Evaluation Of Photocatalytic Activity Research Articles

Nitrogen doped TIO2/g-C3N4 nanocatalyst for photodegradation of methylene blue dye

In this study, the ethanol dispersion procedure was implemented to prepare the g-C3N4/N–TiO2 nanocatalyst structure. Sol-gel synthesis is utilized for synthesizing N–TiO2 and g-C3N4 via urea thermal decomposition. Physicochemical properties of produced photocatalysts were revealed using PL imaging, UV–vis DRS, XRD, FTIR, SEM, BET, and TEM. Evaluation of photocatalytic activity of synthetic photocatalysts by exposure to sunlight and degradation of methylene blue (MB) dye. g-C3N4/N–TiO2 NCs showed excellent photocatalytic activity, reaching 96 % MB degradation efficiency in 80 min. g-C3N4 and N–TiO2 doped form a nanocomposite structure that increases photocatalytic activity, affecting charge separation performance and service life. The system also exhibits the ability to collect visible and ultraviolet light. Even after four consecutive cycles, the efficiency of the MB is still above 85 %. Capture experiments showed that the decomposition of MB was mainly caused by h+ and O22− radicals. The results of kinetic investigations indicate that the degradation rate of g-C3N4/N–TiO2 nanocomposites surpasses that of N–TiO2 nanoparticles.

Heterophase hexagonal/orthorhombic molybdenum trioxide nanorods for photocatalytic hydrogen production

Phase engineering plays a critical role in enhancing photocatalytic performance of metal oxides. Herein, we demonstrate the phase-selective synthesis of MoO3 (hexagonal h-MoO3, orthorhombic α-MoO3, and their junction h/α-MoO3) through controlled phase transitions by adjusting annealing conditions. As evidenced with photocatalytic hydrogen evolution reaction, h/α-MoO3 (14.20 μmol/h) phase junction shows superior performance to either h-MoO3 (9.62 μmol/h) or α-MoO3 (11.31 μmol/h), with a hydrogen yield of 47.6% and 25.6% greater than that of h-MoO3 and α-MoO3 (Pt as cocatalyst), respectively. A systematic study of the chemical structure characterizations, photochemical tests, band structure analysis, and photocatalytic activity evaluation reveal that, the enhancement is attributed to the strong built-in electric field in the h/α-MoO3 phase junction, which effectively facilitates charge separation. Our findings introduce a novel strategy for improving photocatalytic performance using phase engineering.

Self‐cleaning films of biopolymer polyhydroxybutyrate with different semiconductors incorporation: Development, characterization, and photocatalytic activity evaluation

AbstractSelf‐cleaning hydrophobic films were developed using polyhydroxybutyrate (PHB), enhanced with titanium dioxide (TiO2), bismuth oxyiodide (BiOI), and a BiOI/α‐Fe2O3 heterojunction. This is the first study to analyze the photoactivity of BiOI and BiOI/α‐Fe2O3 immobilized into PHB. Alternative solvents for dissolving PHB were investigated. Additionally, formation methods such as casting in Petri dishes, as well as controlled thickness casting through non‐solvent‐induced phase separation (NIPS), and evaporation‐induced phase separation (EIPS), were employed and compared. Despite differing morphologies, both NIPS and EIPS films exhibited similar photocatalytic activity, suggesting that only the catalyst on the external surface of the film is active. The highest pseudo first‐order apparent kinetic constant (0.1468 ± 0.0015 min−1 g−1) was found in films with the lowest polymer and catalyst concentrations analyzed (5% and 3% ). A double‐layer film preparation method was proposed to enhance photocatalytic activity, resulting in a 70% increase in the kinetic constant (0.2506 ± 0.0019 min−1 g−1). Double‐layer composite films with BiOI and BiOI/α‐Fe2O3 showed photocatalytic activity comparable to TiO2 under UV–visible light. Furthermore, their photocatalytic activity under visible light was confirmed, unlike TiO2, which exhibits a negligible kinetic constant in this wavelength range.

