Circulating fluidized bed (CFB) combustion is a important method of waste treatment with the benefits of harmlessness, recycling, and energy recovery. Using the existing co-firing CFB boiler to dispose of waste can reduce investment in boilers and environmental protection equipment. However, there is currently limited research available on the co-combustion of coal and waste (especially for papermaking trash), and the mechanism of pollutant emissions during unit operation remains unclear. In this work, the co-combustion of coal and papermaking trash in a three-dimensional industrial-scale CFB are investigated by using the Dense Discrete Phase Model (DDPM) method. Both homogeneous reactions (such as fuel particle pyrolysis, combustion, and surface reaction) and non-homogeneous reactions (such as gas combustion and pollutant generation) are considered. The co-combustion characteristics are comprehensively analyzed in terms of gas distribution, chemical reaction rates, and bed temperature under various operating conditions, including fuel mixing ratio, secondary air arrangement, and excess air coefficient. The results are obtained by comparing the distribution profile along the height. By reducing the mixing ratio of papermaking trash, the excess air coefficient, and adjusting the secondary air arrangement in the lower region, an expanding, reducing atmosphere is observed in the vicinity of the fuel feeding point. This, in turn, leads to an increase in CO concentration and a decrease in NO emissions, which is attributable to the interplay of gas distribution, chemical reaction rates, and bed temperature. A reduction in NO gas emissions was achieved by adjusting the secondary air arrangement and the excess air coefficient. Overall, this work provides valuable insights into the co-combustion characteristics of coal and papermaking trash in an industrial-scale circulating fluidized bed boilers.
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