Elucidating the structure and composition of Mercury is important for understanding its interior dynamics and evolution. The planet is characterised by unusual chemical characteristics and a weak magnetic field generated in a large metallic core, and its early evolution was also marked by the presence of a magnetic field, widespread volcanism and global contraction. Here we develop a parameterised model of coupled core-mantle thermal and magnetic evolution considering a layered Fe-Si(-S) core structure with chemical and physical properties of the mantle and the core based on previous laboratory studies. We seek successful solutions that are consistent with observations of Mercury's long-lived dynamo, total global contraction, present-day crustal thickness, and present-day interior structure. Successful solutions have a mantle reference viscosity >1021 Pa s (corresponding to a present-day bulk mantle viscosity >2×1020 Pa s), a silicon concentration in the core >13 wt%, a present inner core radius of ∼1000−1200 km and a thermally stable layer ∼ 500−800 km thick below the core-mantle boundary. Our results show that if present, a molten FeS layer atop the core has minimal effect on Mercury's long-term thermal and magnetic evolution. Predictions from our models can be tested with upcoming Bepi-Colombo observations.
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