Role of oxygen vacancy enriched m-BiVO4/t-BiVO4 isotype heterojunction for enhanced photocatalytic degradation of rhodamine B dye and in ferroelastic to paraelastic phase transition

Mixed-phase isotype heterojunction oxide materials with superior photocatalytic activities have recently revealed a significant coupling between individual phases with controlled optical properties. Therefore, we focus on synthesizing a mixed-phase monoclinic-tetragonal (m-t) BiVO4 photocatalyst using hydrothermal method. The increased recombination rate of electron-hole (e−-h+) pairs limits the photocatalytic performance of monoclinic (m) BiVO4 photocatalysts. Therefore, effective spatial charge carrier separation can be improved by creating an isotype heterojunction between the phases m-BiVO4 and t-BiVO4. The precursor pH, mechanical grinding, and calcination temperature regulate the formation of m-t BiVO4. The phase fractions of the two phases in m-t BiVO4 sample are 85% monoclinic and 15% tetragonal. Herein, we demonstrate the optical properties and photocatalytic activity based on the crystal chemistry of m-BiVO4 and m-t BiVO4. Temperature-dependent Raman measurements suggest a second order ferroelastic monoclinic to paraelastic tetragonal phase transition above 530 K owing to optical phonon anharmonic coupling interactions. The small increase (5 °C) in Tc in m-t BiVO4 compared to m-BiVO4 is due to the coexistence of tetragonal and monoclinic phases. The optical band gap of m-t BiVO4 is larger than that of m-BiVO4. Additionally, the evaluation of BiVO4 photocatalytic activity over rhodamine-B (Rh-B) dye suggests that the m-t BiVO4 with 97.5% degradation efficiency is superior compared to m-BiVO4 with 89% degradation efficiency. This is because, the two phases (m and t) of BiVO4 form an isotype heterojunction interface, which results in a high charge separation efficiency, as demonstrated by photocurrent studies and electrochemical impedance spectroscopy. Moreover, oxygen vacancies tune the charge carrier dynamics through the modification of band edges. These findings regarding the isotype phase-junction mechanism provide possibilities for innovative ideas for highly efficient mixed-phase isotype heterojunction photocatalysts for wastewater remediation.

Harnessing the potency of eco-friendly calcium oxide derived from eggshells for enhanced photocatalytic activity and biocompatibility evaluation in HepG2 cell line

Efforts towards sustainable development and pollution prevention are driving the exploration of bio-Calcium oxide (CaO) production from eggshell waste. This work investigates the thermal conversion of eggshell derived CaCO3 into CaO. Powder X-ray diffraction and Fourier transform infrared spectroscopy confirm CaO composition, displaying a cubic structure with 2.405 Å bond length and a mid-bond electron density of 0.2298 e/ų. Electron density studies corroborate this, revealing a three-dimensional distribution and one-dimensional profile. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) confirms spherical CaO particles and EDAX spectra displays the presence of calcium and oxygen. UV absorption spectra reveal a 3.3 eV energy bandgap, showcasing CaO's photocatalytic potential. It demonstrates exceptional photocatalytic against congo red and methylene blue dyes, degrading them by 96.4 % and 98 %, respectively, via pseudo first-order kinetics. Additionally, CaO demonstrates promising anticancer activity against HepG2 liver cancer cells, with an IC50 value of 31.2 μg/mL, positioning it as a cost-effective and potent agent for both wastewater treatment and cancer therapy.

Parmelia perlata mediated microwave-assisted one-pot green synthesis of NiO nanoparticles a noble approach: Antibacterial and photocatalytic activity evaluation

This study reports a green-mediated fabrication of NiO nanoparticles (NiO NPs) using Parmelia Perlata lichen extract as a sustainable source. The Physical, chemical, optical, and morphological behavior of the fabricated NiO NPs were analyzed by employing diverse analytical profiles like XRD, FTIR, UV, and SEM. FTIR spectrum demonstrates the involvement of various phytochemicals in the bio-fabrication of NiO NPs. Furthermore, the appearance of a band at 668 cm−1 indicates the successful formation of NiO NPs. The observations of the SEM analysis depicted that the average particle size was in the range of 40–50 nm. The result of the antibacterial study indicates that the NiO NPs significantly reduce the growth of Staphylococcus aureus (19 mm). The result of the photocatalytic research illustrated that the bio-fabricated NiO NPs exhibited superior photocatalytic activity in the degradation of acridine orange dye achieving 84 % degradation efficiency.

