Fabrication Techniques Research Articles

Self-assembly of 1T/1H superlattices in transition metal dichalcogenides

Heterostructures and superlattices composed of layered transition metal dichalcogenides (TMDs), celebrated for their superior emergent properties over individual components, offer significant promise for the development of multifunctional electronic devices. However, conventional fabrication techniques for these structures depend on layer-by-layer artificial construction and are hindered by their complexity and inefficiency. Herein, we introduce a universal strategy for the automated synthesis of TMD superlattice single crystals through self-assembly, exemplified by the NbSe2-xTex 1T/1H superlattice. The core principle of this strategy is to balance the formation energies of T (octahedral) and H (trigonal prismatic) phases. By adjusting the Te to Se stoichiometric ratio in NbSe2-xTex, we reduce the formation energy disparity between the T and H phases, enabling the self-assembly of 1T and 1H layers into a 1T/1H superlattice. The resulting 1T/1H superlattices retain electronic characteristics of both 1T and 1H layers. We further validate the universality of this strategy by achieving 1T/1H superlattices through substituting Nb atoms in NbSe2 with V or Ti atoms. This self-assembly for superlattice crystal synthesis approach could extend to other layered materials, opening new avenues for efficient fabrication and broad applications of superlattices.

Transparent ultrasonic transducers based on relaxor ferroelectric crystals for advanced photoacoustic imaging

Photoacoustic imaging is a promising non-invasive functional imaging modality for fundamental research and clinical diagnosis. However, achieving capillary-level resolution, wide field-of-view, and high frame rates remains challenging. To address this, we propose a transparent ultrasonic transducer design using our developed transparent Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 crystals. Our fabrication technique incorporates quartz-glass-and-epoxy matching layers with low-resistance indium-tin-oxide electrodes through a brass-ring based structure, enabling a high frequency (28.5 MHz), wide bandwidth (78%), and enhanced pulse-echo sensitivity (2.5 V under 2-μJ pulse excitation). Our Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3-based transparent ultrasonic transducer demonstrates a four-fold enhancement in photoacoustic detection sensitivity when compared to the LiNbO3-based counterpart, leading to a 13 dB improvement of signal-to-noise ratio in microvascular photoacoustic imaging. This enables dynamic monitoring of mouse cerebral cortex microvasculature during seizures at 0.8 Hz frame rates over a 1.5 × 1.5 mm2 field-of-view. Our work paves the way for high-performance and compact photoacoustic imaging systems using advanced piezoelectric materials.

Microfluidics in Cardiac Microphysiological Systems: A review

Abstract Inspired by the advances in microfabrication of microelectromechanical systems (MEMS), microphysiological systems (MPS) capitalized on the fabrication techniques of MEMS technology and pivoted to biomedical applications with select biomaterials and design principles. With the new initiative to refute animal testing and develop valid and reliable alternatives, MPS platforms are in greater demand than ever. This paper will first present the major types of microphysiological systems in the cardiovascular research space, and then review the core design principles of such systems to closely replicate the in vivo physiology. Fabrication methodologies of the platform, as well as technologies that enable patterning and functionalizing scaffolds, and the various sensing modalities that can interface with such MPS platforms, are reviewed and discussed. This review aims to provide a comprehensive picture of cardiac microphysiological systems in which microfluidics play an important role in the design, fabrication, and sensing modalities, and prospects of how this platform can continue to drive further improvements in cardiovascular research and medicine.

