Electron Beam Energy Research Articles

Atomic-scale modeling of C/N kinetic stability descriptors for PGM-free electrocatalysts at finite temperatures

The durability of platinum group metal-free (PGM-free) electrocatalysts is a major barrier to their usage in polymer electrolyte fuel cell cathodes. C and N removal from active sites may play an important role in the catalyst’s ability to maintain high activity. While C degradation mechanisms are kinetically controlled, previous studies have focused on thermodynamic descriptors. In this work, we develop a temperature-dependent kinetic descriptor of C and N stability using an electron beam-damage model. Our approach considers the electron beam energy threshold (EBET) describing the knock-on displacement of C and N atoms as a stability descriptor for atomic structures. The stability of different sites is calculated to be different showing this approach can discriminate between similar sites with varied configurations. In addition, we provide important insight regarding TEM beam damage of proposed active sites. We calculate 60 keV electrons can damage some proposed active site structures even at room temperature.

Design Study for HybriSCU: A HYBRID NbTi/ReBCO Superconducting Undulator

At the European X-ray Free-Electron Laser (XFEL), the undulator systems group has started in 2020 an R&D project dedicated to the development of innovative superconducting undulator (SCU) coils. SCUs are of great interest for storage rings and free electron lasers (FEL) facilities as they enable to widen the tunability range of the generated photon energy for the same electron beam energy compared with the established technology of the permanent magnet undulators. In this contribution, we present the characterization study and the achievable performance of HybriSCU a graded SCU coil combining two different superconductors: NbTi and high temperature superconductor (HTS) based on Rare-Earth Barium Copper Oxide (ReBCO) tape.

Electron energy dissipation in a magnetotail reconnection region

The four Magnetospheric Multiscale spacecraft encountered a reconnection region in the Earth's magnetospheric tail on 11 July 2017. Previous publications have reported characteristics of the electron diffusion region, including its aspect ratio, the reconnection electric field, plasma wave generation from electron beams in its vicinity, and energetic particles in the Earthward exhaust. This paper reports on the investigation of conversion of electromagnetic energy to electron kinetic energy (by J·E) and the ensuing conversion of electron beam energy to electron thermal energy via the pressure–strain interaction. The main result is that omnidirectional, compressive dissipation of electron energy dominates in the positive J·E region, while incompressive parallel dissipation dominates in the inflow region where J·E is small. The existence of parallel electric fields in the inflow region supports previous suggestions that electron trapping by these fields contributes to the parallel dissipation. All of the results are reproduced quantitatively within a factor of two with a 2.5-D particle-in-cell simulation.

Assessing the Quality of Oxygen Plasma Focused Ion Beam (O-PFIB) Etching on Polypropylene Surfaces Using Secondary Electron Hyperspectral Imaging.

The development of Focused Ion Beam-Scanning Electron Microscopy (FIB-SEM) systems has provided significant advances in the processing and characterization of polymers. A fundamental understanding of ion-sample interactions is still missing despite FIB-SEM being routinely applied in microstructural analyses of polymers. This study applies Secondary Electron Hyperspectral Imaging to reveal oxygen and xenon plasma FIB interactions on the surface of a polymer (in this instance, polypropylene). Secondary Electron Hyperspectral Imaging (SEHI) is a technique housed within the SEM chamber that exhibits multiscale surface sensitivity with a high spatial resolution and the ability to identify carbon bonding present using low beam energies without requiring an Ultra High Vacuum (UHV). SEHI is made possible through the use of through-the-lens detectors (TLDs) to provide a low-pass SE collection of low primary electron beam energies and currents. SE images acquired over the same region of interest from different energy ranges are plotted to produce an SE spectrum. The data provided in this study provide evidence of SEHI's ability to be a valuable tool in the characterization of polymer surfaces post-PFIB etching, allowing for insights into both tailoring polymer processing FIB parameters and SEHI's ability to be used to monitor serial FIB polymer surfaces in situ.

Background optimization of powder electron diffraction for implementation of the e-PDF technique and study of the local structure of iron oxide nanocrystals.

