irradiation Research Articles

Implications of transient changes of optical and surface properties of solids during femtosecond laser pulse irradiation to the formation of laser-induced periodic surface structures

The formation of laser-induced periodic surface structures (LIPSS) upon irradiation of silicon wafer surfaces by linearly polarized Ti:sapphire femtosecond laser pulses (pulse duration 130 fs, central wavelength 800 nm) is studied experimentally and theoretically. In the experiments, so-called low-spatial frequency LIPSS (LSFL) were found with periods smaller than the laser wavelength and an orientation perpendicular to the polarization. The experimental results are analyzed by means of a new theoretical approach, which combines the widely accepted LIPSS theory of Sipe et al. with a Drude model, in order to account for transient (intra-pulse) changes of the optical properties of the irradiated materials. It is found that the LSFL formation is caused by the excitation of surface plasmon polaritons, SPPs, once the initially semiconducting material turns to a metallic state upon formation of a dense free-electron-plasma in the material and the subsequent interference between its electrical field with that of the incident laser beam resulting in a spatially modulated energy deposition at the surface. Moreover, the influence of the laser-excited carrier density and the role of the feedback upon the multi-pulse irradiation and its relation to the excitation of SPP in a grating-like surface structure is discussed.

Laser fluence dependence of periodic grating structures formed on metal surfaces under femtosecond laser pulse irradiation

Periodic structures self-formed on the surface of several metals under femtosecond laser-pulse irradiation are investigated by electron microscopy. For the self-formation of periodic gratings on metal surfaces, the interspaces of the periodic structures depend on laser fluence. This dependence is the same for all metals, although the range of laser fluence in which the structures are formed differs between metals. The laser fluence dependence can be explained by the generation of a plasma wave through the parametric decay of laser light [S. Sakabe, M. Hashida, S. Tokita, S. Namba, and K. Okamuro, Phys. Rev. B 79, 033409 (2009)]. This indicates that the formation of periodic structures depends not only on metal properties but also on the electron density of plasma produced on a surface by femtosecond laser pulses.

Mechanism of heat-modification inside a glass after irradiation with high-repetition rate femtosecond laser pulses

Accumulation of thermal energies by highly repeated irradiation of femtosecond laser pulses inside a glass induces the heat-modification whose volume is much larger than that of the photoexcited region. It has been proposed that the heat-modification occurs in the region in which the temperature had overcome a threshold temperature during exposure of laser pulses. In order to understand the mechanism of the heat-modification, we investigated the temperature distribution during laser exposure and the threshold temperature by analyzing the volume of the modification based on a thermal diffusion model. We found that the threshold temperature becomes lower with increasing laser exposure time. The dependence of the threshold temperature on the laser exposure time was explained by the deformation mechanism based on the temperature-dependent viscosity and viscoelastic behavior of a glass under a stress loading by thermal expansion. The deformation mechanism also could simulate a tear-drop shape of a heat-modification by simultaneous double-beams’ irradiation and the distribution of birefringence in a heat-modification. The mechanism proposed in this study means that the temperature-dependence of the viscosity of a glass should be essential for predicting and controlling the heat-modification.

Propagation effects on fusion neutron generation in the Coulomb explosion of deuterated methane clusters

In this paper, fusion neutron yields from the Coulomb explosion of (CD4)N clusters under the irradiation of an intense femtosecond laser pulse is optimized by controlling the propagation of the laser pulse in a cluster jet. A correlated study of fusion neutron yields, kinetic energies of deuterons, together with the plasma channels diagnosed by a pump–probe interferometer, is performed. It has been found that by controlling the focal position related to the cluster jet, the plasma defocusing effect can balance with the tight focusing effect of the laser pulse induced by an off-axis parabolic mirror, and results in a cylindrical-shaped and relatively narrow plasma channel crossing the gas jet. The most energetic deuterons and the maximum yields of fusion neutrons are produced at the same time. For better understanding of the experimental results, numerical simulations for the nonlinear propagation of the femtosecond laser pulse in (CD4)N gas-cluster jets are performed. Simulated results show that plasma defocusing and laser attenuation play dominant roles in this case of optimization.

Self-organized periodic surface structures on ZnO induced by femtosecond laser

Self-organized periodic surface structures on ZnO have been observed after multiple linearly polarized femtosecond laser pulse irradiation. The observed self-organized structures are attributed to the second harmonics in the sample surface excited by the incident laser. The grating orientation could be adjusted by the laser polarization direction. We also find that fluences play an important role in the formation of self-organized nanostructures.

Two-photon absorption of photochromic diarylethene and its application to rewritable holographic recording

A new photochromic diarylethene (1a) has been prepared. Both its photochromic behavior and nonlinear optical properties are investigated. 1a shows excellent ring-opening (λmax = 386 nm) and ring-closing (λmax = 652 nm) photoisomerization with UV-Vis light irradiation. With 800 nm femtosecond pulsed laser irradiation, 1a shows two-photon-induced photoisomerization, and a two-photon absorption cross-section (σ = 423×1050 cm4·s per photon) is obtained by using two-photon induced fluorescence method. The applications of two-photon absorption of 1a to holographic recording has been also investigated. A two-photon induced micro-pattern is recorded on the diarylethene 1a-PMMA film with an femtosecond laser of 800 nm, 100 fs, 1 kHz, 50 mW.

