In order to meet the contradiction between the growing demand for refrigeration and energy scarcity, this paper proposes a novel photovoltaic ice storage air conditioning system. The system is directly driven by a photovoltaic array. The performance of the system was studied through experiments, and a mathematical model was constructed for comparative verification. The experimental results show that the daytime cooling COP of the system is 1.18, the photovoltaic conversion efficiency is 6.29 %, and the nighttime cooling time is 9 h, which basically meets the cooling needs. Through simulation, the performance of the system was optimized, and the results showed that an increase in the initial water volume and temperature of the ice storage tank would increase the cooling COP; the spacing between evaporator pipes increased from 45 mm to 60 mm, resulting in a 7.11% increase in COP; the optimal spacing between evaporator fins is 9 mm, which improves performance by 9.11 %.