Enhancing thermo-mechanical properties of additively manufactured PLA using eggshell microparticle fillers

Polylactic acid (PLA) is a widely studied polymer for potential biomedical applications and is one of the most commonly used polymers for additive manufacturing or 3D printing. Additive manufacturing (AM) technology is a fast-rising method of fabrication of polymer parts compared to other traditional fabrication techniques. In recent years, natural plant-based and animal-based fibers have shown immense potential to be used as fillers or reinforcements for polymer composites. In this study, chicken eggshell particles (ESP) have been used as inorganic calcium carbonate fillers to enhance PLA's mechanical properties. Four different concentrations (0 wt%, 1 wt%, 3 wt%, and 5 wt%) of PLA/ESP composite filaments have been extruded using a single screw extruder. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analyses were used to determine the chemical composition of eggshell powder, showing peaks matching with that of calcium carbonate (CaCO3). Thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis show the effect of the filler on the PLA composite's thermal stability, indicating that pristine PLA has the highest melting temperature of 152 °C while the 5 wt% has the lowest melting temperature of 147 °C. The addition of eggshell particles slightly enhanced the compressive strength and dynamical mechanical properties of the PLA/ESP composites. The eggshell powders enhanced the dynamic mechanical property of PLA, with the 3 wt% concentration having the highest storage modulus at room temperature, with 5.2 % and 3.6 % increase for the filament and 3D printed samples respectively. Finally, the eggshell particles did not have much effect on the tensile and flexural strength of the composite, however, it enhanced the compressive strength of PLA with the 5 wt% sample having an average strength of 66.50 MPa and modulus of 2.27 GPa, respectively.

Advanced three-dimensional textile technique for fabrication of sisal/flax hybrid fiber green biocomposite with enhanced mechanical, thermal, and sound isolation properties

Natural fibers are regarded as ideal reinforcements for fiber-reinforced composites due to their high specific strength and biodegradability. In this study, three-dimensional orthogonal woven sisal/flax yarn hybrid bio-based epoxy resin composites (3DOWSBCs) were firstly employing a novel three-dimensional orthogonal weaving technique, and their mechanical properties were experimentally examined, and compared with those of traditional lamination composites. Secondly, a finite element model (FEM) was constructed to predict and analyze the shear behaviors of 3DOWSBCs in order to elucidate the strengthening mechanisms of Z-yarns. Additionally, the thermal and acoustic properties also discussed. The results suggested that the flexural strength and shear strength of 3DOWSBCs (141.15 MPa, 22.80 MPa) were 37.9 % and 86.9 % higher than the laminates, respectively. The FEM results demonstrated a strong correlation with the experimental data and revealed that the impact of Z-yarns on the mechanical properties in out-of-plane direction was more significant than that in in-plane direction. Furthermore, 3DOWSBCs had low thermal conductivity (0.29 W/m·K) and high sound transmission loss (63 dB). The environmentally friendly and excellent-performance 3DOWSBCs are a promising semi-structural industrial composites with great potential to alleviate energy consumption and promote sustainable industry development.

Effect of inner reinforcement on the torsional load-bearing performance of holed aluminum/composite thin-walled tubes

This research systematically investigated the effect on the static torsional performance of holed Al-hybrid tubes internally reinforced with thin-walled glass fiber tubes. In this context, specimens were fabricated by the filament winding method for various stacking sequences, including [90/Al/90], [Al/90], [90/Al], [±452/Al], [±452/Al/90], and [90/±452/Al]. Subsequently, experimental studies were conducted. The experimental studies indicated that, in the holed aluminum tube, because of buckling deformation of the wall under torque, the part's geometry loses its circularity and tends to take the shape of an ellipse and then loses its load-bearing capacity following tear damage. It is understood that the reinforcement applied with 90° fibers from internally is more effective than the reinforcement applied externally to delay the buckling behavior of the tube under torque in Al-hybrid structures. It is revealed that the torque carrying capacity of the [±452/Al/90] structure increases by a factor of 2.7 compared to the aluminum tube in terms of specific torque; the value of 3.31Nm/gr for the Al tube is found to be 4.15 Nm/gr for the hybrid structure. Regarding fabrication techniques, it is seen that the removable plaster mold method can be successfully used to obtain internally reinforced Al-hybrid specimens.