Synthesis and characterization of hierarchical Sr-doped ZnO hexagonal nanodisks as an efficient photocatalyst for the degradation of methylene blue dye under sunlight irradiation

This study presents the synthesis and comprehensive characterization of hierarchical hexagonal nanodisks of zinc oxide (ZnO) and strontium (Sr) doped ZnO, prepared via a hydrothermal method. The experimental synthesis procedure involved dissolving zinc nitrate in a water–ethanol mixture, followed by the addition of polyethylene glycol (PEG 200), sonication, and subsequent hydrothermal treatment. Different concentrations of Sr were introduced into the ZnO lattice to generate Sr-doped ZnO samples. Analysis of the obtained results revealed successful incorporation of Sr, evidenced by shifts in the X-ray diffraction (XRD) pattern and alterations in lattice parameters. Moreover, the Williamson-Hall plot indicated minimal strain and high structural stability in both pristine ZnO and Sr-doped ZnO. The morphology of the synthesized Sr-doped ZnO was confirmed through field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM), revealing a hexagonal nano disk-shaped morphology akin to pristine ZnO. Elemental composition analysis conducted via X-ray photoelectron spectroscopy (XPS) further confirmed the presence of Sr in the doped ZnO samples. Evaluation of photocatalytic activity against methylene blue dye demonstrated superior performance of the 5 % Sr-doped ZnO catalyst, attributed to its increased surface area compared to pristine ZnO. Notably, the highest degradation rate constant (k) of 0.0389 min−1 was observed for the 5 % Sr-doped ZnO catalyst, emphasizing its efficacy in environmental remediation applications. This research underscores the potential of Sr-doped ZnO as a promising photocatalyst, offering stability, reusability, and effective utilization of UV and visible light for catalytic processes.

A systematic evaluation of physiochemical properties and solar-driven photocatalytic activity of nanosized Mn doped CdS on Methylene Blue dye

Manganese ions were incorporated into CdS nanosystem using wet chemical protocol at different pH values namely 9.0,10.0 and 11.0 and the same were used for photocatalytic degradation of Methylene blue (MB) dye via adsorption phenomena. Several standard analytical techniques were employed to analyse the synthesized nanocompounds: XRD, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, UV-Vis absorption spectroscopy, Fourier transform infrared spectroscopy, and vibrating-sample magnetometry. The structural analysis revealed the presence of primary cubic zinc blende structure with secondary phases. The morphological studies confirmed the formation of nanostructured particles for all pH values, amongst, pH 10.0 grown particles were showing less agglomeration and better particle stabilization. The TEM analysis confirmed the particle size of 23 nm. The absorption edge and its position shown by UV-Vis absorption analysis exhibited a broad envelope and strong blue shift due to an uneven size distribution and nanodimensional state formation of particles, respectively. The elevation to superparamagnetic state from native diamagnetic state of CdS due to Mn ions incorporation was confirmed by VSM studies. The dual phase composition significantly enhanced the photocatalytic efficiency by improving charge separation and extending light absorption. The MnS phase effectively trapped electrons, reduced recombination rates and facilitated the generation of reactive species. The photocatalytic degradation of methylene blue dye was more efficient (88.87 %) under direct sunlight exposure. Additionally, the enhanced surface properties and adsorption characteristics, as confirmed by the Freundlich isotherm and intraparticle diffusion model, contributed to the superior degradation performance.

Green Synthesis, Characterization, and Evaluation of Photocatalytic and Antibacterial Activities of Co3O4-ZnO Nanocomposites Using Calpurnia aurea Leaf Extract.

