Enriched MORB Research Articles

EM1‐Signature in the North Fiji Basin: Evidence for Stagnant Slab‐Derived Mantle Upwelling Beneath the Trench‐Distal Back‐Arc Basin

AbstractBasaltic volcanism at the mature back‐arc spreading axis in the North Fiji Basin (NFB) exhibits significant geochemical heterogeneity from depleted mid‐ocean ridge basalt (MORB) to enriched MORB compositions. The volatile and Sr‐Nd‐Pb‐He isotope composition of basaltic glasses from the Central Spreading Ridge (CSR) of the NFB suggests that a second enrichment mantle component is present in addition to the previously observed Samoan mantle plume. The hydrous OIB‐like basalts from the northern CSR have a weak enriched mantle 1 (EM1) isotopic signature and negative correlation between Ba/Th and Zr/Hf ratios, similar to rejuvenated Samoan lavas associated with tectonic driven volcanism. The EM1 signature is distinct from shield‐stage Samoan basalts and back‐arc basin basalts from the Lau Basin by high Ba/La ratio and negative correlation between Ba/Th and Ba/Ta ratios, indicating contributions from dehydrated and altered oceanic crust and sediments. Our new geochemical data suggest that focused melting above the mantle transition zone (MTZ) triggered by dehydration of stagnant slab can be a source of the EM1‐like melts containing both elevated 3He/4He ratios (up to 12.52 RA) and altered oceanic slab components. Given the spatial coincidence of the inferred EM1 basalts with the clustered deep earthquakes, our results support the presence of detached oceanic slabs in the MTZ beneath the northern NFB.

Mafic rocks with back-arc E-MORB affinity from the Chotanagpur Granite Gneiss Complex of India: relicts of a Proterozoic Ophiolite suite

AbstractThe Proterozoic Chotanagpur Granite Gneiss Complex (CGGC) at the northern boundary of the Central Indian Tectonic Zone (CITZ) of the eastern Indian shield preserves relics of fossilized oceanic back-arc crust. We describe the field, petrographical and geochemical characteristics of the mafic rocks comprising pillow basalts and dolerites from the Bathani area of the northern fringe of the CGGC, eastern India. The basalts consist of plagioclase feldspar, hornblende, opaque minerals (Fe–Ti oxide) and chlorite, and the dolerite consists of plagioclase, hornblende and opaque minerals. Our data indicate that the Bathani mafic rocks have tholeiitic to transitional composition and are overprinted by greenschist facies metamorphic conditions; however, REE and fluid immobile elements preserve their primary geochemical signatures. The (La/Sm)N ratios (1.38–2.15) and chondrite-normalized REE patterns point to an enriched mid-ocean ridge basalt (E-MORB) mantle source. Geochemical characteristics indicate a mixed signature of MORB and arc tholeiite with enrichment of Ba, Th, Eu and Sr, similar to that of back-arc supra-subduction zone ophiolites. These mafic rocks are the product of MORB-like magma derived from a depleted mantle corresponding to < 2% partial melting of spinel lherzolite, enriched by subduction-induced slab metasomatism and melting. The Bathani mafic rocks are representative of the upper part of a supra-subduction zone columnar ophiolite section, which was emplaced onto the present-day northern margin of the CGGC during suturing of the northern and southern Indian block at c. 1.9 Ga during the Nuna amalgamation.

Petrogenesis of the Cenozoic volcanic rocks in Baekdu volcano in northeastern Asia and the expected depth of the magma chamber based on geochemistry, mineral chemistry, and Sr-Nd-Pb isotope chemistry

Baekdu volcano is a Cenozoic composite volcano in northeastern Asia that consists of a basaltic plateau, a basaltic shield, and a trachytic to comenditic stratovolcano. In this study, the petrogenesis and tectonic setting of Baekdu volcano are studied based on the whole-rock geochemistry and Sr-Nd-Pb isotope compositions of the Baekdu volcanic rocks. The K–Ar age and mineral chemistry are also investigated to estimate the evolution of the magma chamber depth beneath Baekdu volcano. The Toudao and Baishan basalts formed ca. 2.5 Ma and 1.1 Ma and erupted from magma chambers located at depths of 11.5 ± 2.2 km and 24.9 ± 3.8 km, respectively. The Xiaobaishan and Middle trachytes and the comendites formed during the Pleistocene from magma chambers located at depths of 2.9 ± 0.2 km, 5.4 ± 0.45 km, and 4.4 ± 0.3 km, respectively. These data suggest that the trachytes and comendites erupted from magma chambers located at depths of approximately 3–5 km. The Baishan basalts have geochemical characteristics comparable with those of ocean island basalt (OIB), whereas the Toudao basalts show enriched mid-ocean ridge basalt (E-MORB) or OIB characteristics. The trends of several components, such as the CaO/Al2O3 ratio and the TiO2 and Sc concentrations, are different between older basalts (>2 Ma, including the Toudao basalts) and younger basalts (<1.5 Ma, including the Baishan basalts), indicating that the magma-forming process changed ca. 2–1.5 Ma. The enrichment in Th/Yb ratios in the Toudao basalts indicates that they experienced crustal contamination. Trachytes and comendites are considered to be products of the fractional crystallization of the Baishan basalt based on the similar geochemical trends of the two rocks. Crustal assimilation (up to 20%) also occurred with fractional crystallization (more than 70%) during the formation of peralkaline silicic volcanic rocks. All volcanic rocks in Baekdu volcano have Sr-Nd-Pb isotope compositions comparable with the enriched mantle (EM1)-like signature. This EM1-like signature may have originated from the contamination of asthenospheric mantle with Paleoproterozoic lithosphere that sank into the asthenospheric mantle due to delamination caused by regional extensional events in northeastern Asia between the Cretaceous and the Cenozoic. The characteristics of trace element compositions indicate a within-plate tectonic setting for Baekdu volcano. These data imply that Baekdu volcano origin may have been related to a plume of EM1-type upper mantle under the North China Craton.