Femtosecond laser fabricated fiber Bragg grating in microfiber for refractive index sensing

Fiber Bragg grating (FBG) is fabricated in the microfiber by the use of femtosecond laser pulse irradiation. Such a grating can be directly exposed to the surrounding medium without etching or thinning treatment of the fiber, thus possessing high refractive index (RI) sensitivity while maintaining superior reliability. The grating in the microfiber may have a number of propagation modes in its transmission spectrum, depending on the fiber diameter, and the higher order of mode has larger RI sensitivity. The RI sensitivity also depends on the fiber diameter and a smaller diameter corresponds to a large sensitivity. The maximum sensitivity obtained is approximately 231.4 nm per refractive index unit at the refractive index value of approximately 1.44 when the fiber diameter is approximately 2 microm. The FBG fabricated in the microfiber has high potential in various types of optical fiber sensor applications.

Morphology and composition on Al surface irradiated by femtosecond laser pulses

We study the surface chemicals and structures of aluminum plates irradiated by scanning femtosecond laser pulses in air for a wide range of laser fluence from 0.38 to 33.6 J/cm 2. X-ray photoelectron spectroscopy and X-ray diffraction analyses indicate clearly that crystalline anorthic Al(OH) 3 is formed under femtosecond laser pulse irradiation. Besides aluminum hydroxide, crystalline α Al 2O 3 is also found in the samples irradiated at high laser fluence. Field emission scanning electron microscopy demonstrates that the surfaces of the samples irradiated with low laser fluence are colloidal-like and that nanoparticles with a few nanometers in size are embedded in glue-like substances. For high laser fluence irradiated samples, the surfaces are highly porous and covered by nanoparticles with uniform size of less than 20 nm.

Laser surface micro-engineering for industrial applications in Singapore

Some recent research in laser-induced surface ripple structures, surface ablation, surface colouration, and their potential industrial applications are discussed in this article. Both wavelength and sub-wavelength periodic surface structures were observed on semiconductors such as InP and GaN/sapphire surfaces after irradiation of femtosecond laser pulses. The orientation of the periodic structures was dependant on the laser beam polarization, and the period was dependent on the incident laser fluence. Such surface periodic structures may find applications in controlling surface hydrophobic and hydrophilic properties. Excimer laser ablation of epoxy compounds from wafer level chip size packages was found to be a feasible method to expose the micron-size Au bumps for solder reflow, which is a critical process in manufacturing portable electronic products. Studies on controlled surface oxidation by laser pulses showed that a range of colours can be achieved on a stainless steel surface. Selective Cr oxidation and iron oxides were detected. The appearance of colour is the result of the light constructive interference of the transparent oxide layer and is determined by the oxide thickness and the refractive index. The potential industrial applications of the techniques are discussed.

Periodic surface nanostructures on polycrystalline ZnO induced by femtosecond laser pulses

Periodic surface nanostructures induced by femtosecond laser pulses on polycrystalline ZnO are presented. By translating the sample line-by-line under appropriate irradiation conditions, grating-like nanostructures with an average period of 160 nm are fabricated. The dependence of surface morphologies on the processing parameters, such as laser fluence, pulse number and laser polarization, are studied by scanning electronic microscope (SEM). In addition, photoluminescence (PL) analysis at room-temperature indicates that the PL intensity of the irradiated area increases significantly compared with the un-irradiated area. Using femtosecond laser pulses irradiation to fabricate periodic surface nanostructures on polycrystalline ZnO is efficient, simple and low cost, which shows great potential applications in ZnO-based optoelectronic devices.

Long period fiber grating formed by periodically structured microholes in all-solid photonic bandgap fiber

A new type long period fiber grating is fabricated in all-solid photonic bandgap fiber by periodically drilling microholes using femtosecond laser pulse irradiation. Such a structure introduces a strong refractive index modulation in the waveguide structure and hence exhibits a compact grating dimension. Both the simulation and the experimental results confirm the existence of the light coupling from core mode to the LP(11) cladding mode. The refractive index sensing capability of the device has been investigated and the resonant wavelength shift corresponding to the refractive index change from 1.30 to 1.35 is 23.7 nm. The average refractive index sensitivity obtained is 537 nm/RIU (refractive index unit).

Ultrafast temperature relaxation evolution in Au film under femtosecond laser pulses irradiation

Ultrafast temperature relaxation processes in Au film including two temperature relaxation and thermal diffusion relaxation with femtosecond laser pulse excitation were investigated numerically by Finite Element Method (FEM). With the temperature dependent thermal parameters, the full 2D temperature field evolution in picosecond and nanosecond domains were obtained. It is proposed that the heat transfer depth can be alternatively localized or enhanced by the distinct temperature relaxation mechanisms. Moreover, the effect of laser parameters and Au film thickness and surface reflectivity on the two temperature relaxation time were analysed.

