Styrene Emission Research Articles

Reducing styrene emissions in composite piping manufacturing

Reducing styrene emissions in composite piping manufacturing

Spatiotemporally resolved emissions and concentrations of styrene, benzene, toluene, ethylbenzene, and xylenes (SBTEX) in the US Gulf region

Abstract. Styrene, benzene, toluene, ethylbenzene, and xylenes (SBTEX) are established neurotoxicants. SBTEX contains hazardous air pollutants (HAPs) that are released from the petrochemical industry, combustion process, transport emission, and solvent usage sources. Although several SBTEX toxic assessment studies have been conducted, they have mainly relied on ambient measurements to estimate exposure and limit their scope to specific locations and observational periods. To overcome these spatiotemporal limitations, an air quality modeling system over the US Gulf region was created, predicting the spatially and temporally enhanced SBTEX modeling concentrations from May to September 2012. Due to the incompleteness of SBTEX in the official US Environmental Protection Agency (EPA) National Emission Inventory (NEI), the Hazardous Air Pollutions Imputation (HAPI) program was used to identify and estimate the missing HAP emissions. The improved emission data were processed to generate the chemically speciated hourly gridded emission inputs for the Comprehensive Air Quality Model with Extensions (CAMx) chemical transport model to simulate the SBTEX concentrations over the Gulf modeling region. SBTEX pollutants were modeled using the Reactive Tracer feature in CAMx that accounts for their chemical and physical processes in the atmosphere. The data show that the major SBTEX emissions in this region are contributed by mobile emissions (45 %), wildfire (30 %), and industry (26 %). Most SBTEX emissions are emitted during daytime hours (local time 14:00–17:00), and the emission rate in the model domain is about 20–40 t h−1, which is about 4 times higher than that in the nighttime (local time 24:00–04:00, about 4–10 t h−1). High concentrations of SBTEX (above 1 ppb) occurred near the cities close to the I-10 interstate highway (Houston, Beaumont, Lake Charles, Lafayette, Baton Rouge, New Orleans, and Mobile) and other metropolitan cities (Shreveport and Dallas). High styrene concentrations were co-located with industrial sources, which contribute the most to the styrene emissions. The HAPI program successfully estimated missing emissions of styrene from the chemical industry. The change increased total styrene emissions by 22 %, resulting in maximum ambient concentrations increasing from 0.035 to 1.75 ppb across the model domain. The predicted SBTEX concentrations with imputed emissions present good agreement with observational data, with a correlation coefficient (R) of 0.75 (0.46 to 0.77 for individual SBTEX species) and a normalized mean bias (NMB) of −5.6 % (−24.9 % to 32.1 % for the individual SBTEX species), suggesting their value for supporting any SBTEX-related human health studies in the Gulf region. The SBTEX data were published at Zenodo (https://doi.org/10.5281/zenodo.7967541) (Wang et al., 2023), and the HAPI tool was also published at Zenodo (https://doi.org/10.5281/zenodo.7987106) (Wang and Baek, 2023).

Improving reactor fluid dynamics enhances styrene degradation by advanced oxidation processes

Styrene, being one of the volatile organic compounds (VOCs), presents a notable environmental risk. This study primarily addresses the mitigation of styrene emissions from waste air streams through advanced oxidation processes. Nonetheless, the development and experimentation of novel photoreactors can incur substantial costs and time commitments. Nevertheless, mathematical modelling can substantially reduce both expenses and reaction times. By experimental analysis, this research aims at comparing two designs of the first step of styrene treatment (dry photolytic reactor (UV185/UV254/O3)) in a two-step pilot plant unit. The new design differed in fluid geometry while maintaining identical dimensions and irradiation field in the photolytic reactor. Increasing the mean residence time of gas inside the reactor increased styrene removal efficiency by 25% at both flow rates, 100 and 150 m3·h−1. The experimental results were effectively explained by mathematical modelling, highlighting its invaluable role in designing new photoreactors. Based on our modeling, we added a baffle to the center of the photolytic reactor to further increase the residence time, thereby enhancing even more the photoreactor. The model with the baffle should completely remove 50ppmv of styrene from a gas stream at a 100 m3·h−1 flow rate already in the first step of the pilot unit. When comparing the cost-effectiveness of the three designs by calculating their electrical energy per order (EEO) values, we found that Design D (the new design with the baffle) reduces styrene emissions by 90% at approximately one quarter of the cost of Design A (original design). Precisely, treatment of air containing 50 ppmv of styrene utilizing Design D would cost 0.0012 € per each cubic meter. This study clearly demonstrates that fluid dynamics have a greater impact on the performance of advanced oxidation processes in air than photoreactor geometry and also the importance of mathematical modelling for reactor design.