Geochemistry and tectonic setting of Middle Ordovician MORB-like basalts in the Kunlun Orogen: implications for a back-arc environment

The Central Kunlun ophiolitic melange zone, northern Tibetan Plateau, represents a remnant of the Early Paleozoic oceanic lithosphere. The Middle Ordovician Longshigeng basalts (LBs) are located in south of this melange zone and have important significance for reconstructing the opening and subduction processes of the Proto-Tethys Ocean. This study presents petrological, whole-rock geochemical, and zircon U-Pb data for these basalts. LA-ICP-MS U-Pb zircon data indicate that these basalts formed ca. 463 Ma. Geochemically, the basalts are characterized by low SiO2 (47.00–50.63 wt%) and K2O (0.22–1.05 wt%), intermediate Mg# (47–57) and high TiO2 (1.51–2.72 wt%), and are identified as tholeiitic basalts. Their chondrite-normalized REE patterns feature slight enrichments in LREEs (LREE/HREE = 2.11–3.08) with mild Eu anomalies (δEu = 0.89–1.06), and their patterns are similar to the reference line of enriched mid-ocean ridge basalt (EMORB). The primitive mantle-normalized trace element diagrams also show similarities with EMORB and are characterized by overall enrichments in large ion lithophile and high field strength elements, without notable Nb, Ta, and Ti depletions. Combining these data with the tectonic discrimination diagrams, we infer that these rocks formed in a back-arc environment in response to the northward subduction of the Proto-Tethys Ocean (South Kunlun Ocean) in the East Kunlun region, northern Tibetan Plateau.

Extreme Heterogeneity in Mid‐Ocean Ridge Mantle Revealed in Lavas From the 8°20′N Near‐Axis Seamount Chain

AbstractLavas that have erupted at near‐axis seamounts provide windows into mid‐ocean ridge mantle heterogeneity and melting systematics which are not easily observed on‐axis at fast‐spreading centers. Beneath ridges, most heterogeneity is obscured as magmas aggregate toward the ridge, where they efficiently mix and homogenize during transit and within shallow magma chambers prior to eruption. To understand the deeper magmatic processes contributing to oceanic crustal formation, we examine the compositions of lavas erupted along a chain of near‐axis seamounts and volcanic ridges perpendicular to the East Pacific Rise. We assess the chemistry of near‐ridge mantle using a ∼200 km‐long chain at ∼8°20′N. High‐resolution bathymetric maps are used with geochemical analyses of ∼300 basalts to evaluate the petrogenesis of lavas and the heterogeneity of mantle feeding these near‐axis eruptions. Major and trace element concentrations and radiogenic isotope ratios are highly variable on &lt;1 km scales, and reveal a continuum of depleted, normal, and enriched basalts spanning the full range of ridge and seamount compositions in the northeast Pacific. There is no systematic compositional variability along the chain. Modeling suggests that depleted mid‐ocean ridge basalt (DMORB) lavas are produced by ∼5%–15% melting of a depleted mid‐ocean ridge (MOR) mantle. Normal mid‐ocean ridge basalts (NMORB) form from 5% to 15% melting of a slightly enriched MOR mantle. Enriched mid‐ocean ridge basalts (EMORB) range from &lt;1% melting of 10% enriched mantle to &gt;15% melting of 100% enriched mantle. The presence of all three lava types along the seamount chain, and on a single seamount closest to the ridge axis, confirms that the sub‐ridge mantle is much more heterogeneous than is commonly observed on‐axis and heterogeneity exists over small spatial scales.

