Excitation Power Research Articles

An Electrically Pumped Topological Polariton Laser.

With a seminal work of Raghu and Haldane in 2008, concepts of topology have been introduced into optical systems, where some of the most promising routes to an application are efficient and highly coherent topological lasers. While some attempts have been made to excite such structures electrically, the majority of published experiments use a form of laser excitation. In this paper, we use a lattice of vertical resonator polariton micropillars to form an exponentially localized topological Su-Schrieffer-Heeger defect. Upon electrical excitation, the system unequivocally shows polariton lasing from the topological defect using a carefully placed gold contact. Despite the presence of doping and electrical contacts, the polariton band structure clearly preserves its topological properties. At high excitation power the Mott density is exceeded, leading to highly efficient lasing in the weak coupling regime. This work is an important step toward applied topological lasers using vertical resonator microcavity structures.

Photoluminescence studies of the charge states of nitrogen vacancy centers in diamond after arsenic ion implantation and subsequent annealing

In this work, nitrogen vacancy (NV) centers of high nitrogen diamond implanted with arsenic ions were investigated by photoluminescence spectroscopy. The transition of the NV center charge state was discussed by the regularly changing laser excitation power and measurement temperature following high-temperature annealing. After high-temperature annealing, the amorphous layer generated by arsenic ion implantation is transformed into a graphitization layer, resulting in a decrease in the NV yield. The electric neutral NV (NV0) center and negatively charged NV (NV−) center are affected by both radiation recombination and Auger recombination with increasing laser power. Accompanied by the increasing measurement temperature, the intensities of NV centers gradually decreased and eventually quenched. In addition, the charge states of NV− and NV0 centers were undergoing a transition. The zero phonon line positions of NV centers were also red shift, it was attributed to the dominant role of electron–phonon interaction in the temperature-dependent displacement of diamond energy gaps. The full width at half maxima of NV center were broadened significantly at higher temperatures.

A versatile Raman setup with time-gating and fast wide-field imaging capabilities

Raman spectroscopy is a well-established method for chemical identification, with a wide variety of applications. The two major limitations are that fluorescence can hamper detection, and that Raman imaging is slow; it typically takes multiple hours to measure even a small surface area. We have developed a multimodal setup that mitigates these limitations. The setup has a point-scanning mode that allows for time-gated as well as continuous Raman spectroscopy, and both modes use an 80 MHz, 532 nm excitation laser with up to 20 W of power. The fluorescence suppression capabilities of the setup were demonstrated by comparing time-gated to continuous detection of a Dracaena leaf. Raman bands showed a 4-8 times improvement in signal-to-background ratio, and one band that was invisible in the continuous measurement, became visible in the time-gated measurement.The setup also has a 4-band simultaneously detected wide-field mode. Using a set of beam splitters, the Raman signal from the sample is split. This signal is imaged onto four separate cameras, each with a specific band-pass filter. The wide-field data were processed using principal component analysis with k-means clustering. To illustrate the wide-field capabilities of the setup, a 1mm2 sample containing aspirin, caffeine and paracetamol was measured using 10 W excitation power. A 10-second measurement enabled identification of the compounds, and a 1-second measurement showed promising results. This brings the setup close to real-time imaging, showing great potential for applications in quality control or for measuring samples that change over time.

Synthesis of NaYbF4:Er nanocrystals with controllable size, morphology, and multicolor upconversion luminescence for Anticounterfeiting applications