Interscalable material microstructure organization in performance-based computational design

Various parameters can be integrated in material-based computational design in architecture. Materials are the main driver of these processes and evaluated with the constraints related to the form, performance, and fabrication techniques. However, current methodologies mostly involve investigating already existing materials. Studies on computational material design, in which new materials are developed by designing their microstructures in response to the performative issues, are generally undertaken at the material scale, and not adopted to the architectural design process yet. To resolve this issue, the methodology titled Interscalable Material Microstructure Organization in Performance-based Computational Design (I2MO_PCD) is developed and presented in three stages, including (1) identification of different types of material microstructures, (2) computational material design, and (3) prototyping. Data-based material modelling and visualization, and algorithmic modelling techniques are utilized, followed by various performance simulations as a part of an iterative process. New microstructure organizations are designed computationally, organized under three main groups as linear-curvilinear, crystal and metaball-voronoi. The outcomes of different performance analyses, including structure, radiation, direct sun hours, acoustics and thermal bridge were compared. Thus, the role of geometrical organization of microstructures, scales and material types in different performance computations were identified, by designing and fabricating synthetic materials.

Review on Hydrogel Based Systems and their use in Drug Delivery for Wound Healing & Wound Management

Abstract: The largest organ of the human body, the skin, shields the body from the outside environment. Despite having a great capacity for regeneration, major skin abnormalities cannot heal on their own and must be covered with artificial skin. In recent years, significant advancements have been achieved in the area of skin tissue engineering to create novel skin replacements. Because of their porous as well as moisturized polymeric structural composition, hydrogels are one of the choices with the greatest ability to imitate the natural skin microenvironment. Naturally derived polymers, synthesized polymers, polymerizable synthetic monomolecules, as well as mixtures of natural and synthesized polymers, can all be used to create hydrogels. They can be used to assist in the regeneration as well as repair of the wounded dermis, epidermis or else both by dressing various wounds permanently or temporarily. Hydrogels possess distinct properties like lightweight, stretchable, biocompatible, and biodegradable; they have the potential to be incorporated as flexible solutions for the care of chronic wounds. Additionally, these characteristics make hydrogels appropriate for use in the pharmaceutical and medical industries. Physical, chemical, and hybrid bonding are all involved in the creation of hydrogels. Several processes, including solution casting, solution mixing, bulk crosslinking polymerization, the free radical mechanism, radiation therapy, and the development of interpenetrating networks, are used to create the bonding. This review primarily focuses on the type of wounds with phases in wound healing and the many kinds of hydrogels based on cross-linking, ionic charge, physical properties, source etc., and it also describes potential fabrication techniques for hydrogel design in biomedical applications, drug delivery as well as wound management hydrogel systems. Hydrogel-based systems for wound recovery and management are described, as well as current research & future prospective of hydrogel-based drug delivery systems in wound healing for topical applications.

Advancements in Artificial Intelligence-mediated Fabrication of 3D, 4D, and 5D Printed for Fabrication of Drug Delivery Formulations

: One of the most powerful and inventive fabrication techniques used to create novel structures and solid materials using precise additive manufacturing technology is 5D and 4D printing, which is an improved version of 3D printing. It catches people's attention because of its capacity to generate fast, highly complex, adaptable product design and fabrication. Real-time sensing, change adaptation, and printing state prediction are made possible by this technology with the use of artificial intelligence (AI). The process of 3D printing involves the use of sophisticated materials and computer-aided design (CAD) with tomography scanning controlled by artificial intelligence (AI). The printing material is deposited according to the specifications of the file, typically in STL format; however, the printing process takes time.4D printing, which incorporates intelligent materials with time as a fourth dimension, can solve this drawback. About 80% of the time will be saved by this technique's self-repair and self-assembly qualities. One limitation of 3D printing is that it cannot print complex shapes with curved surfaces. However, this limitation can be solved by using 5D printing, which uses rotation of the print bed and extruder head to achieve additive manufacturing in five different axes. Some printed materials are made sensitive to temperature, humidity, light, and other parameters so they can respond to stimuli. With its effective and efficient manufacturing for the necessary design precision, this review assesses the potential of these procedures with AI intervention in medicine and pharmacy.

