Explosivity Index Research Articles

The carbon crater: Comparing anthropogenic greenhouse gas emissions to historical planetary events

Equilibrium climate sensitivity modeling relies heavily on paleoclimate records that were affected by meteorite impacts and volcanic explosions. This paper conducts a thought experiment by re-assembling known data and theories to shed new light on anthropogenic carbon waste. Anthropogenic activity, meteorite impacts and volcanic explosions all extract material from the Earth’s crust and deposit it in the atmosphere. This thought experiment tests if the mass of anthropogenic greenhouse gas emissions from 1851 to 2021 is comparable to the mass of atmospheric emissions from historical planetary events. Approximately 3.60 trillion tons of anthropogenic carbon dioxide equivalents are converted into volume and then transformed into the shape of a meteorite impact structure named the “Carbon Crater.” The 35 km crater (bounded by 34%–68% confidence intervals of 25–45 km) would rank 23rd on the list of known impact structures. The 2.6 km projectile required to create the Crater would be a 10 on the 1–10 Torino hazard scale described as “. . .capable of causing global climatic catastrophe. . .” The estimated re-occurrence interval for a projectile of this size is 5.3 million years. An interval of this time in Earth’s recent history predates homo sapiens. The Crater’s volume is exponentially larger than the 1883 eruption of Krakatoa and ranks as an 8 (“mega-colossal”) on the 0–8 Volcanic Explosivity Index. The thought experiment indicates that the Carbon Crater’s scale is comparable with large historical biospheric events. These results likely confer few direct implications for the study of the paleoclimate in climate modeling but might change conceptual understandings of atmospheric human waste. Additional empirical research is required to understand the potential impact of the Carbon Crater on conceptual change.

Tree-ring anomalies as time markers for ice-core chronologies, with special reference to 5281 BCE as the possible date of the Kikai volcanic event

The synchronization of Greenland and Antarctica ice core data with tree-ring data, other proxies, and direct observations of natural processes and events is important to understand past climatic variation and environmental change. One of the methods that is used to correct the dating of ice layers is to match volcanic eruption footprints in ice cores with tree rings, manifested as sulphate spikes and anomalous rings, respectively. In this study, we inventoried the occurrence of tree-ring anatomical anomalies and extremes in ring width during three 200-year periods. These periods included three of the eight largest Holocene volcanic eruptions, each with a Volcanic Explosivity Index (VEI) of 7. The initial period spanned from 6560 to 6360 BCE and included the eruption of Ilyinsky Volcano in Kamchatka. The second period was from 5780 to 5580 BCE, during which Mount Mazama Volcano in North America erupted. The third period was from 5380 to 5180 BCE when the Kikai Volcano in the Japanese Islands erupted. Throughout the first two periods, no substantial tree-ring anomalies were observed suggesting the absence of any significant climate consequences of a major volcanic eruption. However, in the 5380–5180 BCE period, a clear sharp decline in tree growth and an exceptionally high frequency of tree-ring anomalies were identified in 5281 BCE and the subsequent 5 years. We propose that the exceptionally narrow light rings in these 6 years are indicative of the climatic impact resulting from the Kikai volcanic eruption. We suggest utilising the year 5281 BCE as the reference year for synchronising the Greenland and Antarctica ice core chronologies. In the case that our assumption is correct, this would imply the necessity to adjust the time of the event to an earlier date compared to the dates indicated by the existing ice core chronologies of the GICC05 (Greenland Ice Core Chronology 2005), adjusted according to Kobashi (2017), and WD2014 used for creating HolVol 1.0 (Holocene ice-core volcanic eruption catalogue from 9500 BCE - 1900 CE) by 67 and 54 years, respectively, for the period around 5300 BCE. A verification of our assumption could be conducted by examining the nearby Miyake event, a spike in cosmogenic radiocarbon, of 5258 BCE. Ice core layers displaying potential signs of this event should be approximately 25 years later than the markers of the Kikai volcanic eruption.