Chapter 5.3b Mount Early and Sheridan Bluff: petrology

Abstract This study discusses the petrological and geochemical features of two monogenetic Miocene volcanoes, Mount Early and Sheridan Bluff, which are the above-ice expressions of Earth's southernmost volcanic field located at c. 87° S on the East Antarctic Craton. Their geochemistry is compared to basalts from the West Antarctic Rift System to test affiliation and resolve mantle sources and cause of melting beneath East Antarctica. Basaltic lavas and dykes are olivine-phyric and comprise alkaline (hawaiite and mugearite) and subalkaline (tholeiite) types. Trace element abundances and ratios (e.g. La/Yb, Nb/Y, Zr/Y) of alkaline compositions resemble basalts from the West Antarctic rift and ocean islands (OIB), while tholeiites are relatively depleted and approach the concentrations levels of enriched mid-ocean ridge basalt (E-MORB). The magmas evolved by fractional crystallization with contamination by crust; however, neither process can adequately explain the contemporaneous eruption of hawaiite and tholeiite at Sheridan Bluff. Our preferred scenario is that primary magmas of each type were produced by different degrees of partial melting from a compositionally similar mantle source. The nearly simultaneous generation of lower degrees of melting to produce alkaline types and higher degrees of melting forming tholeiite was most likely to have been facilitated by the detachment and dehydration of metasomatized mantle lithosphere.

Origin of geochemically heterogeneous mid-ocean ridge basalts from the Macquarie Ridge Complex, SW Pacific

The Macquarie Ridge Complex (MRC), located at the Australian–Pacific plate boundary south of New Zealand, is a rugged bathymetric ridge comprising a series of submarine seamounts and Macquarie Island, the only subaerial portion of the complex. Mid-ocean ridge basalts (MORBs) from Macquarie Island show various enrichments in incompatible elements with compositions ranging from typical normal MORB to enriched MORB. However, these basalts have isotopic compositions trending towards a high μ-like (μ = 238U/204Pb; HIMU) mantle component, which is unusual for MORB-type rocks. The origin of this mantle signature is not understood, and it is unclear whether this isotopic signature is characteristic of the entire MRC or unique to Macquarie Island. Here we report new major and trace element abundances, and Sr, Nd, and Pb isotopes for samples from the MRC seamounts and from new sampling sites on Macquarie Island. The geochemical and isotopic data show that the entire MRC comprises normal to enriched MORB. Mixing modelling indicates that the heterogeneous isotopic signatures of the MRC basalts are not derived from contamination of the nearby Balleny mantle plume but have affinities with that of the Cenozoic Zealandia intraplate HIMU-like basalts. We propose that the heterogeneous geochemical signatures of the MRC basalts are derived from amphibole-bearing garnet pyroxenite veins, which is supported by the rare earth element partial melting modelling and strong correlations between Nd and Pb isotopic ratios vs La/Sm. We posit that the pyroxenite veins were generated in the oceanic lithospheric mantle, which was metasomatised by hydrous and carbonatitic fluids/melts derived either from delaminated, metasomatised Zealandia subcontinental lithosphere mantle, or from subducted material in the asthenosphere. The subducted material could be derived from ancient and/or recent subduction along the former east Gondwana margin.

Petrology, Geochronology and Geochemistry of the Xar Moron River Ophiolite: Implications for the Tectonic Evolution of the Paleo‐Asian Ocean

AbstractAs the largest accretionary orogen, the crustal tectonic framework and evolution of the Central Asian Orogenic Belt (CAOB) have always been one of the hot topics among geologists (Sengör et al., 1993, 1996; Jahn et al., 2000a; Badarch et al., 2002; Windley et al., 2007; Li et al., 2009). The formation of the main part of the crust in the CAOB involved continuous lateral accretion of island arcs and accretionary complexes along the margins of the Siberian, Sino‐Korean and Tarim paleo‐continents and the final collision between these continental margins because of the subduction of the Paleo‐Asian Ocean plate since Mesoproterozoic. The ophiolites, which represent the fragments of ancient oceanic lithosphere, are the direct evidence for the study of the evolution of orogenic belts. Based on field geological survey, the mantle peridotite (serpentinite), gabbro, basalt and radiolarian bedded chert, which were deemed as the “ophiolite trinity”, were identified as isolated blocks in the matrix of pelitic siltstone and silty mudstone in the Kedanshan, Xingshuwa and Jiujingzi areas along the Xar Monron River in southeast Inner Mongolia of China. Besides, there were plenty of other exotic blocks, such as limestone and sandstone, in the matrix. Both of the matrix and blocks underwent strong foliated deformation. All of these rocks above constitute a tectonic mélange. Zircon U‐Pb dating for the gabbro blocks in the Xingshuwa and Jiujingzi ophiolites reveals that they were formed in early Permian (275–280 Ma). The ages of the gabbros, together with the middle Permian radiolaria fossils in the chert reported by Wang and Fan (1997), indicate that the oceanic basin was not closed in early‐middle Permian. The geochemical compositions of the basaltic blocks distributed in different locations in the Xingshuwa tectonic mélange display different genetic types of normal mid‐ocean ridge basalt (N‐MORB), enriched mid‐ocean ridge basalts (E‐MORB), oceanic island basalt (OIB), island arc basalt and continental marginal arc basalt, which indicates what they represented is a complex oceanic basin. Combining with the studies on regional magmatism, strata and structure data, it is suggested that the Xar Moron River Ophiolite belt represented the final suture zone of the Paleo‐Asian Ocean in the southeast Inner Mongolia, and the ocean did not close before late Permian.