The dopant concentration of lanthanide ions plays one of the critical roles to manipulate size/morphology, photon population pathway, or luminescence color/intensity in upconversion nanoparticles (UCNCs), which have a significant effect on their application developments. Herein, a strategy is demonstrated for simultaneous size, morphology and multicolor luminescence tuning in the single doped lanthanide activator Er3+ ion system through simply tuning the concentration of Er3+ ions. The doping of different Er3+ ion amounts in NaYbF4:Er nanocrystals can control nanoparticle size (from several hundreds to tens of nanometers) and morphology. Moreover, multicolor upconversion luminescence involving green, yellow, orange and red can be obtained in the NaYbF4:Er UCNCs by changing the excitation power density of 980 nm laser. Mechanistic studies reveal the size and morphology evolution process as well as saturation/cross relaxation effects induced tunable multicolor emissions. These nanocrystals have demonstrated promising potential applications in anticounterfeiting. Our results not only provide a simple and feasible route for simultaneous size/morphology control and multicolor upconversion luminescence tuning, but also can further expand the utility of UCNCs in the frontier applications ranging from optical encoding to information security.

Near-infrared two-photon absorption and excited state dynamics of a fluorescent diarylethene derivative

Near-infrared two-photon absorption and excited state dynamics of a fluorescent diarylethene (fDAE) derivative were investigated by time-resolved absorption and fluorescence spectroscopies. Prescreening with quantum chemical calculation predicted that a derivative with methylthienyl groups (mt-fDAE) in the closed-ring isomer has a two-photon absorption cross-section larger than 1000 GM, which was experimentally verified by Z-scan measurements and excitation power dependence in transient absorption. Comparison of transient absorption spectra under one-photon and simultaneous two-photon excitation conditions revealed that the closed-ring isomer of mt-fDAE populated into higher excited states deactivates following three pathways on a timescale of ca. 200 fs: (i) the cycloreversion reaction more efficient than that by the one-photon process, (ii) internal conversion into the S1 state, and (iii) relaxation into a lower state (S1’ state) different from the S1 state. Time-resolved fluorescence measurements demonstrated that this S1’ state is relaxed to the S1 state with the large emission probability. These findings obtained in the present work contribute to extension of the ON–OFF switching capability of fDAE to the biological window and application to super-resolution fluorescence imaging in a two-photon manner.Graphical

Novel Photocatalyst Based on Through‐Space Charge Transfer Induced Intersystem Crossing Enables Rapid and Efficient Polymerization Under Low‐Power Excitation Light

AbstractCurrently, most photoredox catalysis polymerization systems are limited by high excitation power, long polymerization time, or the requirement of electron donors due to the precise design of efficient photocatalysts still poses a great challenge. Herein, we propose a new approach: the creation of efficient photocatalysts having low ground state oxidation potentials and high excited state energy levels, along with through‐space charge transfer (TSCT) induced intersystem crossing (ISC) properties. A cabazole‐naphthalimide (NI) dyad (NI‐1) characterized by long triplet excited state lifetime (τT=62 μs), satisfactory ISC efficiency (ΦΔ=54.3 %) and powerful reduction capacity [Singlet: E1/2 (PC+1/*PC)=−1.93 eV, Triplet: E1/2 (PC+1/*PC)=−0.84 eV] was obtained. An efficient and rapid polymerization (83 % conversion of 1 mM monomer in 30 s) was observed under the conditions of without electron donor, low excitation power (10 mW cm−2) and low catalyst (NI‐1) loading (<50 μM). In contrast, the conversion rate was lower at 29 % when the reference catalyst (NI‐4) was used for photopolymerization under the same conditions, demonstrating the advantage of the TSCT photocatalyst. Finally, the TSCT material was used as a photocatalyst in practical lithography for the first time, achieving pattern resolutions of up to 10 μm.

Moxifloxacin promotes two-photon microscopic imaging for discriminating different stages of DSS-induced colitis on mice