Experimental and simulation studies on suppressing gas explosions with diverse atomized liquid droplets: Insights for improved safety in mining

Gas explosions represent a prevalent thermodynamic hazard in coal mining, significantly endangering worker safety and the operation's overall safety. Water mist stands out among various explosion suppression techniques due to its high heat absorption capacity and environmental sustainability, offering a promising avenue for application. This study introduces a custom-built pipeline gas explosion testing apparatus to investigate the suppression effects of different atomized liquid droplets on gas explosions. By collecting and analyzing experimental data from pressure sensors under varying conditions within the pipeline, we conduct a thorough comparison of the explosion suppression characteristics attributed to different atomized droplets. Based on this foundation, the Fluent software was used for numerical simulation research to further analyze the explosion suppression effects of different atomized droplets. Additionally, numerical simulations were conducted to optimize the nozzle arrangement. Our findings reveal that an increase in atomization pressure, leading to smaller droplet sizes, significantly mitigates the impulse of the gas explosion shock wave. This indicates a marked inhibitory effect of atomized droplets on gas explosions, with finer droplets showing enhanced suppression capabilities. The simulation results from the optimized nozzle arrangement can provide valuable guidance for on-site deployment. Through a combination of experimental and simulation data, this study conducts a qualitative and quantitative analysis of the suppression mechanisms offered by different atomized droplets, considering parameters such as explosion impulse, blast energy, and explosion indices. The insights gained provide a theoretical foundation for reducing the ring-breaking effect of gas explosions and enhancing explosion suppression strategies, which are crucial for ensuring the safety of coal mining operations.

Effects of explosion-venting interlayer within utility tunnels on the characteristics of natural gas explosions

With the rapid expansion of the national economy and strategic adjustments to the energy structure, natural gas, a crucial clean energy source, encounters significant safety challenges during transportation in utility tunnels, owing to its flammable and explosive nature. To effectively address the current issues in response technologies for gas explosions in utility tunnels, such as inadequate control over the flame propagation range, limited attenuation of overpressure, and the mechanical impact damage effects on the internal structures of the utility tunnels and surrounding buildings, a small-scale experimental platform was constructed independently. This platform is designed to explore how the area and position of vents affect the characteristics of methane explosions within tunnels, utilizing the explosion venting mechanism. The results indicate that, for the same venting position, the maximum flame propagation distance, speed, and peak overpressure all decrease as the venting area increases. When the vent is located at position 1 in each compartment, the reduction in maximum flame propagation distance and speed is the most significant. The maximum decrease in peak overpressure occurs at venting position 2. When the venting position is closer to the ignition source, the rate of explosion overpressure rise and the explosion index both decrease with an increase in venting area, with the most significant reduction occurring at venting position 1. Conversely, when the venting position is farther from the ignition source, the rate of explosion overpressure rise and the explosion index actually increase, with the most significant increase occurring at venting position 4. The research findings offer a theoretical foundation and scientific guidance for developing new technologies aimed at mitigating gas explosion disasters in utility tunnels through internal venting.

The 2019 pumice raft forming eruption of Volcano-F (Volcano 0403–091) and implications for hazards posed by submerged calderas

Low volcanic explosivity index (VEI) eruptions are common occurrences in the Southwest Pacific but, as demonstrated by the 2021/2022 eruption of Hunga Volcano, submerged calderas in the region are also capable of producing much larger and more hazardous eruptions. As such, characterising smaller events from potentially hazardous systems is essential. The 2019 eruption of Volcano-F, a submerged caldera, would likely have gone totally undetected had it not produced a pumice raft that inundated beaches in Fiji and eventually washed up in Australia. New data, acquired 5 months after the eruption, reveal the development of a new vent and the accumulation of at least 3.1*107 m3 bulk volume (dense rock equivalent of 5.6*106 m3) of material on the seafloor. Between 30 and 70% of erupted material entered the raft, while the rest remained near to or was dispersed down-current of the vent. This previously unaccounted for material increases the volume estimate for the eruption, confirming it as a VEI 3 event and highlights the importance of considering not just the floating component of a pumice raft forming eruption for VEI estimation. Geochemical analysis reveals the eruption comprised a homogenous batch of dacitic magma, with compositional characteristics similar to that erupted from the same volcano in 2001, and an until-now-unidentified pumice raft in the Coral Sea in 1964. Volcano-F therefore appears to have had at least three explosive eruptions in the last 60 years, indicating it is significantly at unrest. Repeated eruptions of similar composition and low crystal content magma over decadal to centennial scales indicate the existence of a melt-dominant magma body beneath the volcano. Submerged calderas, like Volcano-F, are common in the wider Southwest Pacific region, with many such calderas producing regular eruptions, implicating active magmatic recharge. Our findings motivate a need to carefully monitor and characterise even apparently small eruptions at this volcano, and others along the Tonga-Kermadec Arc. This is because such eruptions have the potential to subsequently prime or trigger more explosive eruptions and provide critical geochemical evidence about the plumbing system and evolution of the volcano, essential for understanding the diverse hazards they pose.

