SBS-modified asphalt produces a large number of hazardous fumes in the preparation process, which severely endangers health and causes environmental pollution. This paper details the design of a fume generation and collection device for asphalt and proposed a comprehensive method for analyzing fume composition. Two deodorants were incorporated into SBS-modified asphalt to mitigate the hazards of the original hazardous emissions. Then, ultraviolet–visible spectrophotometry, gas chromatography–mass spectrometry, and Fourier-transform infrared spectroscopy were combined to analyze the main component differences between asphalt fumes before and after adding deodorant, and to specify the mechanism of action of deodorants on hazardous fumes and SBS-modified asphalt. Finally, the road performance, including the physical and rheological properties of SBS-modified asphalt blended with deodorant, was evaluated. The results indicated that both deodorizers were effective in reducing the emission of hazardous substances in the fumes of SBS-modified asphalt, and no new hazardous substances were generated. Under hot mixing conditions, the addition of 0.3% of deodorant A (high boiling point ester) was effective in reducing the emission of volatile organic compounds (VOCs) by up to 41.7%, while the reduction in benzene congeners reached at least 50%. On the other hand, 1% of deodorant B (silica–magnesium compounds) reduced the emissions of VOCs and benzene congeners by 36% and 20–42%, respectively, under the same conditions. Furthermore, the addition of deodorant did not affect the original road performance, and even improved the rheological properties to a certain extent, which was conducive to the application of deodorant in pavement engineering.
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