Paleoproterozoic tectonic evolution of the northern Yangtze craton from oceanic subduction through continental collision to continental rifting: Geochronological and geochemical records of metabasites from the Tongbai orogen in central China

We report for the first time the existence of multistage Paleoproterozoic collision- and rift-related tectonothermal events in the northern margin of the Yangtze craton. This is achieved through an integrated study of geochronology and geochemistry for Phanerozoic metabasites from the Tongbai orogen in central China. Zircon U-Pb dating and trace element analysis reveal two episodes of magmatism and one episode of metamorphism from ca. 1.96 Ga to 1.63 Ga. Whole-rock geochemistry indicates that the 1.96 Ga metabasite shows typical arc-like trace elemental distribution patterns with enrichment in LREE but depletion in HFSE, whereas the 1.63 Ga metabasites are characterized by enriched mid-ocean ridge basalts (MORB)- or ocean island basalts (OIB)-like trace element distribution patterns with enrichment in LREE but no depletion in HFSE. In addition, a 1.84 Ga granulite facies metamorphic event is recorded by sector zoned domains of zircon from the 1.96 Ga metabasites, showing flat HREE patterns with markedly negative Eu anomalies and a high formation temperature of 825 °C. Integrating the available data from the northern Yangtze craton, we suggest that the 1.96 Ga metabasite was produced by decompressional melting of the metasomatic mantle domain subsequent to exhumation of the high-pressure metamorphic rocks, the 1.84 Ga granulite facies metamorphism was induced by asthenospheric upwelling in response to post-collisional extension, and the 1.63 Ga magmatism was associated with lithospheric extension due to continental rifting. Therefore, the Paleoproterozoic metabasites in the Tongbai orogen witness the tectonic evolution from oceanic subduction through continental collision to continental rifting, indicating that the northern margin of the Yangtze craton was involved in the assembly and breakup of supercontinent Columbia. In comparison to the coeval rift-related igneous rocks in other blocks, the geochemical features of 1.63 Ga metabasites in the northern Yangtze craton are similar to those in the northern Australia, but are significantly different from those in the southern Siberia and the northern Laurentia. This indicates a possible connection between the northern Yangtze and the northern Australia before the Columbia breakup.

Geochemistry and Petrogenesis of Volcanic Rocks from the Continent-Ocean Transition Zone in Northern South China Sea and Their Tectonic Implications

Miocene-Pliocene (22–5 Myr) volcanism and associated seamounts are abundant in the continent-ocean transition (COT) zone in the margin of the north South China Sea (SCS). The petrogenesis of volcanic rocks from these seamounts and regional tectonic evolution of COT zone are poorly known. In this paper, we obtained whole-rock major and trace element compositions and Sr-Nd-Pb isotopic data for these volcanic rocks from the Puyuan and Beipo seamounts within COT zone, in northeastern SCS. Based on the geochemical analyses, the volcanic rocks are classified as alkaline ocean island basalts (OIB) and enriched mid-ocean ridge basalts (E-MORB). The OIBs from the Puyuan seamount are alkaline trachybasalts and tephrites that show enrichment of the light rare earth elements (LREE) relative to heavy rare earth elements (HREE) and more radiogenic Sr-Nd isotopic compositions, and have significant ‘Dupal isotopic anomaly’. In contrast, the E-MORBs from the Beipo seamount are tholeiitic basalts that have less enrichment in LREE and less radiogenic Sr-Nd isotopic compositions than the counterparts from the Puyuan seamount. Petrological and geochemical differences between the OIBs and MORBs from these two seamounts can be explained by different mantle sources and tectonic evolution stages of the COT zone. Syn-spreading OIB type basalts from the Puyuan seamount were derived from an isotopically ‘enriched’, and garnet facies-dominated pyroxenitic mantle transferred by the Hainan mantle plume. In contrast, post-spreading E-MORB type basalts from the Beipo seamount are considered to be derived from the melting of isotopically ‘depleted’ pyroxenite mantle triggered by lithosphere bending and subsequent post-rifting at the lower continental slope of the northern margin.