Hydrothermal calcite formation in Campi Flegrei caldera, Italy: unraveling carbon sink processes in alkaline volcanic systems

Understanding carbon dioxide emissions variability in volcanic regions is vital for detecting instabilities in the subvolcanic plumbing system, crucial for managing both volcanic and environmental risks. While changes in magmatic sources drive these variations, non-magmatic processes can complicate signal interpretation, especially in caldera environments. Here, geothermal systems can sequester CO2 within the bedrock through hydrothermal calcite precipitation, significantly impacting surface-level CO2 emissions. Unfortunately, few studies have explored this phenomenon, examining hydrothermal calcite origins and their effects on carbon balances and temporal gaseous patterns in active volcanic settings. Our study developed a specialized methodology for quantifying CO2 sequestered in hydrothermal calcites within alkaline caldera systems. We focused on analyzing hydrothermal calcite in lithics from volcanic deposits of eruptions of varying ages, Volcanic Explosivity Index (VEI), and eruptive vent locations to enhance the representativeness of the entire caldera bedrock. Unlike core samples from geothermal wells, which are infrequent and limited to specific depths, lithics can be easily collected, offering a comprehensive understanding of CO2 sequestration. Through extensive 3D textural characterization and isotopic investigations on hydrothermal calcite within lithic fragments from selected alkaline volcanic deposits in the Campi Flegrei caldera, our findings emphasized the significant influence of calcite sinks on the overall CO2 budget released by volcanoes throughout their evolution.

Fast, furious, and gassy: Etna's explosive eruption from the mantle

The 3930 BP Fall Stratified (FS) eruption at Mt. Etna is a rare example of a highly explosive eruption of primitive (picritic) magma directly from the mantle. The eruption produced ash plumes up to an estimated 20 km height, leading to a volcanic explosivity index (VEI) 4 (subplinian). Given its volatile-rich and primitive nature, the FS magma may have ascended rapidly from great depths to avoid fractionation and mixing within the extensive plumbing system beneath Etna. To determine the pressures from which the FS magma derived, we perform rehomogenization experiments on melt inclusions hosted in Fo90–91 olivines to resorb shrinkage bubbles and determine the initial H2O and CO2 in the melt. With measured CO2 concentrations of up to 9600 ppm, volatile solubility models yield magma storage pressures of 630–800 MPa. These correspond to depths of 24–30 km, which are comparable to the seismologically estimated Moho. Therefore, the magma's high CO2 concentration must come from carbon in the mantle (likely from subducted carbonates), as opposed to assimilation of shallow (<10 km) crustal carbonates.Diffusion modeling of H2O and forsterite zonation profiles in clear, euhedral, and crystallographically oriented olivines indicates rapid ascent of magma directly from its source region to the surface. Forsterite profiles exhibit a narrow rim of growth zoning but no detectable diffusional zoning, reflecting maximum ascent times of 1–5 days. Eighteen measured H2O profiles result in remarkably uniform decompression rates of 0.47 MPa/s (95% confidence interval of 0.16–1.28 MPa/s), which is among the fastest measured for basaltic-intermediate magmas. These decompression rates indicate that the final stage of magma ascent over the region in which H2O degasses (between the surface and ∼ 15 km) occurred extremely fast at ∼ 17.5 m/s. This eruption may provide a link between primary magma composition and eruption intensity: we propose that the unusually explosive nature of this picritic eruption was driven by high H2O and CO2 concentrations, which led to continuously rapid ascent without stalling, all the way from the Moho.