The green synthesis of transition metal oxide nanocomposites using plant extracts is a new and effective method that avoids the involvement of hazardous chemicals. Nondegradable organic pollutants and antibiotic drug resistance have become serious public health issues worldwide. Hence, the main objective of this study is to synthesize Co3O4-ZnO nanocomposites using Calpurnia aurea leaf extract and evaluate its photocatalytic and antibacterial activities. The green synthesized particles were characterized using UV-vis spectra, Fourier transform infrared spectroscopy, X-ray diffraction techniques, and scanning electron microscopy combined with energy-dispersive X-ray studies. The synthesized particles were found to be crystalline in nature with average crystallite sizes of 23.82, 14.79, 15.99, 16.46, and 21.73 nm. Scanning electron microscopy shows the spherical morphology of Co3O4-ZnO NCs, and energy-dispersive X-ray analysis confirms the formation of highly pure ZnO NPs and Co3O4-ZnO NCs. The photocatalytic activity was performed under natural sunlight using malachite green as an organic dye pollutant. The green synthesized ZnO NPs, Co3O4 NPs, 1:4, 1:3, and 1:2 Co3O4-ZnO NCs showed high degradation efficiency after 60 min of irradiation. The synthetic material showed good potential against Staphylococcus aureus and Escherichia coli, with the highest growth inhibition recorded by 1:2 Co3O4-ZnO NCs. The kinetics study of the photocatalytic degradation was confirmed as pseudo first order, and the possible mechanisms for both photocatalytic and antibacterial activities were clearly determined.

Novel Synthesis of ZnO–Ag2O Nanocomposite Crystals and Their Photocatalytic and Antibacterial Activity Evaluation

Novel Synthesis of ZnO–Ag2O Nanocomposite Crystals and Their Photocatalytic and Antibacterial Activity Evaluation

Green synthesis of silver nanoparticles using Solanum sisymbriifolium leaf extract: Characterization and evaluation of antioxidant, antibacterial and photocatalytic degradation activities

The present study conveyed an in-situ synthesis of silver nanoparticles (Ss-AgNPs) using Solanum sisymbriifolium aqueous leaf extract (SsLE) and their biological activities for the first time. The qualitative and quantitative analysis of SsLE imparted significant amounts of reducing entities/ secondary metabolites. A surface plasmon resonance peak at ∼430 nm of UV–visible spectrum evidenced the formation of Ss-AgNPs. The average particle size of the Ss-AgNPs was found to be 29.87 nm through particle size analyzer. Further, FE-SEM, HR-TEM and XRD analysis verified the spherical shape and high degree of crystallinity with face-centred cubic structure of Ss-AgNPs. The EDX, elemental mapping and FTIR spectral studies, confirmed that various phytochemicals/ metabolites of S. sisymbriifolium leaf extract participated in bio-reduction process and capping of Ss-AgNPs, which might be accountable for the antioxidant activities. Moreover, SsLE and Ss-AgNPs were found to be a rich source of antioxidants and exhibited effective DPPH, H2O2, ṄO scavenging activities along with Ferric ion reducing antioxidant power. The synthesized Ss-AgNPs showed significant antibacterial activity against gram-positive and gram-negative bacteria. In addition to this, Ss-AgNPs supported the degradation of methylene blue (a cationic dye), by performing as a strong photocatalyst under UV and solar irradiations.

Cobalt(II) phenylphenoxides as effective photocatalyst in the degradation of some organic dyes

Removal of toxic dyes by physical, biological and chemical methods have been carried out extensively, of which photochemical degradation, by coordination complexes in particular, has been found to be an effective treatment method owing to the use of natural sunlight as source of energy, resulting in no sludge formation along with the release of less toxic substances in the environment. In this study, synthesis and evaluation of photocatalytic activity of new cobalt(II) phenylphenoxides, 1–4, against some organic dyes viz. Malachite green, methyl orange, crystal violet, methylene blue and fuchsin basic have been studied. The complexes were characterized by physicochemical, 1H NMR, FTIR, high resolution mass spectra (HRMS), powder X-ray diffraction (PXRD) and electrochemical techniques. An attempt has been made to study the effect of varying experimental conditions like concentration of catalyst, nature of ligand, presence of initiator, on the degradation of dyes. Results have shown that the rate of degradation increases with increase in the concentration of catalyst in the presence of environment friendly initiator, hydrogen peroxide. Furthermore, the complexes were found to be more photo-catalytically active towards degradation of malachite green and methyl orange showing degradation of 89.7 % and 95 %, respectively, in the presence of initiator. The photocatalytic degradation of the dyes displayed pseudo first-order kinetics wherein the physical concept of dye degradation i.e. physiosorption governed the adsorption rate of particles onto the adsorbent. The complexes were found to act as effective photocatalyst as well as strong oxidant generator, HO·, carried out by photochemical decomposition of H2O2 under the effect of sunlight. Scavenging studies unveiled the active involvement of hydroxyl radicals (HO·) and electron vacancies (h+) in facilitating the degradation process. Notably, the complexes exhibited remarkable reusability, enduring up to 6 repeat cycles for methyl orange and 5 cycles for malachite green with significant degradation percentages which have revealed their potential role in the degradation of these dyes.