Health Risks Assessment from Cured-in-Place Pipe Lining Fugitive Styrene Emissions in Laterals

The aim of this study was to improve the understanding of styrene emissions in sewer laterals, resulting from the installation and steam curing of a resin impregnated cured-in-place-pipe (CIPP) liner, within a sanitary sewer. The study included development and performance assessment of a controlled field test program that measures and records styrene emissions before, during, and after steam-curing a CIPP liner. Measured styrene emissions are then compared with those of published studies and regulatory exposure guidelines to assess the potential risk exposure. The field study measurements confirmed that high styrene concentrations can exist in sewer laterals during the steam-curing of the CIPP liner. They also confirm that water, in proper functioning P-traps, will prevent high styrene emissions from exiting the lateral and into buildings. Fugitive emission modeling shows that the risk of exceeding the acute exposure guideline limits is very low, even when high styrene concentrations exist in a lateral with a dry P-trap, and the styrene odor threshold is exceeded within the building, that is, when the building occupants smell styrene.

Air Quality Dispersion Modelling to Evaluate CIPP Installation Styrene Emissions.

Cured-in-place pipe (CIPP) is one of the most popular in situ rehabilitation techniques to repair sewer and water pipes. While there are multiple approaches to curing CIPP, steam-curing of styrene-based resins has been found to be associated with air-borne chemical emissions. Health officials, utilities and industry representatives have recognized the need to know more about these emissions, especially styrene. Such concern has led to multiple studies investigating the concentrations of volatile organic compounds on CIPP installation sites. This study expands upon previous effort by modeling worst-case, steam-cured CIPP emissions over a 5-year weather record. The effort also includes calibration of the model to emissions averages over the work day rather than instantaneous field measurements. Dispersion modelling software, AERMOD, was utilized to model the styrene component of CIPP emissions on two CIPP installation sites in the US. Based on the analysis results, it was found that the styrene emitted from stacks dissipates rapidly with styrene concentrations only exceeding minimum health and safety threshold levels at distances close to the stack (2 m or less). The values predicted by the model analysis are comparable with the field measured styrene concentrations from other studies. Current safety guidelines in the US recommend a 4.6-m (15-ft) safety perimeter for stack emission points. The results of this study indicate that significant and lasting health impacts are unlikely outside recommended safety perimeter. The results also validate the importance of enforcing recommended safety guidance on steam-cured CIPP sites.

Preparation and physicochemical characterization of deep eutectic solvents and ionic liquids for the potential absorption and biodegradation of styrene vapors

Styrene emissions can be treated by physicochemical, biological, or physicochemical/biological means. Due to its low solubility in water an alternative to eliminate styrene emissions from air is the use of two-phase partitioning bioreactors (TPPBs) which comprised a hydrophobic non-aqueous phase (NAP) which can improve mass transfer of styrene. This study was devoted to prepare and evaluate the main physicochemical characteristics of novel NAPs such as Ionic liquids (ILs), Deep Eutectic Solvents (DESs) and Natural Deep Eutectic Solvents (NADEs) as well as their toxicity and biodegradability to treat styrene vapors. Absorption experiments of styrene showed that the best NAPs were the DESs formed with Tetrabutylammonium bromide and decanoic acid and the ILs [C6mim][FAP], [C4mim] [NTf2] and [C4mim] [PF6], since they presented a styrene partition coefficient between 0.0015 and 0.0041. Finally, the IL [C6mim][FAP] was used as a NAP in a TPPB batch process given its high styrene affinity, low solubility in water and non-biodegradability; styrene mineralization was three times higher in the TPPB compared with the control. ILs are potential adjuvant phases in biological degradation systems, as well as other solvents like DESs and NADESs.

Styrene Emissions in Steam-Cured CIPP: A Review and Comparison of Multiple Studies

AbstractRecent research by Matthews et al. at the Louisiana Tech University Trenchless Technology Center (TTC) regarding styrene emissions produced during steam-cured, styrene-based cured-in-place ...