Label-free optical control of arterial contraction

The diameters of blood vessels, especially in the brain, change dynamically over time to provide sufficient blood supply as needed. No existing technique allows noninvasive control of vascular diameter in vivo. We report that label-free irradiation with a femtosecond pulsed laser can trigger blood vessel contraction in vivo. In response to laser irradiation, cultured vascular smooth muscle cells showed a rapid increase in calcium concentration, followed by cell contraction. In a murine thinned skull window model, laser irradiation focused in the arterial vessel wall caused localized vascular contraction, followed by recovery. The nonlinear nature of the pulsed laser allowed highly specific targeting of subcortical vessels without affecting the surrounding region. We believe that femtosecond pulsed laser irradiation will become a useful experimental tool in the field of vascular biology.

Time-resolved X-ray Diffraction Studies of Coherent Lattice Dynamics Using Synchrotron Radiation

Significant progress in recent development of synchrotron radiation (SR) sources has offered the opportunity for time-resolved X-ray diffraction studies of fast lattice dynamics in the atomic scale. The coherent atomic motion, as seen in coherent optical and acoustic phonons which are induced by femtosecond pulsed laser irradiation of semiconductor surface has directly been observed with the time-resolved X-ray diffraction technique. In this article, the time-resolved diffraction methods using an SR beam are summarized, and the demonstrations for acoustic pulse echo, coherent acoustic phonon, and optical phonon are reviewed as examples of the investigation on coherent lattice dynamics. The future prospective on the investigation of lattice dynamics using time-resolved X-ray diffraction experiments is also discussed.

Fiber Bragg gratings with enhanced thermal stability by residual stress relaxation

Fiber Bragg gratings with greatly enhanced thermal stability have been fabricated by the use of femtosecond laser pulse irradiation on optical fibers with relaxed residual stress, through using high temperature annealing treatment. The grating reflectivity and resonant wavelength can be maintained for periods up to 20 hours using isothermal measurements and temperatures up to 1200 degrees C. No hysteresis was observed in the wavelength response when the gratings were annealed and the temperature cycled repeatedly between room temperature and 1200 degrees C.

Nonlinear Responses and Optical Properties Modification οf SK3 under Irradiation of Femtosecond Laser Pulses

Nonlinear Responses and Optical Properties Modification οf SK3 under Irradiation of Femtosecond Laser Pulses

Infrared light absorption of silver film coated on the surface of femtosecond laser microstructured silicon in SF 6

Absorptive properties of 100 nm thick silver (Ag) films coated on the surface of microstructured silicon prepared by femtosecond laser pulses irradiation in SF 6 were measured in a wavelength range of 1.33–16.7 µm. Greatly enhanced light absorption of Ag films was observed in the entire measured wavelength range. For sample with 6–8 µm spikes, the absorptance is approximately 0.9 and essentially unchanged in the wavelength region of 1.33–10 µm, and decreases slightly when λ > 10 µm, but keeps higher than 0.75 over the whole measured wavelength range. The infrared absorption is strongly related to the height and density of the spikes. While for the samples without Ag coating, the absorption is much lower than that of the Ag films. Multiple reflection of light between spikes and surface plasmon excitation of nano-particles on the spikes surface may lead to the strongly enhanced infrared absorption in such a wide wavelength range.

Structure formation on the surface of alloys irradiated by femtosecond laser pulses

Laser-induced periodic surface structures with different spatial characteristics have been observed after multiple linearly polarized femtosecond laser pulse (120 fs, 800 nm, 1 Hz to 1 kHz pulse repetition frequency) irradiation on alloys. With the increasing number of pulses, nanoripples, classical ripples and modulation ripples with a period close to half of classical ripples have all been induced. The generation of second-harmonic has been supposed to be the main mechanism in the formation of modulation ripples.

Conventional and Propagation‐based Phase Contrast Imaging of Nanostructures Using Femtosecond Laser Driven Cluster Plasma Source and LiF Crystal Soft X‐ray Detectors

AbstractBright source of soft X‐ray emission was developed. Soft X‐ray radiation was produced by femtosecond laser pulses irradiation of submicron size CO2 clusters. These clusters were produced in custom designed supersonic nozzle from the mixture of the 10% CO2 +90 % He expanding gases. Lithium fluorine based soft X‐ray detectors was used for registration of absorption images of ultrathin (nanoscale) foils and biological structures illuminated by the developed source. It was demonstrated that even ifthe foil is essentially transparent for the soft X‐ray radiation (like 100 nm thick Zr foil), the image contrast could be significantly increased due to the influence of propagation‐based phase‐contrast effect when detector is placed at the proper distance behind the sample (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Room Temperature SnO2 Thin Film Gas Sensor Fabricated on Si Nanospikes

The SnO2 thin film CO gas sensors have been fabricated on silicon nanostructured surface made using a femtosecond pulsed laser irradiation. The measurement shows a significant response to the CO gas at room temperature. While a SnO2 sensor fabricated on a flat surface shows no response when CO gas exists at room temperature. The high area/volume ratio and sharp structures of the nanospikes enhance the sensitivity of SnO2 at room temperature.