The local structural characterization of iron oxide nanoparticles is explored using a total scattering analysis method known as pair distribution function (PDF) (also known as reduced density function) analysis. The PDF profiles are derived from background-corrected powder electron diffraction patterns (the e-PDF technique). Due to the strong Coulombic interaction between the electron beam and the sample, electron diffraction generally leads to multiple scattering, causing redistribution of intensities towards higher scattering angles and an increased background in the diffraction profile. In addition to this, the electron-specimen interaction gives rise to an undesirable inelastic scattering signal that contributes primarily to the background. The present work demonstrates the efficacy of a pre-treatment of the underlying complex background function, which is a combination of both incoherent multiple and inelastic scatterings that cannot be identical for different electron beam energies. Therefore, two different background subtraction approaches are proposed for the electron diffraction patterns acquired at 80 kV and 300 kV beam energies. From the least-square refinement (small-box modelling), both approaches are found to be very promising, leading to a successful implementation of the e-PDF technique to study the local structure of the considered nanomaterial.

Femtosecond Polarization Shaping of Free-Electron Laser Pulses.

We demonstrate the generation of extreme-ultraviolet (XUV) free-electron laser (FEL) pulses with time-dependent polarization. To achieve polarization modulation on a femtosecond timescale, we combine two mutually delayed counterrotating circularly polarized subpulses from two cross-polarized undulators. The polarization profile of the pulses is probed by angle-resolved photoemission and above-threshold ionization of helium; the results agree with solutions of the time-dependent Schrödinger equation. The stability limit of the scheme is mainly set by electron-beam energy fluctuations, however, at a level that will not compromise experiments in the XUV. Our results demonstrate the potential to improve the resolution and element selectivity of methods based on polarization shaping and may lead to the development of new coherent control schemes for probing and manipulating core electrons in matter.

Dosimetric properties of PASSAG polymer gel dosimeter in electron beam radiotherapy using magnetic resonance imaging.

Several physical factors such as photon beam energy, electron beam energy, and dose rate may affect the dosimetric properties of polymer gel dosimeters. The photon beam energy and dose rate dependence of PASSAG gel dosimeter were previously evaluated. This study aims to assess the dosimetric properties of the optimized PASSAG gel samples in various electron beam energies. The optimized PASSAG gel samples are first fabricated and irradiated to various electron energies (5, 7, 10 and 12 MeV). Then, the response (R2) and sensitivity of gel samples are analyzed by magnetic resonance imaging technique at a dose range of 0 to 10 Gy, scanning room temperature range of 15 to 22 °C, and post-irradiation time range of 1 to 30 days. The R2-dose response and sensitivity of gel samples do not change under the evaluated electron beam energies (the differences are less than 5%). Furthermore, a dose resolution range of 11 to 38 cGy is obtained for the gel samples irradiated to different electron beam energies. Moreover, the findings show that the R2-dose response and sensitivity dependence of gel samples on electron beam energy varies over different scanning room temperatures and post-irradiation times. The dosimetric assessment of the optimized PASSAG gel samples provides the promising data for this dosimeter during electron beam radiotherapy.

Electron Energy Spectrometer for MIR-THz FEL Light Source at Chiang Mai University

The linear accelerator system of the PBP-CMU Electron Linac Laboratory has been designed with the aim of generating free-electron lasers (FELs) in the mid-infrared (MIR) and terahertz (THz) regions. The quality of the radiation is strongly dependent on the properties of the electron beam. Among the important beam parameters, the electron beam energy and energy spread are particularly important. To accurately measure the electron beam energy, the first dipole magnet in the bunch compressor system and the downstream screen station are employed as an energy spectrometer. The A Space Charge Tracking Algorithm (ASTRA) software is used for the design and optimization of this system. Simulation results demonstrate that the developed spectrometer is capable of accurately measuring the energy within the 5–25 MeV range. The screen station system is designed and constructed to have the ability to capture a beam size with a resolution of 0.1 mm per pixel. This resolution is achieved with a screen-to-camera distance of 1.2 m, which proves sufficient for precise energy measurement. The systematic error in energy measurement is found to be less than 10%, with a minimum energy spread of 0.4% achievable when the horizontal beam size remains below 3 mm.