Use of Dicyclopentadiene and Methyl Dicyclopentadiene for the Synthesis of Unsaturated Polyester Resins.

Dicyclopentadiene (DCPD) modified unsaturated polyester resins (UPRs) are mostly used for hulls, decks, and bathroom facilities. Main advantages of these polymers over orthophthalic or isophthalic polyesters are their relatively low shrinking, reduced styrene emission, lower cost, and fast curing in thin layers. On the other hand, once cured, these materials are more brittle and have lower glass transition temperatures and lower chemical resistance due to their different chemical constitutions. DCPD UPRs with standard grades are usually produced with high-quality DCPD (over a 85% purity) using the so-called “water process”, a synthesis consisting of two reaction steps. An adduct of maleic anhydride with DCPD is firstly formed with water, and then, it reacts with the other esterification monomers such as acids and glycols. DCPD raw materials used in this study were prepared by a unique distillation process developed by ORLEN Unipetrol and University of Chemistry and Technology, Prague. This technology allows producing a wide spectrum of DCPD quality by adjusting the content of another norbornene dimer: methyl dicyclopentadiene (MeDCPD). The influence of MeDCPD on unsaturated polyester properties was examined throughout this study. It has been discovered that in low concentrations, MeDCPD had a slight influence on flexural mechanical properties whereas its concentrations up to 65% led to a softer and brittle material. Nevertheless, by adjusting the unsaturation degree, it has been shown that MeDCPD may be successfully implanted in UPR formulation.

Comparative Assessment of Carcinogenic Risk of Styrene Vapors Using Two Semi-Quantitative Methods in a Petrochemical Industry

Background: Styrene is one of the chemicals used in industries, especially the petrochemical industry, which affects health. Singaporean methods and the WHO use different parameters to assess the carcinogenic risk of the substance. Therefore, this study aimed to compare the level of carcinogenic risk due to exposure to styrene using the Singapore Department of Occupational Health with the risk levels provided using the WHO to achieve high-reliability results.
 Methods: In this study, 150 air samples were collected from the respiratory area of 50 employees by NIOSH1501 method, after identification of styrene emission units and preparation of identical exposure groups. The samples were analyzed by Varian-cp3800 gas chromatograph. Finally, the risk of styrene's health effects on petrochemical staff was calculated using the method of the Singapore Department of Occupational Health, and the results were compared with the risk levels of styrene presented by WHO.
 Results: The carcinogenicity of styrene was higher in polybutadiene latex (PBL) (2.3 ) and the fire department (1.3 ) in comparison with the other units. The World Health Organization-defined risk levels predicted 22% of staff to be a "definitive" carcinogenic risk. While the Singapore Department of Occupational Health approached a "low" risk rating.
 Conclusion: A "low" risk rating was obtained through the Singapore Department of Occupational Health. But the WHO method for 30 years of exposure to styrene predicted "probable risk" and "definitive risk." This showed a high difference in the results of the two semi-quantitative methods used.

Styrene and Bioaerosol Removal from Waste Air with a Combined Biotrickling Filter and DBD–Plasma System

A combined system of a biotrickling filter and a non-thermal plasma (NTP) in a downstream airflow was operated for 1220 days for treatment of emissions of styrene and secondary emissions of germs formed in the biological process. The biotrickling filter was operated at variable inlet concentrations, empty bed residence times (EBRT), type and dosage of fertilizers, irrigation densities, and starvation periods, while dielectric barrier discharge and corona discharge were operated at different specific input energy levels to achieve optimal conditions. Under these conditions, efficiencies in the removal of volatile organic compounds (VOCs), germs and styrene of 96–98%, 1–4 log units and 24.7–50.1 g C m−3 h−1 were achieved, respectively. Fluid simulations of the NTP and a germ emission-based clocking of the discharge reveal further energy saving potentials of more than 90%. The aim of an energy-efficient elimination of VOCs through a biotrickling filter and of secondary germ emissions by a NTP stage in a downstream airflow for potential re-use of purified waste gas as process gas for industrial application was successfully accomplished.

Emission fluxes of styrene monomers and other chemicals for products containing expanded polystyrene beads.