New geochemical and Sr-Nd-Pb isotope evidence for FOZO and Azores plume components in the sources of DSDP Holes 559 and 561 MORBs

Enriched mid-ocean ridge basalts (E-MORBs) near hotspots are commonly ascribed to be products of mantle plume-ridge interaction, but the genesis of E-MORBs far from hotspots remains controversial. Here we report new major and trace element and Sr-Nd-Pb isotopic data for lavas from Holes 559 and 561 of Deep Sea Drilling Project (DSDP) Leg 82 that are located west of the Mid-Atlantic Ridge (MAR) midway between the Oceanographer and Hayes fracture zones (33–35°N). Our data reveal that E-MORBs from Hole 559 have high (87Sr/86Sr)i (0.70292–0.70294) and (206Pb/204Pb)i (19.504–19.692) and low (143Nd/144Nd)i (0.51297–0.51299) values, similar to the mantle focal zone (FOZO) component, that could be partly coming from the New England mantle plume. We propose that the FOZO component could be widely distributed beneath the northern portion of MAR at ~35 Ma. Hole 561 lavas contain both depleted (D-) and E-MORB. The D-MORBs have depleted Sr-Nd-Pb isotope compositions and were derived from the depleted asthenospheric mantle. Hole 561 E-MORBs have radiogenic (87Sr/86Sr)i (0.70337–0.70341), (143Nd/144Nd)i (0.51296–0.51297) and (206Pb/204Pb)i (19.463–19.525) values that are similar to the proposed common component in the mantle plume sources of lavas in all the Azores islands except for the eastern part of São Miguel. In addition, Hole 561 E-MORBs also display higher Th/La and Nb/La ratios than the most plume-influenced E-MORBs near the Azores hotspot and even the Azores lavas. These suggest that Hole 561 E-MORBs were derived from partial melting of a depleted mantle metasomatized by deep, low-degree melts of the common Azores plume component. We propose that variable amounts of such metasomatized mantle are widely distributed in the asthenospheric mantle beneath the MAR 33–35°N ridge segment since ~19 Ma and their partial melting is also probably responsible for the generation of the modern MAR 33–35°N E-MORBs.

Late Paleozoic Chingiz and Saur Arc Amalgamation in West Junggar (NW China): Implications for Accretionary Tectonics in the Southern Altaids

AbstractThe Saur‐Chingiz Belt (SCB) in northern West Junggar is regarded as the amalgamation zone of the Saur and Chingiz arcs. It contains diagnostic rocks of accretionary origin, providing critical information about the evolution of the southern Paleo‐Asian Ocean. We recognize various lithologies in the SCB, including an ophiolitic mélange, turbidites, conglomerates, rhyolites, breccias, and diorites, and investigate the structures of the Hebukesaier ophiolitic mélange. Kinematic analysis indicates top‐to‐the‐N thrusting. A coarse‐grained gabbro (ca. 490 Ma) and a fine‐grained gabbro (ca. 318 Ma) have normal mid‐ocean ridge basalt (N‐MORB)‐type geochemical signatures, and three groups of pillow basalts exhibit N‐MORB, enriched mid‐ocean ridge basalt (E‐MORB), and ocean island basalts (OIB) fingerprints, respectively. Detrital zircons in tuffs, conglomerates, and turbidites associated with the Hebukesaier mélange display predominant ages of 410–440 Ma, which are consistent with the age of the Chingiz Arc. This suggests that the mafic rocks (ophiolitic components) in the Hebukesaier mélange were generated at a mid‐ocean ridge and were later accreted to the Chingiz Arc, which formed above a southward‐dipping subduction zone that consumed the Paleo‐Asian Ocean. The predominant zircon age peaks of turbidites from the Saur area, north of the Hebukesaier mélange, range from 326 to 360 Ma, which areconsistent with a provenance from the Saur Arc. The distinctive detrital zircons of the Chingiz and Saur arcs indicate that the northern boundary of the Hebukesaier mélange is the tectonic boundary between the Chingiz and Saur arcs. We suggest that Paleo‐Asian Ocean closed before Late Triassic as indicated by a diorite vein (ca. 218 Ma) that intruded the Hebukesaier mélange.

Ages and tectonic settings of the Neoproterozoic igneous rocks in the Gyeonggi Massif of the southern Korean Peninsula and the correlation with the Neoproterozoic igneous rocks in China