A Survey Paper on Plastic Solar Cell Technology

The demand of energy is increasing day by day so non-conventional source of energy has to be used. Sun is the nonconventional source of energy. Conventional solar panels convert solar energy into electrical energy. A plastic solar cell is the type of photovoltaic that makes use of organic electronics dealing with conductive organic polymers or small molecules for light absorption and charge transport to produce electricity from sunlight by the photovoltaic effect. Polymers Provide the Advantage of Solution Processing at Room Temperature, which is Less Expensive and Enables One to Use Plastics. Therefore, If Silicon Is Replaced with Polymer Nanowires, The Solar Cell Would Be Much Lighter and Ultimately Less Costly. These Solar Cells are Thin, Several Microns in Diameter, and Scavenge All the Rays from the Sun's Radiation. Plastic Solar Cell Technology is Based on Conjugated Polymers and Molecules. Polymer Solar Cells have Generated Considerable Interest Since it Provides Environmentally Friendly, Flexible, Lightweight, Low Cost, Possibility of High-Efficiency Solar Cells in the Last Couple of Decades. Plastic Solar Cells are More Efficient and Viable in Usage. This dissertation focuses on the development and optimization of plastic solar cell technology, in particular this potential towards flexible, lightweight, and cost-effective alternative sources to traditional silicon-based solar cells. The focus of the present research work is to find optimum organic materials for higher efficiency and stability in plastic solar cells, varying from conjugated polymers to small organic molecules. Some of the main goals are improving the charge transport mechanisms and optimizing the architecture of devices through state-of-the-art techniques of fabrication, like roll-to-roll printing and layer-by-layer deposition. The other key aspect is that the project assesses the environmental aspects and lifecycle of plastic solar cells to ensure an environmentally friendly production process. Huge preliminary results were achieved at high power conversion efficiencies and durability has been greatly improved, targeting very wide spread application from portable electronics up to building-integrated photovoltaics. Therefore, the discovery of plastic solar cells might be a major step for applicable solutions in renewable energy and towards overcoming the world's increasing energy challenges.

Stochastic to Deterministic: A Straightforward Approach to Create Serially Perfusable Multiscale Capillary Beds.

Generation of in vitro tissue models with serially perfused hierarchical vasculature would allow greater control of fluid perfusion throughout the network and enable direct mechanistic investigation of vasculogenesis, angiogenesis, and vascular remodeling. In this work, we have developed a method to produce a closed, serially perfused, multiscale vessel network fully embedded within an acellular hydrogel, where flow through the capillary bed is required prior to fluid exit. We confirmed that the acellular and cellular gel-gel interface was functionally annealed without preventing or biasing cell migration and endothelial self-assembly. Multiscale connectivity of the vessel network was validated via high-resolution microscopy techniques to confirm anastomosis between self-assembled and patterned vessels. Lastly, using a simple acrylic cassette and fluorescently labeled microspheres, the multiscale network was demonstrated to be perfusable. Directed flow from inlet to outlet mandated flow through the capillary bed. This method for producing closed, multiscale vascular networks was developed with the intention of straightforward fabrication and engineering techniques so as to be a low barrier to entry for researchers who wish to investigate mechanistic questions in vascular biology. This ease of use offers a facile extension of these methods for incorporation into organoid culture, organ-on-a-chip (OOC) models, and bioprinted tissues.

Controllable Microwave Heating for Energy-Efficient and Universal Synthesis of Atomically Dispersed Metals on Nitrogen-Doped Carbon Nanofibers.