Green fabrication of titanium dioxide nanoparticles via Syzygium cumini leaves extract: characterizations, photocatalytic activity and nematicidal evaluation

ABSTRACT The most significant plant parasitic nematode in terms of economic impact is root-knot nematode (Meloidogyne incognita), which severely harms essential crops used for agriculture. This study investigated green fabrication of titanium dioxide nanoparticles (TiO2 NPs) utilizing Syzygium cumini (SC) leaf extract and evaluated its nematotoxic activity against M. incognita in vitro and in pots. During experiments, second-stage juveniles (J2s) and egg masses of M. incognita were treated with different concentrations (125, 250, 375 and 500 ppm) of SC-TiO2 NPs. After 48 h and five days of exposure, respectively, lowest J2s mortality and per cent inhibition in egg hatching was discovered at 125 ppm, and highest J2s mortality and maximum per cent inhibition in egg hatching determined at 500 ppm. The treatment of SC TiO2 NPs considerably reduced M. incognita infection and enhanced carrot plants' growth and physiological characteristics. The characterization of green synthesized SC-TiO2 NPs made by X-ray diffraction, Photoluminescence, FTIR, SEM, UV-Visible Diffuse Reflectance Spectrophotometer, TEM, and photocatalytic activity also examined. In conclusion, it can be said that SC-TiO2 NPs possess nematode-toxic potential against M. incognita and are used as substitutes for high-risk chemical nematicides without causing any phytotoxicity.

Self-nitrogen-doped hierarchical porous carbon spheres as metal-free catalyst for efficient photocatalytic CO2 reduction

It is rather important to develop an efficient, stable and economical photocatalyst for solar-driven CO2 reduction. Herein, N-doped hierarchical porous carbon spheres (NPCS-F6) with metal-like activity is synthesized using acrylamide and F127 as nitrogen source and soft template, and the effective synergy between nitrogen-containing species and hierarchical pore structure makes the samples exhibit excellent CO2 reduction properties. XPS characterization illustrates that the introduced pyridine nitrogen and pyrrole nitrogen groups contribute to the increase of CO2 reduction sites on the surface of the material. N2 adsorption analysis verifies the existence of hierarchical pore structures in which micropores facilitate the exposure of more adsorption active sites, while mesopores and macropores can be used as transfer channels to connect the internal micropores and reduce the molecular diffusion resistance to improve CO2 adsorption performance. In addition, the pore structure of the samples prepared with P123 and CTAB as templates is mainly microporous, whereas carbon spheres with hierarchical pores coexisting are obtained with F127 as template. The evaluation of photocatalytic CO2 reduction activity shows that the CO yield of NPCS-F6 could reach 17.56 μmol·g−1 for 8 h, which is 1.17 times, 1.08 times and 1.07 times of the original NCS-8 (15.05 μmol·g−1), NPCS-P6 (P123 as soft template, 16.25 μmol·g−1) and NPCS-C1 (CATB as soft template, 16.39 μmol·g−1), respectively. Comprehensive characterization results are analyzed to propose a possible mechanism for photocatalytic CO2 reduction, in which photogenerated electron-hole pairs are generated inside the material under light conditions, and the photogenerated electrons are transferred to the N-6/N-5 active sites through the electron transfer channel N-Q to react with CO2 molecules adsorbed on the surface to be reduced to CO. Finally, our results provide a favorable and feasible strategy to synthesize metal-free photocatalysts for high-efficiency CO2 adsorption and targeted reduction of CO2 to CO.