Influence of temperature and duration of pyrolysis process on calorific value of cereal straw biochar and dust explosive index

Influence of temperature and duration of pyrolysis process on calorific value of cereal straw biochar and dust explosive index

Hazard evaluation of ignition sensitivity and explosion severity for aluminum and aluminum powder-petroleum ether mixtures

The safety implications of aluminum powder and petroleum ether have garnered significant attention as two typical materials in the production process of energetic materials. To investigate the effect of the common solvent petroleum ether on the ignition and explosion characteristics of aluminum powder, ignition energy, flame propagation characteristics, and explosion pressure of three aluminum powder sizes and their mixtures with petroleum ether through a Hartmann tube test device and a 20 L spherical explosion vessel test system. Findings show that the ignition energy of aluminum powder initially decreases and then increases with the increase of petroleum ether content. At the petroleum ether concentration of 5.5 % and 11 %, the minimum ignition energies of the mixed systems of Al-Flake, Al-T4, and Al-T2 are 1–20 mJ, 5–30 mJ, 450–485 mJ, and 1–20 mJ, 5–25 mJ, 440–480 mJ, respectively. Lower than the minimum ignition energy of the original sample (1–30 mJ, 10–40 mJ, 470–510 mJ), indicating that the aluminum powder dust containing low concentration solvent (5.5%, 11 %) is more sensitive to an electric spark. The ignition energy of the mixed system is rather increased when the content of petroleum ether is further increased to 16.5 %. On the contrary, the probability of ignition and the electric spark sensitivity are decreased. With the addition of petroleum ether to Al-Flake and Al-T4, the flame propagation speed slightly decreases and the phase duration lengthens. The flame propagation characteristics and combustion state of Al-T2 with large particles remained largely unchanged after the addition of petroleum ether. During the 20 L spherical explosion vessel test, the maximum explosion pressure and explosion index of the mixed samples initially increase and then decrease with the increase in petroleum ether concentration. A small quantity of petroleum ether intensifies the reaction intensity of aluminum dust. At an aluminum powder dust concentration of 250 g m-3, the explosion pressure and explosion index of Al-Flake and Al-T4 peak at a petroleum ether content of 5.5 %, while Al-T2 reaches its peak at 11 %.

Variation Law of Hybrid Explosion Characteristic Parameters of Gas and Coal Dust Coupled with Multiple Factors.

This study aims at extensively investigating the explosion characteristics of a hybrid mixture of gas and coal dust. Accordingly, the standard 20 L spherical explosion system was applied to measure parameters such as the lower explosion limit, maximum explosion pressure, and index of the hybrid mixture of different concentrations of gas and coal dust. Moreover, different coal dust particle sizes and components were measured. With regard to coal dust with different particle sizes and components, the obtained results revealed that, while the addition of gas significantly reduced the lower explosion limit, the maximum explosion pressure and index were increased; that is to say, the presence of gas will increase the explosion risk of coal dust. However, under conditions in which the particle size of the coal dust was large or the volatile content was low, the addition of gas was found to lead to a higher decrease of the lower explosion limit; this is, while the maximum explosion pressure and explosion index were increased. Consequently, gas can be argued to have a greater influence on the explosion risk of coal dust with a large particle size or low volatile content. Furthermore, regardless of the particle size or the volatile content of coal dust, the maximum explosion pressure and explosion index of the hybrid mixture were observed to be higher than that of the pure coal dust but lower than that of the pure gas. That is to say, the explosion intensity of the gas/coal dust composite system is higher than that of pure coal dust but less than that of pure gas. The research results can provide theoretical basis for coal mine explosion disaster prevention and control and have important significance.