Styrene in indoor air can adversely affect human health. In this study, styrene monomer and other chemical emission fluxes for products containing expanded polystyrene beads (pillows, cushions, and soft toys) were measured at various temperatures to simulate typical product use. The contributions of the products to styrene and other chemical concentrations in indoor air and human exposure to these chemicals were estimated, and health risk assessments were performed. The styrene monomer emission fluxes for the samples at 25°C were between 25.3 and 8.73×103 μg/(m2 h). The styrene emission fluxes for the product surfaces increased strongly as the temperature increased, from between 124 and 2.44×104 μg/(m2 h) at 36°C (simulating human body temperature) to between 474 and 4.59×104 μg/(m2 h) at 50°C (simulating inside an automobile in summer). The hexane, heptane, toluene, octane, ethylbenzene, m- and p-xylene, o-xylene, and dodecane emission fluxes at 25°C for the sample that emitted the analytes most readily were high. The maximum estimated styrene and xylene concentrations in indoor air caused by emissions from expanded polystyrene beads at 36°C in a bedroom and automobile were higher than the relevant guidelines. The maximum contribution of a product containing expanded polystyrene beads in a living room, bedroom, or automobile could cause the total volatile organic compound concentration in air to exceed the advisable value (400 μg/m3). The estimated maximum hazard quotients for styrene, toluene, and xylene emitted by a product containing expanded polystyrene beads at 36°C in a bedroom were 0.59, 0.30, and 0.37, respectively. These non-carcinogenic risk values for single products could contribute to the non-carcinogenic risk thresholds being exceeded when multiple products and other sources of chemicals are taken into consideration. The estimated styrene concentrations suggest that products containing expanded polystyrene beads are important sources of styrene to indoor air.

Source apportionment of biogenic and anthropogenic VOCs in Bolu plateau

Total of 69 volatile organic compounds (VOCs) including both biogenic (isoprene, monoterpenes and oxygenated compounds) and anthropogenic ones were investigated in Bolu plateau by passive sampling technique. The main objective of this study was to determine spatial distributions, seasonal variations and possible sources for a wide variety of VOCs. Two-week passive sampling campaigns were performed in the winter and summer of 2017. Anthropogenic VOCs were predominant with a high percentage of contribution, 91% and 69% for winter and summer, respectively. Relatively higher concentrations of biogenic VOCs during the summer campaign were found to be related to higher solar intensity, temperature and amount of broad-leaved tree species. Benzaldehyde, toluene, phenol, benzene, hexane, decanal, benzothiazole, dodecane and acetophenone were anthropogenic VOCs with higher concentrations. Among biogenic VOCs, hexanal, alpha-pinene and limonene were found to be in higher concentrations. Spatial distribution maps were drawn for each VOC. Elevated concentrations of VOCs around the city center and major roads indicate that emissions from domestic heating activities and vehicular emissions can be significant sources of VOCs. The results were also supported by Positive Matrix Factorization (PMF) analyses and G-score distribution maps. Solvent evaporation, wood-coal combustion, biogenic emissions (pine, grain, grass), city atmosphere (styrene emissions from plastic production), biogenic (hornbeam, pine, juniper) and vehicle emissions were the identified as the primary VOC sources in Bolu plateau, contributing 31%, 22%, 8.0%, 8.0%, 13%, and 18%, respectively to the total VOC concentrations.

Emissions of selected monoaromatic hydrocarbons as a factor affecting the removal of single-use polymer barbecue and kitchen utensils from everyday use

The main focus of this study is the emission of monoaromatic hydrocarbons because these are the preliminary factors of potential solvent and monomer residues present in single-use plastic barbecue and kitchen utensils comprising polystyrene, polypropylene, natural cellulose, and biodegradable polymers intended for use with hot meal or beverages. Herein, the emissions of monoaromatic hydrocarbons (styrene, benzene, toluene, ethylbenzene, and xylene compounds and the total volatile organic compounds (TVOC)) from nine types of disposable plastic utensils are reported. Seventy two samples of single-use plastic utensils were conditioned at 40 and 80 °C using a stationary emission microchamber system. The average TVOC released from the studied polystyrene, polypropylene, and natural or biodegradable utensils were (2.3 ± 1.3), (1.01 ± 0.15), and (0.48 ± 0.37) μg g−1, respectively, at 40 °C and (11.1 ± 1.2), (46.1 ± 9.5), and (5.5 ± 1.1) μg g−1, respectively, at 80 °C. Significant emissions of styrene (ranged from 3.5 up to 15.3 × 103 ng∙g−1), toluene (from 2.8 up to 0.53 × 103 ng∙g−1), and ethylbenzene (from 3.7 up to 5.7 × 103 ng∙g−1) from the studied samples were observed, especially at 80 °C. Thus, elevated temperatures increase the potential emission of solvent and monomer residues from plastics and could affect the quality of consumed meals or beverages, such as taste. Additionally, to determine the possible interactions between the measured chemical compounds in the plastic utensils, the Pearson's correlation coefficients were calculated.