Optical properties of N2/Ar plasma generated by electron beams with silicon nitride transmission window at high pressures

In this paper, we report the generation of nitrogen/argon electron beam plasmas with a 0.4 μm-thick silicon nitride transmission window. The measured transmittance of the electron beam is about 92% when the incident energy of electron beam is 40 keV. The optical properties of the electron beam plasma are investigated at high pressures. The luminescence intensity distribution of nitrogen and argon electron beam plasmas shows a good similarity with changing the gas pressure, suggesting that electron beam ionization is independent of background gas. At the same gas pressure, the nitrogen plasma with conical structure has a longer length along the incident direction of the electron beam and a smaller divergence cone angle compared with the argon plasma. In the nitrogen discharge, it is found that the intensities I380.4, I399.7, and I391.4 corresponding to characteristic lines at 380.4, 399.7, and 391.4 nm decrease along the incident direction of the electron beam, which is correlated with the reduction of the electron density along the incident direction of the electron beam. There is no change in the ratio of I399.7 to I380.4, indicating the spatial uniformity of the electron temperature. When the pressure increases, the ionization process induced by primary electron is enhanced, generating more plasma electrons, which is responding to the increase in the characteristic line intensity. At the same time, the neutral particle collision processes are enhanced and the electron temperature decreases with the increase in the pressure, which is believed to contribute to the observed reduction of the I399.7/I380.4 ratio.

Superconducting undulator activities at the European X-ray Free-Electron Laser Facility

For more than 5 years, superconducting undulators (SCUs) have been successfully delivering X-rays in storage rings. The European X-Ray Free-Electron Laser Facility (XFEL) plans to demonstrate the operation of SCUs in X-ray free-electron lasers (FELs). For the same geometry, SCUs can reach a higher peak field on the axis with respect to all other available technologies, offering a larger photon energy tunability range. The application of short-period SCUs in a high electron beam energy FEL > 11 GeV will enable lasing at very hard X-rays > 40 keV. The large tunability range of SCUs will allow covering the complete photon energy range of the soft X-ray experiments at the European XFEL without changing electron beam energy, as currently needed with the installed permanent magnet undulators. For a possible continuous-wave (CW) upgrade under discussion at the European XFEL with a lower electron beam energy of approximately 7–8 GeV, SCUs can provide the same photon energy range as available at present with the permanent magnet undulators and electron energies. This paper will describe the potential of SCUs for X-ray FELs. In particular, it will focus on the different activities ongoing at the European XFEL and in collaboration with DESY to allow the implementation of SCUs in the European XFEL in the upcoming years.

Analysis of different protocols using an Exradin A12 cylindrical chamber for electron beam reference dosimetry

The Technical Report Series 398 (TRS-398), Electron Dosimetry Working Party (EWDP), and Task Group 51 (TG 51) are the most important protocols for reference dosimetry. In the case of electron beam reference dosimetry, these protocols recommend using parallel-plate ionization chambers for beams with R50 values below specific thresholds. However, recent papers suggested using cylindrical chambers for reference dosimetry of all electron beam energies. Here we compared different protocols using a cylindrical chamber with the recommendations of using a parallel-plate chamber and the TRS-398 formalism for the dosimetry of several electron beam energies. We employed electron beams with nominal energies of 4, 6, 9, 12, and 15 MeV of a Varian 2100C linear accelerator, an Exradin A12, and an Exradin P11 chamber for the analysis. The results showed differences below 3% when comparing the cylindrical chamber and alternative protocols with the parallel-plate chamber and the TRS-398 formalism for electron beams reference dosimetry. These results can bring confidence in using a cylindrical chamber for reference electron beam dosimetry, which can make the electron beam dosimetry procedure simpler and faster.

Measurement of the Tensor-Analyzing Power Component T20 for Incoherent Negative Pion Photoproduction on a Deuteron

New results for the T20-component of the tensor-analyzing power of the incoherent negative pion photoproduction are presented. The experiment was performed for the electron beam energy of 800 MeV at the VEPP-3 storage ring in 2021. To extract the T20-component, we used asymmetry with respect to the change in the sign of the tensor polarization of the deuteron target. Identification of the reaction events was carried out by the detection of two protons in coincidence. Experimental data were compared with the results of statistical simulation, considering the interaction between the NN and πN subsystems in the final state of the reaction.