Reconstructing the Belbaşhanı Pumice Plinian eruption, Hasandağ Volcano, Turkey

Hasandağ volcano (Central Anatolia, Turkey) has recently underwent an increase in local seismicity and fumarolic activity since 2013. In the past, this volcano has produced multiple large explosive eruptions during the last million years. The Belbaşhanı Pumice is the product of a sub-Plinian to Plinian eruption dated at ~ 417 ± 20.5 ka (40Ar/39Ar). Here, we present a complete volcanological study including stratigraphy, glass chemistry, pumice morphology, geochronology, and eruption source parameters with the associated uncertainties, to characterize the Belbaşhanı Pumice eruption. The eruption involved a column of 18–29 km in height, with the main dispersal axis towards the northeast. A pumice layer up to ~ 17-m-thick accumulated in proximal deposits along the Belbaşhanı path, and up to 2-m-thick in medial-distal areas (~ 18 km northeast from the vent). The high and tubular vesicularity of the pumice clasts indicates that the Belbaşhanı eruption was predominantly magmatic. The bulk volume of the Belbaşhanı Pumice fallout deposit has been estimated as 0.5 and 8 km3 (with ~ 2 km3 being the mean value), which corresponds to Volcanic Explosivity Index (VEI) of at least 4 and up to 6. Both isopach and isopleth maps indicate that the volcanic vent may have been located at the intersection of the Tuz Gölü fault and Ulukışla caldera, within the Hasandağ volcanic complex. The glass composition of Belbaşhanı Pumice confirms that the eruption belongs to the Hasandağ magmatic system. The reconstruction of the Belbaşhanı Pumice eruption represents an essential baseline in providing volcanological constraints for further investigations of tephra fallout hazard assessment in Central Anatolia, especially considering that a new Plinian eruption cannot be ruled out at Hasandağ volcano in the future. The chemical and geochronological datasets presented here could aid in refining tephrochronological correlations, with the goal of synchronizing paleoenvironmental and paleoclimatic records alongside archaeological sites.

Investigation into the ignition sensitivity and detonation kinetics of Al/RDX energetic dust

Given the prevalence of Al/RDX energetic dust in industrial production, this study investigates their ignition safety and explosion hazards using Hartmann tubes and 20 L spherical explosion containers. The minimum ignition energy (MIE) increases from 20 mJ to 55 mJ as RDX content increases, indicating that adding RDX enlarges the effective particle size of the dust, thereby reducing its ignition sensitivity. A logistic regression model was used to develop a fitting equation for ignition probability, correlating dust concentration and ignition energy. The flame propagation velocity and explosion pressure of the energetic dust initially increase and then decrease with increasing RDX content. Optimal combustion characteristics were observed at 20 % RDX, with the maximum flame propagation velocity of 101 m s−1. However, the peak flame temperature decreases with increasing RDX content. The maximum explosion pressure and maximum explosion index at 1.77 MPa and 186.99 MPa m s−1 respectively, at 40 % RDX content. These findings highlight that 20 % RDX content yields the best combustion characteristics, while 40 % RDX content offers the maximum explosive potential, providing valuable insights for enhancing safety measures in industrial applications involving energetic dusts.

Hazard Identification and Risk Assessment of Biogas Plant with Proton Exchange Membrane Fuel Cell Technology

Biogas-fed proton exchange membrane fuel cell (PEMFC) plants offer a sustainable energy solution, but their operation can pose significant hazards and risks. Ensuring the safety of these plants is paramount, especially given the potential for fires, explosions, and chemical exposures. This study evaluated hazards and risks in biogasfed proton exchange membrane fuel cell (PEMFC) plants using six analytical methods: Dow's fire and explosion index (FEI), Dow's chemical expo-sure index (CEI), Hazard and Operability Study (HAZOP), Risk Matrix Analysis (RMA), Bayesian Network (BN) and ALOHA® software hazard modelling. The FEI analysis revealed that the anaerobic digester and bio-gas storage tank exhibited severe hazards (FEI =170), thereby signifying the highest risks within the plant. CEI analysis revealed the spread of the highest hydrogen sulfide (H2S) concentration up to 129 meters from the anaerobic digester and storage tank location. Further assessment was conducted, calculating risk values using the RMA and performing additional HAZOP analysis specifically for these units. The results confirmed similar risk levels (4-20) between the units, except for a higher explosion risk in the storage tank. The novelty of this research lies in the application of Bayesian Network (BN) analysis. In addition to assessing the hazards associated with PEMFC, our BN analysis reveals that the risk of fire attributed to PEMFC ranges between 10% and 18%, while the risk of explosion falls within the range of 3% to 17%. Based on the hierarchy control concept, several effective mitigation controls were proposed to enhance the safety of biogas-fed PEMFC plants. In future research, a deeper exploration of human error and equipment malfunctions within hazard modelling is crucial for a more precise hazard assessment.