The Neoproterozoic igneous rocks in the northern and southern Gyeonggi Massifs in the southern Korean Peninsula are important for the interpretation of the Neoproterozoic tectonic evolution of the Korean Peninsula and northeastern Asia. The Gonamsan and Chuncheon metabasites in the northern Gyeonggi Massif intruded in a within-plate tectonic setting at ca. 851–873 Ma and 888 Ma, respectively. The Nb/Yb ratios (7–23) of these metabasites represent enriched mid-ocean ridge basalt (E-MORB) to ocean island basalt (OIB) characteristics. Most zircons found within the Gonamsan metabasites have positive εHf(t) values and Paleoproterozoic to Mesoproterozoic isotopic model ages (TDM2). These metabasites have initial 87Sr/86Sr ratios that range between 0.7033 and 0.7058 and εNd(t) values of −0.68 to 5.02. These geochemical characteristics of these metabasites indicate that these rocks formed in a rift-related environment.The Neoproterozoic metabasites from the Dangjin area in the southwestern Gyeonggi Massif can be subdivided into arc and rift types. The Dangjin arc-type metabasites intruded at ca. 820–833 Ma. These metabasites have Nb/Yb ratios of 4–7, Nb/U ratios of 3.58–27.5 and show an increase in Th/Nb ratios with increasing La/Sm ratios. Most zircons from these metabasites have negative εHf(t) values and Paleoproterozoic-Archean TDM2 ages, except one that has positive εHf(t) values and a Mesoproterozoic TDM2 age. Most these metabasites have initial 87Sr/86Sr ratios of 0.7048–0.7105 and negative εNd(t) values from −11.67 to −5.25. These geochemical characteristics indicate that the arc type Dangjin metabasites experienced crustal contamination during differentiation in an arc tectonic environment.The rift-related Dangjin metabasites intruded at ca. 793 Ma in a similar manner to the Gonamsan and Chuncheon metabasites. The Nb/Yb ratios (8–11) of these metabasites are higher than those of the arc-type metabasites. These metabasites have lower initial 87Sr/86Sr ratios of 0.704 and higher εNd(t) values of 1.96 than the Dangjin arc-type metabasites. Together with the results of previous work, this study indicates that the tectonic setting of the Dangjin-Hongseong area was an arc during the period 820–900 Ma and then changed into a rift during the period 703–793 Ma.The Neoproterozoic igneous rocks in the northern Gyeonggi Massif can be correlated with those formed in the within-plate tectonic setting in the southern and southeastern margins of the North China Craton during the period 830–930 Ma. On the other hand, the Neoproterozoic igneous rocks in the southwestern Gyeonggi Massif can be correlated to the Neoproterozoic arc- and rift-related igneous rocks in the northern margin of South China Craton, which intruded during 850–871 and 637–820 Ma, respectively.

Alkalic to tholeiitic magmatism near a mid-ocean ridge: petrogenesis of the KR1 Seamount Trail adjacent to the Australian-Antarctic Ridge

ABSTRACT Coexisting alkalic and tholeiitic basalt lavas has been identified in a seamount chain located near the Australian–Antarctic spreading ridge. The KR1 Seamount Trail (KR1 ST) is a series of volcanic seamounts extending to the southeast in the spreading direction of the Australian–Antarctic Ridge (AAR). We herein report Sr, Nd and Pb isotopic compositions and (U–Th)/He and K–Ar geochronology for dredge samples from the KR1 ST in order to evaluate mantle processes and the role of enriched components for alkalic to tholeiitic magma generation in this region. The KR1 ST is a medium-sized seamount chain that extends for ~60 km, has a maximum height of ~1600 m above the seafloor, and consists of alkaline basalts and tholeiites with formation ages of ~0.4 Ma to ≤1.3 Ma. The isotopic characteristics of the alkaline basalts (206Pb/204Pb = 19.52–19.91; 87Sr/86Sr = 0.7030–0.7033; 143Nd/144Nd = 0.5128–0.5130) from the KR1 ST reflect a dominant ‘PREMA (or FOZO)’ mantle component represented by radiogenic Pb and mildly enriched Sr and Nd isotopic compositions. On the other hand, the weak PREMA (FOZO)-affinity (206Pb/204Pb = 18.89–18.93; 87Sr/86Sr = 0.7028–0.7029; 143Nd/144Nd = ~0.5130; 3He/4He = 7.64 ± 0.13 (R/RA)) coupled with their enriched mid-ocean ridge basalt (E-MORB) characteristics of tholeiites from the KR1 ST largely overlap with the KR1 MORB composition. The potential source materials for the alkaline basalts are considered to be ancient, recycled oceanic crust (i.e. eclogite) as well as sub-KR1 depleted MORB mantle (DMM). Whereas the main source materials for the KR1 ST tholeiites are presumed to be the DMM-dominant lithology with minor recycled material. We interpret the KR1 ST as a submarine hotspot chain that was formed by asthenospheric upwelling and spreading processes that delivered fertile blobs of recycled oceanic crust to the sub-KR1 region. The fundamental reason for sub-KR1 upper mantle enrichment might be attributed to a mantle plume event that possibly occurred prior to the formation of the KR1 ST.

Lithogeochemistry of the Mid-Ocean Ridge Basalts near the Fossil Ridge of the Southwest Sub-Basin, South China Sea

Mid-ocean ridge basalts (MORB) in the South China Sea (SCS) record deep crust-mantle processes during seafloor spreading. We conducted a petrological and geochemical study on the MORBs obtained from the southwest sub-basin of the SCS at site U1433 and U1434 of the International Ocean Discovery Program (IODP) Expedition 349. Results show that MORBs at IODP site U1433 and U1434 are unaffected by seawater alteration, and all U1433 and the bulk of U1434 rocks belong to the sub-alkaline low-potassium tholeiitic basalt series. Samples collected from site U1433 and U1434 are enriched mid-ocean ridge basalts (E-MORBs), and the U1434 basalts are more enriched in incompatible elements than the U1433 samples. The SCS MORBs have mainly undergone the fractional crystallization of olivine, accompanied by the relatively weak fractional crystallization of plagioclase and clinopyroxene during magma evolution. The magma of both sites might be mainly produced by the high-degree partial melting of spinel peridotite at low pressures. The degree of partial melting at site U1434 was lower than at U1433, ascribed to the relatively lower spreading rate. The magmatic source of the southwest sub-basin basalts may be contaminated by lower continental crust and contributed by recycled oceanic crust component during the opening of the SCS.