A novel green synthesis of CuFe2O4 Nanoparticles from Cissus rotundifolia for photocatalytic and antimicrobial activity evaluation

This paper reports a novel green fabrication of copper ferrite (CuFe2O4) nanoparticles (NPs) from Cissus rotundifolia plant extract. The NPs were characterized by different spectroscopic techniques.The Fourier transform infrared (FT-IR) spectrum exhibited intrinsic stretching at the tetrahedral position of Fe–O at 591 cm−1 and the octahedral stretching of Cu–O at 402 cm−1 respectively. The fine diffraction pattern in the X-Ray diffraction analysis (XRD) showed the formation of well-crystalline NPs. The mean crystallite size of the NPs was calculated to be 17.33 nm. The High-resolution Transmission Electron Microscopic (TEM) analysis showed roughly spherical shape and irregular morphology of the NPs. The Zeta potential was calculated to be −29.7±0.3 mV, indicating a negative charge over the CuFe2O4 NPs. The formation of spinel ferrite was confirmed from the characterization data. The photocatalytic activity of the CuFe2O4 NPs was examined against the methylene blue (MB) dye, showing 82% degradation under UV–Visible light. The reusability experiment showed that the catalytic activity was not much decreased even till the 4th cycle. The antibacterial activity of the synthesized CuFe2O4 NPs was tested against Bacillus subtilis, Staphylococcus aureus, Bacilus pumilis, Escherichia coli, Pseudomonas aeruginosa, and Salmonella abony through the Agar well diffusion method. A zone of inhibition of 12±0.2, and 11±0.4 mm was obtained against Bacillus subtilis and Bacillus pumilis, whereas against E. coli, P. aeruginosa and S. abony it was found to be 14±0.4, 18±0.3, and 12±0.2 mm respectively at 75 mg/mL dose, showing appreciable antibacterial activity.

Cadmium oxide nanoparticles doped with nickel and silver: Photocatalytic activity for environmental remediation

In this work, we used a co-precipitation approach to create CdO nanoparticles that were co-doped with nickel (Ni) and silver (Ag). X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) were employed to assess the structural attributes of the nanoparticles that were synthesized. Co-doping with Ni and Ag resulted in a steady rise in nanoparticle crystallite size, increasing from 20.97 nm to 32.16 nm. Following the co-doping procedure, FESEM pictures demonstrated a morphological shift from tiny, rock-like formations in pure CdO to bigger rock-like structures. Energy-dispersive X-ray spectroscopy (EDX) was utilised to explore the compositional characteristics of Ni and Ag-doped CdO nanoparticles. The existence of particles’ agglomerations was observed, which may have limited the real surface area available for gas adsorption and resulted in smaller apparent pore sizes in the Brunauer-Emmett-Teller (BET) investigation. Diffused Reflectance Spectroscopy (DRS) revealed a decline in the band gap from 2.45eV to 2.30eV, which was most likely caused by structural changes caused by cadmium ion replacement or the occupancy of interstitial spaces within the lattice by nickel and silver ions. The chemical and electronic states of the atoms were assessed using X-ray photoelectron spectroscopy (XPS), which examined the formation of defects in the form of oxygen vacancies, which contributed to accelerated photocatalytic performance. The deterioration of Crystal Violet (CV) dye during sunlight exposure utilising co-doped CdO nanoparticles vs pristine CdO is being evaluated in the evaluation of photocatalytic activity. Notably, co-doped nanoparticles improved photocatalytic activity significantly, with CV degradation reaching up to 95 % within 180 min of exposure. The potential of Ni and Ag impregnated CdO nanoparticles as effective photocatalysts for environmental remediation applications is highlighted in this study.

Evaluation of photocatalytic activity of Cu3(PO4)2/MgO nanocomposite for the efficient removal of amaranth dye under solar light irradiation