Carbon-supported single-atom catalysts (SACs) have shown great potential in electrocatalysis, whereas traditional synthesis methods typically involve energy-intensive carbonization processes and unfavorable atomic migration and aggregation. Herein, an energy-efficient and universal strategy is developed to rapidly fabricate various SACs on nitrogen-doped hierarchically porous carbon nanofibers (M-TM/NPCNFs, TM = Fe, Co, Ni, FeCo, and FeNi) by electrospinning and controllable microwave heating technique. Such microwave heating technique enables an ultrafast heating rate (ramping to 900°C in 5 min) to greatly suppress the random migration and aggregation of metal species. Meanwhile, the energy consumption and time can be reduced to 2.5% and less than half an hour, respectively, compared to traditional pyrolysis methods. As a proof of concept, the synthesized M-Fe/NPCNFs with abundant Fe-N4 sites exhibit remarkable oxygen reduction reaction (ORR) activity with a high half-wave potential (E1/2 = 0.88 V) in alkaline media, excellent performance in Zn-air battery with a large discharge specific capacity (801 mAh g-1) and long-term cycle durability (over 1000 h), demonstrating the great potential of the microwave heating technique in efficient fabrication of SACs for energy related applications.

Advances and Challenges in Polymer-Based Scaffolds for Bone Tissue Engineering: A Path Towards Personalized Regenerative Medicine

Polymers have become essential in advancing bone tissue engineering, providing adaptable bone healing and regeneration solutions. Their biocompatibility and biodegradability make them ideal candidates for creating scaffolds that mimic the body’s natural extracellular matrix (ECM). However, significant challenges remain, including degradation by-products, insufficient mechanical strength, and suboptimal cellular interactions. This article addresses these challenges by evaluating the performance of polymers like poly(lactic-co-glycolic acid) (PLGA), polycaprolactone (PCL), and polylactic acid (PLA) in scaffold development. It also explores recent innovations, such as intelligent polymers, bioprinting, and the integration of bioactive molecules to enhance scaffold efficacy. We propose that overcoming current limitations requires a combination of novel biomaterials, advanced fabrication techniques, and tailored regulatory strategies. The future potential of polymer-based scaffolds in personalised regenerative medicine is discussed, focusing on their clinical applicability.

Recent Advancements in Fabrication, Separation, and Purification of Hierarchically Porous Polymer Membranes and Their Applications in Next-Generation Electrochemical Energy Storage Devices

Abstract: In recent years, hierarchically porous polymer membranes (HPPMs) have emerged as promising materials for a wide range of applications, including filtration, separation, and energy storage. These membranes are distinguished by their multiscale porous structures, comprising macro-, meso-, and micropores. The multiscale structure enables optimizing the fluid dynamics and maximizing the surface areas, thereby improving the membrane performance. Advances in fabrication techniques such as electrospinning, phase separation, and templating have contributed to achieving precise control over pore size and distribution, enabling the creation of membranes with properties tailored to specific uses. In filtration systems, these membranes offer high selectivity and permeability, making them highly effective for the removal of contaminants in environmental and industrial processes. In electrochemical energy storage systems, the porous membrane architecture enhances ion transport and charge storage capabilities, leading to improved performance in batteries and supercapacitors. This review highlights the recent advances in the preparation methods for hierarchically porous structures and their progress in electrochemical energy storage applications. It offers valuable insights and references for future research in this field.

