Against the backdrop of the profound restructuring in global climate governance, China’s energy management system is undergoing a comprehensive transition from dual energy consumption control to dual carbon emissions control. This policy shift fundamentally alters the underlying logic of energy-focused regulation and inevitably impacts the economy–energy–environment (3E) system. This study innovatively constructs a “Triangular Trinity” theoretical framework integrating internal, intermediate, and external triangular couplings, as well as providing a granular analysis of their transmission relationships and feedback mechanisms. Using Guangdong Province as a case study, this study takes the dual control emissions policy within the external triangle as an entry point to research the restructuring logic of dual carbon emissions control for the coupling coordination mechanisms of the 3E system. The key findings are as follows: (1) Policy efficacy evolution: During 2005–2016, dual energy consumption control significantly improved energy conservation and emissions reduction, elevating Guangdong’s 3E coupling coordination. Post 2017, however, its singular focus on total energy consumption revealed limitations, causing a decline in 3E coordination. Dual carbon emissions control demonstrably enhances 3E systemic synergy. (2) Decoupling dynamics: Dual carbon emissions control accelerates economic–carbon emission decoupling, while slowing economic–energy consumption decoupling. This created an elasticity space of 5.092 million tons of standard coal equivalent (sce) and reduced carbon emissions by 26.43 million tons, enabling high-quality economic development. (3) Mechanism reconstruction: By leveraging external triangular elements (energy-saving technologies and market mechanisms) to act on the energy subsystem, dual carbon emissions control leads to optimal solutions to the “Energy Trilemma”. This drives the systematic restructuring of the sustainability triangle, achieving high-order 3E coupling coordination. The Triangular Trinity framework constructed by us in the paper is an innovative attempt in relation to the theory of energy transition, providing a referenceable methodology for resolving the contradictions of the 3E system. The research results can provide theoretical support and practical reference for the low-carbon energy transition of provinces and cities with similar energy structures.
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