Transport and deposition of the 39.8 ka Campanian Ignimbrite large-scale pyroclastic density currents (Italy)

Processes of transport and deposition of large-scale pyroclastic density currents, which transport 102−103 km3 of material, are still poorly understood. The volcanic explosivity index (VEI) 7 Campanian Ignimbrite pyroclastic density current is one such poorly understood case that is subject to lively scientific debates about its origin and processes. The Campanian Ignimbrite is related to the 39.8 ka eruption that formed the partly submarine and active Campi Flegrei caldera in Italy. The related pyroclastic density current extended over an area of more than 6000 km2 on land around the caldera, with a final runout of ∼75 km, and surmounted mountain ridges higher than 1000 m above sea level, even at distal reaches. We used physical characteristics of the ignimbrite to understand the transport and emplacement dynamics of the Campanian Ignimbrite pyroclastic density current. Thickness, mass, and clast-size distributions across paleotopography were used to infer that the main transport system was a dilute, density-stratified pyroclastic density current, which was at least 1.5 km thick, which was short-lived (possibly as short as ∼20 min), and which had a mass flow rate of ∼1011 kg/s. At its base, high-concentration undercurrents formed and interacted with the rough paleotopography, laying down a low-aspect-ratio ignimbrite sheet when on flat plains, but generating back-flows from ridges and channeling in paleovalleys. The deposit is predominantly a massive valley-pond ignimbrite facies, even across rough mountain terrains. The absence of veneer facies on steep slopes reflects the near-Newtonian rheology of the undercurrents, interpreted as fluidized dense granular flows. This work advances the interpretations of pyroclastic density current deposits, which do not necessarily directly reflect conditions in the transport system.

Comparative study on the thermal runaway characteristics of Li(NixCoyMnz)O2 batteries

Lithium-ion batteries (LIBs) generate substantial gas during the thermal runaway (TR) process, presenting serious risks to electrochemical energy storage systems in case of ignition or explosions. Previous studies were mainly focused on investigating the TR characteristics of Li(NixCoyMnz)O2 batteries with different cathode materials, but they were conducted in isolation. In this study, the thermal runaway characteristics of prismatic cells that use Li(NixCoyMnz)O2 (with x ranging from 0.33 to 0.9) cathode materials in an inert environment, which are commonly used or proposed for energy storage applications, are examined. The findings of this research show that the normalized gas generation rate remains consistent, regardless of the battery capacity or experimental chamber volume, with a value of 0.1 ± 0.03 mol∙Ah⁻1. High-capacity cells have short jetting durations, and a high nickel content leads to increased mass loss rates. The flammability limits of the gases expelled during thermal runaway, represented by the lower flammability limit (LFL), remain stable at 8 ± 1.8 % with minimal variations. However, the upper flammability limit (UFL) varies significantly, ranging from 30 % to 60 %. Increasing the battery capacity or reducing the experimental chamber volume increases the explosion index. The explosive, combustibility, and jetting duration characteristics of the emitted gases from five different battery chemical compositions provide valuable insights for risk assessment in future electrochemical energy storage systems.

Pyrolysis as a Method for Processing of Waste from Production of Cultivated Tobacco (Nicotiana tabacum L.)

Because of the current energy crisis, researchers are looking into new potential substrates for production of biofuels and for possible ways to enhance their parameters. In line with such efforts, the current study focuses on the feasibility of processing waste from the production of cultivated tobacco. The aim of this study was to assess the potential of tobacco waste as a raw material for the production of solid biofuels, such as biochar produced through pyrolysis, and to determine its basic physicochemical properties, compared to other materials used for the production of green fuels. The analyses showed calorific values of 16.16 MJ kg−1 for the raw biomass and those in the range of 24.16–27.32 MJ kg−1 for the products of pyrolysis conducted at temperatures of 400–500 °C and with a heating time in the range of 5 to 15 min. To address the safety-related issues, the study also measured the explosion index (Kst max), which, in the raw biomass, amounted to 72.62 bar s−1 and in the biochar was in the range between 82.42 and 88.11 bar s−1. The registered maximum explosion pressure was 7.37 bar in the case of raw biomass, whereas in the biochars, the value ranged from 8.09 to 8.94 bar. The findings show that tobacco waste has parameters comparable to those identified in the case of other solid biofuels, whereas the process of pyrolysis enhances the energy-related parameters without increasing the explosion class of the product.