2025 Roadmap on 3D Nano-magnetism.

The transition from planar (2D) to three-dimensional (3D) magnetic nanostructures represents a significant advancement in both fundamental research and practical applications, offering vast potential for next-generation technologies like ultrahigh-density storage, memory, logic, and neuromorphic computing. Despite being a relatively new field, the emergence of 3D nanomagnetism presents numerous opportunities for innovation, prompting the creation of a comprehensive roadmap by leading international researchers. This roadmap aims to facilitate collaboration and interdisciplinary dialogue to address challenges in materials science, physics, engineering, and computing.
The roadmap comprises eighteen sections, roughly divided into three parts. The first section explores the fundamentals of 3D nanomagnetism, focusing on recent trends in fabrication techniques and imaging methods crucial for understanding complex spin textures, curved surfaces, and small-scale interactions. Techniques such as two-photon lithography and focused electron beam-induced deposition enable the creation of intricate 3D architectures, while advanced imaging methods like electron holography and Lorentz electron Ptychography provide sub-nanometer resolution for studying magnetization dynamics in three dimensions. Various 3D magnetic systems, including coupled multilayer systems, artificial spin ice, magneto-plasmonic systems, topological spin textures, and molecular magnets, are discussed.
The second section introduces analytical and numerical methods for investigating 3D nanomagnetic structures and curvilinear systems, highlighting geometrically curved architectures, interconnected nanowire systems, and other complex geometries. Finite element methods are emphasized for capturing complex geometries, along with direct frequency domain solutions for addressing magnonic problems.
The final section focuses on 3D magnonic crystals and networks, exploring their fundamental properties and potential applications in magnonic circuits, memory, and spintronics. Computational approaches using 3D nanomagnetic systems and complex topological textures in 3D spintronics are highlighted for their potential to enable faster and more energy-efficient computing.&#xD.

Realization of High-Fidelity CZ Gate Based on a Double-Transmon Coupler

Striving for higher gate fidelity is crucial not only for enhancing existing noisy intermediate-scale quantum devices, but also for unleashing the potential of fault-tolerant quantum computation through quantum error correction. A recently proposed theoretical scheme, the double-transmon coupler (DTC), aims to achieve both suppressed residual interaction and a fast high-fidelity two-qubit gate simultaneously, particularly for highly detuned qubits. Harnessing the state-of-the-art fabrication techniques and a model-free pulse-optimization process based on reinforcemefor example, would\nenable not only efficient fault-tolerant quantum computing with error correction but also\neffective mitigation of errors in current noisy intermediate-scale quantum devices. for single-qubit gates. The performance of the DTC scheme demonstrates its potential as a competitive building block for superconducting quantum processors. Published by the American Physical Society 2024

Development platform for UV-NIL processes using polymer masters produced by laser ablation and photolithography

Ultraviolet nanoimprint lithography (UV-NIL) is a versatile and cost-effective technique for the fabrication of micro- and nanostructures by copying master patterns in a planar or a roll-to-roll process through curing of a liquid UV-sensitive precursor. For applications with a high pattern complexity, new UV-NIL process chains must be specified. Master fabrication is a challenging part of the development and often cannot be accomplished using a single master fabrication technique. Therefore, an approach combining different patterning fabrication techniques is developed here for polymer masters using laser direct writing and photolithography. The polymer masters produced in this way are molded into inverse silicone stamps that are used for roll-to-roll replication into an acrylate formulation. To fit the required roller size for large-area UV-NIL, several submasters with micrometer-sized dot and line gratings and prism arrays, which have been patterned by these different techniques, are assembled to final size of ∼200 × 600 mm2 with an absolute precision of better than 50 µm. The size of the submasters allows the use of standard laboratory equipment for patterning and direct writing, thus enabling the fabrication of micro- and even nanostructures when electron-beam writing is utilized. In this way, the effort, time, and costs for the fabrication of masters for UV-NIL processes are reduced, enabling further development for particular structures and applications. Using this approach, patterns fabricated with different laboratory tools are finally replicated by UV-NIL in an acrylate formulation, demonstrating the high quality of the whole process chain.

A facile approach for fabricating efficient and stable perovskite solar cells.

Perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs) can be produced using a variety of methods, such as different fabrication methods, device layout modification, and component and interface engineering. The efficiency of a perovskite solar cell is largely dependent on the overall quality of the perovskite thin-film in every scenario. The utilization of spin-coating followed by the antisolvent pouring (ASP) method is prevalent in nearly all fabrication techniques to achieve superior perovskite thin-films. Nevertheless, there are a few guidelines that must be followed precisely when using the ASP approach, including the antisolvent amount, duration, and area for dropping. The aforementioned challenging and necessary strategies frequently result in perovskite thin-films with pinholes, tiny grains, and broad grain boundaries, which impair the performance of PSCs. Therefore, the implementation of a straightforward approach that does not require the use of such complex ASP steps is crucial. Here, we employ a simple process that involves the hot-dipping of lead iodide (PbI2) thin-films in a hot solution of methylammonium iodide (MAI) and formamidinium iodide (FAI) in isopropanol (IPA) to produce high-quality perovskite thin-films. As the time required for the desired perovskite to crystallize is critical, we carefully examined various hot-dipping process times, such as 10 seconds, 20 seconds, 30 seconds, and 40 seconds. These time intervals yielded thin-films, which were named PSK-10, PSK-20, PSK-30, and PSK-40, respectively. Morphological and optoelectronic characterization demonstrated the high quality of the perovskite thin-films obtained through dipping PbI2 for 30 seconds. Consequently, the PSK-30-based PSCs produced higher PCEs of up to 21.52% compared to those of the ASP-based devices (20.79%). Furthermore, the unsealed PSCs prepared with PSK-30 and ASP were assessed for 252 hours at 25 °C and 40-45% relative humidity in order to determine their operational stability. The ASP-based device showed poor stability, retaining only 10% of its original PCE, whereas the PSK-30-based device retained 70% of its initial PCE. These results offer a new and viable approach for producing highly efficient and stable PSCs.

Interfacial Engineering of Polymer Solid-State Lithium Battery Electrolytes and Li-Metal Anode: Current Status and Future Directions.

A combination of material innovations, advanced manufacturing, battery management systems, and regulatory standards is necessary to improve the energy density and safety of lithium (Li) batteries. High-energy-density solid-state Li-batteries have the potential to revolutionize industries and technologies, making them a research priority. The combination of improved safety and compatibility with high-capacity electrode materials makes solid-stateLi-batteries with polymer solid-electrolytes an attractive option for applications where energy density and safety are critical. While polymer-based solid-state Li-batteries hold enormous promise, there are still several challenges that must be addressed, particularly regarding interface between polymer solid-electrolyte and Lianode. There are significant advancements in improving the performance of solid-state Li batteries, and researchers continue to explore new methods to address these challenges. These improvements are critical for enabling the widespread adoption of solid-state Li-batteries invariety of applications, from electrical vehicles to portable electronics. Here, common polymer solid-electrolyte and its interface challenges with Lianode are first introduced, highlighting the trend in polymer solid-state-electrolyte research toward enhancing stability, safety, and performance of solid-state Li-batteries. This includes developing novel polymer materials with improved properties, exploring advanced fabrication techniques, and integrating these electrolytes into battery designs that optimize both safety and energy density.

Recent Progress on Advanced Flexible Lithium Battery Materials and Fabrication Process.

Flexible energy storage devices have attracted wide attention as a key technology restricting the vigorous development of wearable electronic products. However, the practical application of flexible batteries faces great challenges, including the lack of good mechanical toughness of battery component materials and excellent adhesion between components, resulting in battery performance degradation or failure when subjected to different types of deformation. It is imperative to develop flexible batteries that can withstand deformation under different conditions and maintain stable battery performance. This paper reviews the latest research progress of flexible lithium batteries, from the research and development of new flexible battery materials, advanced preparation processes, and typical flexible structure design. First, the types of key component materials and corresponding modification technologies for flexible batteries are emphasized, mainly including carbon-based materials with flexibility, lithium anode materials, and solid-state electrolyte materials. In addition, the application of typical flexible structural designs (buckling, spiral, and origami) in flexible batteries is clarified, such as 3D printing and electrospinning, as well as advanced fabrication techniques commonly used in flexible materials and battery components. Finally, the limitations and coping strategies in the practical application of flexible lithium batteries are discussed, which provides new ideas for future research.