Focusing and reduction of correlated energy spread of chirped electron beams in passive plasma lens

All-optical compact plasma focusing and transportation of electron beams, in the passive mode of a plasma lens, is studied via real geometry particle-in-cell simulations for its suitability for the laser wakefield acceleration technique. The focusing of an electron beam by a passive plasma lens is a non-linear and dynamic process, which strongly depends on the space charge induced evacuation of the plasma electrons in the vicinity of the propagating electron beam. Effects of such focusing on the energy spread, divergence, and emittance of laser-driven electron beams are analyzed numerically for different plasma densities. An initially negative chirp in electron beam energy is shown to be instrumental in suppressing the unwanted growth in the relative energy spread of the electron beam during the passive lensing. Usefulness of such a passive plasma element for a single and multi-stage laser wakefield acceleration configuration is demonstrated.

Development of the high energy engineering X-ray (HEX) superconducting wiggler, magnetic measurement, installation, and commissioning.

The High energy Engineering X-ray (HEX) diffraction beamline at the National Synchrotron Light Source II (NSLS-II) at Brookhaven National Lab (BNL) is the first high-energy beamline capable of reaching 200keV for a monochromatic beam. With the 3 GeV electron beam energy for the NSLS-II ring, only the superconducting wiggler (SCW) producing greater than 4T peak field can cover these ranges with a sufficient number of photons. The 1.2 m-long HEX-SCW has a period length of 70mm and a field strength on-axis of 4.3T. It utilizes no liquid helium, and the vertical aperture size of the electron beam vacuum chamber is 8mm. Unlike regular undulators/wigglers, there is no standard configuration for the magnetic measurement system for superconducting insertion devices. The NSLS-II Insertion Devices group has developed, in collaboration with the vacuum group, a novel in-vacuum Hall mapper with a 1.75m in-vacuum linear motor and an in-vacuum flip coil system utilizing many commercial-off-the-shelf products. The measurements were conducted at the BNL, and the device was installed in the ring and commissioned. This paper provides a description of the SCW and its magnetic measurement systems, as well as a brief account of the installation and commissioning efforts.

Spatial profiles of collimated laser Compton-scattering γ-ray beams

The intensity and energy spatial distributions of collimated laser Compton scattering (LCS) γ-ray beams and of the associated bremsstrahlung beams have been investigated as functions of the electron beam energy, electron beam phase space distribution, laser optics conditions and laser polarization. We show that the beam halo is affected to different extents by variations in the above listed parameters. In the present work, we have used laser Compton scattering simulations performed with the eliLaBr code (https://github.com/dan-mihai-filipescu/eliLaBr) and real LCS and bremsstrahlung γ-ray beams produced at the NewSUBARU synchrotron radiation facility. A 500 μm MiniPIX X-ray camera was used as beamspot monitor in a wide γ-ray beam energy range between 1.73 MeV and 38.1 MeV.

Multi-pico-Coulomb and multi-GeV electron beam generation from LWFA with a cm scale gas cell

Analytical calculations are made for the scaling and design parameters for the generation of a multi-pico Coulomb and multi-GeV electron beam from a laser Wakefield acceleration (LWFA). The numerical values are optimized for electron acceleration from a cm-scale gas cell and self-guided laser plasma in the bubble domain, where the low-density plasma serves as an accelerating medium. A graphical analysis of the matched parameters is presented for 1–10 GeV electron beam energy gain, where the laser pulse is powered between 30 ∼ 700 TW with delivery capabilities of 1–100 J pulse energy, 25–150 fs pulse duration, and 15–95 μm spot size operating with 1018–19 W cm−2 laser intensity at a plasma density ∼1017 cm−3. The result shows the generation of multi-pico-Coulomb and multi-GeV electron beams. These parameters will be helpful for the future LWFA related experiments using cm scale gas cells in the bubble regime.

A New Method for Dead Time Calibration and a New Expression for Correction of WDS Intensities for Microanalysis.