Adsorption effect of added powder graphite on reduction of volatile organic compounds emissions from expanded polystyrene

Volatile organic compounds (VOCs) were evaluated with application of a thermal load of thermal insulation boards made of expanded polystyrene (EPS). Samples of commercially produced polystyrene EPS 100S and EPS GreyWall were tested at 60 °C. For qualitative and quantitative analyses, headspace gas chromatography mass spectrometry (HS-GC-MS) was used. To reduce VOC emissions, the chemically non-bound powder graphite was added to the EPS 100S in experiments. The aim of this research was to analyse the effects of graphite bound in EPS structure and of added free powder graphite on the VOC emissions, especially styrene. The research revealed that the graphite bounded in the GreyWall EPS structure had an effect on the reduction of VOCs emissions, and reduced styrene emissions by 14.6%. The addition of powder graphite resulted in a reduction in VOCs emissions below the detection limit.

COMPARISON BETWEEN NORSODYNE AND TRADITIONAL PLASTINATION MATERIALS

Background: Norsodyne is a new material which initially is semiliquid, but under the action of a hardener is solid and transparent, and stays in this state interminable. Therefore, it is comparable to the BiodurP35 and BiodurP40 products that are used to make brain sheets. According to the manufacturers, Norsodyne H 13212 TAE that we use, is unsaturated polyester resin in styrene with low styrene emission for general purpose. We take for granted that in solid form. Comparison: Biodur P35 and P40 (BiodurTM, Heidelberg, Germany) are Polyester Co-polymers. The dehydrated brain plates are impregnated with this material and then solidified under UV light. The process lasts for 2 to 8 weeks. The final preparations are transparent, solid and safe for human health. Inclusion of the anatomical material in Norsodyne takes just a few minutes, and curing takes 15 to 30 minutes. The final preparations are transparent and solid too. We have no final data that Norsodyne is safe for human health. Conclusion: Due to the rapid production and high quality of the obtained with Norsodyne anatomical preparations, they can be used for anatomy training at medical universities, but after establishment of their safety.

CHARACTERISTICS OF NORSODYNE AS PLASTINATION AGENT

Background: Norsodyne is a new material for conservation and durable preservation of biological objects. The form we use is H 13212 TAE (Polynt Composites USA, Inc., Bergamo, Italy). This is an unsaturated polyester resin in styrene that is of low styrene emission. Features: resin has a specific weight 1.10 g/cm2 at 20°C. Using test method MT-CUT23V the manufacturer has established that Brookfield viscosity at 23°C is 450-650 mPa.s. The jelly starts in 14-18 minutes and reaches its peak in 27-37 minutes at 23°C too. Acording to the test results of ISO 527 (2012) tensile strength of Norsodyne is 57 MPa and flexural strength is 98 MPa (ISO 178 (2011). Conclusion: This characteristic of Norsodyne indicates that the material can be used for the preservation and long-term storage of anatomical preparations for the needs of anatomy training. However, the Norsodyne needs special storage conditions. The material should be stored in a dark place. According to the manufacturer shelf life at 23°C in the dark is six months then spontaneous rubbing begins. The manufacturer's recommendations are: Store in the shade, out of direct sunlight. Keep storage temperature below 25°C. Unseal container just before use. Shelflife will be reduced reaching higher temperature.

Determinants of environmental styrene exposure in Gulf coast residents.