The amaranth dye was removed using photocatalysis on a Cu3(PO4)2/MgO nanocomposite synthesized by co-precipitation method. The crystalline component and the nanostructure of the samples were analyzed by XRD, FTIR, UV–vis-DRS, SEM, EDS, HR-TEM and EIS confirming the successful formation of the nanocomposite. In powder XRD, the average crystallite size is found to be ∼ 26–37 nm. Electrochemical impedance spectroscopy, Nyquist plots represents the charge-transfer resistance at contact interface and the arc diameter of Cu3(PO4)2/MgO is much smaller than that of pure MgO and Thermo gravimetric analysis (TGA), from TGA curve the weight-loss of Cu3(PO4)2 and Cu3(PO4)2/MgO nanocomposite was calculated as 14.18 % and 18.16 % which gives the more contribution to the large enhancement of photocatalytic activity. The photocatalytic degradation efficiency of Cu3(PO4)2/MgO nanocomposite (0.1 g/L, 10 μM and 150 min) was investigated under natural direct solar light irradiation against the dyes. The rate of degradation of amaranth with Cu3(PO4)2/MgO followed pseudo–first order kinetics in the dye concentration. Degradation efficiency (99 %) and degradation rates of amaranth were increases with increasing Cu3(PO4)2/MgO concentration. Generally, this research work advances the possible utilization of Cu3(PO4)2/MgO as an efficient catalyst for taking away of dye from aqueous solution and improvement the catalyst to be used for a numerous cycles. The Cu3(PO4)2/MgO nanocomposites showed good activity against bacteria of Staphylococcus aureus, Staphylococcus pyogenes and Klebsilla pneumoniae.

Spray Coated of ZnO Particles on ePA Nylon-Carbon Fiber Substrate and Its Photocatalytic Activity Evaluation

This work studies a simple deposition of ZnO particles on the ePA Nylon–Carbon Fiber substrate by sol-gel-spray-coating technique. The ZnO films were deposited on the substrate with deposition parameters such as suspension concentration, nozzle-to-substrate distance, nozzle size, coats, pump pressure, and deposition temperature. The ZnO gel suspension concentrations were varied (ZnO-0.06g/ml; ZnO-0.03g/ml), and the post-heated treatment was carried out at 120°C in vacuum condition. The temperature at 45°C during spray coating deposition was also applied to ZnO with the concentration of 0.03g/ml, which was noted as ZnO-0.03 TS. The films were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/EDS), and Contact Angle (CA) to determine the structure, morphology, and hydrophilicity. The XRD pattern revealed that all samples have a hexagonal wurtzite structure. The SEM results showed that ZnO-0.06 relatively shows a dense surface, while ZnO-0.03 and ZnO-0.03 TS have a porous surface. The atomic ratio (Zn:O) revealed from the EDS measurement of the films was stoichiometric. The CA measurement showed that the film surfaces are hydrophilic. In addition, the photocatalytic activity was evaluated by the degradation of 2 mg/L methylene blue irradiated by sunlight for 180 mins—the photodegradation efficiencies were 88.37 %, 90.22 %, and 89,47 %, respectively.

AG2O Nanoparticle and Its Composite with Coordination Polymers of Cu: Synthesis, Characterisation and Photocatalytic Activity

In this study, we report the synthesis, characterisation, and photocatalytic activity evaluation of Ag2O nanoparticles (NPs) and their composite, Ag2O/Cu-CP, with coordination polymers (CPs) of Cu. Ag2O NPs were synthesised using the coprecipitation method. The composite was prepared via the sonication method. FTIR and XRD patterns revealed the formation of the nanoparticles and composite. Photocatalytic activity of the NPs and Composite was performed under solar irradiation for Methylene Blue (MB) as a dye. The photocatalytic degradation efficiency was monitored for concentration decay over time using UV-Vis. Spectrophotometer. The synthesised Ag2O/Cu-Cp composite showed a degradation efficiency of 97.59%, whereas Ag2O NPs showed an efficiency of 82.23%. The composite exhibited 1.18 times higher activity than Ag2O NPs. The band gap plays a crucial role in enhancing activity. The incorporation of Cu-Cp with Ag2O NPs reduced the band gap to an optimum level for radical formation. So, this kind of composite could be widely used in the effluent treatment of industry for a green environment.Keywords: Ag2O nanoparticles, composite, powder-XRD, dye degradation, photocatalytic activity, UV-vis spectroscopy

Bio-extract-mediated microwave-assisted synthesis of Cr2O3 nanoparticles: Characterization, antibacterial, antioxidant, and photocatalytic activity evaluation

Bio-extract-mediated microwave-assisted synthesis of Cr2O3 nanoparticles: Characterization, antibacterial, antioxidant, and photocatalytic activity evaluation