BackgroundAccurate diagnosis of patients with ulcerative colitis (UC) can reduce their risk of developing colorectal cancer. This study intended to explore whether moxifloxacin, an agent with fluorescence potential, could promote two-photon microscopy (TPM) diagnosis for mice with dextran sodium sulfate (DSS)-induced colitis, which could imitate human UC. Methods32 Balb/c mice were randomly divided into 4 groups: control, acute colitis, remission colitis and chronic colitis. Fluorescence parameters, imaging performance, and tissue features of different mouse models were compared under moxifloxacin-assisted TPM and label-free TPM. ResultsExcitation wavelength of 720 nm and moxifloxacin labeling time of 2 min was optimal for moxifloxacin-assisted TPM. With moxifloxacin labeling for colonic tissues, excitation power was decreased to 1/10 of that without labeling while fluorescence intensity was increased to 10-fold of that without labeling. Photobleaching was negligible after moxifloxacin labeling and moxifloxacin fluorescence kept stable within 2 h. Compared with the control group, moxifloxacin fluorescence was reduced in the three colitis groups (P < 0.05). Meanwhile, the proportion of enhanced moxifloxacin fluorescence regions was (22.4 ± 1.6)%, (7.7 ± 1.0)%, (13.5 ± 1.7)% and (5.0 ± 1.3)% in the control, acute, remission and chronic groups respectively, with significant reduction in the three colitis groups (P < 0.05). Besides, variant tissue features of experimental colitis models were presented under moxifloxacin-assisted TPM, such as crypt opening, glandular structure, adjacent glandular space and moxifloxacin distribution. ConclusionsWith unique biological interaction between moxifloxacin and colonic mucosa, moxifloxacin-assisted TPM imaging is feasible and effective for accurate diagnosis of different stages of experimental colitis.

Plasmon-driven substitution of 4–mercaptophenylboronic acid to 4-nitrothiophenol monitored by surface-enhanced Raman spectroscopy

Plasmon-driven reactions on plasmonic nanoparticles (NPs) occur under significantly different conditions from those of classical organic synthesis and provide a promising pathway for enhancing the efficiency of various chemical processes. However, these reactions can also have undesirable effects, such as 4-mercaptophenylboronic acid (MPBA) deboronation. MPBA chemisorbs well to Ag NPs through its thiol group and can subsequently bind to diols, enabling the detection of various biological structures by surface-enhanced Raman scattering (SERS), but not upon its deboronation. To avoid this reaction, we investigated the experimental conditions of MPBA deboronation on Ag NPs by SERS. Our results showed that the level of deboronation strongly depends on both the morphology of the system and the excitation laser wavelength and power. In addition, we detected not only the expected products, namely thiophenol and biphenyl-4,4-dithiol, but also 4-nitrothiophenol (NTP). The crucial reagent for NTP formation was an oxidation product of hydroxylamine hydrochloride, the reduction agent used in Ag NP synthesis. Ultimately, this reaction was replicated by adding NaNO2 to the system, and its progress was monitored as a function of the laser power, thereby identifying a new reaction of plasmon-driven −B(OH)2 substitution for –NO2.

Numerical investigation on vortex characteristics in a low-head Francis turbine operating of adjustable-speed at part load conditions

In this paper, the vortex characteristics in a low-head Francis turbine operating of adjustable-speed at part load conditions are numerically investigated. First, the rules of fixed-speed and adjustable-speed operations are introduced in detail, aiming at operating limits extension. Second, comparative analysis on vortex rope is conducted, with emphasis on vortex rope volume, tail water excitation and spontaneous power swing. Finally, inter-blade vortex has been analyzed and successfully demonstrated, and its induced high amplitude pressure fluctuation characteristic is explored. It is found that at deep part load, vortex rope volume and power swing coefficient of adjustable-speed operation decreased by 69 % and 61 % respectively. The amplitude of Rheingans frequency decreased by 17 %, while the amplitude of blade passing frequency increased by 83 %. After decreasing runner speed, inter-blade vortex is stranded at blade suction surface leading-edge. In addition to low-frequency disturbance, pressure fluctuation shows high-frequency wide-band characteristics. It is concluded that adjustable-speed operation has beneficial effects on improvement of cavity cavitation and energy stability. As for hydraulic stability, the Rotor-Stator Interaction effect cannot be ignored. After changing runner speed, the inter-blade vortex becomes more serious, which could provoke low-cycle and high-cycle fatigue of the blades.