Ophiolite hosted chromitite formed by supra-subduction zone peridotite –plume interaction

Chromitite bodies hosted in peridotites typical of suboceanic mantle (s.l. ophiolitic) are found in the northern and central part of the Loma Caribe peridotite, in the Cordillera Central of the Dominican Republic. These chromitites are massive pods of small size (less than a few meters across) and veins that intrude both dunite and harzburgite. Compositionally, they are high-Cr chromitites [Cr# ​= ​Cr/(Cr ​+ ​Al) atomic ratio ​= ​0.71–0.83] singularly enriched in TiO2 (up to 1.25 ​wt.%), Fe2O3 (2.77–9.16 ​wt.%) as well as some trace elements (Ga, V, Co, Mn, and Zn) and PGE (up to 4548 ​ppb in whole-rock). This geochemical signature is unknown for chromitites hosted in oceanic upper mantle but akin to those chromites crystallized from mantle plume derived melts. Noteworthy, the melt estimated to be in equilibrium with such chromite from the Loma Caribe chromitites is similar to basalts derived from different source regions of a heterogeneous Caribbean mantle plume. This mantle plume is responsible for the formation of the Caribbean Large Igneous Province (CLIP). Dolerite dykes with back-arc basin basalt (BABB) and enriched mid-ocean ridge basalt (E-MORB) affinities commonly intrude the Loma Caribe peridotite, and are interpreted as evidence of the impact that the Caribbean plume had in the off-axis magmatism of the back-arc basin, developed after the Caribbean island-arc extension in the Late Cretaceous. We propose a model in which chromitites were formed in the shallow portion of the back-arc mantle as a result of the metasomatic reaction between the supra-subduction zone (SSZ) peridotites and upwelling plume-related melts.

Slab-controlled elemental–isotopic enrichments during subduction initiation magmatism and variations in forearc chemostratigraphy

Supra-subduction zone (SSZ) ophiolites formed in forearc settings and the Izu–Bonin–Mariana (IBM) in-situ forearc show conversions from normal mid-ocean ridge basalt (MORB) to boninitic affinities, which are widely interpreted as rules for the evolving chemical geodynamics of subduction initiation magmatism (SIM). Nevertheless, forearc sequence generated by subduction initiation need not always include boninitic rocks. Here we reconstruct a forearc chemostratigraphy without boninitic affinity based on the Central Palawan and Amnay (CPA) ophiolites of the west Philippines to show diversity in melt evolution of SIM. Zircon U–Pb dating on the MORB-type Amnay gabbros reveal a 10 m.y. of seafloor spreading from 33 to 23 Ma. These ages together with the progressively enriched zircon in-situ oxygen isotopes (δ18O= 1.62–10.1‰) and whole rock elemental and Nd–Hf isotopic signatures ([La/Yb]N= 0.19–3.45; Nb/Yb= 0.07–5.24; εNd= 2.1–10.2; εHf= 11.2–24.1) indicate that the depleted MORB mantle (DMM)-type source of the Amnay ophiolite was getting enriched by fluxing of aqueous slab fluid in the early stage followed by addition of adakitic and Nb-enriched slab melts in the later stage. This distinct mantle evolution together with higher εHf at a given εNd of the Amnay mafic samples than the contemporaneous South China Sea (SCS) oceanic samples do not support previous interpretation that the Amnay ophiolite was a fragment of the SCS. However, the 33–23 Ma Amnay ophiolite can be the younger part of the 34 Ma forearc-type Central Palawan ophiolite, and both (i.e. the CPA ophiolites) represent on-land fragments of the NW Sulu Sea. We propose that the 34–23 Ma CPA ophiolites and the NW Sulu Sea constitute forearc basin of the late Oligocene–middle Miocene island arc–backarc basin duo of the Cagayan Ridge and SE Sulu Sea, associated with subduction of the Cretaceous to Eocene Proto-SCS since 34 Ma. The CPA ophiolites lack boninite but show geochemical progression from normal to enriched MORB affinities, whose melt evolution differs from that of the IBM SIM. We attribute the differences in SIM and variations in forearc chemostratigraphy to the subduction of a younger slab with thick terrigenous sediment cover of the Proto-SCS versus an older slab with thin pelagic sediment cover of the Pacific Plate.

