It is an urgent challenge to develop low-cost and high-performance catalysts for the oxygen evolution reaction (OER).Herein,Fe-V co-doping Ni3S2-based oblate-nanorod arrays electrocatalysts supported by nickel foam (FV-Ni3S2/NF) have been successfully synthesized through hydrothermal technique. An increase in electrochemically active surface area and a decrease in charge-transfer resistance by the synergistic incorporation of Fe and V as well as the presence of α-Ni(OH)2 and γ-FeOOH on the surface of the catalysts effectively accelerate the OER kinetic process, and display an enhanced OER activity and stability in the alkaline media, resulting in a considerable improved overpotential of 259 mV at 100 mA cm−2and a Tafel slope of 22.38 mV dec−1, farsuperiorto pure NF, Ni3S2/NF, V-Ni3S2/NF, Fe-Ni3S2/NF and IrO2. Furthermore, i-t stability test after 50 h of FV-Ni3S2/NF indicates that the current density drop ratio is only 1.3 %, exhibiting excellent electrocatalytic stability. Thus, our studies provide a new strategy of designing cost-effective and high-performance catalysts through the introduction of double heteroatoms and interface/surface synergistic regulating engineering.