Evaluation of typical rail defects by induction thermography: experimental results and procedure for data analysis during high-speed laboratory testing

ABSTRACT Rail inspection via non-destructive testing (NDT) techniques is a critical area of research in the railway industry, significantly affecting transport safety and security. Conventional NDT methods face limitations in on-site applications, with emerging techniques improving defect detectability and inspection speed. Recent advances have highlighted infrared thermography, particularly induction thermography, as a promising alternative due to its non-contact, full-field capabilities for detecting both surface and subsurface rail defects. This study explores induction thermography in detecting key defects such as transversal cracks and head checks in different rail tracks. Novel approaches and procedure for data reconstruction that enhance the thermographic inspection results and allow for dynamic testing conditions are proposed. Additionally, the potential for high-speed on-site applications was investigated, utilizing infrared mirrors and optimally shaped coils. Various test parameters, including geometrical resolution, excitation power, and inspection speed up to 20 km/h, were systematically examined.

Novel transparent glass-ceramics of NaLu2F7:Yb3+, Er3+ for accurate temperature sensing and anti-counterfeiting

The development of up-conversion materials with strong emission and low thermal effect is crucial for achieving higher temperature sensing accuracy. In this work, novel transparent NaLu2F7:xYb3+, 0.02Er3+ (x = 0, 0.2, 0.4, 0.6, 0.8, 1) glass-ceramics (GCs) were manufactured by melt-quenching technique. The temperature sensing capabilities of GC20 based on thermally coupled energy levels (TCELs) and non-thermally coupled energy levels (nTCELs) were studied, which enable self-calibration. Our findings reveal that the maximum relative sensitivity (SRmax) of TCELs and nTCELs are 1.19% K−1 and 0.89% K−1 at 313 K, respectively. More importantly, the UC luminescence color of GC20 varies from yellow to green as the excitation power increases. The unique phenomenon can be utilized for anti-counterfeiting purposes without any background interference. Overall, our results demonstrate that these novel GCs possess significant potential in accurate temperature sensing and anti-counterfeiting fields.

Study of optical properties birefringent of hema - DR13

The following paper is a detailed study of the optical properties of HEMA-DRI3 from optical birefringence can be induced azopolymeric material. Based on the method of two-photon absorption, anisotropy is generated due to the reorientation of the chromophores in the sample of HEMA-DR13. Using allow-power laser He-Ne, and a laser Nd-YAG medium power, it was possible to implement an optical system which allows observing the subsequent quantification of photoinduced bireftingence in said material. Subsequently comparing the results obtained with different theoretical models, thereby determining the characteristic times (time of excitation and relaxation time) of HEMA-DR13. Additionally, a study of the response signal based on the excitation power and the temperature of the material being able to obtain the relationship between this variables and the intensity of bircfringence.

Strong coupling between colloidal quantum dots and dielectric cavity investigated by both photoluminescence spectrum and reflection spectrum at room temperature

In this study, the angle-resolved photoluminescence spectra and reflection spectra from colloidal quantum dots on SiO2/Si material were investigated at room temperature. The strong coupling between quantum dots and F-P cavity was verified by both the photoluminescence spectral splitting and reflection dispersion. A Rabi splitting was obtained from both angle-resolved photoluminescence spectra and reflection spectra. The Hopfield coefficient of exciton and photon for polariton branches were calculated and analyzed. The relationship between Rabi frequency and excitation power for colloidal quantum dots was also studied. A method was proposed and used to characterize the cavity mode and the reflection dispersion by using open-aperture and close-aperture reflection spectra.