Origin of Devonian mafic magmatism in the East Kunlun orogenic belt, northern Tibetan Plateau: implications for continental exhumation

AbstractThis paper presents a comprehensive study of the zircon geochronology, geochemistry and Sr–Nd isotope geology of Devonian mafic rocks developed in the East Kunlun orogenic belt, northern Tibetan Plateau, and reveals their mantle sources, petrogenesis and geodynamic implications for continental exhumation. The zircon geochronology of typical samples indicates that these mafic rocks crystallized at 406∼408 Ma. They can be classified into two different groups based on petrographic observations and geochemical compositions. Group 1 rocks exhibit low TiO2 and FeOt contents and Nb/Y ratios and have enriched mid-ocean ridge basalt (E-MORB)-like compositions with slight negative Nb and Ta anomalies. However, Group 2 rocks have distinctly high TiO2 and FeOt contents and Nb/Y ratios, comparable to typical Fe–Ti-rich mafic rocks worldwide. All the samples exhibit weak enrichments in light rare earth elements, Nb and Ta relative to the primitive mantle. Based on geochemical and isotopic studies, Group 1 rocks are suggested to be derived from depleted asthenospheric mantle that was metasomatized by c. 3–5 % continental crustal components, while Group 2 rocks originated from partial melting of enriched lithospheric mantle. The high contents of Fe, Ti and Nb for Group 2 rocks could be attributed to a high degree of olivine crystallization under low fO2 conditions with delayed nucleation of Fe–Ti oxides. Combining those results with other geological data, we conclude that slab break-off was the key factor causing exhumation of eclogites and triggering flare-up of the Devonian magmatism, and that continental collision or continental subduction may have initiated at 431∼436 Ma.

Continental extension of northern Gondwana margin in the Eastern Himalaya: Constraints from geochemistry and U–Pb zircon ages of mafic intrusives in the Siang window, Arunachal Himalaya, India

We report new U–Pb zircon age and whole-rock geochemical data from the Pangin mafic intrusive rocks of the Siang window, eastern Himalayas. These mafic rocks are medium to coarse-grained gabbros, consisting mainly of plagioclase and clinopyroxene with accessory phases (hornblende + Fe–Ti oxides) that retain granular and interlocking texture. Geochemically, they display enriched-mid oceanic ridge basalt (E-MORB) affinity characterized by moderate to slightly fractionated REE patterns marked by (La/Yb) N =2.65-3.99. Their geochemical characteristics suggest that the parental magmas of these rocks were formed by medium to higher degrees (∼12–28%) of partial melting similar to that of the asthenospheric mantle in the garnet-spinel transition zone. Magmatic zircons from two gabbros yield U–Pb ages of 521.50 ± 2.53 Ma and 568 ± 2 Ma. This new age reveals two pulses of Late Neoproterozoic and Early Cambrian mafic magmatism that are inconsistent with the temporal distribution of Paleozoic magmatism in the Siang window of the Eastern Himalayas. However, based on the results of this study and the correlation of continental extensional mafic magmatism in the Northwest Himalaya, we suggest that investigated mafic intrusive rocks might have been generated in an extensional tectonic environment during the long-lasting Pan-African orogenic cycle of the late Neoproterozoic to early Cambrian which ended with the formation of the Gondwana supercontinent.

The passive margin of northern Gondwana during Early Paleozoic: Evidence from the central Tibet Plateau

The central–south domain of the Tibet Plateau represents an important part of the northern segment of Gondwana during the early Paleozoic. Here we present zircon U–Pb, Lu–Hf isotope, and whole–rock geochemical data from a suite of early Paleozoic magmatic rocks from the central Tibet Plateau, with a view to gain insights into the nature and geotectonic evolution of the northern margin of Gondwana. Zircon grains in four granitic rocks yielded ages of 532−496 Ma with negative εHf(t) values (−13.7 to −0.6). Zircon grains in meta–basalt and mafic gneiss yielded ages of 512 ± 5 Ma and 496 ± 6 Ma, respectively. Geochemically, the granitic rocks belong to high–K calc–alkaline and shoshonitic S–type granite suite, with the protolith derived from the partial melting of ancient crustal components. The mafic gneiss and meta–basalt geochemically resemble OIB (Oceanic Island Basalt) and E–MORB (Enriched Mid–Ocean Ridge Basalt), respectively. They were derived from low degree (∼5–10%) partial melting of an enriched mantle (garnet and spinel lherzolite) that was contaminated by upper crustal components. The parental magmas experienced orthopyroxene–dominated fractional crystallization. Sedimentological features of the Cambrian–Ordovician formations indicate that the depositional cycle transformed from marine regression to transgression leading to the formation of parallel/angular unconformities between the Cambrian and Ordovician strata. The hiatus associated with these unconformities are coupled with the peak of the early Paleozoic magmatism in Tibet Plateau, indicating a tectonic control. We conclude that the Cambrian–Ordovician magmatic suite and sedimentary rocks formed in an extensional setting, and we correlate this with the post–peak stage of the Pan–African orogeny. The post–collision setting associated with delamination, orogenic collapse or lithospheric extension along the northern margin of Gondwana, can account for the Cambrian–Ordovician magmatism and sedimentation, rather than oceanic subduction along the external margin. We thus infer a passive margin setting for the northern Gondwana during the Early Paleozoic.