Observed photon count rates must be corrected for detector dead time effects for accurate quantification, especially at high count rates. We present the "constant k-ratio" method, a new approach for calibrating dead time for wavelength dispersive spectrometers by measuring k-ratios as a function of beam current. The method is based on the observation that for a given emission line at a specific take-off angle and electron beam energy, the intensity ratio from two materials containing the element should remain constant as a function of beam current, if the dead time calibration is accurate. The method has the advantage that it does not rely on the linearity of the beam current picoammeter, yet also allows the analyst to evaluate the picoammeter linearity, another critical parameter in EPMA calibration. By simultaneously comparing k-ratios for all spectrometers, one can also ascertain k-ratio consensus, essential for inter-laboratory comparisons. We also introduce improved dead time expressions and provide best practices on how to perform these instrument calibrations using this new "constant k-ratio" method. These improvements enable quantitative analysis of major and minor elements with high accuracy at high beam currents, simultaneously with trace elements with high sensitivity, for point analyses and X-ray mapping.

Role of ionizing radiation in the management of the Greater Wax Moth (Galleria mellonella L.): a comparative analysis of different types of ionizing radiation

Galleria mellonella L., is an insect pest of the honey bee combs and causes huge economic losses worldwide. Its management heavily relies on the use of chemical pesticides. However, chemical pesticides have drawbacks, including the incidence of colony collapse disorder and the development of pesticide resistance. Ionizing radiation has the potential to treat infested bee combs without leaving chemical footprints, thereby increasing agricultural output in general and honey production in particular. In the current study, research on how the type, energy, and dose rate of ionizing radiation affect radiation-induced damage was done on the eggs and larvae of G. mellonella. It was observed that although larval mortality increases with electron beam energy, egg hatchability depends more on dose rate and less on the energy of gamma and x-ray radiation in the MeV range of energy. Additionally, a significant association between dose rate and larval mortality was seen. Doses of 179.40 Gy and 158.60 Gy, respectively, of 0.66 MeV gamma rays and 15 MeV electrons, were required to stop pupal development completely. Gamma radiation in the MeV range of energy was found to be the most suitable modality of all ionizing radiation.

Analysis of Sialic Acid Linkage in N-Linked Glycopeptides Using Liquid Chromatography-Electron-Activated Dissociation Time-of-Flight Mass Spectrometry.

Herein, we report a novel liquid chromatography coupled with tandem mass spectrometry method to characterize N-acetylneuraminic acid (Neu5Ac, Sa) linkage in N-linked glycans in glycopeptides with no sialic acid derivatization. First, we established a separation in reversed-phase high-performance liquid chromatography (HPLC) using a higher formic acid concentration in the mobile phases, which separated the N-glycopeptides depending on the Sa linkage. We also demonstrated a novel characterization method of Sa linkages in N-glycopeptides using electron-activated dissociation. We found that hot electron capture dissociation using an electron beam energy higher than 5 eV cleaved glycosidic bonds in glycopeptides, resulting in each glycosidic bond in the antennas being broken on both sides of the oxygen atom. Such glycosidic bond cleavage at the reducing end (C-type ion) showed the difference in Sa linkages between Sa-Gal, Gal-GlcNAc, and GlcNAc-Man. We proposed a rule to characterize the Sa linkages using the Sa-Gal products. This method was applied to N-glycopeptides in tryptic fetuin digest separated by an optimized reversed-phase HPLC. We successfully identified a number of isomeric glycoforms in the glycopeptides with different Sa links, whose peptide backbones were also simultaneously sequenced by hot ECD.

Characterization of infrared free electron laser output profile through sum frequency generation spectroscopy

Infrared free electron laser is a unique broadband tuning IR light source and useful tool to trace the reaction and vibrational energy transfer dynamics. It is essential for the infrared free electron laser debug and optimization to accurately characterize the wavelength and micropulse profile of the infrared free electron laser output. By synchronizing the infrared free electron laser and tabletop femtosecond laser with high precision, infrared free electron laser-sum frequency generation setup, a sum frequency generation spectroscopy setup using infrared free electron laser pulses, is developed. Through sum frequency generation cross-correlation, the infrared free electron laser output wavelength and micropulse duration are measured from the delaytime-dependent infrared free electron laser-sum frequency generation spectra of a ZnS window. The infrared free electron laser-sum frequency generation measured infrared free electron laser wavelength is linearly correlated with the theoretically calculation with the fixed electron beam energy and variable undulator magnetic gaps. And the measured micropulse duration is 2.0 ps@5.25 µm and 2.9 ps@8.35 µm. These results demonstrate the excellent ability of sum frequency generation in the diagnostic and characterization of infrared free electron laser output profile, and the quality of the infrared free electron laser pulse structure.