Metallic photoluminescence of plasmonic nanoparticles in both weak and strong excitation regimes

Abstract The luminescent nature of plasmonic nanoparticles (NPs) has been intensively investigated in recent years. Plasmon-enhanced electronic Raman scattering and the radiation channels of metallic photoluminescence (PL) involving conventional carrier recombinations and emergent particle plasmons are proposed in the past few decades but largely limited to weak excitation regimes. Here, we systematically examine the PL evolution of plasmonic NPs under different excitation power levels. The spectral resonances and chromaticity of PL are investigated within and beyond the scope of geometry conservation. Results indicate the nature of PL in plasmonic NPs could be a process of graybody radiation, including one factor of plasmonic emissivity in the weak excitation regime and the other factor of blackbody radiation in the strong excitation regime. This comprehensive analysis provides a fundamental understanding of the luminescent nature of plasmonic NPs and highlights their potential applications in transient temperature detection at the nanometer scale.

Investigation of Exciton Dynamics to Confirm Coupling Effects Using a Comparison between Ensemble and Single Laterally‐Coupled GaAs Quantum Dot Molecules

Herein, time‐integrated and time‐resolved photoluminescence (PL) measurement experiments are performed on coupled GaAs quantum dot (QD) molecules with larger laser spot size and a single‐coupled QD molecule to investigate the dynamics of exciton states. A linearly polarized laser along the coupled direction of a laterally‐coupled GaAs QD molecule [10] is used to determine the coupling effects of the different exciton states. For the ensemble of coupled QD molecules, the exciton PL peak shifts to lower energy (≈70 meV) and shows a linear increase in the PL intensity, demonstrating the properties of exciton states as a function of the laser excitation power. In addition, a power‐dependent redshift is observed in the single‐coupled GaAs QD molecule as a function of the excitation power; however, the two distinguished exciton states become resolved and show different power factors when the laser excitation power is linearly increased. This result clearly indicates the presence of energy transfer between the two different exciton states, X1 and X2. Furthermore, when the polarized laser excitation power is increased, a coupled biexciton consisting of two different localized exciton states (X1 and X2) is clearly observed, and a power‐dependent spectral redshift is detected in the exciton and biexciton states. At a high excitation power (15 I0), the decay times of the two different localized exciton states clearly show different lifetimes; and the decay time difference due to the size difference can be ignored at a low excitation power. Theoretically, the decay times of the two different exciton states, wherein the size deviation can be ignored, should be the same. Based on the results of the time‐integrated and time‐resolved PL measurements and the comparison between the ensemble and single exciton PL peaks, it is concluded that the coupling process in laterally‐coupled GaAs QD molecules is strongly supported against long‐range separation.

UVC Up-Conversion and Vis-NIR Luminescence Examined in SrO-CaO-MgO-SiO2 Glasses Doped with Pr3.

The application of ultraviolet-C light in the field of surface treatment or photodynamic therapy is highly prospective. In this regard, the stable fluorescent silicate SrO-CaO-MgO-SiO2-Pr2O3 glasses able to effectively convert visible excitation on the ultraviolet praseodymium emission were fabricated and examined. An unusual wide-range visible-to-UVC up-conversion within 240-410 nm has been achieved in Pr3+-doped glasses, revealing their potential advantage in different sophisticated disinfection technologies. The integrated emission intensity was studied as a function of light excitation power to assess a mechanism attributed to UVC luminescence. Especially, it was revealed that the multicomponent silicate glass qualities and praseodymium 3PJ excited state peculiarities are favorable to obtaining useful broadband ultraviolet up-converted luminescence. The glass dispersion qualities were determined between 450-2300 nm. The impact of praseodymium concentration on Vis-NIR spectroscopic glass qualities was evaluated employing absorption spectra, emission spectra, and decay curves of luminescence associated with two involved praseodymium excited states. Especially, efficient interionic interactions can be inferred by investigating the decrease in 1D2 state experimental lifetime in the heavily doped samples. Examination of absorption spectra as a function of temperature implied that excitation at 445 nm should be quite effective up to T = 625 K. Contrary to this, temperature elevation gives rise to a moderate lowering of the visible praseodymium luminescence.