Hazardous explosive eruptions of a recharging multi-cyclic island arc caldera

Caldera-forming eruptions of silicic volcanic systems are among the most devastating events on Earth. By contrast, post-collapse volcanic activity initiating new caldera cycles is generally considered less hazardous. Formed after Santorini’s latest caldera-forming eruption of ~1600 bce, the Kameni Volcano in the southern Aegean Sea enables the eruptive evolution of a recharging multi-cyclic caldera to be reconstructed. Kameni’s eruptive record has been documented by onshore products and historical descriptions of mainly effusive eruptions dating back to 197 bce. Here we combine high-resolution seismic reflection data with cored lithologies from International Ocean Discovery Program Expedition 398 at four sites to determine the submarine architecture and volcanic history of intra-caldera deposits from Kameni. Our shore-crossing analysis reveals the deposits of a submarine explosive eruption that produced up to 3.1 km3 of pumice and ash, which we relate to a historical eruption in 726 ce. The estimated volcanic explosivity index of magnitude 5 exceeds previously considered worst-case eruptive scenarios for Santorini. Our finding that the Santorini caldera is capable of producing large explosive eruptions at an early stage in the caldera cycle implies an elevated hazard potential for the eastern Mediterranean region, and potentially for other recharging silicic calderas.

A history of explosive eruptions at Young Damavand volcano, Iran

Young Damavand volcano is a steep isolated volcano in the Central Alborz Mountains, Iran, that is characterized by extensive lava flows and pyroclastic successions and is placed on the eroded remains of Old Damavand. Pyroclastic fall and density current deposits on all flanks of the volcano were sampled and studied. From a tephrostratigraphic and geochemical study of the proximal-medial sequences, 14 phases of explosive volcanic activity are identified, characterized by a combination of ash and pumice fall deposits, and/or dense and dilute pyroclastic density current deposits. Some explosive phases of Damavand are thought to have happened one after the other with only short time intervals, since almost no traces of paleosol can be identified between them. We also show that the intensity of the eruptions varied between different phases, confirmed by relative thickness and grain size of the different fall deposits and their distance from the crater. The evidence of numerous explosive eruptions, five of which with Volcanic Explosivity Index 4 in the history of the activity of Young Damavand volcano, shows the importance of assessing its potential volcanic hazards.

A study of the effect of hydrogen on methane deflagration characteristics in a square confined space

Macroscopic and microscopic explosion kinetic properties of H2/CH4/air mixtures are investigated. The explosion characteristics of CH4/air mixtures with different hydrogen blending ratios(0–25%) are investigated experimentally. It is found that the increase of hydrogen blending ratios has almost no effect on the peak overpressure of the methane gas explosion, but the rate of maximum pressure rise, the explosion index and the flame propagation velocity increase significantly. The effect of hydrogen blending ratios on the chemical kinetics of CH4-air mixtures is analyzed based on the CHEMKIN software. The concentration of key radicals, which play a major role in the reaction, does not change much as the hydrogen blending ratio increases. A prediction model of explosion overpressure in a square confined space is established using the segmentation method, and it is verified that the relative errors between the model calculation results and experimental results are less than 10%.

Turbulence generated by dust dispersion in the standard 1 m3 vessel

The standard 1 m3 vessel is an apparatus recommended for an assessment of dust explosion indices by ISO, European and American Standards. However the definition of the vessel construction given in the Standards leaves some room when designing it. That may lead to significantly different results obtained in vessels built in different laboratories even when all of them meet the requirements of the Standards. One of key parameters that should be controlled in the tests is turbulence. Several authors reported measurements of turbulence intensity in the 1 m3 vessel. However, all of those results were obtained for pure air dispersed from the dust dispersion system. The paper presents results of turbulence measurements performed in the 1 m3 vessel built and used at Experimental Mine Barbara of Central Mining Institute, Poland. In previous measurements transient flow velocity in the vessel was generated by dust injection from the dust dispersion system. For the measurement the Bi-Directional Velocity Probe developed by McCaffrey and Heskestad ((McCaffrey B.J. (1976)) was used. The construction of the probe was modified to improve its performance in the dusty conditions. The tests were performed for several nominal dust concentrations of two dusts. From the measurements the root-mean-square of instantaneous velocity (u'rms) was calculated. The results were compared with the results obtained for pure air in the dust dispersion system. The presence of dust modifies turbulence in the vessel. Its intensity is reduced and the flow development is delayed.