Background:In a previous study of exposure to oil-related chemicals in Gulf coast residents, we measured blood levels of volatile organic compounds. Levels of styrene were substantially elevated compared to a nationally representative sample. We sought to identify factors contributing to these levels, given the opportunities for styrene exposure in this community.Methods:We measured blood styrene levels in 667 Gulf coast residents and compared participants’ levels of blood styrene to a nationally representative sample. We assessed personal and environmental predictors of blood styrene levels using linear regression and predicted the risk of elevated blood styrene (defined as above the National Health and Nutrition Examination Survey 95th percentile) using modified Poisson regression. We assessed exposure to styrene using questionnaire data on recent exposure opportunities and leveraged existing databases to assign ambient styrene exposure based on geocoded residential location.Results:These Gulf coast residents were 4–6 times as likely as the nationally representative sample to have elevated blood styrene levels. The change in styrene (log ng/mL) was 0.42 (95% CI: 0.34, 0.51) for smoking, 0.34 (0.09, 0.59) for time spent in vehicles and 1.10 (0.31, 1.89) for boats, and −0.41 (−0.73, −0.10) for fall/winter blood draws. Residential proximity to industrial styrene emissions did not predict blood styrene levels. Ambient styrene predicted elevated blood styrene in subgroups.Conclusions:Personal predictors of increasing blood styrene levels included smoking, vehicle emissions, and housing characteristics. There was a suggestive association between ambient and blood styrene. Our measures of increased regional exposure opportunity do not fully explain the observed elevated blood styrene levels in this population.

A systematic approach for selecting an optimal strategy for controlling VOCs emissions in a petrochemical wastewater treatment plant

This study assessed the fate of benzene, toluene, and styrene in a full-scale petrochemical wastewater treatment plant (WWTP) with respect to the selection of an efficient and cost-effective control strategy. To prepare input parameters for TOXCHEM, wastewater samples were collected from the inlet of treatment units. Subsequently, the resultant emission rates were applied in AERMOD to study the dispersion patterns of the target volatile organic compounds (VOCs). Based on the TOXCHEM results, the overall emission of benzene, toluene, and styrene was 123,935 g/day, of which 73.4, 13.3, and 13.4% were benzene, toluene, and styrene, respectively. The results indicated that up to 99.5% of the target VOCs were removed from wastewater by volatilization and biodegradation mechanisms. Also, more than 85% of the VOCs emission occurred from the primary treatment units (American Petroleum Institute oil separator, equalization basin, and dissolved air flotation system). In some cases, the concentration distribution profiles resulting from AERMOD showed higher values than EPA reference concentrations (RfC) around the study area. The most affected area was near the WWTP with maximum 1-h concentrations of 8166, 1267, and 1228 μg/m3 of benzene, toluene, and styrene, respectively. Based on the modeling results, the most applicable and available methods for separating and ultimately disposing of VOCs were investigated and compared with the aim of reducing emission rates to meet ambient air quality standards. The results revealed that steam stripping is the most efficient and cost-effective VOCs control strategy in the studied plant. Moreover, thermal incineration was marked as the first choice for ultimate disposal of the contaminated air streams.

Experimental evaluation of static and dynamic properties of low styrene emission vinylester laminates reinforced by natural fibres

The aim of this experimental investigation is to perform a thorough analysis in terms of mechanical properties of thermoset composites built with an eco-friendly resin and reinforced by natural fibres. Flax and basalt were the reinforcements selected, being applied both in single and hybrid layouts with a low-styrene emission (LSE) vinylester matrix, and glass synthetic fibre composites were also studied for comparison purposes. Tensile, flexural and low-velocity impact tests were carried out according to their respective ASTM standards, showing that basalt and flax laminates are respectively the strongest and the weakest materials analysed, where the hybrid composition offers similar tensile and flexural moduli to glass, being 30% stronger in tension and 10% in bending. Impact tests performed at a same shock energy of 30.6 J perforated glass fiber specimens, while small indentations were noticed in naturally reinforced coupons characterized by fiber tensile breakage and matrix compressive failure regions.

End-Cap Modified Unsaturated Polyesters With Low Styrene Emission

A benzyl end-cap-unsaturated polyester resin (BP-UPR) with low styrene emission was synthesized. The structure of BP-UPR was characterized by Fourier transform infrared (FT-IR) spectroscopy. According to gel permeation chromatography (GPC) measurement, the BP-UPR has a relative low molecular weight (Mn=1754) and narrow polydispersity of 1.68. The styrene content of BP-UPR is only 25.1%, 8.3% lower than that of a commercial unsaturated polyester resin (C-UPR) with similar viscosity. The styrene emission of BP-UPR and C-UPR was compared by Luong–Walewski method. At the gel point (17 minutes), the styrene emission of BP-UPR is only 38.9g/m2, 15.9% lower than that of C-UPR. After curing for 2 hours, the total styrene emission of BP-UPR is only 62.5 g/m2, which is 48.0% lower than that of C-UPR.