β-β-alkynyl-bridged BODIPY dimers: Synthesis, one- and two-photon photophysical properties

Six β-β-linked BODIPY dimers with different EDG-EDG and EDG-EWG were synthesized by changing the nature of the EDG and EWG at the meso position. The fluorescence lifetimes and quantum yield of z4 and z5 with the same substituent groups at the two meso positions are much higher than those of the BODIPY dimers with two different substituents. Compound z4 exhibits the highest fluorescence quantum yield (11.24 %) and fluorescence lifetime (1.32 ns). Both compounds z4 and z5 show important two-photon induced fluorescence in the 800–1000 nm region with a clear quadratic dependency of the emission intensity vs the laser excitation power.

Photoluminescence Excitation Spectroscopy of Stimulated Emission from AlGaN‐Based Multiple Quantum Wells with an Emission Wavelength Around 280 nm

Stimulated emission properties of AlGaN‐based multiple quantum wells with an emission wavelength of about 280 nm are studied by photoluminescence excitation (PLE) spectroscopy. The excitation power density dependence of the PLE spectra is evaluated at excitation energies from 4.4788 to 4.6293 eV, which allows the spontaneous and stimulated emission PLE spectra to be obtained. A clear peak is observed in the PLE spectrum for spontaneous emission, indicating that the spontaneous emission is due to the excitonic optical transition. A clear peak is also observed in the PLE spectrum for stimulated emission, suggesting that excitons are involved in the stimulated emission process. Furthermore, the threshold excitation power density for stimulated emission is analyzed as a function of the excitation energy and the threshold excitation power density depends on the excitation energy. The excitation energy at which the threshold excitation power density is minimized agrees with the peak of the stimulated emission PLE spectrum. This observation directly indicates that excitons are important in optical gain formation.

Power-dependent up-conversion emissions and temperature sensing properties of NaYF4:Er/Yb@NaYF4 phosphors

Rare earth doped luminescent materials have unique up-conversion properties and can be applied to optical temperature sensing. In this work, the power-dependent emission intensity from bare core NaYF4:Er/Yb and core–shell structured NaYF4:Er/Yb@NaYF4 phosphors and the temperature sensing properties of NaYF4:Er/Yb@NaYF4 phosphors are investigated. The NaYF4:Er/Yb and NaYF4:Er/Yb@NaYF4 phosphors are prepared through typical co-precipitation method. The enhancement factor of emissions located at 520, 540 and 654 nm reach 1.51, 1.42 and 1.75, respectively, which is originated to the suppression of surface quenching. The enhancement factor decreases slowly with excitation power increasing due to the more sensitivity to laser power of the bare core phosphors. In addition, the green emissions (520 and 540 nm) exhibit distinct temperature-dependent behaviors, including relatively sensing sensitivity and thermal repeatability stability. The maximal relatively sensing sensitivity reaches 1.2% K−1 at 294 K and The value of thermal repeatability stability reaches 98.4%.

Bioinspired photonic crystal structures from Papilio Ulysses butterfly wings for versatile laser applications

Photonic crystals found within the wing of a Papilio Ulysses butterfly have demonstrated their efficacy in facilitating laser processes, particularly as a scattering material for imaging and illumination applications. This study delves into the investigation of the photonic crystal's band gap within the butterfly's wing, aiming to realize blue band-edge lasing using a newly developed gain medium comprising diphenylaminofluorene-based chromophores featuring a donor-acceptor-donor (D-A-D) motif. The versatility of the fabricated sample is highlighted, as it can function as both a single-mode laser and a random laser, with the operational mode determined by adjusting the excitation power and the direction of the pump source. Specifically, it exhibits a threshold of 2.5 μJ for random laser operation and 7.6 μJ for single-mode laser operation. The unique architectural elements found in the butterfly's wing, including the ridges on the wing scale and the photonic crystal within the scales, play distinct roles in enabling random laser and single-mode laser actions, respectively. This distinctive butterfly wing architecture holds promise for inspiring the development of future photoelectronic circuits requiring a hybrid design that incorporates both single-mode and comb-mode laser functionalities.